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1.
A Long‐Life Lithium Ion Battery with Enhanced Electrode/Electrolyte Interface by Using an Ionic Liquid Solution
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Dr. Giuseppe Antonio Elia Ulderico Ulissi Franziska Mueller Dr. Jakub Reiter Dr. Nikolaos Tsiouvaras Prof. Yang‐Kook Sun Prof. Bruno Scrosati Prof. Stefano Passerini Prof. Jusef Hassoun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(20):6808-6814
In this paper, we report an advanced long‐life lithium ion battery, employing a Pyr14TFSI‐LiTFSI non‐flammable ionic liquid (IL) electrolyte, a nanostructured tin carbon (Sn‐C) nanocomposite anode, and a layered LiNi1/3Co1/3Mn1/3O2 (NMC) cathode. The IL‐based electrolyte is characterized in terms of conductivity and viscosity at various temperatures, revealing a Vogel–Tammann–Fulcher (VTF) trend. Lithium half‐cells employing the Sn‐C anode and NMC cathode in the Pyr14TFSI‐LiTFSI electrolyte are investigated by galvanostatic cycling at various temperatures, demonstrating the full compatibility of the electrolyte with the selected electrode materials. The NMC and Sn‐C electrodes are combined into a cathode‐limited full cell, which is subjected to prolonged cycling at 40 °C, revealing a very stable capacity of about 140 mAh g?1 and retention above 99 % over 400 cycles. The electrode/electrolyte interface is further characterized through a combination of electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) investigations upon cell cycling. The remarkable performances reported here definitively indicate that IL‐based lithium ion cells are suitable batteries for application in electric vehicles. 相似文献
2.
Frontispiece: A Long‐Life Lithium Ion Battery with Enhanced Electrode/Electrolyte Interface by Using an Ionic Liquid Solution
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Dr. Giuseppe Antonio Elia Ulderico Ulissi Franziska Mueller Dr. Jakub Reiter Dr. Nikolaos Tsiouvaras Prof. Yang‐Kook Sun Prof. Bruno Scrosati Prof. Stefano Passerini Prof. Jusef Hassoun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(20)
3.
Katherine L. Van Aken Dr. Majid Beidaghi Prof. Yury Gogotsi 《Angewandte Chemie (International ed. in English)》2015,54(16):4806-4809
An effective method to expand the operating potential window (OPW) of electrochemical capacitors based on formulating the ionic‐liquid (IL) electrolytes is reported. Using model electrochemical cells based on two identical onion‐like carbon (OLC) electrodes and two different IL electrolytes and their mixtures, it was shown that the asymmetric behavior of the electrolyte cation and anion toward the two electrodes limits the OPW of the cell and therefore its energy density. Also, a general solution to this problem is proposed by formulating the IL electrolyte mixtures to balance the capacitance of electrodes in a symmetric supercapacitor. 相似文献
4.
Irene Osada Henrik de Vries Prof. Dr. Bruno Scrosati Prof. Dr. Stefano Passerini 《Angewandte Chemie (International ed. in English)》2016,55(2):500-513
The advent of solid‐state polymer electrolytes for application in lithium batteries took place more than four decades ago when the ability of polyethylene oxide (PEO) to dissolve suitable lithium salts was demonstrated. Since then, many modifications of this basic system have been proposed and tested, involving the addition of conventional, carbonate‐based electrolytes, low molecular weight polymers, ceramic fillers, and others. This Review focuses on ternary polymer electrolytes, that is, ion‐conducting systems consisting of a polymer incorporating two salts, one bearing the lithium cation and the other introducing additional anions capable of plasticizing the polymer chains. Assessing the state of the research field of solid‐state, ternary polymer electrolytes, while giving background on the whole field of polymer electrolytes, this Review is expected to stimulate new thoughts and ideas on the challenges and opportunities of lithium‐metal batteries. 相似文献
5.
