基于Weiss分子场理论对极性液体中静态介电常数随温度变化及其相应取向关联的研究

迄今为止,并没有被普遍接受的液体静态介电常数的微观理论模型, 主要原因是对属于强关联系统的液体中分子之间的取向关联特征仍不十分清楚. 本文基于Weiss分子场理论(WMFT), 对水(water, H₂O)、甲醇(methanol, CH₄O)、乙醇(ethanol, C₂H₆O)和正丙醇(1-propanol, C₃H₈O)等4种极性液体中静态介电常数, 具体为Curie-Weiss常数、Curie温度和Weiss分子场因子随温度变化规律进行分析研究, 得出上述液体中: 1)铁电关联(ferroelectric correlation, FC)和反铁电关联(anti-ferroelectric correlation, AFC)共存, 且FC比AFC强得多, 以及随温度降低FC减弱和/或AFC增强; 2)结构均匀的WMFT不能定量描述上述液体中足够低的温度下反常大的静态介电常数. 可以想象FC和较弱AFC的共存必然导致极性液体中关联序的空间不均匀, 由此作者提出了空间不均匀关联序的粗粒近似的Weiss分子场理论, 并用此理论对上述液体中静态介电常数随温度快速变化的行为进行了解释. 上述结果对深入认知液体物理学, 包括玻璃化转变机制的探索, 无疑是有价值的.     

飞秒激光-固体靶相互作用中渡越辐射的测量

为了探索超热电子的加热机制,利用光学CCD相机和OMA光学多道分析仪,分别在靶背法线方向测量了光学渡越辐射（OTR）积分成像图案和光谱。实验在100 TW掺钛蓝宝石激光器上进行,飞秒激光与铜膜靶作用后,靶表面发光信号由空间分辨装置聚焦成像并引到CCD或OMA谱仪的狭缝上。测得的积分成像图案呈圆环状,光斑形成区域直径约为225 μm,在圆环边缘附近出现局部化明亮光信号,该现象表明,超热电子在传输的过程中存在成丝效应,其分布也不均匀。光谱在300～500 nm之间出现一系列非周期锐利尖峰,在400 nm（2ω0）附近出现的尖峰应归因于v×B加热机制产生的超热电子引起的相干渡越辐射（CTR）。     

径向渡越时间振荡器的初步实验研究

 对径向渡越时间振荡器进行了实验研究，在非最优化条件下得到了辐射功率大于30MW、主频为3.66GHz的微波，同时研究了微波功率随电压、电流的变化，所得结果和规律与理论分析和数值模拟基本相符。     

径向渡越时间振荡器的初步实验研究

对径向渡越时间振荡器进行了实验研究,在非最优化条件下得到了辐射功率大于30MW、主频为3.66GHz的微波,同时研究了微波功率随电压、电流的变化,所得结果和规律与理论分析和数值模拟基本相符。     

飞秒激光-固体靶相互作用中渡越辐射的测量

 为了探索超热电子的加热机制，利用光学CCD相机和OMA光学多道分析仪，分别在靶背法线方向测量了光学渡越辐射（OTR）积分成像图案和光谱。实验在100 TW掺钛蓝宝石激光器上进行，飞秒激光与铜膜靶作用后，靶表面发光信号由空间分辨装置聚焦成像并引到CCD或OMA谱仪的狭缝上。测得的积分成像图案呈圆环状，光斑形成区域直径约为225 μm，在圆环边缘附近出现局部化明亮光信号，该现象表明，超热电子在传输的过程中存在成丝效应，其分布也不均匀。光谱在300～500 nm之间出现一系列非周期锐利尖峰，在400 nm（2ω0）附近出现的尖峰应归因于v×B加热机制产生的超热电子引起的相干渡越辐射（CTR）。     

渡越辐射及其在北京自由电子激光置束测中的应用

在北京自由电子激光器装置的性能改进中,采用了基于渡越辐射的电子束诊断方法。描述了渡越辐射应用于电子束参数测量的基本理论,介绍了BFEL中利用渡越辐射进行的实验方案,并报导了初步的结果。     

