Influence of surface modification of SrFe12O19 particles with oleic acid on magnetic microsphere preparation

Oleic acid was used as surface modification agent to improve the hydrophobicity of magnetic strontium hexaferrite particles. The structure and properties of treated magnetic particles were characterized by scanning electronic microscopy （SEM）, Fourier transform infrared spectra （FTIR）, powder X-ray diffraction （XRD） and magnetic property measurement system （MPMS）. The results show that oleic acid is chemically enwrapped on the surface of SrFe12O19 particles. Magnetic particles modified by oleic acid are highly dispersible and strongly responsive to magnetism but with slight decrease in saturated magnetization. The affinity between magnetic particles and monomers is improved by surface modification, resulting in increased particle incorporation in magnetic polymeric microspheres. The surface modification mechanism of magnetic particles by oleic acid is addressed in this work.     

Influence of surface modification of SrFe12O19 particles with oleic acid on magnetic microsphere preparation

Oleic acid was used as surface modification agent to improve the hydrophobicity of magnetic strontium hexaferrite particles. The structure and properties of treated magnetic particles were characterized by scanning electronic microscopy (SEM), Fourier transform infrared spectra (FTIR), powder X-ray diffraction (XRD) and magnetic property measurement system (MPMS). The results show that oleic acid is chemically enwrapped on the surface of SrFe12O19 particles. Magnetic particles modified by oleic acid are highly dispersible and strongly responsive to magnetism but with slight decrease in saturated magnetization. The affinity between magnetic particles and monomers is improved by surface modification, resulting in increased particle incorporation in magnetic polymeric microspheres. The surface modification mechanism of magnetic particles by oleic acid is addressed in this work.     

Preparation and ion exchange properties of egg-shell glass beads with different surface morphologies

A subcritical water treatment method was developed for preparing porous-surfaced glass beads with an egg-shell structure in a batch reactor. Based on the "corrosion-ion-migration-recondensation" strategy, ordinary soda-lime glass beads with a diameter of about 100 m were made first to react with subcritical water to effect controlled quantity of silicate dissolution of glass by adjusting treatment time and temperature. The dissolved silicate was then made to recondense on the glass core to form different porous shell morphologies: pores, flakes and fibers. Among these, glass beads coated with fibers with surface area of 154.5 m2/g, pore volume of 0.27 cm3/g and pore size of 7.1 nm were obtained at 573 K after 2 h of treatment. The prepared porous-surfaced glass beads were then used as adsorbent for heavy metal ions, showing various ion exchange properties. Glass beads covered with fibers displayed fast kinetics and high sorption capacity because of their egg-shell structure and high surface area. More than 90% of copper ions were adsorbed within 100 min from a solution with an initial concentration of 110 mg/L at 313 K. Ion sorption capacities were 149.33, 81.33 and 42.96 mg/g respectively for Ag+, Cu2+ and Ni2+ at 313 K. A green and low-cost method was thus developed to produce egg-shell-structured porous glass with high sorption capacity.     

Surface structuring of case hardened chain pins by cold-sprayed microparticles to modify friction and wear properties

This paper presents the results of the application of a cold spray technique for structuring metallic surfaces with microparticles. The resulting changes in surface properties were characterized to observe their influences on the tribological behavior of the structured surface. The spray technique was applied to a technical component, a 16MnCr5 steel chain pin, designed to be mounted in a linear reciprocating tribometer. TiO₂ microparticles were used to structure the surface with a homogeneous distribution of singly dispersed particles, rather than a homogeneous closed coating on the surface. Tribometer tests were performed to directly compare structured and unstructured chain pins, and a significantly reduced sliding friction coefficient was observed for the structured pin. The pins were characterized in detail by surface analysis prior to and after application of the tribological load to set the surface parameters and surface chemistry, even on the microscale. It was confirmed that the particle structuring induced changes in the surface properties, and the durability of the changes after tribological loading was evaluated.     

Electrical double layer and rheological properties of yttria-stabilized zirconia suspensions in solutions of high molecular weight polyacrylic acid polymers

This work deals with the effect of the adsorption of two high molecular weight polyacrylic acid polymers (Carbopol) on the interfacial properties, and the rheology of aqueous zirconia suspensions. Since the Carbopol-covered particles can be thought of as soft colloids, Ohshimas theory was used to gain information on the surface potential and the charge density of the polymer layer (Ohshima H (1995) Electrophoretic mobility of soft particles. Colloids Surf A Physicochem Eng Aspects 103:249–255). The effect of the pH of the solution on the double layer characteristics is related to the different conformations of the adsorbed molecules provoked by the dissociation of the acrylic groups present in polymer molecules. The electrokinetic properties of the suspensions are studied for different pH and Carbopol concentrations in solution in order to investigate the possible stabilization of the suspensions by electrostatic repulsion between the particles. The rheological behavior of the suspensions was investigated in steady-state and dynamic conditions, and the corresponding yield stress and storage modulus were obtained in absence and presence of polymer in solution. The competition between bridging flocculation provoked by polymer adsorption and electrosteric stabilization determines the rheological properties of the suspensions. In the pH range investigated, bridging flocculation predominates at the neutral pH because of the graft of the uncoiled polymer to more than one particle, while at the extreme pH values (pH 3, pH 9) steric or electrosteric stabilization seems to be the predominant mechanism that explains the rheological results. These facts were confirmed by estimating the zirconia particle (or aggregate) diameter in the liquid medium by means of light scattering measurements.     