A tandem transformation that involves the formation of three bonds and two heterocyclic rings in a one‐pot fashion through amino‐alkylation of an ionic‐liquid‐immobilized diamine with keto acids followed by successive double intramolecular cyclizations to afford a tricyclic framework has been explored. This tandem cyclization has been utilized to develop a rapid and efficient method to synthesize various pyrrolo[1,2‐a]benzimidazolones and pyrido[1,2‐a]benzimidazolones on an ionic‐liquid support by using focused microwave irradiation. The application of this tandem cyclization was further extended to the aromatic keto acids to provide isoindolinone‐fused benzimidazoles, a structurally heterogeneous library with skeletal diversity. The outcome of the cascade reaction was confirmed by the X‐ray crystallographic study of the product directly attached to the ionic‐liquid support. Use of the ionic liquid as a soluble support facilitates purification by simple precipitation along with advantages like high loading capacity, homogeneous reaction conditions, and monitoring of the reaction progress by regular conventional spectroscopic methods, whereas application of microwave irradiation greatly accelerates the rate of the reactions. 相似文献
6.
Dendrite‐Free Nanocrystalline Zinc Electrodeposition from an Ionic Liquid Containing Nickel Triflate for Rechargeable Zn‐Based Batteries
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Dr. Zhen Liu Tong Cui Dr. Giridhar Pulletikurthi Dr. Abhishek Lahiri Dr. Timo Carstens Mark Olschewski Prof. Dr. Frank Endres 《Angewandte Chemie (International ed. in English)》2016,55(8):2889-2893
Metallic zinc is a promising anode material for rechargeable Zn‐based batteries. However, the dendritic growth of zinc has prevented practical applications. Herein it is demonstrated that dendrite‐free zinc deposits with a nanocrystalline structure can be obtained by using nickel triflate as an additive in a zinc triflate containing ionic liquid. The formation of a thin layer of Zn–Ni alloy (η‐ and γ‐phases) on the surface and in the initial stages of deposition along with the formation of an interfacial layer on the electrode strongly affect the nucleation and growth of zinc. A well‐defined and uniform nanocrystalline zinc deposit with particle sizes of about 25 nm was obtained in the presence of NiII. Further, it is shown that the nanocrystalline Zn exhibits a high cycling stability even after 50 deposition/stripping cycles. This strategy of introducing an inorganic metal salt in ionic liquid electrolytes can be considered as an efficient way to obtain dendrite‐free zinc. 相似文献
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8.
Chao Li Ziyang Guo Bingchang Yang Yao Liu Prof. Yonggang Wang Prof. Yongyao Xia 《Angewandte Chemie (International ed. in English)》2017,56(31):9126-9130
The utilization of CO2 in Li-CO2 batteries is attracting extensive attention. However, the poor rechargeability and low applied current density have remained the Achilles’ heel of this energy device. The gel polymer electrolyte (GPE), which is composed of a polymer matrix filled with tetraglyme-based liquid electrolyte, was used to fabricate a rechargeable Li-CO2 battery with a carbon nanotube-based gas electrode. The discharge product of Li2CO3 formed in the GPE-based Li-CO2 battery exhibits a particle-shaped morphology with poor crystallinity, which is different from the contiguous polymer-like and crystalline discharge product in conventional Li-CO2 battery using a liquid electrolyte. Accordingly, the GPE-based battery shows much improved electrochemical performance. The achieved cycle life (60 cycles) and rate capability (maximum applied current density of 500 mA g−1) are much higher than most of previous reports, which points a new way to develop high-performance Li-CO2 batteries. 相似文献
9.
