共查询到17条相似文献,搜索用时 125 毫秒
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迄今为止,并没有被普遍接受的液体静态介电常数的微观理论模型, 主要原因是对属于强关联系统的液体中分子之间的取向关联特征仍不十分清楚. 本文基于Weiss分子场理论(WMFT), 对水(water, H2O)、甲醇(methanol, CH4O)、乙醇(ethanol, C2H6O)和正丙醇(1-propanol, C3H8O)等4种极性液体中静态介电常数, 具体为Curie-Weiss常数、Curie温度和Weiss分子场因子随温度变化规律进行分析研究, 得出上述液体中: 1)铁电关联(ferroelectric correlation, FC)和反铁电关联(anti-ferroelectric correlation, AFC)共存, 且FC比AFC强得多, 以及随温度降低FC减弱和/或AFC增强; 2)结构均匀的WMFT不能定量描述上述液体中足够低的温度下反常大的静态介电常数. 可以想象FC和较弱AFC的共存必然导致极性液体中关联序的空间不均匀, 由此作者提出了空间不均匀关联序的粗粒近似的Weiss分子场理论, 并用此理论对上述液体中静态介电常数随温度快速变化的行为进行了解释. 上述结果对深入认知液体物理学, 包括玻璃化转变机制的探索, 无疑是有价值的. 相似文献
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范德瓦尔斯方程的分子平均场理论推导 总被引:1,自引:0,他引:1
利用气体分子动理论和分子平均场理论,导出了真实气体物态方程--范德瓦尔斯方程,并与统计力学严格的理论推导结果作比较,得到了反映真实气体分子作用域大小的一个较为具体的参考值. 相似文献
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根据Nd2Fe14B的冲击加载实验,计算了3.3—7.2 GPa压力范围内冲击波阵面上压力与温度的关系.基于分子场理论,引入压力等效场,改进了双亚点阵理论模型,并分析了在不同温度和压力下Nd2Fe14B的磁性转变机理.计算了压力对Nd2Fe14B磁致伸缩系数、磁化率、磁化强度以及居里温度的影响,给出了Nd2Fe14B发生铁磁–顺磁相变的压力和温度判据.计算结果表明:压力使Nd2Fe14B的居里温度逐渐向低温区转移,当压力从0 GPa增加到1.15 GPa时,居里温度从584 K降至292 K;随着压力的增加,Nd2Fe14B的磁化强度不断下降,且临界去磁压力随温度的升高呈下降趋势;在3.3—7.2 GPa压力范围内,Nd2Fe14B发生了铁磁-顺磁相变. 相似文献
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基于以Lanczos方法为杂质求解器的动力学平均场理论,研究了非局域轨道间跃迁对于双轨道强关联体系中轨道选择Mott相变的影响.计算了轨道间跃迁系数不同的双轨道Hubbard模型的准粒子权重和态密度,并构建了它们在相互作用强度U和轨道带宽比t2/t1影响下的相图.通过正则变换引入两个有效的退耦和轨道,在一定条件下轨道间跃迁会有利于轨道选择Mott相变的发生.还比较了Bethe晶格和正方晶格的相图,虽然基于两种不同晶格能带结构得到的轨道选择Mott相变的相变点存在一定的差异,但其中关于轨道选择Mott相变的基本物理图像具有一致性.并将方法拓展到半满的Ba2CuO4–δ材料的研究中,与根据密度泛函理论得到的能带对比,我们发现各向同性的轨道间跃迁对能带结构影响较大,进一步采用动量空间各向异性的非局域轨道间跃迁项,得到了材料的相图,在半满条件下Ba2CuO4–δ应为轨道选择Mott材料. 相似文献
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采用热力学非线性理论,研究了外加电场对立方基底Pb(Zr0.3Ti0.7)O3(PZT)铁电薄膜相变的影响.通过数值计算,得到了"失配应变-外加电场"相图,及外加电场与极化强度的关系.当外加电场达到186 kV/cm时,能使生长在SrTiO3 基底上PZT铁电薄膜从单斜r相转变为c相.在实验上,采用扫描探针显微镜通过对PZT薄膜施加不同的极化电场来研究了它的电畴翻转.从得到的压电响应相图可以看出,绝大多数的电畴是清晰可
关键词:
铁电薄膜
相变
扫描探针显微镜
失配应变 相似文献
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Mehmet Erta?Mustafa Keskin Bayram Deviren 《Journal of magnetism and magnetic materials》2012,324(8):1503-1511
Using an effective field theory with correlations, we study a kinetic spin-5/2 Blume-Capel model with bilinear exchange interaction and single-ion crystal field on a square lattice. The effective-field dynamic equation is derived by employing the Glauber transition rates. First, the phases in the kinetic system are obtained by solving this dynamic equation. Then, the thermal behavior of the dynamic magnetization, the hysteresis loop area and correlation are investigated in order to characterize the nature of the dynamic transitions and to obtain dynamic phase transition temperatures. Finally, we present the phase diagrams in two planes, namely (T/zJ, h0/zJ) and (T/zJ, D/zJ), where T absolute temperature, h0, the amplitude of the oscillating field, D, crystal field interaction or single-ion anisotropy constant and z denotes the nearest-neighbor sites of the central site. The phase diagrams exhibit four fundamental phases and ten mixed phases which are composed of binary, ternary and tetrad combination of fundamental phases, depending on the crystal field interaction parameter. Moreover, the phase diagrams contain a dynamic tricritical point (T), a double critical end point (B), a multicritical point (A) and zero-temperature critical point (Z). 相似文献
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Mehmet Erta? Bayram DevirenMustafa Keskin 《Journal of magnetism and magnetic materials》2012,324(5):704-710
