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利用混合物理化学气相沉积法(hybrid physical-chemical vapor deposition, HPCVD)可以制备出高性能的MgB2超导薄膜, 再对薄膜进行钛(Ti)离子辐照处理.经过辐照处理后的样品被掺入了Ti元素, 与未处理的干净MgB2样品相比,其超导转变温度没有出现大幅度的下降, 而在外加磁场下的临界电流密度得到了明显的提高,同时样品的上临界磁场也得到了提高. 在温度5 K, 外加垂直磁场为4 T的情况下, Ti离子辐照剂量为1× 1013/cm2的样品的临界电流密度达到了1.72× 105 A/cm2, 比干净的MgB2要高出许多,而其超导转变温度仍能维持在39.9 K的较高水平. 相似文献
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采用基于第一性原理密度泛函理论的平面波赝势方法,对0.5NdAlO3-0.5CaTiO3晶体进行结构优化,并对其能带结构,态密度和光学性质进行了理论计算.结构优化后晶格参数与实验数据相符合,误差小于1%;能带计算结果表明0.5NdAlO3-0.5CaTiO3为间接带隙,带隙值为0.52eV;费米面附近的能带由Nd-4f,O-2p,Nd-4p,Al-3p,Ti-4d层的电子态密度确定.同时也计算了该结构的介电函数,反射率和复折射率等光学性质. 相似文献
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报道了利用蓝宝石介质谐振器技术测量MgB2超导薄膜的微波表面电阻Rs sub>、0K时的穿透深度λ(0)和超导能隙Δ(0).λ(0)和Δ(0)的值是通过先测量样品穿透深度λ(T)的变化量Δλ(T),然后由BCS理论模型拟合Δλ(T)的实验数据得到的.测试样 品是利用化学气相沉积技术在MgO(111)基片上制备的c轴织构的MgB2超导薄膜, 薄膜的超导转变温度和转变宽度分别为38K和01K.微波测试结果表明在10K,18GHz下M gB2薄膜的Rs约为100μΩ,可以和高质量的YBCO薄膜的Rs值相比拟;BCS理论拟合得到的MgB2超导薄膜的λ(0)=102nm,Δ(0)=113k Tc. 相似文献
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本文计算了Heusler合金Li2AlGa和Li2AlIn的晶格参数、体积模量、体积模量的一阶导数、 电子能带结构、声子色散曲线和声子态密度,并与密度泛函理论中的广义梯度近似计算结果进行比较. 计算的晶格参数与文献有很好的一致性. 两个Heusler合金的电子能带结构表明它们是半金属结构. 并利用声子色散曲线和声子密度图研究Heusler合金晶格动力学. Li2AlGa和Li2AlIn Heusler合金在基态呈现动力学稳定. 相似文献
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采用原位粉末装管工艺,分别以Mg粉(99.5%),无定形B粉(99.9%)为原料,以纳米SiC(10—30nm)作为掺杂材料制备铁基MgB2线.首先将已混合的原料在丙酮介质中球磨,真空干燥后,将粉末填入铁管内,然后通过孔型轧制、旋锻和拉拔等冷加工工艺得到11m长外径Ф1.75mm铁基MgB2超导线.用扫描电镜,电子能谱,X射线衍射仪和超导量子干涉仪测试发现,样品微观结构整齐,晶粒大小均匀,内部仅含微量MgO,TC(onset)=35.1K,ΔTC=5.3K.纳米SiC掺杂后,其中C造成MgB2晶格畸变,形成有效磁通钉扎中心,C元素在MgB2中分布均匀.标准四引线测试结果表明,11m线均分10段后,各点的Jc(4.2K,10T)均超过1.0×104A/cm2,最高值达到1.2×104A/cm2.在10—18T范围各点临界电流值分布均匀,变化率小于10%. 相似文献
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稀土正铁氧体YFeO3呈正交钙钛矿结构,其晶体和纳米晶材料在电极材料、 传感器和光催化领域具有重要的应用价值.用平面波赝势方法,采用广义梯度近似、改进的Perdew-Burke-Emzerhof交换-关联势、 实空间超软赝势计算方案,研究了YFeO3晶体的几何结构、电子结构和光学性质. 计算得到的晶格参量与报道的实验结果一致.通过对能带结构、态密度、介电函数、吸收系数和光电导率的计算和分析, 确定YFeO3是直接能隙半导体,能隙Eg约为2.22 eV,阐明了YFeO3晶体和纳米晶具有较好的可见光催化性能. 相似文献
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采用平面波赝势密度泛函理论方法对0—60 GPa静水压下BC5 六角晶系P3m1和四方晶系I4m2结构的平衡态晶格常数、弹性常数、各向异性以及泊松比与Cauchy扰动进行了研究. 研究结果表明, BC5的两种结构在高压下是稳定的, 且不可压缩性随着压强的增加而增大. 另外, 对其电子结构也进行了计算, 计算结果表明, BC5存在一个较宽的带隙, 两种原子间有较强的共价杂化, 材料的性质主要由B的2p1和C的2p2态电子共同决定. 压强对材料带隙和费米能级附近的态密度几乎没有影响, 只引起微小的漂移, 可推断其很好的高压稳定性. 相似文献
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Lei Chen Jing Zuo Yanyan Lu Hai Huang 《Physica C: Superconductivity and its Applications》2011,471(23-24):1591-1594
Based on two-band Ginzburg–Landau theory, we study the temperature dependence of upper critical field for superconducting crystal NbSe2. The results reproduce the experimental data in a broad temperature range, especially the upward curvature near the transition temperature. Our calculations also indicate that in NbSe2 the band with the smaller gap is almost isotropic, and most probably located on the bonding Nb Fermi sheets. 相似文献
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《Current Applied Physics》2001,1(4-5):333-336
Earlier this year a new type of high-temperature superconductivity has been reported in MgB2 with a transition temperature of 39 K. In a recent paper we proposed a simple BCS model with an anisotropic s-wave order parameter which accounts for the available thermodynamic and scanning tunneling microscopy data obtained from polycrystalline palets of MgB2. In this work, we further investigate the physical consequences of this theory by calculating the temperature dependence of the thermal conductivity, the nuclear spin relaxation rate, and the angular dependence of the upper critical field. 相似文献
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We report on μ Hall probe measurements on single crystals of 2H–NbS2. This compound is the only superconducting 2H-dichalcogenide which does not develop a charge density wave. At low temperature and low magnetic field, a Bean profile is observed, allowing to evaluate the critical current. Moreover, the anisotropy and temperature dependence of the first critical field in 2H–NbS2 was measured down to 1.2 K. A linear temperature dependence of the first penetration field is clearly observed. The absolute magnetic penetration depth is found to be 83 nm which is slightly reduced compared to the iso-structural compound 2H–NbSe2. 相似文献
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The dissipative mechanism at low current density is compared in three different classes of superconductors. This is achieved