Borohydride Ionic Liquids and Borane/Ionic‐Liquid Solutions as Hypergolic Fuels with Superior Low Ignition‐Delay Times
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Songqing Li Prof. Dr. Haixiang Gao Prof. Dr. Jean'ne M. Shreeve 《Angewandte Chemie (International ed. in English)》2014,53(11):2969-2972
In propellant systems, fuels of choice continue to be hydrazine and its derivatives, even though they comprise a class of acutely carcinogenic and toxic substances which exhibit rather high vapor pressures and require expensive handling procedures and costly safety precautions. Hypergolic ionic liquids tend to have low volatility and high thermal and chemical stability, and often exhibit wide liquid ranges, which could allow the use of these substances as bipropellant fuels under a variety of conditions. A new family of borohydride ionic liquids and borane–ionic‐liquid solutions is described which meets nearly all of the desired important criteria for well‐performing fuels. They exhibit ignition‐delay times that are superior to that of any known hypergolic ionic liquid and may thus be legitimate replacements for hydrazine and its derivatives. 相似文献
10.
Triphilic Ionic‐Liquid Mixtures: Fluorinated and Non‐fluorinated Aprotic Ionic‐Liquid Mixtures
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Dr. Oldamur Hollóczki Dr. Marina Macchiagodena Henry Weber Martin Thomas Dr. Martin Brehm Prof. Dr. Annegret Stark Dr. Olga Russina Dr. Alessandro Triolo Prof. Dr. Barbara Kirchner 《Chemphyschem》2015,16(15):3325-3333
We present here the possibility of forming triphilic mixtures from alkyl‐ and fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which instead of the often observed two domains—polar and nonpolar—three stable microphases are present: polar, lipophilic, and fluorous ones. The fluorinated side chains of the cations indeed self‐associate and form domains that are segregated from those of the polar and alkyl domains. To enable miscibility, despite the generally preferred macroscopic separation between fluorous and alkyl moieties, the importance of strong hydrogen bonding is shown. As the long‐range structure in the alkyl and fluoroalkyl domains is dependent on the composition of the liquid, we propose that the heterogeneous, triphilic structure can be easily tuned by the molar ratio of the components. We believe that further development may allow the design of switchable, smart liquids that change their properties in a predictable way according to their composition or even their environment. 相似文献
11.
Zhixin Xu Prof. Jiulin Wang Prof. Jun Yang Xiaowei Miao Prof. Renjie Chen Ji Qian Rongrong Miao 《Angewandte Chemie (International ed. in English)》2016,55(35):10372-10375
The lithium–sulfur battery is regarded as one of the most promising candidates for lithium–metal batteries with high energy density. However, dendrite Li formation and low cycle efficiency of the Li anode as well as unstable sulfur based cathode still hinder its practical application. Herein a novel electrolyte (1 m LiODFB/EC‐DMC‐FEC) is designed not only to address the above problems of Li anode but also to match sulfur cathode perfectly, leading to extraordinary electrochemical performances. Using this electrolyte, lithium|lithium cells can cycle stably for above 2000 hours and the average Coulumbic efficiency reaches 98.8 %. Moreover, the Li–S battery delivers a reversible capacity of about 1400 mAh g?1sulfur with retention of 89 % for 1100 cycles at 1 C, and a capacity above 1100 mAh g?1sulfur at 10 C. The more advantages of this cell system are its outstanding cycle stability at 60 °C and no self‐discharge phenomena. 相似文献
12.
Dr. Wei Guo Dr. Yongzhu Fu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(59):13322-13331
Sulfur (S) and selenium (Se) have been considered as promising high capacity cathode materials for rechargeable batteries. They have differences in their physical properties (e.g., electronic conductivity) but the same number of electrons in their outermost shells, which leads to similarity in their electrochemical behavior in batteries. In recent years, some efforts have been taken to combine them in electrodes in the hope of improved battery performance. The S−Se bonds of these electrode materials lead to unusual properties and intriguing electrochemical behavior, which have attracted increasing interest. In this Minireview, electrode materials containing S−Se bonds are summarized, including inorganic SxSey solid solutions, organic compounds, and organic–inorganic hybrid materials. Our understanding in these materials is still premature, but they have shown unique properties to be electrode materials. We hope this Minireview could provide a new insight into the design, synthesis, and understanding of these materials, which could enable high energy density rechargeable batteries. 相似文献
13.
