Resonant structure due to the 3p→3d transition in the photoionization of Ca+

Many-body perturbation theory has been used to calculate the resonance structure (3p→3d) into the photoionization (4s→kp) for ion Ca⁺. This resonance structure results from the interference between a photoionization process or a photoionization with excitation process and a resonant Auger process. The coupled equation method has been improved to calculate this interference by the summation of specific classes of diagrams of perturbation theory to infinite order. The resonance structure in the region of the 3p threshold is enhanced via a super-Coster–Kronig transition. The theoretical results are in good agreement with experiment.     

Landau damping and frequency-shift of a quadrupole mode in a disc-shaped rubidium Bose–Einstein condensate

The damping and frequency-shift in Landau mechanism of a quadrupole mode in a disc-shaped rubidium Bose–Einstein condensate are investigated by using the Hartree–Fock–Bogoliubov approximation. The practical relaxations of the elementary excitations and the orthometric relation among them are taken into account to obtain advisable calculation formula for damping as well as frequency-shift. The first approximation of Gaussian distribution function is employed for the ground-state wavefunction to suitably eliminate the divergence of the analytic three-mode coupling matrix elements.According to these methods, both Landau damping rate and frequency-shift of the quadrupole mode are analytically calculated. In addition, all the theoretical results agree with the experimental ones.     

Fine structure in the α decay of202Rn

The α decay of mass-separated²⁰²Rn is studied at the ISOLDE separator. Time sequential α-singles spectra together with α-X-t and α-e-t coincidence events are collected. Fine structure in the α decay is observed and feeding of a low-lying 0 ₂ ⁺ state at 816 keV in¹⁹⁸Po is evidenced. This 0⁺ state can be interpreted as the bandhead of an intruder-state based deformed band, coexisting with the spherical groundstate band. Mixing between normal and intruder states is discussed. A preliminary α-decay study of²⁰⁰Rn did not yet reveal any fine structure.     

Admixture of the giant dipole resonance to low lying 1−-states in heavy nuclei

The mass of ¹³ Be has been measured with the reaction ¹³ C(¹⁴ C,¹⁴ O)¹³ Be at E _Lab =337 MeV. A Q-value of Q ₀=–37.02(5) MeV was obtained and the mass excess is M.E.=35.16(5) MeV. If the observed line corresponds to the ground state,¹³ Be is particle unstable with respect to the oneneutron emission by 2.01 MeV. The observed line width of 0.3(2) MeV supports an assignment ofJ =5/2⁺ or 1/2^–, but excludesJ =1/2⁺. An excited state is seen at 3.12(7) MeV; there are indications of a second excited state at 6.5(2) MeV.     

Determination of the Landau–Lifshitz damping parameter by means of complex susceptibility measurements

A new experimental method for the determination of the Landau–Lifshitz damping parameter, α$\alpha$, based on measurements of the frequency and field dependence of the complex magnetic susceptibility, χ(ω,H)=χ^′(ω,H)-iχ^″(ω,H)$\chi (\omega ,H)={\chi }^{\prime }(\omega ,H)-\mathrm{i}{\chi }^{″}(\omega ,H)$, is proposed. The method centres on evaluating the ratio of f_max/f_res, where f_res is the resonance frequency and f_max is the maximum absorption frequency at resonance, of the sample susceptibility spectra, measured in strong polarizing fields. We have investigated three magnetic fluid samples, namely sample 1, sample 2 and sample 3. Sample 1 consisted of particles of Mn_0.6Fe_0.4Fe₂O₄ dispersed in kerosene, sample 2 consisted of magnetite particles dispersed in Isopar M and sample 3 was composed of particles of Mn_0.66Zn_0.34Fe₂O₄ dispersed in Isopar M  . The results obtained for the mean damping parameter of particles within the magnetic fluid samples are as follows: 〈α(_{Mn0.6Fe0.4Fe2O4})〉=0.057$〈\alpha ({\mathrm{Mn}}_{0.6}{\mathrm{Fe}}_{0.4}{\mathrm{Fe}}_2{\mathrm{O}}_4)〉=0.057$ with the corresponding standard deviation SD=0.0104$\mathrm{SD}=0.0104$; 〈α(_Fe3O4)〉=0.1105$〈\alpha ({\mathrm{Fe}}_3{\mathrm{O}}_4)〉=0.1105$ with the corresponding standard deviation, SD=0.034$\mathrm{SD}=0.034$ and 〈α(_{Mn0.66Zn0.34Fe2O4})〉=0.096$〈\alpha ({\mathrm{Mn}}_{0.66}{\mathrm{Zn}}_{0.34}{\mathrm{Fe}}_2{\mathrm{O}}_4)〉=0.096$ with the corresponding standard deviation, SD=0.037$\mathrm{SD}=0.037$.     