The dynamic phase transitions are studied in the kinetic spin-2 Blume-Capel model under a time-dependent oscillating magnetic field using the effective-field theory with correlations. The effective-field dynamic equation for the average magnetization is derived by employing the Glauber transition rates and the phases in the system are obtained by solving this dynamic equation. The nature (first- or second-order) of the dynamic phase transition is characterized by investigating the thermal behavior of the dynamic magnetization and the dynamic phase transition temperatures are obtained. The dynamic phase diagrams are constructed in the reduced temperature and magnetic field amplitude plane and are of seven fundamental types. Phase diagrams contain the paramagnetic (P), ferromagnetic-2 (F2) and three coexistence or mixed phase regions, namely the F2+P, F1+P and F2+F1+P, which strongly depend on the crystal-field interaction (D) parameter. The system also exhibits the dynamic tricritical behavior. 相似文献
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Dynamic behavior of a site diluted Ising ferromagnet in the presence of a periodically oscillating magnetic field has been analyzed by means of the effective field theory (EFT). The dynamic equation of motion has been solved for a honeycomb lattice (z=3) with the help of a Glauber type stochastic process. The global phase diagrams and the variation of the corresponding dynamic order parameter as a function of the Hamiltonian parameters and temperature has been investigated in detail and it has been shown that the system exhibits reentrant phenomena, as well as a dynamic tricritical point which disappears for sufficiently weak dilution. 相似文献
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基于随机场Ising模型描述的有序无序相变中偶极子在电场作用下的反转运动, 研究了有序无序相变过程中电场与极化强度的关系. 认为tanh(x) 的函数关系与位移型二阶铁电相变极化强度随电场变化的实验结果完全相同. 由此得出基本结论: 偶极子的集体转向造成了极化强度的增大并等同于内电场的增加. 通过区分光学模和偶极子对介电隔离率的贡献, 考虑偶极子极化对介电常数复数形式的频率色散关系, 发现从高斯分布的居里温度可以导出二阶铁电相变过程中介电常数与温度和频率的色散关系.
关键词:
铁电相变
极化强度
随机场 相似文献
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Paraelectric--ferroelectric interface dynamics induced by latent heat transfer and irreversibility of ferroelectric phase transitions 下载免费PDF全文
The temperature gradients that arise in the paraelectric--ferroelectric
interface dynamics induced by the latent heat transfer are studied from the
point of view that a ferroelectric phase transition is a stationary,
thermal-electric coupled transport process. The local entropy production is
derived for a ferroelectric phase transition system from the Gibbs equation.
Three types of regions in the system are described well by using the Onsager
relations and the principle of minimum entropy production. The
theoretical results coincides with the experimental ones. 相似文献
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Shu-Tao Ai Chang-Tan Xu Yong–Long Wang Shao–Yin Zhang Xue–Feng Ning Eli Noll 《Phase Transitions》2013,86(5):479-490
In this article, we compared and commented on two thermodynamic approaches, i.e. the reversible and irreversible ones to ferroelectric phase transitions especially in the case of first-order. The reversible approach, otherwise known as the Landau–Devonshire theory proved not to possess a firm physical basis according to the concepts and methods originating from the field theory and those originating from the analytical dynamics. The metastable states hypothesis underlying the Landau–Devonshire theory causes an unpleasant consequence and a logical conflict. As for the new-developed irreversible approach, we demonstrated that the fundamental hypothesis of stationary states underlying it, is reliable with the aid of non-equilibrium variational principles. The difficulties encountered within the Landau–Devonshire theory can be overcome while this approach is applied to the first-order ferroelectric phase transitions. There is some justification made to prove the proposition. 相似文献