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运用金刚石对顶砧(Diamond Anvil Cell,DAC)技术,以液氩作为传压介质,在最高压力为67 GPa的压力范围内对NiO进行了原位的同步辐射X射线衍射研究。在整个实验过程中,并未发现第一类结构相变,也没有发现T.Sasaki等预测的在60 GPa左右轴比c/a随压力的变化率而突然增大的现象,且此压力范围内NiO的结构畸变程度随压力的变化趋势相比以前的研究结果要平缓一些。用三阶的Brich-Murnaghan方程对实验数据进行拟合,得到的体弹模量及其对压力的一阶导数分别为B0=195(4) GPa和B0′=5.3(2)。 相似文献
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利用X射线粉末衍射方法,在室温高压下观察到了Hg1-xCdxTe(x=0.19)的相变。实验是在DAC高压装置上完成的,压力从0逐步加至10.1 GPa。在常温常压下Hg1-xCdxTe(x=0.19)具有闪锌矿结构。从实验结果看到,在压力为3 GPa和6.8~8.3 GPa之间有两个结构相变存在。初步认为,后一个相变与Hg1-xCdxTe(x=0.19)的金属化有密切关系。通过计算,得到了它在相变前的状态方程,并且与二元HgTe化合物在相变规律上进行了比较。 相似文献
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现代天文学的知识有很多是通过分析天体的电磁辐射得到的,天体的电磁辐射的范围是相当宽阔的,它从无线电波、红外光、可见光、紫外光-直延伸到X射线、γ射线.对天体辐射观测越广,就越能较全面地认识宇宙.所以天文学家总希望把研究领域扩展到所有波段. 相似文献
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利用金刚石压腔同步辐射X射线就位衍射技术,在室温、最高压力达13 GPa条件下,对采自云南个旧锡矿的天然锡石做了X衍射测量。结果表明,在实验压力范围内锡石未发生相变,其晶胞参数随压力增大而逐渐减小。与前人合成锡石实验结果相比,本次实验测定的晶胞参数偏大。由Birch状态方程对实验结果p-V进行最小二乘法拟合,得出锡石的KT(0)=228 GPa。分析认为,在天然矿物晶体中,Zr对Sn的类质同象置换是晶胞参数偏大的主要原因。 相似文献
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采用同步辐射能量色散X射线衍射技术和金刚石对顶砧高压装置,对晶粒尺寸分别为13,49,100nm的Ge进行了原位高压X射线衍射实验,最高压力为35GPa. 所得的体弹性模量分别为112,92,88GPa. 可以看出 随着晶粒尺寸的减小,其体弹性模量逐渐升高. 同时由立方金刚石结构转变为四方白锡结构的相变压力亦随之提高,其值分别为16.4,12.4,11.5GPa. 建立了一个描述晶粒尺寸与体弹性模量关系的模型,并用理论公式计算了相变压力随晶粒尺寸的变化. 尽管在数值上存在一定的误差,但理论计算结果成功预示了随着晶粒尺寸的减小,体弹性模量和相变压力增加的趋势,与实验结果相一致. 相似文献
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在金刚石压腔高压装置(DAC)上采用同步辐射角度色散X射线衍射技术,在室温、最高压力9.16GPa条件下,对天然绿帘石进行了状态方程研究。在实验压力范围内,未观察到绿帘石发生相变。通过Birch-Murnaghan状态方程,对所获得的实验数据进行了状态方程拟合,获得了天然绿帘石的体弹模量值为116(7)GPa,体弹模量的压力导数值为7.8(8),若将体弹模量的压力导数值固定为4,获得绿帘石的体弹模量值为132(4)GPa。另外,绿帘石存在较为明显的轴向压缩各向异性:c轴方向压缩系数最大,b轴方向压缩系数最小,说明天然绿帘石在c轴方向更易于压缩,而b轴方向最抗压。 相似文献
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金刚石压砧的几何结构使得在高压下封垫内的样品通常处于单轴应力场中:压砧轴向加载应力最大,径向应力最小.由于金刚石压砧内非静水压单轴应力场的影响,用传统的高压原位X射线衍射方法测得的物质压缩曲线一般位于理想静水压压缩曲线之上.利用金刚石压砧径向X射线衍射技术以及晶格应变理论,结合最近的钨、金刚石和硼六氧样品的高压原位同步辐射径向X射线衍射实验结果,从宏观差应力、样品强度、标压物质和待测物质强度的关系三个方面分析讨论了金刚石压砧内单轴应力场对物质状态方程测量的影响及解决方案.
