Physical properties of voltage gated pores

Experiments on single ionic channels have contributed to a large extent to our current view on the function of cell membrane. In these experiments the main observables are the physical quantities: ionic concentration, membrane electrostatic potential and ionic fluxes, all of them presenting large fluctuations. The classical theory of Goldman–Hodking–Katz assumes that an open channel can be well described by a physical pore where ions follow statistical physics. Nevertheless real molecular channels are active pores with open and close dynamical states. By skipping the molecular complexity of real channels, here we present the internal structure and calibration of two active pore models. These models present a minimum set of degrees of freedom, specifically ion positions and gate states, which follow Langevin equations constructed from a unique potential energy functional and by using standard rules of statistical physics. Numerical simulations of both models are implemented and the results show that they have dynamical properties very close to those observed in experiments of Na and K molecular channels. In particular a significant effect of the external ion concentration on gating dynamics is predicted, which is consistent with previous experimental observations. This approach can be extended to other channel types with more specific phenomenology.     

The OPCL control method for entrainment,model-resonance,and migration actions on multiple-attractor systems

A survey is given of three different control objectives that can be achieved with the use of the Open-Plus-Closed-Loop (OPCL) control method, developed by Jackson and Grosu. For a system that can be characterized by N first-order ordinary differential equations, these objectives are: (1) the asymptotic entrainment of the system's dynamics to a prescribed "goal" dynamics, g(t); (2) an experimental-search method to determine an approximate dynamic model; (3) the transferal of the system from one attractor to any "target" attractor. For one class of systems, this may be accomplished without a model, by using only a short-duration record of the natural dynamics in the target attractor, as demonstrated experimentally using the Chua system. (c) 1997 American Institute of Physics.     

Description of far-from-equilibrium processes by mean-field lattice gas models

Mean-field kinetic equations are a valuable tool to study the atomic dynamics and spin dynamics of simple lattice gas and Ising models. They can be derived from the microscopic master equation of the system and contain analytical expressions for kinetic coefficients and thermodynamic quantities which are usually introduced phenomenologically. We review several methods to obtain such equations, and discuss applications to the dynamics of order–disorder transitions, spinodal decomposition, and dendritic growth in the isothermal or chemical model. In the case of dendritic growth we show that the mean-field kinetic equations are equivalent to standard continuum equations for this problem and derive expressions for macroscopic quantities, e.g. the surface tension and kinetic coefficients, as functions of the microscopic order parameters. In spinodal decomposition, we focus our attention on the vacancy mechanism, which is a more faithful picture of diffusion in solids than the more widely examined exchange mechanism. We study the interfaces between an unstable mixture and a stable ‘vapour’ phase, and analyse surface modes that lead to specific surface patterns. For order–disorder transitions, studied in the framework of a repulsive two-sublattice model, we derive sets of coupled equations for the mean concentration (a conserved quantity) and for the occupational difference between the two sublattices emerging from the symmetry breaking due to ordering (non-conserved order parameter). These equations are applied to transport in the presence of ordered domains. Finally, we discuss the possibilities of improving the simple mean-field approximation by density functional theories and various forms of the dynamic pair approximation, including the path-probability method.     

基于区分矩阵约简的制冷系统故障诊断

针对区分矩阵的特点,给出了一种求决策表的属性约简和属性核的方法,以制冷系统的故障为对象,对制冷系统的故障诊断特征参数的属性进行约简,剔除其中不必要的属性,降低了故障分析的复杂性,并根据约简后的决策表得出了决策规则。     

Clusterisation and isospin effects in heavy-ion collisions at intermediate energies

We study the multifragmentation phenomenon in heavy-ion collisions by varying the spatial constraint criterion in minimum spanning tree (MST) clusterisation procedure. Within the framework of isospin-dependent quantum molecular dynamics (IQMD) model, the role of isospin-dependent spatial constraint, i.e. iso-MST version, is investigated on different fragment observables in various isobaric pair of reaction systems varying in the entrance channel isospin (N / Z) content. The fragment observables such as persistence, gain, average yield of free nucleons, light and intermediate mass fragments are slightly sensitive to the isospin-dependent spatial constraint criterion particularly in heavier reaction systems. For a given isobaric pair of reaction systems, the fragment production, however, remains indifferent to isospin content of the colliding nuclei.     