by measuring the resistance as a function of temperature and magnetic field in clean polycrystalline samples of NbSe2, MgB2 and Bi2Sr2Ca2Cu3O10 (BSCCO) superconductors. Thermally activated flux flow behaviour is seen in all the three systems and clearly identified
in bulk MgB2. While the activation energy at low fields for MgB2 is comparable to Bi2Sr2Ca2Cu3O10, its field dependence follows a parabolic behaviour unlike a power-law dependence seen in Bi2Sr2Ca2Cu3O10. We analyse our results based on Kramer’s scaling for grain boundary pinning in MgB2 and NbSe2.
相似文献
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C. Ferdeghini V. Ferrando V. Braccini M.R. Cimberle D. Marré P. Manfrinetti A. Palenzona M. Putti 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(2):147-151
The anisotropy of MgB2 is still under debate: its value, strongly dependent on the kind of sample and on the measuring method, ranges between 1.2
and 13. In this work we present our results on MgB2 c-oriented superconducting thin film. To evaluate the anisotropy, we followed two different approaches. Firstly, magnetoresistivity
was measured as a function of temperature at selected magnetic fields applied both parallel and perpendicular to the c-axis; secondly, we measured magnetoresistivity at selected temperatures and magnetic fields, varying the angle θ between the magnetic field and the c-axis. The anisotropy estimated from the ratio between the upper critical fields parallel and perpendicular to the c-axis and the one obtained in the framework of the scaling approach within the anisotropic Ginzburg-Landau theory are different
but show a similar trend in the temperature dependence. Some differences in the upper critical field and in its anisotropy
of our film with respect to single crystals are emphasized: some of these aspects can be accounted for by an analysis of upper
critical fields within a two-band model in presence of disorder and/or crystallographic strain.
Received 12 July 2002 / Received in final form 17 September 2002 Published online 29 November 2002 相似文献
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I. N. Askerzade 《JETP Letters》2005,81(11):583-586
The temperature dependence of the anisotropy parameter of the upper critical field \(\gamma _{H_{c2} } (T) = H_{c2}^\parallel (T)/H_{c2}^ \bot (T)\) is calculated using the two-band Ginzburg-Landau theory for layered superconductors. It is shown that the anisotropy parameter γ(T) increases with decreasing temperature. The results of the calculations are in agreement with experimental data for single crystals of MgB2 and with other calculations. 相似文献
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Satoru Noguchi Akihiro Kuribayashi Yoshitomo Harada Shigehito Miki Hisashi Shimakage Zhen Wang Kazuo Satoh Tsutomu Yotsuya Takekazu Ishida 《Journal of Physics and Chemistry of Solids》2008,69(12):3240-3243
We present experimental and calculated phase diagrams of the upper critical field Hc2 and the anisotropy parameter γ of various MgB2 thin films prepared by the molecular beam epitaxy (MBE) and the multiple-targets sputtering system. Experimental data of the Hc2(T) and γ are analyzed by fitting the Gurevich theory. We obtained the result that for these MgB2 films the Hc2(T) is explained as the case of Dπ/Dσ>1, which means the films are classified to the cleaner π band than the σ band. We discuss temperature dependence of the transition width obtained from the magnetoresistance measurements. 相似文献
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The upper critical field of clean MgB2 is investigated
using the two-band layered Ginzburg--Landau (GL) theory. The
calculated results are fitted to the experimental data of clean
MgB2 crystal very well in a broad temperature range. Based
on the GL theory for clean superconductors, a phenomenological
theory for dirty superconductor is proposed. Selecting appropriate
parameters, two-band layered GL theory is successfully applied to
the crystal of Mg(B1-xCx)2 and the neutron
irradiation samples of MgB2. 相似文献
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Xiaosheng Huang William Mickelson B.Christopher Regan Alex Zettl 《Solid State Communications》2005,136(5):278-282
We have measured the temperature dependence of the upper critical field, Hc2(T), of carbon-doped MgB2. Hc2(T) does not follow the well-known Werthamer-Helfand-Hohenberg (WHH) result for a one-gap dirty superconductor but can be described well by the result of a recent theoretical calculation for a two-gap dirty superconductor. Hc2(0) of the carbon-doped material is determined to be between 29 and 38 T, substantially higher than that of pure MgB2 (15-23 T). 相似文献