共查询到18条相似文献,搜索用时 61 毫秒
1.
半经典闭合轨道在外场和激光参数的某些值附近发生分岔,导致波函数的发散,使原有的半经典闭合轨道理论失效-计算了高激发的Li原子在标度能量为ε=-2-94,标度电场在135 -86-1/4<160-11范围内光吸收谱的Fourier变换,分析了轨道分岔现 象及其影 响,并采用了一种适用于不同能域的统一近似方法修正了分岔点附近波函数-计算中考虑了 原子实多重散射组合回归效应,并把所得回归谱与用标准半经典闭合轨道理论对Li原子及H 原子的计算结果相比较,证明了轨道分岔效应的重要性-
关键词:
分岔
统一近似
半经典闭合轨道理论
回归谱 相似文献
2.
考虑完全相同的两束激光脉冲与原子相互作用的过程,研究氢里德堡波包在磁场中随时间的演化。结果显示了波包的运动与闭合轨道密切相关。讨论了双脉冲的相位参数以及脉冲宽度对谱的影响。 相似文献
3.
考虑完全相同的两束激光脉冲与原子相互作用的过程,研究氢里德堡波包在磁场中随时间的演化.结果显示了波包的运动与闭合轨道密切相关.讨论了双脉冲的相位参数以及脉冲宽度对谱的影响. 相似文献
4.
利用分子轨道理论,结合一个新的模型势,我们给出了里德堡NO分子中激发态电子所受到的作用势的解析表达式.利用分子的闭合轨道理论和分区自洽的迭代方法,首次从理论上计算了NO分子在强磁场中的回归谱.通过和A.Matzkin等人给出的NO分子在强磁场中的实验谱的比较,表明我们的计算是正确的. 相似文献
5.
半经典闭合轨道理论已经成功地计算了在外加磁场和平行电磁场中的里德堡原子的回归谱.但对于垂直电磁场中的里德堡原子,理论和计算都变得更为复杂.本文把闭合轨道理论推广到三维情况,采用 B.Hüpper的模型势计算了ε=-0.03,主量子数n≈ 40,m=0下He原子在垂直电磁场中的光吸收谱和回归谱,并和H原子在垂直电磁场中的回归谱作比较,突出了实散射的贡献.计算中应用了离子实散射的分区自洽迭代方法,并考虑到轨道的多次重复和离子实的多次散射效应.这是对闭合轨道理论的验证和进一步推广. 相似文献
6.
利用散射矩阵理论,结合扩展的半经典闭合轨道理论和多通道量子亏损理论,计算了磁场中高里德堡H2分子的回归谱.该方法使用了两个空间散射矩阵来描述里德堡电子的动力学性质,计算中可以包括所有阶的实散射的作用.回归谱的每一个尖峰对应着一条闭合轨道,新的额外峰是由于弹性散射和非弹性散射所引起的通道内和通道间的轨道组合,进一步证明了体系通道间和通道内的散射具有同等的重要性. 相似文献
7.
利用散射矩阵理论,结合扩展的半经典闭合轨道理论和多通道量子亏损理论,计算了磁场中高里德堡H2分子的回归谱.该方法使用了两个空间散射矩阵来描述里德堡电子的动力学性质,计算中可以包括所有阶的实散射的作用.回归谱的每一个尖峰对应着一条闭合轨道,新的额外峰是由于弹性散射和非弹性散射所引起的通道内和通道间的轨道组合,进一步证明了体系通道间和通道内的散射具有同等的重要性. 相似文献
8.
利用散射矩阵理论,结合扩展的半经典闭合轨道理论和多通道量子亏损理论,计算了磁场中高里德堡H2分子的回归谱.该方法使用了两个空间散射矩阵来描述里德堡电子的动力学性质,计算中可以包括所有阶的实散射的作用.回归谱的每一个尖峰对应着一条闭合轨道,新的额外峰是由于弹性散射和非弹性散射所引起的通道内和通道间的轨道组合,进一步证明了体系通道间和通道内的散射具有同等的重要性. 相似文献
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Based upon our previous work [Commun. Theor. Phys.. 40,702 (2003)], we developed the closed orbit theory from two degrees of freedom to three non-separable degrees of freedom and calculated the recurrence spectra of Li Rydberg atom in strong perpendicular electric and magnetic fields. The Fourier transformed spectra of Li atom has allowed direct comparison between the resonance peaks and the scaled action values of closed orbits, whereas the nonhydrogenic resonance can be explained in terms of the new orbits created by the core scattering. The semiclassical result is in good agreement with the quantum one, which suggests that our calculation is correct. 相似文献
12.