Towards a Safe Lithium–Sulfur Battery with a Flame‐Inhibiting Electrolyte and a Sulfur‐Based Composite Cathode
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Prof. Jiulin Wang Fengjiao Lin Hao Jia Prof. Jun Yang Prof. Charles W. Monroe Prof. Yanna NuLi 《Angewandte Chemie (International ed. in English)》2014,53(38):10099-10104
Of the various beyond‐lithium‐ion batteries, lithium–sulfur (Li‐S) batteries were recently reported as possibly being the closest to market. However, its theoretically high energy density makes it potentially hazardous under conditions of abuse. Therefore, addressing the safety issues of Li‐S cells is necessary before they can be used in practical applications. Here, we report a concept to build a safe and highly efficient Li‐S battery with a flame‐inhibiting electrolyte and a sulfur‐based composite cathode. The flame retardant not only makes the carbonates nonflammable but also dramatically enhances the electrochemical performance of the sulfur‐based composite cathode, without an apparent capacity decline over 750 cycles, and with a capacity greater than 800 mA h?1 g?1(sulfur) at a rate of 10 C. 相似文献
14.
A Bio‐Inspired,Heavy‐Metal‐Free,Dual‐Electrolyte Liquid Battery towards Sustainable Energy Storage
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Wide‐scale exploitation of renewable energy requires low‐cost efficient energy storage devices. The use of metal‐free, inexpensive redox‐active organic materials represents a promising direction for environmental‐friendly, cost‐effective sustainable energy storage. To this end, a liquid battery is designed using hydroquinone (H2BQ) aqueous solution as catholyte and graphite in aprotic electrolyte as anode. The working potential can reach 3.4 V, with specific capacity of 395 mA h g?1 and stable capacity retention about 99.7 % per cycle. Such high potential and capacity is achieved using only C, H and O atoms as building blocks for redox species, and the replacement of Li metal with graphite anode can circumvent potential safety issues. As H2BQ can be extracted from biomass directly and its redox reaction mimics the bio‐electrochemical process of quinones in nature, using such a bio‐inspired organic compound in batteries enables access to greener and more sustainable energy‐storage technology. 相似文献
15.
Aleksandra Maršavelski Dr. Vilko Smrečki Dr. Robert Vianello Prof. Dr. Mladen Žinić Prof. Dr. Andrea Moguš‐Milanković Dr. Ana Šantić 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(34):12121-12128
Supramolecular ionogels were prepared by the gelation of room‐temperature ionic liquid 1‐butyl‐3‐methylimidazolium tetrafluoroborate ([BMIm][BF4]) with (S,S)‐bis(leucinol)oxalamide. Remarkably, the ionic conductivity of solutions and ionogels with low gelator concentrations is higher than that of neat [BMIm][BF4]. On the basis of molecular dynamics simulations and quantum mechanical calculations, the origin of this phenomenon is attributed to the higher affinity of gelator molecules towards [BF4]? ions, which reduces the electrostatic attraction between [BMIm]+ and [BF4]? and thus increases their mobility. With increasing gelator concentration, the ionic conductivity decreases due to the formation of a denser gelator matrix, which hinders the pathways for ionic transport. However, even for very dense ionogels, this decrease is less than one order of magnitude relative to neat [BMIm][BF4], and thus they can be classified as highly conductive materials with strong potential for application as functional electrolytes. 相似文献
16.
