P-branch operation of CD3F and CH3F Raman FIR lasers

Multi-kolowatt pulses with limited wavelength tunability have been produced in several bands between 186 and 817 m by pumping v3 P-branch transitions in¹²CH₃F and¹²CD₃F with the 10.6 m band of a ten-atmosphere CO₂ laser. The FIR emissions are all restricted to the immediate neighborhood of the resonances associated with successive J-numbers, but there is some evidence that additional off-resonant emission could be produced with stronger pumping. The optimum operating pressure for the various molecule/J-number combinations range from 7 to 75 torr and increase rapidly with increasing J-number.     

Compact Raman CH3F, NH3 optically pumped FIR laser

Conclusion The compact superradiant FIR laser is developed using Herriott cell with long optical path as a FIR cell. The employment of the multipass cell gave an opportunity to increase the IR to FIR conversion efficiency in comparison with traditionally constructed FIR lasers and to observe many intensive FIR lines. The given of multipass cell can be useful for employment in continuously tunable FIR lasers.     

Cavity operation of a pulsed C13H3F laser

Cavity operation of an optically pumped, pulsed, C¹³H₃F far-infrared laser is described. The use of a Fabry-Perot output coupler has resulted in selectable line emission at 1222, 1207, 1006, 388 and 412 m with power levels in the 1–20 kW range. In addition, single mode operation on the longer wavelength lines has been achieved. Experimental evidence is also presented for a collisionally coupled two-photon absorption process which is responsible for the observed short wavelength emission.     

A high power CH3OH FIR laser system with long-term stability

A CH₃OH FIR system has been developed for plasma diagnostics. A CO₂ laser devoted to pump the CH₃OH molecule has been studied. Different internal diameters of FIR cavity, input coupling holes and focusing lenses have been experimented.It has been found that the system formed by three subsystems-pump laser, guiding channel and FIR cavity-behaves like an unique system. A long term stability has been reached with a proper system design.Work supported by ENEA contract No. C/451 (Dipart. Fusione, Associazione Euratom-Enea, CRE Frascati, C.P. 65, 00044 Frascati, Italy).Student     

Pump polarization effect in a superradiant NH3 and CH3F FIR Raman laser

The pump polarization has an evident effect on a superradiant FIR Raman laser both in NH₃ and CH₃F gases when the pump detuning from the resonant line is larger than the Raby frequency. In particular for R resonant lines the circular polarization shows a spontaneous gain about 1.5 times greater than the linear polarization as expected from the theory.     

FIR Stark spectroscopy on optically pumped CH3OH laser

An extensive theoretical and experimental analysis of the absorption and emission spectrum of a CH₃OH FIR-laser excited by a conventional CO₂ laser is presented. Particular interest is devoted to the Stark shifts of the pump and lasing lines and to the electric field dependence of the Fir-laser output of the various lines. The offsets with respect to the exciting radiation and the Stark shifts of the IR absorption (pump) lines are measured by means of the transferred Lamb dip technique. The theoretical behaviours of the Stark patterns are calculated for several choices of the quantum numbers and selection rules involved in the transitions. A large variety of experimental results are reported and compared to theory. Non-linear Stark shifts have been observed for the 37.5m FIR laser line and for the IR-pump transitions excited by the 9-P(38) and 10-R(38) CO₂ laser Lines. Line assignments are proposed and new FIR laser lines are reported.     

Theoretical study of multi-mode optically pumped NH3 FIR laser

The two or multi-mode optically pumped NH₃ FIR laser had been studied theoretically. The NH₃ molecular gas was assumed to be a three-level system and obeyed the time-dependent behavior of the density matrix equations. Considering the situation of playing the two or multi-mode optical pumping and the FIR laser field were same polarized. The gain coefficient and the output FIR power of the system could be calculated by using the iteration method.It had been predicted that the two or multiple longitudinal mode optically pumped NH₃ FIR laser could have a greater output power or higher lasing efficiency than single mode pumped FIR laser under suitable selected operating parameters of laser.Supported by The Education Foundation of PRC.     

10 kW cavity operation of a submillimetre CH3F laser

Operation of a CH₃F laser at 496μ has been obtained in a hemispherical optical cavity pumped by up to 42 J of 9.55μ CO₂ TEA laser radiation. Highly modulated 1μ pulses delivering 6 mJ at peak powers greater than 10 kW have been recorded.     

Emission spectra of the tunable Raman CH3F optically pumped fir laser

The six-level model using a density matrix approach to simulate properties of a gas resorant media in optically pumped FIR lasers was developed. The model accounts for multiphoton as well as parametric processes. Advantages of the developed model are demonstrated by calculation and discussion of the gain and saturated emission spectra of CH₃F laser when transitions with different J rotational numbers of CH₃F are pumped.     

