Filler-matrix thermal boundary resistance of diamond-copper composite with high thermal conductivity

A composite material with a high thermal conductivity is obtained by capillary infiltration of copper into a bed of diamond particles of 400 μm size, the particles having been pre-coated with tungsten. The measured thermal conductivity of the composite decreases from 910 to 480 W m⁻¹ K⁻¹ when the coating thickness is increased from 110 to 470 nm. Calculations of the filler/matrix thermal boundary resistance R and the thermal conductivity of the coating layer λ _i using differential effective medium, Lichtenecker’s and Hashin’s models give similar numerical values of R and λ _i ≈ 1.5 W m⁻¹ K⁻¹. The minimal thickness of the coating h ∼ 100 nm necessary for ensuring production of a composite while maximizing its thermal conductivity, is of the same order as the free path of the heat carriers in diamond (phonons) and in copper (electrons). The heat conductance of the diamond/tungsten carbide coating/copper interface when h is of this thickness is estimated as (0.8–1) × 10⁸ W m⁻² K⁻¹ and is at the upper level of values characteristic for perfect dielectric/metal boundaries.     

Excess 1/f noise in systems with an exponentially wide spectrum of resistances and dual universality of the percolation-like noise exponent

The excess 1/f noise in a random lattice with bond resistances r∼exp(−λx), where x is a random variable and λ≪1, is studied theoretically. It is shown that if the correlation function {δr ²}∼r r ^θ+2, then the relative spectral density of the noise in the system is expressed as C _e∼λ^m exp(−λ(1−p _c)), where p _c is the percolation threshold and m=νd (ν is the critical exponent of the correlation length and d is the dimensionality of the problem). It is hypothesized that the exponent m possesses a dual universality: It is independent of 1) the geometry of the lattice and 2) the θ-mechanism responsible for the generation of the local noise. Numerical modeling in a three-dimensional lattice gives m=52.3 for θ=1 and θ=0, in agreement with the hypothesis. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 8, 614–618 (25 April 1996)     

Experimental study of optical gas-dynamic processes of polymeric material ablation by ultrashort laser pulses

Optical gas-dynamic processes occurring in polymeric targets ((CH₂O) _n , (C₂F₄) _n ) exposed to ultrashort laser pulses (τ _0.5 ∼ 45 − 70 fs; λ _I,II,III = 266, 400, 800 nm; and E/S ∼ 0.1 − 40 J/cm² at r ₀ ∼ 20 μm) were studied under normal conditions and in vacuum (p ∼ 10⁻² Pa). The dynamics of the mass flow from the target surface (m′ ∼ 10⁻⁵ − 10⁻⁴ g/J) was studied and the spectral-energy thresholds of laser ablation, the electron density distribution (n _e ∼ 10¹⁴ − 10¹⁸ cm⁻³), the mass-averaged velocity of the material flow from the target surface (∼ 10³ m/s), and the chemical composition and average temperature in the near-surface plasma formation (T ∼ 5000 K) were determined using interference microscopy, emission spectroscopy, and shadowgraphy.     

Non-steady-state photo-EMF in nanostructured GaN and polypyrrole within porous matrices

We report an experimental investigation of the non-steady-state photoelectromotive force in nanostructured GaN within porous glass and polypyrrole within chrysotile asbestos. The samples are illuminated by an oscillating interference pattern created by two coherent light beams and the alternating current is detected as a response of the material. Dependences of the signal amplitude versus temporal and spatial frequencies, light intensity, and temperature are studied for two wavelengths λ=442 and 532 nm. The conductivity of the GaN composite is measured: σ=(1.1–1.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=442 nm, I ₀=0.045–0.19 W/cm², T=293 K) and σ=(3.5–4.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=532 nm, I ₀=2.3 W/cm², T=249–388 K). The diffusion length of photocarriers in polypyrrole nanowires is also estimated: L _D=0.18 μm.     

Thermal conductivity of crystalline fullerite C60 in the simple cubic phase

The behavior of the thermal conductivity k(T) of bulk faceted fullerite C₆₀ crystals is investigated at temperatures T=8–220 K. The samples are prepared by the gas-transport method from pure C₆₀, containing less than 0.01% impurities. It is found that as the temperature decreases, the thermal conductivity of the crystal increases, reaches a maximum at T=15–20 K, and drops by a factor of ∼2, proportional to the change in the specific heat, on cooling to 8 K. The effective phonon mean free path λ _p, estimated from the thermal conductivity and known from the published values of the specific heat of fullerite, is comparable to the lattice constant of the crystal λ _p∼d=1.4 nm at temperatures T>200 K and reaches values λ_p∼50d at T<15 K, i.e., the maximum phonon ranges are limited by scattering on defects in the volume of the sample in the simple cubic phase. In the range T=25−75 K the observed temperature dependence k(T) can be described by the expression k(T)∼exp(Θ/bT), characteristic for the behavior of the thermal conductivity of perfect nonconducting crystals at temperatures below the Debye temperature Θ (Θ=80 K in fullerite), where umklapp phonon-phonon scattering processes predominate in the volume of the sample. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 8, 651–656 (25 April 1997)     

