Two successive magnetic transitions in Y2Cu2O5 studied by μSR

Zero field muon spin rotation and magnetic susceptibility experiments on investigation of magnetic properties of cuprateY ₂Cu₂O₅ have been performed in the temperature range 4.2–30 K. Transverse fieldSR-experiments have been also carried out in order to obtain accurate information about transition temperature and to study the influence of the external magnetic field. Our data show that two magnetic phase transitions occur inY ₂Cu₂O₅ with lowering temperature. Upper Neel temperatureT _N=13 K is consistent with previous experimental data. We obtained the temperature dependence of the local magnetic field on the muonB (T) in the antiferromagnetic phase.B (T) reveals a peculiarity (some change of the slope) near the temperatureT _N=7.5 K, which can be interpreted as an additional magnetic phase transition caused by a change in magnetic ordering of the copper subsystem. Applying a small external magnetic field 50 Oe leads to smearing of the peculiarity inB (T) dependence.     

Onset of superconductivity at 107K in YBa2Cu3O7 − δ at high pressure

Electrical resistivity measurements under pressure have been carried out on the high-temperature superconductor YBa₂Cu₃O_{7 –} as a function of temperature T between 1 and 300 K at various pressures between 8 kbar and 149 kbar. The superconducting transition temperature T_c increases almost linearly with pressure at the rate dT_c/dP - 0.13 K/kbar. The onset of T_c, defined as the temperature at which(T) drops to 90% of its extrapolated normal state value, increases from 95 K at 8 kbar to 107 K at 149 kbar. These results suggest that higher pressures will yield yet higher values of T_c.     

Iron-57 Mössbauer Spectroscopic Studies of the High Temperature Properties of Metal-Doped Iron Oxides

⁵⁷Fe Mössbauer spectra recorded in situ in vacuo from chromium- and gallium-doped Fe₃O₄ at elevated temperatures show the dopant ions to depress the Curie temperature of Fe₃O₄ by ca. 70 K. Spectra recorded from aluminium-doped -Fe₂O₃ show the onset of conversion to aluminium-doped -Fe₂O₃ to begin at ca. 750 K, which is ca. 100 K above the conversion temperature for undoped -Fe₂O₃. The variation in magnetic hyperfine fields at temperatures exceeding ca. 750 K is similar to that recorded from -Fe₂O₃ when doped with zinc or magnesium. At temperatures exceeding 900 K the zinc doped -Fe₂O₃ partially converts to spinel-related ZnFe₂O₄.     

Measurements of effective quasiparticle recombination times and of densities of electronic states at the Fermi level in superconducting Al- and Pb-films

Temperature-dependent quasiparticle recombination lifetimes _exp(T) and densitiesN ₀ of electronic states at the Fermi level have been measured from time decay experiments of excess quasiparticle concentrations in evaporated, superconducting Al- and Pb-tunnel junctions. Current pulses were used to inject excess, nonthermal quasiparticles in a single junction acting simultaneously as generator and detector. The experimental lifetimes in unperturbed Al show satisfactory agreement with calculations based on the 2-phonon trapping lifetime model. _exp decreases with increasing perturbations of the Al film structure by oxygen background evaporation. In Pb the measured times indicate 2-phonon volume losses. The densitiesN ₀ in Pb-films and unperturbed as well as oxygen-perturbed Al-films differ by less than 5% from the corresponding bulk material data. Therefore, in trying to explain the enhancement of the transition temperature from 1.23 K to 1.85 K in perturbed, granular Al-films a change ofN ₀ can be ruled out.     

Coherent raman spectroscopy of nitrogen molecules and clusters in supersonic jets

Coherent Stokes and anti-Stokes Raman scattering CSRS and CARS have been employed to study the spectroscopy of nitrogen molecules and clusters in the expansion of a supersonic jet. In the vibrational spectrum, at strong stagnation conditions, an intense redshifted peak is observed which can be assigned to the intramolecular vibrations in large N₂ clusters having adopted the -phase structure. Another weak feature is assigned to nitrogen clusters in the -phase. In the rotational region of the spectrum only monomer features have been observed. The failing to observe librational motions is consistent with the finding that the nitrogen clusters are predominantly in the orientationally unordered -phase. The low rotational temperature suggests supercooling of the -phase.     