Is the negative temperature coefficient of the resistivity of the quasicrystals due to chemical disorder?

We have found that the electronic transport of the binary icosahedral (i) Cd-Yb is extremely sensitive to a minute substitution of Mg for Cd atoms; the positive temperature coefficient of the resistivity (TCR) at low temperatures seen in the binary i Cd-Yb disappears by addition of only 0.1 at. % Mg and, moreover, the TCR stays negative well up to 60 at. % Mg. Such sensitiveness of the resistivity in the very dilute Mg concentration region, which is a consequence of the long coherence length (>28 A) of the conduction electrons in the quasiperiodic lattice, has led us to an unexpected conclusion: The negative TCR in the ternary i phase is due to partial chemical disorder; i.e., it is not a consequence of the quasiperiodicity.     

A numerical investigation of the evolution of 2-D disturbances in hypersonic boundary layers and the effect on the flow structure due to the existence of shocklets

~~A numerical investigation of the evolution of 2-D disturbances in hypersonic boundary layers and the effect on the flow structure due to the existence of shocklets~~     

Fine structure in the α-decay of radium isotopes with mass numbers 209-212

Radium isotopes with mass numbers from 209 to 212 have been produced by heavy-ion fusion reactions ²⁰⁴Pb( ¹²C, xn) ^216-Ra. Radioactive decay properties were investigated by means of α- and α-γ-spectroscopy after in-flight separation of the evaporation residues from the projectile beam by the velocity filter SHIP and implantation into a 16-strip position-sensitive Si detector. For the even-even nuclei ^210,212Ra we identified α transitions into the first-excited 2⁺-state of the daughter nuclei ^206,208Rn. Weak α transitions into excited levels of the odd-A daughter nuclei ^205,207Rn were also observed. Received: 19 August 2002 / Accepted: 6 November 2002 / Published online: 18 February 2003 RID="a" ID="a"e-mail: f.p.hessberger@gsi.de Communicated by D. Guerreau     

Fine structure and inverse population in the MnKβ1 spectra of MnxZnyFezO4 ferrites

The electronic structure of Mn_xZn_yFe_zO₄ single-crystal ferrites was investigated. The fine structure of their X-ray spectra was found to correlate with the populations of quantum states. A scheme is suggested for the evolution of the electronic structure with strengthening exchange interaction of valence electrons as the chemical composition of the system becomes more complex. The metal-insulator phase transition is possible in the range of compositions corresponding to densities from ρ=5.097 g/cm³ to ρ=5.125 g/cm³, where manganese changes its charge state.     

Observation of the charge order in perovskite manganite Pr 0.5 Ca 0.5 MnO 3 by M?ssbauer quadrupole effect

Based on the temperature dependence of the hyperfine parameters of the ⁵⁷Fe nuclei, the qualitative and quantitative phase composition of nanocrystalline iron oxides on the surface and on the tails of the “classic” multiwalled carbon nanotubes (CNT) was investigated. From the observed temperature dependence it was shown that the contribution of the nonmagnetic iron-containing phase is caused by small size nanoparticles on the CNTs surface.     

Fine and hyperfine structure in the X2Σ+ state of gas-phase yttrium monoxide

The A²Π_r-X²Σ⁺ visible spectrum of gas-phase yttrium monoxide has been studied at sub-Doppler resolution to obtain information on the spin-rotation and ⁸⁹Y nuclear magnetic hyperfine interactions. The observations were fitted to an effective Hamiltonian model that neglected the nuclear magnetic hyperfine interactions in the excited electronic state. An interpretation of the determined parameters in terms of possible electronic configurations is presented.     