Experimental determination of the difference of the beta-decay constants for atomic and molecular tritium

The results of an experiment measuring the difference Δλ=λ_a−λ _m of the beta-decay constants of atomic and molecular tritium are reported. The difference Δλ is determined by comparing the rates of growth of the relative content of radiogenic helium-3 in samples containing atomic and molecular tritium. The result Δλ=(4.6±0.8)×10⁻¹²s⁻¹ corresponds to a relative change of the decay constant by ∼0.26%. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 3, 167–170 (10 August 1998)     

Microwave energy channeling in plasma waveguides created by a high-power UV laser in the atmosphere

The grazing mode of microwave propagation in a hollow plasma waveguide formed by ionization of atmospheric air with a small easily ionized additive by strong UV pulses of the Garpun KrF laser (λ = 248 nm, the pulse duration and energy are ∼70 ns and ∼50 J) was experimentally demonstrated for the first time. The annular laser beam produced a hollow tube ∼10 cm in diameter with an electron density of ∼10¹² cm⁻³ in a plasma wall ∼1 cm thick, over whichmicrowave radiation with λ _mw ∼ 8 mm was transmitted to a distance of 60 m. Themicrowave signal transmitted by the waveguide was amplified by a factor of 6 in comparison with propagation in free space.     

Thermal expansion of thin C60 films

The thermal expansion coefficient a and structure of C₆₀ films with thickness t∼3–10 nm were investigated in the temperature interval from room to liquid-nitrogen temperature by electron-optical methods. The thermal expansion coefficient was determined from the temperature shift of the diffraction maxima in the electron diffraction patterns. The objects of investigation were epitaxial C₆₀ films condensed in vacuum on a (100) NaCl cleavage surface and oriented in the (111) plane. A surface-induced size effect in the thermal expansion coefficient was observed. It was established that as t decreases α _f increases and is described well by the relation α _f=17·10⁻⁶ K⁻¹+8.3·10⁻⁵ nm K⁻¹ t ⁻¹. This relation was used to estimate the linear expansion coefficient α _s of the C₆₀ surface in the (111) plane as α _s=60·10⁻⁶K⁻¹, which is several times larger than the bulk value. The experimental results agree satisfactorily with the theoretical calculations of the mean-square displacements of molecules located in a region near the surface. Zh. éksp. Teor. Fiz. 114, 1868–1875 (November 1998)     

Hydrothermally prepared oxide-ion and Mixed Conductors based on CeO2

The structure, thermal expansion coefficients, electrical and electrochemical properties of Ce_1−xM_xO_2−δ (M=Bi, La, Pr, Eu, Tb; x=0–0.30) solid solutions, prepared hydrothermally for the first time, are surveyed. For all cation substitution a solubility limit depending on the cation size was found. The uniformly small particle size (10–50 nm) of the hydrothermally prepared materials allows sintering of the samples into highly dense ceramic pellets at 1300–1400 °C, a significantly lower temperature, compared to that at 1600–1650 °C required for samples prepared by solid state techniques. X-ray absorption near edge spectroscopy (XANES) was used for the identification of Tb³⁺/Tb⁴⁺ or Pr³⁺/Pr⁴⁺ ions. The maximum of total conductivity in all solid solutions was found for x ∼ 0.15–0.25 with electronic contribution to the total conductivity ∼ 50 % for Tb/Pr substitution and close to zero in all other cases. The conductivity becomes more ionic with decreasing Tb/Pr substitution. The thermal expansion coefficients, determined from high-temperature X-ray diffraction data, are 11.7×10⁻⁶ K⁻¹ for CeO₂ and slowly decrease for Tb and increase for all other cases with increasing substitution. Paper presented at the 7th Euroconference on Ionics, Calcatoggio, Corsica, France, Oct. 1–7, 2000.     