The time-local view of nonequilibrium statistical mechanics. II. Generalized Langevin equations

On a semiphenomenological level, generalized Langevin equations are usually obtained by adding a random force (RF) term to macroscopic deterministic equations assumed to be known. Here this procedure is made rigorous by conveniently redefining the RF, which is shown to be colored noise weakly correlated with the observables at earlier times due to the finite lifetime of microscopic events. Corresponding fluctuation-dissipation theorems are derived. Explicit expressions for the spectral density of the fluctuations are obtained in a particularly simple form, with the deviation of the line shape from the Lorentzian being related most explicitly to the spectral density of the RF. Well-known low-frequency expressions and the Einstein relation of (generalized) Brownian motion theory are modified so as to include lifetime effects. New sum rules are obtained relating dissipative quantities to contour integrals (in the complex frequency domain) over spectral densities or corresponding response functions. The Heisenberg dynamics of a complete set of macroobservables is shown to be equivalent to a generalized Orstein-Uhlenbeck stochastic process which is a non-Markovian process due to the lifetime effects.     

Kinetic models for socio-economic dynamics of speculative markets

In this paper we introduce a simple model for a financial market characterized by a single stock or good and an interplay between two different trader populations, chartists and fundamentalists, which determine the price dynamics of the stock. The model has been inspired by the microscopic Lux-Marchesi model (Lux and Marchesi (2000, 1999) [3] and [25]). The introduction of kinetic equations permits to study the asymptotic behavior of the investments and the price distributions and to characterize the regimes of lognormal behavior and the formation of power law tails.     

On the Stability of a Quantum Dynamics of a Bose-Einstein Condensate Trapped in a One-Dimensional Toroidal Geometry

We rigorously analyze the stability of the “quasi-classical” dynamics of a Bose-Einstein condensate with repulsive and attractive interactions, trapped in an effective 1D toroidal geometry. The “classical” dynamics, which corresponds to the Gross-Pitaevskii mean field theory, is stable in the case of repulsive interaction, and unstable (under some conditions) in the case of attractive interaction. The corresponding quantum dynamics for observables is described by using a closed system of linear partial differential equations. In both cases of stable and unstable quasi-classical dynamics the quantum effects represent a singular perturbation to the quasi-classical solutions, and are described by the terms in these equations which consist of a small quasi-classical parameter which multiplies high-order “spatial” derivatives. We demonstrate that as a result of the quantum singularity for observables a convergence of quantum solutions to the corresponding classical solutions exists only for limited times, and estimate the characteristic time-scales of the convergence.     

Vortex-pair dynamics in anisotropic bistable media: a kinematic approach

In isotropic bistable media, a vortex pair typically evolves into rotating spiral waves. In an anisotropic system, instead of spiral waves, the vortices can form wave fragments that propagate with a constant speed in a given direction determined by the system's anisotropy. The fragments may propagate invariably, shrink, or expand. We develop a kinematic approach for the study of vortex-pair dynamics in anisotropic bistable media and use it to capture the wave fragment dynamics.     

Distribution function and diffusion of electrons in the Rydberg energy space in a nonideal ultracold plasma

The distribution functions and diffusion coefficient of electrons in the Rydberg energy space in an ultracold plasma are obtained as functions of temperature by numerically solving a system of kinetic balance equations. As the initial conditions, the results obtained in previous papers by the molecular dynamics method are used. From calculation of Rydberg electron fluxes, the temperature dependence of the recombination coefficient is obtained, in good agreement with the recombination coefficient calculated previously by the molecular dynamics method.     

From the <Emphasis Type="Italic">N</Emphasis>-body problem to Euler equations

This paper contains a rigorous mathematical example of direct derivation of the system of Euler hydrodynamic equations from the Hamiltonian equations for an N point particle system as N → ∞. “Direct” means that the following standard tools are not used in the proof: stochastic dynamics, thermodynamics, Boltzmann kinetic equations, and the correlation functions approach due to Bogolyubov.     