Upper critical fields of single-crystalline and polycrystalline Ca-Sr-Bi-Cu-O compounds

The ac resistivity of a 110 K phase multiphase polycrystalline Ca-Sr-Bi-Cu-O compound and an 85 K phase single-crystalline Ca_0.9Sr_2.1Cu_2.0O_{8 +} has been measured in various magnetic fields up to 8 T. Values forB _c ^2/ (0) of 71.5 T and forB _c2 (0) of 542 T are found for the 85 K phase sample. A value forB _c2(0) of 57.9 T is estimated for the 110K phase compound.     

Thes-f model with Coulomb repulsion: Thermodynamics of two atomic cluster. Spin 1/2

A cluster of two atoms described by thes-f model with Coulomb repulsion has been considered. The interaction between localized 4f electrons (S=1/2) is taken in the molecular field approximation. The thermodynamic quantities like magnetization, specific heat and correlation functions n , n , S ^z n , S ^z n , S ^z (n –n ), n n and S ⁺ a ⁺ a as functions of temperature are presented for different band fillingN=0, 0.5, 1, 1.5, 2. The dependence of Curie temperature onN is calculated. The phase diagram forN=1 (T=0K) shows the possibility of existence of two phases: paramagnetic and ferromagnetic.The Curie temperature and the specific heat as functions ofN exhibit similar trends as found in experiments on doped magnetic semiconductors.     

The prediction of the behaviour of Λ-hyperon electromagnetic form factors

The behaviour of the -hyperon electric and magnetic form factors is predicted within the modified three resonance ((783), (1020), (1680)) vector-meson dominance (VMD) model with correct analytic properties and the asymptotic behaviour predestinated by the quark model for baryons. The resonance couplings to are evaluated from the known couplings to nucleons by utilizing theSU(3) symmetry and normalization conditions for Dirac and Pauli form factors. The masses and widths of the considered vector mesons are fixed at the world averaged values. The optimal position of the effective inelastic threshold, common for Dirac and Pauli form factors, is determined from the fit of the only existing Orsay DM2 point on the cross section att=5·693 GeV². The mean square charge and magnetic radii of the -hyperon are found to be r _E ² =0·018 F² and r _M ² =–0·027 F², respectively.The authors are very much indebted to Prof. R. Baldini-Ferroli for calling their attention to the problem of -hyperon e.m. ff 's in connection with the FENICE experiment.     

Unbounded derivations and invariant states

Let be a von Neumann algebra with a cyclic and separating vector . Let =i[H, ·] be the spatial derivation implemented by a selfadjoint operatorH, such thatH=0. Let be the modular operator associated with the pair (, ). We prove the equivalence of the following three conditions:1)H is essential selfadjoint onD(), andH commutes strongly with .2) The restriction ofH toD() is essential selfadjoint onD(^1/2) equipped with the inner product(|)_#=(|)+(^1/2|^1/2), , D(^1/2).3) exp (itH) exp (–itH)= for anyt.We show by an example, that the first part of 1),H is essential selfadjoint onD(), does not imply 3). This disproves a conjecture due to Bratteli and Robinson [3].Part of this work was done while O.B. was a member of Zentrum für interdisziplinäre Forschung der Universität Bielefeld     

Magnetic susceptibility and electrical conductivity of the highest chromium germanide

Results are given of measurements over the temperature range 80–1000 ° K of the magnetic susceptibility () and the electrical resistivity () of the highest chromium germanide Cr₁₁Ge₁₉. A ferromagnetic spin ordering is indicated at T < 86 ° K. From the (T) dependence and the values of the resistivity, thermo-emf and Hall constant, it is concluded that the compound studied is a semimetal with p-type conductivity.     

