Anisotropic magnetic fluctuations in the ferromagnetic superconductor UCoGe studied by direction-dependent 59Co NMR measurements

We have carried out direction-dependent 59Co NMR experiments on a single crystal sample of the ferromagnetic superconductor UCoGe in order to study the magnetic properties in the normal state. The Knight-shift and nuclear spin-lattice relaxation rate measurements provide microscopic evidence that both static and dynamic susceptibilities are ferromagnetic with strong Ising anisotropy. We discuss that superconductivity induced by these magnetic fluctuations prefers spin-triplet pairing state.     

Microstructural aspects of the hcp-fcc allotropic phase transformation induced in cobalt by ball milling

A detailed correlation between microstructure evolution and allotropic phase transformations occurring in Co when subjected to ball milling has been carried out. After short-term milling, the starting mixture of hcp + fcc Co develops into an almost pure hcp phase. However, for longer milling times, plastic deformation introduces large amounts of stacking faults, especially of twin type, in the hcp structure. As a consequence, some of the hcp Co is converted back into fcc and the hcp unit cell is progressively anisotropically distorted. After long-term milling, a steady 'pseudo-equilibrium' state is observed, where all microstructural parameters, including the fcc percentage, tend to level off. However, the milling intensity can still be adjusted to increase further the stacking-fault probability and, consequently, the amount of fcc Co in the milled powders. The results imply that the stacking-fault formation, rather than the local temperature rise or crystallite size reduction associated with the milling process, is the main mechanism governing the hcp-fcc transformation.     

59Co, 23Na NMR and electric field gradient calculations in the layered cobalt oxides NaCoO2 and HCoO2

⁵⁹Co and ²³Na NMR has been applied to the layered cobalt oxides NaCoO₂ and HCoO₂ at three different magnetic field strengths (4.7, 7.1 and 11.7 T). The ⁵⁹Co and ²³Na quadrupole and anisotropic shift tensors have been determined by iterative fitting of the NMR line shapes at the three magnetic field strengths. Due to the large ⁵⁹Co quadrupole interaction in NaCoO₂, a frequency-swept irradiation procedure was used to alleviate the limited bandwidth of the excitation. While the ⁵⁹Co and ²³Na shift and quadrupole coupling tensors in NaCoO₂ are found to be coincident and axially symmetric in agreement with the crystal symmetry requirements, the fits of the ⁵⁹Co NMR spectra clearly show the presence of structural disorder in HCoO₂. The ²³Na chemical shift anisotropy can be reproduced by shift tensor calculations using a point dipole model and considering that the magnetic susceptibility in NaCoO₂ is due to Van Vleck paramagnetism for Co³⁺. Electric field gradient calculations using either the empirical point charge model or the ab initio full potential-linearized augmented plane wave method are compared with the experimental NMR data.     

Instanton paths for the problem of coherent quantum tunneling in small ferromagnetic particles

It is shown that the problem of instantons in ferromagnetic materials in a large-spin model is reduced to an exactly integrable dynamical system with a finite number of variables. For a rather wide class of models, there exists a continuum of instanton paths that form a one-parameter family of paths with essentially different shapes but with the same value of the Euclidean action. On the basis of the formalism developed, exact instanton solutions are constructed that describe macroscopic quantum tunneling for a small ferromagnetic particle with uniaxial or biaxial quadratic anisotropy in the presence of a magnetic field applied perpendicularly to the easy axis. These solutions are valid for any relations between the anisotropy parameters and for any magnitude of the magnetic field and its direction in the base plane. Based on the solutions obtained, the principles of macroscopic quantum tunneling in high-spin-molecule-type magnetic particles are described. Tunneling regimes of two types are obtained: (1) regimes that are characterized by destructive interference of instanton trajectories and oscillatory dependence of the transition probability on the magnitude of the magnetic field and (2) regimes in which all instantons have the same purely real value of the Euclidean action and there is no destructive interference.     