Does the excitation of a plasmon resonance induce a strong chemical enhancement in SERS? On the relation between chemical interface damping and chemical enhancement in SERS

In this contribution, a fundamental new approach is made to explain high enhancement factors in surface-enhanced Raman spectroscopy (SERS) on the basis of chemical enhancement. Usually, high SERS enhancement factors are explained by electromagnetic enhancements due to the excitation of localized surface plasmon resonances and strong near field dipole–dipole coupling. However, very often the corresponding SERS spectra show clear signatures of a chemical enhancement. I propose that this contradiction is easily solved by taking chemical interface damping of the plasmon resonance into account. Chemical interface damping is caused by an electron transfer from the metallic structure into an adsorbate. However, this mechanism is also the basis for chemical enhancement in SERS, i.e., an electron transfers in the lowest unoccupied molecular orbital of the molecule and back to the metal. Hence, if a molecule causes a strong chemical interface damping, the excitation of plasmons is still the key factor for the SERS enhancement. But the reason for this enhancement might be not solely due to electromagnetic fields rather than by a chemical enhancement due to electron transfers from the metal to the molecules.     

Fine structure of the okα X-ray emission band in Sc3+-activated lithium-manganese ferrites

The ok x-ray emission band of oxygen in a group of magnetically soft lithium squareloop ferrites has been obtained for the first time. The form of this band is complicated, by number and position it is similar to the FeK₅ band in the same ferrites, which suggests that the 3d states of Fe are significantly hybridized with the 2p states of oxygen and that the latter could participate in Anderson indirect exchange. The effect of small additions of Sc ions, improving the properties of the ferrite, on the spectrum of the ferrite is discussed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 53–56, November, 1987.     

Direct determination of the magnetic quadrupole contribution to the Lyman-α₁ transition in a hydrogenlike ion

We report the observation of an interference between the electric dipole (E1) and the magnetic quadrupole (M2) amplitudes for the linear polarization of the Ly-α1 (2p3/2→1s1/2) radiation of hydrogenlike uranium. This multipole mixing arises from the coupling of the ion to different multipole components of the radiation field. Our observation indicates a significant depolarization of the Ly-α1 radiation due to the E1-M2 amplitude mixing. It proves that a combined measurement of the linear polarization and of the angular distribution enables a very precise determination of the ratio of the E1 and the M2 transition amplitudes and the corresponding transition rates without any assumptions concerning the population mechanism for the 2p3/2 state.     

Observation of the matrix effect due to the electron transfer in laser ablation plasma

We investigate the so-called “matrix effect” on the relative intensities of ions in mixed solutions of alkali salts by using femtosecond laser ablation time-of-flight mass spectrometry (fsLA-TOFMS). For the 1:1 mixed solution of sodium and potassium salts, the intensity ratio of cations (Na⁺/K⁺) decreases as the total concentration increases. From the measurement for the mixed solution of lithium, sodium, potassium, rubidium, and cesium solutions, we find out significant dependence of each ion intensity on the total concentration. The results suggest that the electron transfer from neutral atoms to cations coexistent in the ablation plasma affects the relative ion intensities observed with TOFMS when the total ion concentration is high.     

Changes in the thermoelectric response of vitreous carbon due to the irradiation by γ-rays

In order to study variations in the thermoelectric properties, some commercial glassy carbon samples were subjected to a sequence of steps consisting of a combination of irradiation with γ-rays produced by radioisotopes ⁶⁰Co, and hydrogen adsorption when the samples were put in an over pressured atmosphere of this gas. With this procedure it was possible to observe that the irradiation decreases the electrical conductivity of glassy carbon samples and the hydrogenation changes the sign of Seebeck coefficient. The material initially is an n-type semiconductor, but with hydrogenation changes to p-type semiconductor. X-ray diffraction analysis showed that the hydrogenated vitreous carbon is more amorphous than the pristine material and the γ-rays irradiation produces changes in the crystallite size and shape.     

Fine structure of the emission spectrum of a two-dimensional electron–hole liquid in SiGe/Si quantum wells

The fine structure of the emission spectrum of a quasi-two-dimensional electron–hole liquid in shallow SiGe/Si quantum wells is observed experimentally. This fine structure is explained by the occurrence of steps in the density of states resulting from the coexistence of light and heavy holes in the liquid phase and by the interaction of charge carriers with charge-density oscillations in the liquid.