The thermoelectrical properties of manganese ferrites

The paper gives the measurements of the Seebeck coefficient in the temperature range of 20 to 600C on single crystals with a chemical composition of Mn _x Fe_3–x O₄, Ox<2·5. In the neighbourhood of the Curie temperature no anomalous behaviour in the temperature dependence was observed in the majority of cases. The behaviour of magnetite differs from that of other manganese ferrites which can be described well by the phenomenological theory with localized electron levels.In conclusion, the author would like to thank Dr. S. Krupika and K. Závta, C.Sc., for valuable remarks.     

A μSR study of spin density wave condensation in Cr85Mo15

Zero field SR spectra from Cr₈₅Mo₁₅ are well described by the sum of a lightly damped (0.02s^–1<₁<0.2s^–1) and a heavily damped (2s^–1<₂<15s^–1) exponential. The temperature dependence of these components is discussed in relation to the condensation of the incommensurate spin density wave and the onset of the antiferromagnetic state in this Cr-like alloy below T_N=120K. Evidence is presented for the nucleation of the spin density wave at temperatures greater than 1.5T_N.     

Effect of hydrogen doping on the magnetic properties of Gd2CuO4

We report the results of ac-susceptibility and dc-magnetization measurements for H_yGd₂CuO₄ (0y0.54). It is shown thatH doping lowers the weak ferromagnetic component in the material. The distinct hysteresis loops observed atT=77 K for both non- and hydrogenated samples change its shape withy. The magnetic ordering temperatures T _N ^Cu and T _N ^Gd , as determined from the temperature dependencies of ac-susceptibility, remain unchanged with sample's hydrogenation. This result seems to indicate that extra electrons are not doped onto the Cu-O planes of Gd₂CuO₄. The frequency dependencies ofx(, T) andx(, T) for bothy=0 andy=0.15 samples are analysed., The maximums ofx andx found at about 200K are considered in terms of susceptibility dependence on the spin-lattice relaxation time (). The anomalies in ac-susceptibility found recently in Gd₂CuO₄ atT _a=8 K andT _b=9.5 K decrease significantly withy. Results are discussed in the context of available data on 214T-type compounds.     

Transport properties of LaCu2Si2 and CeCu2Si2 between 1.5K and 300K

We report measurements of the electrical resistivity, the thermal conductivityk and the thermoelectric powerS between 1.5K and 300K on the anomalous CeCu₂Si₂ compound and on LaCu₂Si₂ as reference compound. For LaCu₂Si₂ the temperature dependences of andS are in accord with those found in otherd band metals. For CeCu₂Si₂ the observed resistivity (220 µ cm at 200K) leads to a very short electronic mean free path which is of the order of the Ce-Ce spacing. Correspondingly,k is almost identical with the phonon contributionk _p . Below 20K, resistivity and thermoelectric power strongly suggest Fermi liquid behavior with a degeneracy temperature between 20K and 40K. Above 200K, both andS decrease proportionally to –ln(T/1 K).Work performed within the research program of the Sonderforschungsbereich 125 Aachen/Jülich/KölnPart of this work will be presented at the Int. Conf. on Rare Earths in the Metallic State, St. Pierre de Chartreuse, Sept. 1978     

CARS thermometry in a transversely heated graphite-tube atomizer used in atomic absorption spectrometry

An experimental setup for gas-temperature diagnostics using Coherent Anti-Stokes Raman Scattering (CARS) in very small sample volumes with great spatial and temporal temperature variations is presented. Studies have been started of a newly designed transversely heated graphite-tube atomizer for atomic absorption spectrometry (Perkin-Elmer, 4100 ZL). For the investigations, high spatial resolution and precise time synchronization of the measurements and also automatic control of the time-dependent intensity of the anti-Stokes signal were realized. The graphite-tube atomizer also offers the possibility of high-temperature-gas spectroscopy. A high-temperature CARS spectrum of CO₂, recorded in the graphite tube at 2300 K, is shown for the first time. A number of hot-band transitions in the spectral region of the Fermi doublet at a Raman shift from 1230 to 1450cm^–1 was observed and assigned, making possible the use of CO₂ as spectroscopic thermometer gas, similar to N₂.     