Multidimensional NMR experiments to observe the nature of non-exponential relaxation in glasses

Multidimensional echo NMR experiments on polymers are reported that yield insight into the nature of the non-exponential relaxation above the glass transition. By comparing a two-time correlation function to a four-time correlation function, the timescale of fluctuations within the heterogeneous contribution of the rate distribution is analyzed for poly(methyl methacrylate). In agreement with recent measurements on various glass-forming materials fluctuations are observed on the same time scale as the relaxation rates themselves. Furthermore a method is presented which allows one to determine whether the relaxation is mainly heterogeneous or homogeneous by comparing a two-time and three-time correlation function. It turns out for poly(styrene) that the reorientational dynamics is mainly heterogeneous.     

129Xe NMR study of the homogeneity and the size distribution of small sodium metal particles in NaY zeolite

NaY zeolite samples loaded with sodium metal by vapor phase deposition have been investigated using¹²⁹Xe NMR spectroscopy. At low sodium concentration, the¹²⁹Xe NMR spectrum showed three resonance lines which clearly indicate the existence of distinct domains in the zeolite sample. Such an observation suggests that the diffusion of the xenon atoms into each domain only occurs with respect to the NMR time scale (2.9 ms). As the sodium concentration increases, observation of a single broad line indicate a macroscopic homogenization of the system. The shift of this line is explained in part due to a paramagnetic interaction between the xenon atoms and the unpaired electrons of particles containing an odd number of sodium atoms. The linewidth is due to the distribution of the local magnetic fields partially averaged by the rapid motion of the xenon atoms and to the statistical distribution of the sodium particles in the supercage cavities. The paramagnetic interaction vanishes with the oxidation of the sample leading to a narrowing and a shift of the line to higher magnetic fields.     

NMR studies of the magnetic state of interfacial cobalt in (Co/Ge) n films

The results of NMR studies of film structures in a cobalt-germanium system as a function of the cobalt layer thickness are presented. Two phases of cobalt, one is a face-centered cubic phase and the other is presumably a Co-Ge alloy with a weakly ferromagnetic order, have been found to exist. A “dead” layer no more than 2 nm in thickness is formed at the interface.     

Effect of Co on magnetic property and phase stability of Ni--Mn--Ga ferromagnetic shape memory alloys: A first-principles study

The effect of Co content on magnetic property and phase stability of Ni50-xMn25Ga25Cox ferromagnetic shape memory alloys has been investigated using first-principles calculations. The total energy difference between paramagnetic and ferromagnetic state of austenite plays an important role in the magnetic transition. The high Curie temperature can be attributed to the stronger Co-Mn exchange interaction as compared to the Ni-Mn one. The phase stability of Ni50-xMn25Ga25Cox austenite increases with increasing Co content, which is discussed based on the electronic structure.     

A contribution to the study of ferromagnetic resonance in manganese zinc ferrites

A study is made of the temperature dependence of ferromagnetic resonance in the 9300 Mc band on three samples of manganese zinc ferrite. The results are discussed from the point of view of the Tsuya model for the production of an additional internal field during ferromagnetic resonance.     

On the stability of bcc Co in Co/Fe superlattices an NMR and XRD study

While RHEED observations show that 10 to 11 As is the stability limit for an open bcc Co layer when grown on an Fe substrate, our XRD and NMR studies have shown that, in MBE grown Co/Fe superlattices, cobalt can be stabilised in a bcc structure up to a critical Co thickness of 21 Ås. In order to understand this apparent discrepancy, NMR experiments have been carried out in Co_x/Fe_y multilayers with thickness varying in the range 5 Å < x < 42 Å and 24 Å < y < 60 Å, grown on GaAs (1 1 0) as well as on MgO (1 0 0) substrates. The analysis of the chemical short range order by NMR concludes that the larger bcc Co thickness observed in superlattices results from the formation of a rather homogeneous CoFe_20% bcc alloy which contains the supplementary 10–11 As of Co and which coexists with pure Co grains. The concentration of about 20% Fe in the alloyed part of the Co layer happens to be close to the stability limit for a bcc structure in the equilibrium phase diagram of bulk CoFe alloys. However, while a mixture of bcc and fcc phases is observed in bulk alloys, the bcc structure is preserved in all phases under the MBE growth conditions and below the critical thickness. Above the critical thickness amixture of bcc Co, bcc CoFe and hcp Co is observed.     

