BaO-TiO_2-SiO_2系统微晶玻璃窗口的制作及光学性质

讨论了以ＢａＯＴｉＯ２ＳｉＯ２系统作为基础玻璃组分烧制的散射型微晶玻璃窗口的部分光学性质。这种窗口在激光测量中的使用，可退偏振降低探测器的偏振效应误差，提高探测器的抗光损伤能力。针对不同的情况，可扩大探测器的线性动态范围一至两个数量级。     

硫化镉纳米微晶掺杂Na2O—B2O3—SiO2系统玻璃的制备及光学性质 …

本文采用Ｓｏｌ－ｇｅｌ方法制备了掺杂ＣｄＳ纳米微晶的Ｎａ２Ｏ－Ｂ２Ｏ３－ＳｉＯ２系统玻璃,研究了这种玻璃材料的合成反应机理和结构特性。利用各种温度下玻璃中掺杂纳米尺寸ＣｄＳ半导体微晶的光致发光光谱,研究了其光致发光带的峰值能量和线宽对温度的信赖关系,拟合了其带隙发光带的线宽随温度的变化曲线,获得样品的非均匀线宽。ＣｄＳ微晶的非均匀线宽主要是由于微晶的尺寸分布引起的,可以利用ＣｄＳ微晶的非均匀宽化系     

硫化镉纳米微晶掺杂Na2O-B2O3-SiO2系统玻璃的制备及光学性质的研究

本文采用Sol－gel方法制备了掺杂CdS纳米徽晶的Na2O－B2O3－SiO2系统玻璃,研究了这种玻璃材料的合成反应机理和结构特性．利用各种温度下玻璃中掺杂纳米尺寸CdS半导体微晶的光致发光光谱,研究了其光致发光带的峰值能量和线宽对温度的依赖关系,拟合了其带隙发光带的线宽随温度的变化曲线,获得样品的非均匀线宽．CdS微晶的非均匀线宽主要是由于微晶的尺寸分布引起的,可以利用CdS微晶的非均匀宽化系数来评价微晶的尺寸分布．报道了此种玻璃的三阶非线性极化率X（3）＝6.5×10－12esu．简要分析了影响这种材料三阶非线性极化率的因素．     

全波段光窗玻璃及微晶化

研究了GeSe2-Ga2Se3-MX(M=Cs,K,X=I,Br,Cl)系玻璃的形成和性能。研究表明,这些系统均具有较大的玻璃形成区,其中,GeSe2-Ga2Se3-CsI系统的成玻能力和热稳定性最佳。随碱金属卤化物含量的增加,GeSe2-Ga2Se3-MX玻璃的短波吸收限逐渐蓝移至可见光区(可至550 nm以下),长波截止边无明显变化,部分玻璃在0.6~16μm范围内具有良好的透过率。玻璃的转变温度Tg、显微硬度Hv、断裂韧性K1c和弹性模量E随卤化物的含量增加而减小,而膨胀系数α增大。研究发现,该系统玻璃随热处理温度的提高,首先发生滴状分相,随后在滴状分相区内产生析晶。通过采取合适的热处理制度,研制获得了具有较好的K1c和红外透光性的微晶玻璃。研究结果表明,GeSe2-Ga2Se3-MX硫卤玻璃和玻璃陶瓷是一种具有应用前途的全波段透射和红外透射材料。     

CaO对MgO-Al2O3-SiO2微晶玻璃烧结和性能的影响

研究了氧化钙对MgO-Al2O3-SiO2系微晶玻璃烧结特性和性能的影响。结果表明:氧化钙替代氧化镁能够促进微晶玻璃粉体的烧结致密化,影响玻璃的晶化特性、介电性能和热膨胀特性。随着氧化钙量的增加,样品的介电常数和热膨胀系数增加,但其介质损耗呈现先减小后稍微增加的趋势。含3%CaO(质量分数)的样品可在900℃烧结致密化,并具有低的εr(5.4)、低的tgδ(≤0.13×10-2)和低的α(3.55×10-6℃-1),是一种有应用前景的低温共烧陶瓷基板材料。     

掺Pbse半导体微晶玻璃的热致色散光学双稳态

本文首次报导了掺PbSe半导体微晶玻璃的热致色散光学双稳性,在建立理论模型的基础上,指出对于掺半导体微晶的材料,可以通过减小基底材料的热传导系数来降低器件的阈值功率.     

Ba2—xSrxTiSi2O8微晶玻璃的光及SAW性能

以Ba2-xSrxTiSi2O8为主晶相,制备透明微晶玻璃,测试了材料的二阶非线性光学性能;以晶粒定向微晶玻璃基片制作了声表面波（SAW）滤波器,测试了器件的性能参数,分析了材料结构与性能的关系和材料的改进方向。     

铝硼桂酸盐微晶玻璃系统的制造与特性

目前微电子封接需要用低温烧制的低介电常数材料做基底，含ＳｉＯ２、Ｂ２Ｏ、Ａｌ２Ｏ３及ＣａＯ的基底材料，可以在空气中，低于１０００℃的温度下进行烧结。对烧制的基底材料电气特性，热膨胀系数、机械性能，本文进行了评估。     