关键词:
金刚石压砧
单轴应力场
高压原位X射线衍射
状态方程 相似文献
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同步辐射X射线光源已经成功地应用到高压科学研究的诸多领域.文章简要回顾了同步辐射高压技术的发展历史,简要介绍了同步辐射X射线衍射技术在高压状态方程、强关联体系、地球内部物质以及早期生命起源等研究中的应用.介绍了同步辐射X射线光谱技术(包括晶格振动声子谱的测量)在高压研究中的应用,此外,还介绍了时间分辨的同步辐射技术在冲击压缩研究中的应用,最后展望了未来先进光源应用于高压科学研究的前景. 相似文献
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The strength and equation of state of molybdenum triboride have been determined under nonhydrostatic compression up to 80?GPa, using an angle-dispersive radial X-ray diffraction technique in a diamond anvil cell (DAC). The RXD data yield a bulk modulus and its pressure derivative as K0?=?342(6)?GPa with K0′?=?2.11(17) at ψ?=?54.7°. Analysis of diffraction data using the strain theory indicates that the ratio of differential stress to shear modulus (t/G) ranges from 0.002 to 0.050 at pressures of 4–80?GPa. Together with theoretical results on the high pressure shear modulus, our results here show that molybdenum triboride sample under uniaxial compression can support a differential stress of ~10?GPa when it started to yield with plastic deformation at ~30?GPa. In addition, we draw a conclusion that MoB3 is not a superhard material but a hard material. 相似文献
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We report the results of a natural phenacite from 0 to 30.9 GPa using in situ angle-dispersive X-ray diffraction and a diamond anvil cell at the National Synchrotron Light Source, Brookhaven National Laboratory. Over this pressure range, no phase change or disproportionation has been observed. The isothermal equation of state was determined. The values of V0, K0, and K0′ refined with a third-order Birch-Murnaghan equation of state are V0=1116.1±1.2 Å3, K0=223±9 GPa, and K0′=5.5±0.8. Furthermore, we confirm that the linear compressibilities (β) along a and c directions of phenacite are elastically isotropic (βa=1.50×10-3 and βc=1.34×10-3 GPa-1). Consequently, it can be concluded that the compressibility of phenacite under high pressures has been accurately constrained. 相似文献
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D. Martíinez-García Y. Le Godec M. Mézouar G. Syfosse J. P. Itié J. M. Besson 《高压研究》2013,33(1-6):339-344
Abstract A synchrotron X-ray diffraction study on MgO has been done at simultaneous high pressure and temperature. The lattice parameter of MgO has been measured up to a static pressure of 6 GPa and a temperature of 1273 K, using a large volume pressure cell and energy-dispersive synchrotron X-ray powder diffraction. The compression was made following six high-temperature isotherms. A Vinet equation of state was used to fit the experimental P-V-T data. The Vinet's model compares very well with the experimental data above the Debye temperature (760 K) and allows the use of MgO as an alternative internal pressure calibrant for experiments at high temperature. 相似文献
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CHEN Jun LONG Yao LIU YongGang NIE FuDe & SUN JinShan Laboratory of Computational Physics 《中国科学:物理学 力学 天文学(英文版)》2011,(5)
The equation of states (EOS) of high energy explosive HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) has been studied by using the first principle method. Our results include the lattice constants, elastic constants, and the dependence of total energy and pressure on volume for βand δ-HMX. The calculated elastic constants and the pressure-volume relationship of β-HMX are also compared with the experimental values. The theoretical tensile experiments are implemented on the β-HMX. The atomic-scale ana... 相似文献
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Abstract Equation of state and phase transformations of thorium metal have been investigated to 300 GPa at 300 K in a diamond anvil cell using energy dispersive X-ray diffraction employing synchrotron source. Phase transformations in the 70–100 GPa range indicative of 5f-electron bonding are observed and thorium metal is isostructural with its 4f counterpart cerium at ultra high pressures. The measured static equation of state of thorium to 300GPa (volume fraction V/V o = 0.40) at 300K is given. At high pressures, the sd to f electronic transfer has significant influence on the measured equation of state of thorium. 相似文献