Study of opto-mechanical characteristics of interaction of ultrashort laser pulses with polymer materials

The opto-mechanical characteristics, such as the specific mechanical recoil momentum, the specific impulse, and the energy efficiency, of the laser ablation of flat polymer targets ((C₂F₄) _n , (CH₂O) _n ) have been determined experimentally for the first time for the case of excitation with femtosecond pulses (τ ∼ 45–70 fs) of UV-IR (λ ∼ 266, 400, 800 nm) laser radiation (I ₀ up to 10¹⁵ W/cm²) under normal atmospheric and vacuum (p ∼ 10⁻⁴ mbar) conditions. The efficiency of mechanical recoil momentum generation is analyzed for various regimes of the laser irradiation.     

Temperature dependence of electric resistance and magnetoresistance of pressed nanocomposites of multilayer nanotubes with the structure of nested cones

Bulk samples of carbon multilayer nanotubes with the structure of nested cones (fishbone structure) suitable for transport measurements, were prepared by compressing under high pressure (∼25 kbar) a nanotube precursor synthesized through thermal decomposition of polyethylene catalyzed by nickel. The structure of the initial nanotube material was studied using high-resolution transmission electron microscopy. In the low-temperature range (4.2–100 K) the electric resistance of the samples changes according to the law ln R ∝ (T ₀/T)^1/3, where T ₀∼7 K. The measured magnetoresistance is quadratic in the magnetic field and linear in the reciprocal temperature. The measurements have been interpreted in terms of two-dimensional variable-range hopping conductivity. It is suggested that the space between the inside and outside walls of nanotubes acts as a two-dimensional conducting medium. Estimates suggest a high value of the density of electron states at the Fermi level of about 5×10²¹ eV⁻¹ cm⁻³. Zh. éksp. Teor. Fiz. 113, 2221–2228 (June 1998)     

The exponent λ (x, Q2) of the proton structure functionF2(x, Q2) at lowx

The exponent λ of the structure function F₂ ∼x ^−λ is calculated using the solution of the DGLAP equation for gluon at lowx reported recently by the present authors. The quantity λ is calculated both as a function ofx at fixedQ ² and as a function ofQ ² at fixedx and compared with the most recent data from H1     

Variation in the fluorescent background in Raman spectra of distilled water purified by different methods

The contribution of impurity fluorescence was determined in the water Raman spectra excited by the second harmonic (λ = 532 nm) of a pulsed Nd:YAG laser. Water samples prepared by different techniques (tap water (undistilled), distilled water, Milli-Q water, water for injections, and water subjected to cavitation treatment) were investigated. The Raman (bands at ν ₂ ∼ 1550 cm⁻¹ and ν ₃ ∼ 3400 cm⁻¹) and fluorescence (Stokes shift 2500 cm⁻¹) signals were separated spectrally and according to the differences in the emission kinetics. It was established that all investigated samples, including distilled and specially purified water for injections, exhibit afterglow. The highest sensitivity to the presence of impurities was revealed near ∼ 2500 cm⁻¹. The least contribution to the fluorescence signal was found in the water for injections.     

Theoretical analysis of the thermal conductivity of high-temperature superconductors

Summary The thermal conductivity of YBa₂Cu₃O_7−δ high-T _c superconductor is analysed self-consistently on both normal and superconducting states on the base of the Bardeen-Rickayzen-Tewordt extended theory to take into account the effects of magnetic field and superconducting fluctuations. It is shown that experimental data are in a quantitative agreement with theory even if the number and variation intervals of adjustable parameters are substantially reduced in comparison with previous works. Phonon relaxation rates due to different mechanisms of phonon scattering as well as the parameters of electron-phonon interaction are estimated. It is shown that thermal conductivity in YBa₂Cu₃O_7−δ is consistent with the BCS model with intermediate electron-phonon coupling λ=1–3 the phonon-electron and electron-phonon relaxation times near critical temperature are evaluated to be 10⁻¹⁰s and 10⁻¹²s, respectively.     

Discovery of a narrow resonance state of the system K S K S at mass 1520 MeV

Data are presented which indicate the existence of a previously unknown narrow resonance near mass 1520 MeV, discovered while analyzing the system K _S K _S . The data were obtained at ITEP using the 6-m magnetic spectrometer in a beam of 40-GeV negative particles. The resonance is observed in π⁻ p and K ⁻ p interactions with a total statistical confidence of not less than 5 standard deviations. The width of this state is comparable to the mass resolution of the spectrometer (∼5 MeV). The mass is 1521.5±2.5 MeV. Estimates of the product σ·BR (K _S K _S ) give ∼5.0 nb in π⁻ p interactions and ∼250 nb in K ⁻ p interactions. From the fact that the production cross section of this resonance in the K ⁻ beam is approximately 50 times greater than the production cross section in the π⁻ beam, it can be concluded that this new state belongs to a system of mesons with hidden strangeness. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 4, 242–246 (25 August 1999)     