The influence of ball milling on the structure and electroluminescence of zinc sulphide powder

The paper describes the influence of ball milling on the structure and electroluminescent emittance of zinc sulphide powder activated with manganese and copper. It is shown that in the initial stage of ball milling there is a sudden decrease in the EL emittance and later the EL emittance fluctuates. The maximum in fluctuation, however, does not exceed 25% of the initial emittance. The ball milling mechanism of powder and the quenching of its EL emittance was proposed on the basis of measurements obtained by X-ray, spectral and integrated EL emittance as a function of the milling time. From Goldberg's relation for EL emittance a new relation was obtained for the emittance as a function of the structural parameters such as the magnitude of the powder grain, its so-called critical value, and the density of imperfections produced during milling.The author thanks J. Waková from the Research Institute of Inorganic Chemistry in Ústí nad Labem for making it possible to perform the diffractometric measurements in their laboratory, J. Pasterák from the Institute of Physics, Czechoslovak Academy of Sciences, who made it possible to measure the EL spectral emittance, Prof. A. Kochanovská for advice in evaluating the X-ray results, M. Trlifaj, K. Pátek and J. Kubátová for advice in interpreting the EL spectral emittance and A. Kleprlík for help in elaborating the results.     

A model of the properties of colloidal dispersions of weakly interacting fine ferromagnetic particles

A Monte Carlo technique has been used to simulate the magnetic properties of a colloidal dispersion of weakly interacting fine ferromagnetic particles. The initial susceptibility is shown to obey a Curie-Weiss like law in its variation with temperature. The ordering temperature in the Curie-Weiss law is found to increase with the diameter of the particles, the increase being associated with an increase in the local order in the system. Data from the Monte Carlo simulation is also used to assess the effects of interactions on the determination of particle size parameters from magnetic measurements. Investigation of the spatial correlation within the system reveals evidence of field induced particle agglomeration.     

The application of some beam-foil measurements for Co I and Co II to the cobalt photospheric abundance

The mean lives of a number of energy levels in Co I and Co II have been measured. Particular attention has been paid to the energy loss incurred by the ions in the foil, which was found to be somewhat larger than the loss forecast by Lindhard's theory.A-values derived for Co I (using relativegA-values from the literature) are found to be significantly lower than those reported previously by other authors. Fair agreement is obtained for Co II with theA-values forecast by Warner. The Co IA-values indicate that the cobalt solar abundance given by Goldberget al. (LogN _Co=4.64) should be increased to about 4.9.     

Influence of high-energy ball milling on the solid-phase sintering kinetics of ultrafine-grained heavy tungsten alloy

The mechanisms for the sintering of ultrafine-grained 95%W–3.5%Ni–1.5%Fe heavy tungsten alloy powders have been investigated. It has been established that a decrease in the activation energy of grain boundary diffusion and the formation of a nonequilibrium solid solution of nickel and iron in the surface layer of tungsten particles upon high-energy ball milling are responsible for the decrease in optimal sintering temperature.     

Study on the photocatalytic activity of TiN/TiO2 nanoparticle formed by ball milling

TiN/TiO₂ nanoparticle photocatalyst was prepared by ball milling of TiO₂ in H₂O solution doped with TiN. The photocatalyst was characterized by UV–Vis diffuse reflection spectroscopy, X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Based on the results of the characterization, the mechanism of the increase in photocatalytic activity was investigated. The results show that when the amount of doped TiN is 0.15 wt%, the photocatalytic activity of the TiN/TiO₂ is at its peak. Compared with TiO₂, the photoabsorption wavelength range of the TiN/TiO₂ photocatalyst red-shifts about 30 nm, and the photoabsorption intensity increases as well. The photocatalytic activities of the photocatalyst are higher than that of TiO₂ under UV and visible light irradiation. The increase of surface Ti³⁺ reactive center and the extension of the photoabsorption wavelength are the main factors for the increase in the photocatalytic activity of the TiN/TiO₂. Doped TiN neither changes the TiO₂ crystal phase nor creates new crystal phase by ball milling.     

Quantum size effects in the elastic scattering of light from small metal particles

A quantum mechanical calculation of the differential elastic scattering cross-section of light from a metal microparticle is presented. The scattering intensity is found to exhibit oscillations as a function of the frequency due to the discreteness of the electron energy levels. The magnitudes of the oscillations have a sensitive dependence on the size of the electron mean free path relative to the diameter of the particle.