半导体微晶掺杂玻璃的电致二阶非线性光学效应

报道了若干半导体微晶掺杂玻璃的电致二阶非线性光学效应的一些实验结果，并对其形成机理进行了讨论     

超微OLED的制备及其光电特性的研究

为了实现高亮度有机电致发光器件(OLED)及其尺寸的微型化,采用接触式光刻技术,通过真空热蒸镀制备了具有不同掩膜版结构的OLED。器件的结构为玻璃衬底/ITO/LiF/空穴传输层(HTL,NPD)/发光层(EML,0.5-0.6vol%Rubrene:Alq3)/电子传输层(ETL,Alq3)/阴极,其中LiF作为绝缘层。分别制得发光面积为45μm×2mm的微细器件和直径为44μm的微小器件。实验研究了其光电特性,结果表明,4.5μm×2.0mm微细器件的最大电流密度为7A/cm2,为44μm微小器件的最大电流密度为40A/cm2。     

Fabrication and properties of polymer optical fibers containingNd-chelate

Graded-index poly(methyl methacrylate) optical fibers (GI POF) containing a Nd-chelate have been fabricated. The absorption spectrum of the fiber exhibited several strong bands in the visible and infrared regions. We have observed infrared fluorescence (0.90, 1.06, and 1.3 μm) of the Nd³⁺ ion of the fiber at room temperature when it was pumped with an Ar⁺-pumped dye laser at 580 nm     

两种不同方法制备的硅纳米颗粒的特性研究

采用激光烧蚀法和电化学腐蚀法制备硅纳米颗粒,两种方法制备的硅纳米颗粒粒径与形貌都不同,而且紫外-可见吸收谱也有很大差别.分析紫外-可见吸收谱发现,硅纳米颗粒与单晶硅相比发生了能带展宽、吸收边蓝移现象,并且有直接能隙的特点;两种方法制备的硅纳米颗粒的光致发光都与硅颗粒的粒径分布和表面层成分密切相关,并且光致发光谱还随激发波长的变化而规律地改变.用量子限制和表面层成分结合模型分析解释了这些现象.     

Fabrication process and optical properties of perdeuterated graded-index polymer optical fiber

We proposed a graded-index polymer optical fiber (GI-POF) enabling greater-than-gigabit data transmission in a short reach network by applying a two-step interfacial-gel polymerization process to a perdeuterated polymer material. Using this process, it is possible to fabricate a nearly optimum refractive-index profile with good reproducibility. In this paper, the preparation of a perdeuterated polymethyl methacrylate (PMMA-d8)-based GI-POF utilizing a PMMA cladding is described. This means that the low-loss PMMA-d8 material is used only for the core. Because the cladding transmits only a small fraction of the optical power, a low-loss material is not necessarily required for the cladding. It was verified that the low attenuation of the PMMA-d8 was maintained even if the cladding was composed of hydrogenated PMMA. As a result, a gigabit data transmission over 300 m was achieved by the PMMA-d8-core and PMMA-cladding GI-POF, which was impossible by the conventional PMMA-based GI-POF.     

Fabrication and optical properties of neodymium-, praseodymium- anderbium-chelates-doped plastic optical fibres

Neodymium, praseodymium and erbium ions are successfully incorporated into the core of deuterated polymer-based optical fibres. The spectra of three fibres have several strong absorption bands in the visible and infrared regions. The fluorescence lifetime (6.24 μs) at 1060 nm of Nd-chelate doped plastic optical fibre with an uncooled photodiode is obtained     

Fabrication and optical properties of photonic crystals based on opal-GaP and opal-GaPN composites

Nanocrystalline GaP and amorphous GaPN solid solution have been synthesized in voids of artificial opal. The opal-GaP and opal-GaPN composites obtained clearly demonstrate properties of photonic crystals. The reflection spectra of the opal-GaPN composite exhibit specific features related to multiple Bragg diffraction on two systems of {111} planes, parallel and nonparallel to the surface of the photonic crystal. The study of photoluminescence spectra revealed a considerable modification of the emission band of the opal-GaPN composite, which was attributed to the influence of the photonic band gap.     

Fabrication of PMMA doped with griseofulvin material and its optical rotatory dispersion

Recently,effects of chiral media on electromagneticwaves have attracted a great deal of attentions[1-3].Re-lated studiesindicated that the left-hand and right-handelectromagnetic wave which has different velocity couldbe transmitted in the chiral medium. …     

新型挤压法制备硫系玻璃光纤及其性能研究

选用组分为Ge15Sb20S65和Ge25Sb5Se70的两组硫系玻璃,制备了多种尺寸的高质量硫系玻璃,分析了两组玻璃的物理、热学和光学性能;利用复合层叠挤压法制备了硫系玻璃光纤预制棒,避免了钻孔法或其他机械加工引起的预制棒界面缺陷,且光纤端面结构可随模具尺寸自由设计,挤压后光纤预制棒结构整齐,内外界面整洁光滑;利用高温聚合物保护的预制棒具有良好的机械性能,用光纤拉丝机将具有保护层的预制棒拉制成光纤;利用普通光纤抛光机进行端面抛光,光纤端面结构均匀,界面无明显缺陷。傅里叶红外光纤光谱仪(FTIR)测试光纤损耗谱表明,在波长4.8μm处光纤的最低损耗为2.63dB/m。