C波段新型渡越管模拟研究

在三腔渡越管的基础上设计了一种工作在C 波段的新型低阻轴向六腔渡越管,其阻抗为15 Ω左右,采用同轴输出。该器件采用大面积发射阴极,无须外加磁场,结构简单紧凑。采用2.5维PIC软件对该器件进行了2维数值模拟,在输入电压为483 kV、电流为32.5 kA的条件下,输出微波平均功率达到3.0 GW,主频为3.75 GHz,微波模式为TEM模。微波功率效率大于19%,比普通低阻抗器件有明显提高。     

C波段新型渡越管模拟研究

 在三腔渡越管的基础上设计了一种工作在C 波段的新型低阻轴向六腔渡越管,其阻抗为15 Ω左右,采用同轴输出。该器件采用大面积发射阴极,无须外加磁场,结构简单紧凑。采用2.5维PIC软件对该器件进行了2维数值模拟,在输入电压为483 kV、电流为32.5 kA的条件下,输出微波平均功率达到3.0 GW,主频为3.75 GHz,微波模式为TEM模。微波功率效率大于19%,比普通低阻抗器件有明显提高。     

渡越辐射及其在北京自由电子激光置束测中的应用

 在北京自由电子激光器装置的性能改进中,采用了基于渡越辐射的电子束诊断方法。描述了渡越辐射应用于电子束参数测量的基本理论,介绍了BFEL中利用渡越辐射进行的实验方案,并报导了初步的结果。     

渡越辐射及其在北京自由电子激光置束测中的应用

在北京自由电子激光器装置的性能改进中,采用了基于渡越辐射的电子束诊断方法。描述了渡越辐射应用于电子束参数测量的基本理论,介绍了BFEL中利用渡越辐射进行的实验方案,并报导了初步的结果。     

Effect of Cu doping on the static dielectric constant of nanocrystalline ZnO

Cu-doped ZnO nanoparticles were synthesized by a simple rheological phase reaction–precursors method using zinc acetate, cupric acetate and oxalic acid for different atomic percentages of Cu doping. X-ray diffraction studies confirmed the correct phase formation and compositions were obtained by energy dispersive X-ray analysis. Particle sizes were recorded from small angle X-ray scattering studies. The static dielectric constant, calculated from the shift in band-gap energy, showed a gradual decrease with Cu doping. A simple theoretical calculation, based on the Penn model, was performed to explain the observed change in dielectric constant with doping. The model could successfully describe the dependence of the static dielectric constant of nanocrystalline ZnO on doping concentration.     

Influence of fluorination and chain length on the static dielectric properties of nematogenic bi-cyclohexyl phenyl derivatives

Effects of fluorination and chain length of six bi-cyclohexyl phenyl compounds (3ccp-f, 3ccp-ff, 3ccp-fff, 5ccp-f, 5ccp-ff, 5ccp-fff) on their physical properties have been investigated. All the compounds exhibit nematic phase over a wide range of temperatures. Molecular mechanics calculation reveals that dipole moments of the molecules increases (1.93D to 3.37D) with fluorination in both propyl- and pentyl-based systems; increment in f to ff derivatives is more than in ff to fff derivatives. However, no change in dipole moment is observed with increased chain length. In the nematic phase, average value of dielectric constant (?_avg) is less than the extrapolated values of ?_iso in isotropic phase. Increased fluorination also decreases splay elastic constant, and thus faster response is expected in triply fluorinated compounds.     

Simulation calculation of dielectric constants: Comparison of methods on an exactly solvable model

A mean spherical model of classical dipoles on a simple cubic lattice of sideM=2N+1 sites is considered. Exact results are obtained for finite systems using periodic boundary conditions with an external dielectric constant and using reaction field boundary conditions with a cutoff radiusR _c N and an external dielectric constant. The dielectric constant in the disordered phase is calculated using a variety of fluctuation formulas commonly implemented in Monte Carlo and molecular dynamics simulations of dipolar systems. The coupling in the system is measured by the parametery=4 ²/9kT, where ² is the fixed mean square value of the dipole moments on the lattice. The system undergoes a phase transition aty2.8, so that very high dielectric constants cannot be obtained in the disordered phase. The results show clearly the effects of system size, cutoff radius, external dielectric constant, and different measuring techniques on a dielectric constant estimate. It is concluded that with periodic boundary conditions, the rate of approach of the dielectric constant estimate to its thermodynamic limit is asN ^–2/3 and depends only weakly on. Methods of implementing reaction field boundary conditions to give rapid convergence to the thermodynamic limit are discussed.     