The magnetic behavior of CeB6: Comparison between elastic and inelastic neutron scattering,initial susceptibility and high-field magnetization

We report measurements of the elastic and inelastic neutron scattering, initial susceptibility and high-field magnetization on thoroughly prepared poly- and single crystalline samples of CeB₆. Part of these experiments have been performed at temperatures down to 60 mK and magnetic fields up to 70 kØe. Our neutron-diffraction data provide the first proof that CeB₆ is an antiferromagnet belowT _N2K as has been suggested by previous bulk experiments. The reduced value of the low-temperature magnetic moment both below and aboveT _N points to the existence of a Kondo effect of the ₇ crystal-field (CF) ground state of Ce³⁺. From the low-temperature width of the quasielastic neutron line, the Kondo temperature is inferred to beT _K3 K. The thermal variation of the initial susceptibility (forT>20K) is semiquantitatively explained invoking, besides the Kondo effect, a ₇- ₈ CF splitting of 70 K and magnetic interactions, which are about 10 times stronger between ₈ states than those between ₇ states. This large ₈- ₈ exchange interaction is also assumed to account for the most striking result of this work, i.e. the lack of any CF-transition peak up to 44 meV in our inelastic neutron-scattering spectra.     

Eliashberg theory for disordered superconductors. II. Tunneling into disordered two-dimensional Pb films

A series ofc-axis oriented YBa₂Cu₃O _x -films with different oxygen content were prepared by laser deposition. The oxygen contentx was determined by X-ray diffraction and by resonant Rutherford-back-scattering (RRBS) measurements. Thec-axis length in these films of YBa₂Cu₃O _x is about 0.5% larger compared to bulk values. We describe transport measurements in magnetic fields up to 7 Tesla between room temperature andT _c in samples with an oxygen content between the orthorhombic-to-tetragonal transition (x6.4) and full oxygenation (x7). The ratio /R _H was investigated with respect to the two-dimensional Luttinger liquid theory and the model of the two-dimensional ionic metal. We report on deviations from the expected quadratic temperature behaviour of /R _H , especially in films with high oxygen content.     

Magnetic moments of Gd nuclei

Low temperature nuclear orientation experiments down to 2 mK on¹⁴⁷GdFe,¹⁴⁹GdFe,¹⁴⁹GdGd and¹⁵³GdGd have yielded the magnetic hyperfine interaction strength. Bhf as 31.0(1.6) _NT, 28.3(2.0) _NT, 33.8(4.7) _NT and 13.3(2.1) _NT respectively. From these values the respective ground state magnetic moments ¦¦ of¹⁴⁷Gd,¹⁴⁹Gd and¹⁵⁹Gd were deduced as 1.12(20) _N, 1.01(16) _N and 0.40(8) _N.     

Hyperfine Interactions at 181Ta in Hf2Co7

In this paper we report a time differential perturbed angular correlation (TDPAC) study of hyperfine interactions at ¹⁸¹Ta in Hf₂Co₇ compound. The TDPAC measurements have been performed in the temperature range 77–1023K. The measured spectra showed broad distribution of hyperfine interactions up to 388K. Above this temperature, in a reversible manner, two nuclear electric quadrupole interactions (EQI) have been observed: at 393K, _Q1=449.0(27)MHz, ₁=0.00(4) and _Q2=144.7(41)MHz, ₂=0.44(2). Since the Curie temperature for this compound is known from the literature to be around 420K, only magnetic order transition could be responsible for such an observation. However, the measurements of magnetization did not exhibit any drastic change in this temperature range.     

Mössbauer study of oxygen-related lattice instabilities in oriented 1-2-3 HTSC

⁵⁷Fe Mössbauer effect measurements as a function of temperature between 78 and 293 K in grain-aligned YBaCuO (T _c=89 K, T _c<2 K) with bothc andc orientations revealed a sequence of anomalies in the recoilless fraction, center shift and linewidth of all⁵⁷Fe quadrupole doublets in the host lattice. These anomalies are believed to arise due to antiferroelectric phase transitions driven by a nonlinear anharmonic vibrational motion of oxygen atoms in a breathing mode configuration. The results obtained are indicative of a possible coexistence of high-T _c superconductivity and antiferroelectricity in 1-2-3 ceramics.