Optoacoustic Laser Stark spectroscopy and FIR laser action on CH3Br using a waveguide CO2 laser

The optoacoustic spectrum of CH₃Br around 10 m band lines of a tunable cw waveguide CO₂ laser is investigated. Several new infrared absorptions are observed and most of the correspond ing molecular transitions are assigned. Far infra red laser action is reported by pumping with the same CO₂ laser: pump offsets are given using the Transferred Lambs dip (TLD) technique. A new FIR laser emission is obtained and assigned. An optoacoustic Laser Stark spectroscopy technique is used to investigate off resonance infrared tran sitions.     

Frequencies of cw FIR laser lines from optically pumped CH2F2

The frequencies of 48 optically pumped cw FIR CH₂F₂ laser lines have been measured relative to stabilized CO₂ lasers. Uncertainties are estimated to be about 5 parts in 10⁷.     

R branch tuning characteristics of the13CH3F Raman FIR laser

Summary We described a¹³CH₃F Raman laser pumped by a grating tuned 20 atmospheres CO₂ laser. The emission characteristics of the¹³CH₃F laser extends from 14 cm^–1–35 cm^–1 and from 49 cm^–1–72 cm^–1; about 65% of these frequency ranges can be covered with tunable radiation. The characteristics shows a strong dependence on the rotaional quantum numbers of the states involved in the Raman laser transitions and, within each tuning interval, on the frequency offset with respect to the frequencies of resonant transitions. We obtained, at 51 cm^–1, a maximum FIR laser pulse energy of about 800 J (at a pump energy of 200 mJ), corresponding to a photon conversion of about 8%. In some cases we have observed simultaneous emission at a Raman and a cascade frequency. In addition, FIR emission power dependence on¹³CH₃F gas pressure and pump pulse power were investigated for different J quantum numbers.     

Frequency measurement of the 496 μm line of a CH3F FIR laser

A direct frequency measurement of the 496 μm, K = 2 line from a CH₃F laser is reported. Our laser is a metallic wave-guide device pumped by a frequency stabilized CO₂ laser; its output is mixed in a CaAs-Au Schottky barrier diode with a 100 GHz klystron and the beat note is observed on a spectrum analyzer. The result is f_CH3F(496 μm, K = 2) = 604 297.5 ± 0.2 MHz.     

Assignments of optically pumped CH3OD laser lines

Fifteen laser lines from CH₃OD pumped by a CO₂ laser are assigned to specific rotational energy transitions. These assignments have been obtained from the approximation that, except for one constant, the molecular constants in the excited CO stretching state are same as those in the ground state.     

Tuning characteristics of a high pressure CO2 laser pumped CH3F Raman laser

Conclusion We described a CH₃F Raman laser pumped by a two stage 20 atmospheres CO₂ laser. The emission spectrum of the CH₃F laser at 11 Torr extends from 23 cm^–1 to 45 cm^–1 when the CO₂ laser is scanned over the 9R emission branch at a fixed pump power of 180 mJ. The emission spectrum shows a strong structure with large parts where the FIR energy decreases to zero. This fact makes the use of such a laser for spectroscopic scanning experiments in the FIR difficult. The laser is, however, very suited for working at fixed but adjustable FIR frequencies. The pulse energy in the maxima of the emission characteristics at a pump energy of 180 mJ exceeds 300 J, which corresponds a photon conversion coefficient of more than 6%.     

Assignments of laser lines in optically pumped CH3CN

A careful analysis of the rotovibrational spectroscopic data of CH₃CN is presented taking into account Fermi and Coriolis interactions. A large majority of the FIR lines obtained by optical pumping is assigned. New values are proposed for some molecular constants and the need of more accurate experimental investigation is pointed out.     

远红外可调谐喇曼激光器理论

本文用缀饰原子方法解出四能级系统远红外激光增益系数的解析表达式。结果表明,远红外增益谱一般由四个共振峰组成,取合适的失谐量,可能得到两个正的增益极大,并分别对应于喇曼增益和线中心增益。     

Optically pumped CW CF3BR FIR laser. New emission lines and tentative assignments

Eight new CW FIR lines from the CF₃Br molecules pumped by a¹²C¹⁶O₂ laser are reported. Tentative assignments have allowed to assign eight among the ten lines reported.     

Compact, high power FIR NH3 laser pumped in a three mirror CO2 laser cavity

A compact CO₂–NH₃ FIR laser system where an NH₃ laser cavity was inserted in pump, three mirror CO₂ laser cavity was designed. The total length of this system was about 1.8 m. Output energy of about 1 mJ (10 KW pea power) was obtained at the 152 m and 90 m lines in NH₃. Power conversion efficiency of 1.7 percent was obtained at the 90 m line.     

New FIR laser lines and frequency measurements for optically pumped CD3OH

Twenty new cw FIR laser lines in CD₃OH, optically pumped by a CO₂ laser, are reported. The frequencies of 39 of the stronger laser lines were measured relative to stabilized CO₂ lasers with a fractional uncertainty, as determined by the reproducibility of the FIR frequency itself, of 2 parts in 10⁷.Contribution of the U.S. Government, not subject to copyright.