The error of brightness temperature of sea water caused by the error of dielectric constant

Comparing three formulas of calculating complex dielectric constant of saline solutions shows that two of them will yield errors of no more than 5% at frequency 34.88GHz except at temperature 0°C. An expression of the relative error of brightness temperature has been developed, which claims that the relative error of brightness temperature is at least less than half of the relative error of complex dielectric constant.     

超高介电常数非铁电单晶

关键词：     

PZT四方相区介电常数εr与晶格畸变关系的研究

从Haun的PZT热力学理论出发，给出了PZT四方相区介电常数ε_r与晶格畸变c/a关 系的基本方程，并深入地根据相关实验资料和物理图像的合理推论，建立了关于晶格畸变c/ a与介电常数ε_r相互依赖的基本关系式.然后，根据该基本关系式仔细地研究了PZT四 方相区晶格畸变c/a对介电常数ε_r影响的物理图像.与相关实验资料比较表明，基本 关系式得到的介电常数ε_r随晶格畸变c/a的变化规律,与相关实验结果相比较，两者 吻合得 关键词： 晶格畸变 r')" href="#">介电常数ε_r 四方相 PZT     

氧含量对BiFeOδ多晶陶瓷介电特性的影响

采用固相反应法制备了不同含氧量的BiFeO_δ多晶陶瓷样品，利用HP4294A阻抗分析仪测量了样品的介电特性随频率和氧含量的变化，用正电子湮没寿命谱学的方法研究了样品中因氧含量的变化所引起的结构缺陷. 实验结果表明：引入氧空位和氧填隙离子缺陷都会使介电常数减小，而介电损耗则随氧含量的增加而增加，二者的变化范围均在10%—35%之间；对不同氧含量的BiFeO_δ样品，介电常数和介电损耗随测量频率的增加而减小. 氧空位的引入使得局域电子密度变小，正电子平均寿命τ_m增加. 在氧含量δ=2.99时电子密度最大(n_e=3.90×10²³/cm³)，继续增加氧含量对正电子寿命与局域电子密度的影响不大. BiFeO_δ样品的介电常数和介电损耗随氧含量的变化可以在空间电荷限制电导的框架下来理解.     

The Born repulsive parameters and dielectric behaviour of alkali halides

The dependence of the Born repulsive parameters of alkali halides on elastic and dielectric data has been discussed. The values of hardness parameter in alkali halides have been recalculated using the revised values of van der Waals energies. It is observed that the two sets of hardness parameter corresponding to elastic and dielectric data differ from each other but become compatible if an effective charge parameter for the ions is introduced. Its usefulness has been demonstrated by calculating the strain derivative of static dielectric constant of alkali halides.     

Dielectric absorption in mixtures of anisole with some primary alcohols at microwave frequency

Dielectric properties of binary mixtures of anisole with methanol (MeOH), 1-propanol (1-PrOH), 1-butanol (1-BuOH) and 1-heptanol (1-HeOH) over an entire concentration range have been studied at a fixed temperature 40°C. The dielectric constant (ε′) and dielectric loss (ε″) of the binary mixtures of polar liquids have been determined at a microwave frequency of 9.1?GHz. The static dielectric permittivity (ε ₀) of the liquid samples was also determined using a precision LCR meter. Determined values of static dielectric permittivity (ε ₀) and dielectric permittivity (ε*) at 9.1?GHz frequency were used to evaluate relaxation time (τ) and high frequency limit dielectric permittivity (ε _∞). Dielectric parameters were interpreted in terms of molecular interaction between the anisole and alcohol molecules.