Closed-orbit theory is a semiclassical technique for explaining the spectra of Rydberg atoms in external fields. Using the closed-orbit theory and classical perturbation theory, we calculate the scaled recurrence spectra of Lithium atom in magnetic field plus a weak perpendicular electric field. The results show when the crossed electric field is added, the recurrence spectra are weakened greatly. As the scaled electric field f increases, the peaks of the recurrence spectra lose strength. Some recurrences are very sensitive and fall off rapidly as f increases; others persist till much higher f . As the electric field is stronger, some of the peaks revive. This phenomenon, caused by the interference among the electron waves that return to the nucleus, can be computed from the azimuthal dependence of the classical closed orbits. 相似文献
13.
WANGDe-Hua DINGShi-Liang 《理论物理通讯》2003,40(6):702-706
Closed-orbit theory is a semiclassical technique for explaining the spectra of Rydberg atoms in external fields. Using the dosed-orblt theory and classical perturbation theory, we calculate the scaled recurrence spectra of Lithium atom in magnetic field plus a weak perpendicular electric field. The results show when the crossed electric field is added, the recurrence spectra are weakened greatly. As the scaled electric field f increases, the peaks of the recurrence spectra lose strength. Some recurrences are very sensitive and fall off rapidly as f increases, others persist till much higher f. As the electric field is stronger, some of the peaks revive. This phenomenon, caused by the interference among the electron waves that return to the nucleus, can be computed from the azimuthal dependence of the classical closed orbits. 相似文献
14.
Correspondence between classical dynamics and recurrence spectra of Rydberg hydrogen atom near a metal surface 下载免费PDF全文
The chaotic behaviours of the Rydberg hydrogen atom near a metal surface are presented. A numerical comparison of Poincare surfaces of section with recurrence spectra for a few selected scaled energies indicates the correspondence between classical motion and quantum properties of an excited electron. Both results demonstrate that the scaled energy dominates sensitively the dynamical properties of system. There exists a critical scaled energy εc, for ε 〈 εc, the system is near-integrable, and as the decrease of ε the spectrum is gradually rendered regular and finally turns into a pure Coulomb field situation. On the contrary, if ε 〉 εc, with the increase of ε, the system tends to be non-integrable, the ergodic motion in phase space presages that chaotic motion appears, and more and more electrons are adsorbed on the metal surface, thus the spectrum becomes gradually simple. 相似文献
15.
The closed-orbit and the photoabsorption spectra of lithium atom in varying'magnetic fields 下载免费PDF全文
Using a simple analytic formula from closed orbit theory, we have calculated the photoabsorption spectra of Li atom in different magnetic fields. Closed orbits in the corresponding classical system have also been obtained for B=5.96T.We demonstrate schematically that the closed orbits disappear gradually with the decrease of the magnitude of the magnetic field. This gives us a good method to control the closed orbits in the corresponding system by changing the magnetic field, and thus changing the peaks in the photoabaorption spectra. By comparing the photoabsorption spectra of Li atom with those of hydrogen case, we find the core-scattered effects play an important role in multi-electron Rydberg atoms. 相似文献
16.
Recurrence spectra of non—hydrogen Rydberg atoms in paralled electric and magnetic fields 总被引:2,自引:0,他引:2 下载免费PDF全文
We present a new method for computing the recurrence spectra of n≈40, m=0 lithium Rydberg atoms in strong parallel external electric and magnetic fields. This method is based on an extended closed-orbit theory allowing the computation of the scattering of the electron by the ionic core. We pay particular attention to the scaling properties, which are extremely important for understanding the correspondence between classical and quantum mechanics. The spectra with a constant scaled electric field \tilde F=0.01 and a scaled energy ε=-0.03 are recorded and compared with those of hydrogen obtained by the standard closed-orbit theory. The result shows that the additional strong resonance structures can be interpreted in terms of the core-scattered classical closed orbits. 相似文献
17.
Using core-scattered closed-orbit
theory and region-splitting iterative
method, we calculated the scaled recurrence spectra of helium atom in
parallel electric and magnetic fields. Closed orbits in the corresponding
classical system have also been obtained. When we search the closed orbits, in order to remove the Coulomb singularity of the classical Hamiltonian
motion equations, we implement the Kustaanheimo-Stiefel transformation,
which transforms the system from a three-dimensional to a four-dimensional
one. The Fourier transformed spectrum of helium atom has allowed direct
comparison between peaks in such plot and the scaled action values of closed
orbits. The results are compared with those of the hydrogen case, which shows
that the core-scattered effects play an important role in the recurrence
spectra of the multi-electron Rydberg atom. 相似文献
18.
选择激光偏振方向,同步改变激发激光的波长(即原子的激发能量E)和外加电场强度 F,使标度能ε=E/F保持为常数,得到了原子束中Ba Rydberg原子在标度 能ε=-300时M=0激发的常数标度能谱.由实验标度能谱的Fourier变换得到的回 归谱与氢的均匀化近似后的闭合轨道理论计算相比较,发现实验回归谱的峰值位置与理论计 算符合较好,而峰值强度则与理论相差较大,分析认为是由于受到核散射和双电子微扰态的 影响所致.
关键词:
标度能谱
闭合轨道理论 相似文献