Theory of creep deformation with kinematic hardening for materials with different properties in tension and compression

A constitutive model for creep deformation that describes the loading-history-dependent behavior of initially isotropic materials with different properties in tension and compression under stress vector rotations limited by 50–60° is presented within a thermodynamic framework. In the proposed constitutive model a kinematic hardening rule is adopted. This model also introduces an effective equivalent stress in the creep potential that is based on the first and second invariants of the effective stress tensor, and on the joint invariant of the effective stress tensor and eigenvector associated with the maximum principal Cauchy stress. The formulation of the kinematic hardening rule is presented and discussed. All the material parameters in the model have been obtained from a series of proposed basic experiments with constant stresses. These model parameters are then used to predict the creep deformation of the aluminum alloy under multiaxial loading with constant stresses, and under non-proportional uniaxial and non-proportional multiaxial loadings for both isothermal and nonisothermal processes.     

不同尺寸砂岩动态力学性质和应力平衡性的试验研究

采用大直径分离式霍普金森压杆系统获得的不同尺寸试样的实验冲击动态力学参数有差异,因此在直径100 mm压杆上进行了3种直径（50、75和100 mm）和5种长径比（0.4、0.5、0.6、0.8和1.0）的砂岩试样冲击试验,分析了不同尺寸试样应力-应变曲线和应变率曲线随尺寸的变化,提出了用于比较波形对齐重合度的波形叠加系数,并与应力平衡因子共同构建了动态应力平衡性研究体系,由此确定大直径霍普金森压杆试验的试样建议尺寸。同时,利用高速摄影机监测试样的动态破坏状况。结果表明:当长径比相同时,直径75与100 mm岩石试样的动态抗压强度测试值相近,直径50 mm试样具有更明显的长度效应;随着试样直径的增大,应变率曲线从单峰变为双峰;小尺寸试样更易发生轴向劈裂破坏,大尺寸试样受内部应力波叠加影响产生了较大的拉应力,易发生层裂拉伸和轴向劈裂的复合型破坏;对直径75 mm且长径比0.3~0.4的试样,波形对齐后重合度较高,在起始破坏前拥有充足的应力平衡时间,应变率加载效果较好。获得了砂岩试样冲击压缩试验的尺寸效应,可为大直径岩石试样的尺寸选择提供参考。     

Construction of constitutive equations of creep in orthotropic materials with different properties under tension and compression

Constitutive equations of steady creep are proposed for structural aluminum alloys that possess significant anisotropy at elevated temperatures in addition to different resistances to tension and compression.     

Dynamics of coaxial torsional resonators consisting or segments with different radii,material properties and surrounding media

High-Q torsional resonators constitute the most sensitive transducers for high frequency dynamic viscoelastic measurements of dilute polymer solutions. Most such resonators described in the literature are segmented. Because of the need for torque and torsional displacement transducers the Q-value of the individual segments most often differ, but normally all segments have the same radius.A detailed analysis of the dynamics of such resonators when both the radii, material properties and surrounding media may be different for each segment, is presented. For resonators where all segment lengths equal an integer multiple of a quarter of the torsional wavelength, we find that the Q-value of the resonator as a whole is mainly determined by the Q-value of the segment with the smallest radius. We further find that reduction of the radius of the segment surrounded by polymer solution results in a stronger mechanical coupling between the resonator as a whole and the polymer solution. These findings suggest that the segment radii are important optimization parameters of segmented torsional resonators used to measure the high frequency dynamic viscoelastic properties of e.g. polymer solutions.     

High-frequency dielectric properties of BSTO ceramic prepared with hydrothermal synthesized SrTiO3 and BaTiO3 powders

BSTO dielectric ceramic was prepared from SrTi03 and BaTi03 powders synthesized by hydrothermal method, as well as from Bao.sSro.4TiO3 powder synthesized by conventional solid-state reaction. The former can be sintered at a relatively low temperature of 1120 ℃. Characterization by SEM showed that the grain shapes of both ceramics are cubical, though the grain size of the former is much smaller. Dielectric constants measured at 20℃ were shown to vary with frequency in the range from I kHz to 2 MHz and dc bias field, and further that the dielectric loss of the former to be less than 2 × 10^- 3 in the frequency range of 20 kHz to 1 MHz, much smaller than that of the latter sample. For the former, temperature dependence of dielectric constant is much flatter and there exists an extended phase transition diffusion covering a wide temperature range of Curie temperature To. The smaller grain size of the former depresses the dc bias electrical field dependence of dielectric constant. The tunability is 7% under a bias field of 0.6 kV/mm dc.     

Rheological properties and self-assembled structures of a newly synthesized organogelator: cyclohexane carboxamido-2C<Subscript>8</Subscript>/oleyl in different solvent oils

We synthesized a low-molecular-mass organogelator, cyclohexanecarboxamide (HPMDA-R), which is composed of four amide groups with two kinds of side chains (R and R′). We selected two different alkyl groups, 2-ethylhexyl and oleyl, as side chains, considering the solubility and formation of a self-assembled structure within the solvents. We measured the rheological properties of HPMDA-2C₈/oleyl dissolved in paraffin oil and three kinds of ester oils as solvents. The results indicated that the compound contributed to viscoelasticity in both isododecane and 2-ethylhexyl isononanoate, but increased viscosity only in cetyl caprylate. In addition, the compound behaved as a gelator for isostearyl isostearate. We were able to associate differences in function with the morphology of self-assembly observed by TEM. The formation of a gel may have contributed to the presence of the minute network structure. Our measurements for time-dependency supported that notion.