Salt‐Based Organic–Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li10GeP2S12 Solid Electrolyte Interface
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Yue Gao Daiwei Wang Yuguang C. Li Dr. Zhaoxin Yu Prof. Dr. Thomas E. Mallouk Prof. Dr. Donghai Wang 《Angewandte Chemie (International ed. in English)》2018,57(41):13608-13612
Solid‐state Li metal battery technology is attractive, owing to the high energy density, long lifespans, and better safety. A key obstacle in this technology is the unstable Li/solid‐state electrolyte (SSE) interface involving electrolyte reduction by Li. Herein we report a novel approach based on the use of a nanocomposite consisting of organic elastomeric salts (LiO‐(CH2O)n‐Li) and inorganic nanoparticle salts (LiF, ‐NSO2‐Li, Li2O), which serve as an interphase to protect Li10GeP2S12 (LGPS), a highly conductive but reducible SSE. The nanocomposite is formed in situ on Li via the electrochemical decomposition of a liquid electrolyte, thus having excellent chemical and electrochemical stability, affinity for Li and LGPS, and limited interfacial resistance. XPS depth profiling and SEM show that the nanocomposite effectively restrained the reduction of LGPS. Stable Li electrodeposition over 3000 h and a 200 cycle life for a full cell were achieved. 相似文献
17.
Shengjie Zhang Junhao Li Ningyi Jiang Xuqiu Li Sivakumar Pasupath Yanxiong Fang Quanbing Liu Dai Dang 《化学:亚洲杂志》2019,14(16):2810-2814
It is a very urgent and important task to improve the safety and high‐temperature performance of lithium/lithium‐ion batteries (LIBs). Here, a novel ionic liquid, 1‐(2‐ethoxyethyl)‐1‐methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (PYR1(2o2)TFSI), was designed and synthesized, and then mixed with dimethyl carbonate (DMC) as appropriate solvent and LiTFSI lithium salt to produce an electrolyte with high ionic conductivity for safe LIBs. Various characterizations and tests show that the highly flexible ether group could markedly reduce the viscosity and provide coordination sites for Li‐ion, and the DMC could reduce the viscosity and effectively enhance the Li‐ion transport rate and transference number. The electrolyte exhibits excellent electrochemical performance in Li/LiFeO4 cells at room temperature as well as at a high temperature of 60 °C. More importantly, with the addition of DMC, the IL‐based electrolyte remains nonflammable and appropriate DMC can effectively inhibit the growth of lithium dendrites. Our present work may provide an attractive and promising strategy for high performance and safety of both lithium and lithium‐ion batteries. 相似文献
18.
A Hybrid Anion for Ionic Liquid and Battery Electrolyte Applications: Half Triflamide,Half Carbonate
Kaitlyn E. Gunderson‐Briggs Thomas Rüther Adam S. Best Mega Kar Craig Forsyth Ekaterina I. Izgorodiana Douglas R. MacFarlane Anthony F. Hollenkamp 《Angewandte Chemie (International ed. in English)》2019,58(13):4390-4394
The synthesis of a new imide type anion, methylcarbonate(trifluoromethylsulfonyl)imide (MCTFSI) is described and the physicochemical properties of its sodium and N‐butyl‐N‐methyl pyrrolidinium salts as well as structural information obtained by X‐ray diffraction studies of the sodium salt are discussed in terms of charge delocalisation, coordination chemistry and electrochemical behaviour with respect to the analogous imdides bis(trifluoromethanesulfonyl)imide (TFSI) and bis(fluorosulfonyl)imide (FSI). The insight obtained from studying the new anion informs and reemphasizes the concept of weakly coordinating anions and coordination chemistry in designing electrolyte salts. 相似文献
19.
Practical applications of Zn–air batteries are usually limited by sluggish kinetics of oxygen reduction reaction. Replacing Pt‐based catalysts with convenient, efficient and low‐cost materials to boost oxygen reduction reaction is highly desirable. Herein, a class of Fe?N co‐doped carbon nanofibers is successfully synthesized by pyrolysis of polyacrylonitrile/metal‐containing ionic liquid‐based electrospun films. The ionic liquids act as porogen to provide multiscale pores as well as activator to bring carbon nanofibers active sites. The catalyst possessing appropriate active sites and unique 3D porous architecture exhibits remarkable long‐term stability and electrocatalytic activity. Particularly, the catalyst maintains a shape of membrane after carbonization, manifesting its direct use as air electrode without binders. It is notable that an all solid‐state Zn–air battery based on the carbon nanofibers exhibits good flexibility, indicating its promising application as wearable devices. 相似文献