完整力学系统的高阶运动微分方程

从质点系的牛顿动力学方程出发,引入系统的高阶速度能量,导出完整力学系统的高阶Lagrange方程、高阶Nielsen方程以及高阶Appell方程,并证明了完整系统三种形式的高阶运动微分方程是等价的.结果表明,完整系统高阶运动微分方程揭示了系统运动状态的改变与力的各阶变化率之间的联系,这是牛顿动力学方程以及传统分析力学方程不能直接反映的.因此,完整系统高阶运动微分方程是对牛顿动力学方程及传统Lagrange方程、Nielsen方程、Appell方程等二阶运动微分方程的进一步补充. 关键词： 高阶速度能量 高阶Lagrange方程 高阶 Nielsen方程 高阶Appell方程     

Kinetic equation for the processes of local reorganization of molecular systems with charged species

A molecular dynamic theory based on the lattice-gas model for the local reorganization of multi-component systems containing charged species is considered. Expressions for the mono- and bimolecular stages of the elementary processes that describe chemical reactions and displacements and rotations of molecules in dense gases and liquids are derived, with consideration given to direct and indirect effects of the initiation of electron and proton transfer. The proposed kinetic equations describe small-scale restructuring of solutions containing components of different sizes under the influence of changes in the external parameters of the molecular system at the kinetic stage of evolution of the system. The theory retains the effects of direct spatial correlations in the distribution of all the components of the mixture with the help of pair distribution functions in the quasi-chemical approximation. The dynamics of the local reorganization of molecules includes the kinetic equations for the local densities and pair distribution functions. The equations derived are intended to describe liquid-phase reactions, ion charge exchange, mutual diffusion of components of different sizes in multicomponent solutions, extraction processes at liquid phase boundaries, and photochemical processes in condensed phases.     

Projection operator techniques and Hilbert space averaging in the quantum theory of nonequilibrium systems

The development of efficient strategies for the treatment of the dynamics of relevant observables in complex quantum systems plays a decisive role in the theory of quantum relaxation and transport behavior. Here we discuss the most important tools that are based on the projection operator techniques of nonequilibrium statistical mechanics. For both the Nakajima-Zwanzig and the time-convolutionless projection operator technique we derive the equations of motion for a set of relevant observables and develop explicit expressions in second and fourth order of the corresponding perturbation expansions. We also discuss the Hilbert space average method which is based on the idea of a best guess of conditional quantum expectations determined by an average over a suitable region in the underlying Hilbert space, and relate this method to the projection operator technique.     

Stochastic Description of Traffic Flow

We propose a traffic model based on microscopic stochastic dynamics. We built a Markov chain equipped with an Arrhenius interaction law. The resulting stochastic process is comprised of both spin-flip and spin-exchange dynamics which models vehicles exiting, entering and interacting in a two-dimensional lattice environment corresponding to a multi-lane highway. The process is further equipped with a novel look-ahead type, anisotropic interaction potential which allows drivers/vehicles to ascertain local fluctuations and advance to new cells forward or sideways. The resulting vehicular traffic model is simulated via kinetic Monte Carlo and examined under both, typical and extreme traffic flow scenarios. The model is shown to correctly predict both qualitative as well as quantitative traffic observables for any highway geometry. Furthermore it also captures interesting multi-scale phenomena in traffic flows after a simulated accident which lead to oscillatory, dissipating, traffic waves with different periods per lane.     

A New Method and a New Scaling for Deriving Fermionic Mean-Field Dynamics

We introduce a new method for deriving the time-dependent Hartree or Hartree-Fock equations as an effective mean-field dynamics from the microscopic Schrödinger equation for fermionic many-particle systems in quantum mechanics. The method is an adaption of the method used in Pickl (Lett. Math. Phys. 97 (2) 151–164 2011) for bosonic systems to fermionic systems. It is based on a Gronwall type estimate for a suitable measure of distance between the microscopic solution and an antisymmetrized product state. We use this method to treat a new mean-field limit for fermions with long-range interactions in a large volume. Some of our results hold for singular attractive or repulsive interactions. We can also treat Coulomb interaction assuming either a mild singularity cutoff or certain regularity conditions on the solutions to the Hartree(-Fock) equations. In the considered limit, the kinetic and interaction energy are of the same order, while the average force is subleading. For some interactions, we prove that the Hartree(-Fock) dynamics is a more accurate approximation than a simpler dynamics that one would expect from the subleading force. With our method we also treat the mean-field limit coupled to a semiclassical limit, which was discussed in the literature before, and we recover some of the previous results. All results hold for initial data close (but not necessarily equal) to antisymmetrized product states and we always provide explicit rates of convergence.