Ion-electron transfer in solid solutions Rb2 ? 2xFe2 ? xPxO4

The rubidium monoferrite RbFeO₂-based solid solutions with the composition Rb_{2 − 2x} Fe_{2 − x} P _x O₄ have been synthesized, and their crystal structure and the temperature and concentration dependences of the total and electron conductivities have been studied. The introduction of P⁵⁺ ions has been found to sharply decrease the electron conductivity that prevails in pure rubidium monoferrite and, at the same time, to increase the ionic conductivity. The latter becomes dominant as the phosphorus concentration increases. The maximum rubidium-cation conductivity of the materials under study is ∼3 × 10⁻² S/cm at 300°C and ∼3 × 10⁻¹ S/cm at 700°C. The results have been compared with the previously obtained data for similar solid solutions based on rubidium monogallate and monoaluminate.     

Thermal effects in quantum cascade lasers at λ～4.6 μm under pulsed and continuous-wave modes

The thermal effects in InGaAs/InAlAs quantum cascade lasers (QCLs) emitting at λ∼4.6 μm under pulsed and continuous-wave (CW) modes using a three-dimensional (3D) heat dissipation model were investigated. Based on the experimentally measured results, the thermal characteristics were theoretically analyzed for various device and heatsinking structures. Also, the heat accumulation effects and dissipation processes were studied in detail under pulsed operation. High cooling efficiencies were achieved by a relatively fast heat diffusion rate from the active core region for the epilayer-down bonded single ridge waveguide buried heterostructure (BH) with a thick electroplated Au around the laser ridge. A further improvement was made by the use of InP embedding layer. In CW mode, the thermal conductance (G _th) value of 445 W/(K cm²) at 298 K was obtained for the epilayer-down bonded double-channel ridge waveguide QCL with AlN submount, which indicates a reasonable consistency with the available experimental data. By optimizing the device and heatsinking structures, the G _th was improved to a high value of 673 W/(K cm²) at 298 K for the epilayer-down bonded single ridge waveguide BH QCL with InP embedding layer on diamond submount in CW mode.     

The Co-luminescence Effect of Eu–Gd–Ofloxacin–SDBS System and its Analytical Application

A fluorescence enhancement phenomenon in the europium (Eu)–Ofloxacin (OF)–Sodium Dodecyl Benzene Sulfonate (SDBS) fluorescence system was observed when Gd³⁺ was added. The fluorescence intensity of the systems was measured (λ _ex/λ _em = 280/612 nm) at pH 7.8. Under optimum conditions, a linear relationship between the enhanced fluorescence intensity and the Eu³⁺ concentration in the range of 5.0 × 10⁻¹⁰ ∼ 2.0 × 10⁻⁷ mol·L⁻¹ was observed. The detection limit of Eu³⁺ was 1.46 × 10⁻¹⁰ mol·L⁻¹ (S/N = 3). This method was used for the determination of trace amounts of europium in synthetic rare earth samples with satisfactory results. In addition, the interaction mechanism is also studied.     

Atomic effects accompanying the beta decay of tritium

The results of the first experiment designed to measure the difference between the beta-decay constants of atomic and molecular tritium Δλ=λ_a–λ_m are presented. The experimental scheme calls for the creation of two identical samples of a gas mixture containing helium-4 and molecular tritium followed by the treatment of one of them for the purpose of bringing the tritium into the atomic state. The value of Δλ is determined by comparing the growth rates of the ratio of the concentration of radiogenic helium-3 to the concentration of helium-4 in the samples with molecular and atomic tritium. The value Δλ=(4.6±0.8)×10⁻¹² s⁻¹, which corresponds o a relative change in the decay constant amounting to ∼0.26%, is obtained. Zh. Tekh. Fiz. 69, 19–21 (September 1999)     

Thermo-optic coefficients of monoclinic KLu(WO<Subscript>4</Subscript>)<Subscript>2</Subscript>

The three thermo-optic coefficients of the biaxial laser host KLu(WO₄)₂ are measured at 633 nm by a deflection method. Their values at 300 K amount to ∂ n _g /∂ T=−7.4×10⁻⁶ K⁻¹; ∂ n _m /∂ T=−1.6×10⁻⁶ K⁻¹ and ∂ n _p /∂ T=−10.8×10⁻⁶ K⁻¹. Nearly athermal propagation directions are found for polarizations along the N _m and N _p dielectric axes.