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1.
Calculations of vibrational and rotational level spacings of homonuclear inert gas diatomic molecules by numerical integration of the radial Schrödinger equation are presented. The potentials which were used for the ground states of Ar2, Kr2, and Xe2 were obtained from accurate fits to the molecular beam scattering data. From the calculated ΔGv+12's and Bv's, the following spectroscopic constants (in cm?1) were fitted: for Ar2ωe = 31.92, ωexe = 3.31, ωeye = 0.11, Be = 0.060, αe = 0.004; for Kr2 ωe ? 23.99, ωexe ? 1.30, ωeye ? 0.021, Be ? 0.024, αe ? 0.001; for Xe2 ωe ? 21.26, ωexe ? 0.75, ωeye ? 0.008, Be ? 0.013, αe ? 0.0004.  相似文献   

2.
The (1-0), (2-0), and (3-0) transitions of 15N16O and 15N18O are investigated. The wavenumbers of the rotation-vibration lines are reported for the overtone bands and the 2Π32-2Π12 (1-0) subband. It is shown that in the data reduction it is advantageous to calculate first merged spectroscopic constants ignoring the Λ-type doubling. The vibrational constants ωe, ωexe, ωeye and the vibrational dependence of the rotational constants are determined. The study of 15N18O allows the determination of the equilibrium values of the centrifugal distortion correction ADe to the spin-orbit constant and of the spin-rotation constant γe from the isotopic invariance of the ratios ADeBe and γeBe. It is found that ADeBe = (?3.9 ± 1.3) × 10?6 and γeBe = (?4.00 ± 0.05) × 10?3.  相似文献   

3.
The investigation of the emission infrared spectrum of P2 was performed with a high resolution Fourier spectrometer. Two new electronic systems were attributed to b3Πgw3Δu and A1ΠgW1Δu transitions. The molecular parameters are obtained by a complete fitting procedure. The main equilibrium constants of the new states are (in cm?1):
ω3Δu Te = 243228.07 ωe = 591.3 ωeXe = 2.5
Be = 0.256040 δe = 0.001409 De = 19.0 X 10?8
W1ΔuTe = 31096.64 We = 627.206 WeXe = 2.331
Be = 0.2628 δe = 0.0014 De = 23 X 10?8
  相似文献   

4.
The infrared spectrum of yttrium monoiodide has been excited in an electrodeless microwave discharge and explored between 2500 and 12 000cm?1 with a high-resolution Fourier transform spectrometer. A unique system is observed (ν00 = 9905.520 cm?1), which we attribute to a 1Π1Σ transition and an extensive analysis is made. Rovibrational constants are obtained for both states mainly from a simultaneous multiband fitting. This procedure is applied to the whole set of 2231 observed line wavenumbers in the 1-0, 0-0, and 0–1 bands, yielding a final weighted standard deviation of 0.0038 cm?1. Furthermore, a partial analysis of the 2-0 and 3-1 bands is performed. The following equilibrium constants are derived (cm?1):
ω′e=192.210 ω′ex′e=0.463
B′e=0.0399133 α′e=0.0001150
ω″e=215.815 ω″ex″e=0.514
B″e=0.0422163 α″e=0.0001125
High-order constants Dv and Hv are also calculated for the various vibrational levels (v′ = 0, 1, 2, 3; v″ = 0, 1).  相似文献   

5.
The simplest four-quark SU(2) ? U(1) models with an anomally-free heavy lepton sector can have two charged heavy leptons and one or two neutral leprons. Such models also explain the rise in R (the ratio of hadronic to muon pair production in e+e? collisions). We study some consequences of different choices of leptonic numbers for L1 and L2. In particular, we derive, the leptonic decay width when several final-stae leptons are massive; the cross section for e+e?L1L2 production; the branching ratio for e+e?L2L2e3μ+missing energy.  相似文献   

6.
Cross sections for charmed baryon pair production near threshold in e+e? annihilation are calculated using pole-dominated form factors modified to take intoccount continuum effects. When the C0+C0? production cross section is normalized with the help of data for e+e?pX it is found that the total charmed baryon production cross (C0C0, C1C1, C1C11 + C11C1, C11C11) reaches a peak value of approximately 2.7 nb at √s = 5 GeV.  相似文献   

7.
Molecular constants of the first E 0+ ion-pair state of IBr vapor have been determined using polarization-labeling spectroscopy applied to the sequential transitions E 0+B′ 0+X 0+, while the second f 0+ ion-pair state is reported and characterized for the first time. A least-squares, simultaneous analysis of data for the I79Br and I81Br isotopes gives the following constants (in cm?1) for I79Br:
E state: Te = 39487.32(12), ωe = 119.518(21), ωeξe = 0.2109(12)
,
ωeye = ? 2.34(22) × 10?4, Be = 2.9701(14) × 10?2
,
αe = 5.43(59) × 10?5, and γe = ? 6.8(16) × 10?7
.
F state: Te = 45382.58(17), ωe = 128.805(66), ωeξe = 0.3630(69)
,
ωeye = ? 9.7(22) × 10?4, Be = 3.0073(30) × 10?2, and αe = 8.52(48) × 10?5
. Preliminary data for the first Ω = 1 ion-pair state, accessed in the sequence 1(3P2) ← A(Ω = 1) ← X 0+, indicate that Te is ?30 cm?1 higher in energy than that of the E state.  相似文献   

8.
The scale cross section sdσdxp for inclusive charged-particle production in e+e? annihilation has been studied for c.m. energies W between 12.0 and 36.7 GeV. Scale breaking is observed. For xp>0.2 the cross section decreases by ≈20% when W increases from 14 to 35 GeV. The production angular distribution was used to separate the longitudinal and transverse cross-section contributions and to determine the ratio of the structure functions mW1 and vW2.  相似文献   

9.
The semileptonic and leptonic decay modes of charmed hadrons produced in e+e? collisions above 4 GeV in the cm have been investigated by selecting events with a single electron plus at least two charged tracks. The electron momentum spectrum peaks near 0.5 GeV/c with few events above 0.7 GeV/c. The spectrum excludes large rates for the decays Deve and Deveπ, but is compatible with DeveK1(892), DeveK or a mixture of both. The semileptonic branching ratio is obtained both by comparing the inclusive electron cross section with the total cross section attributable to charm, and by studying the fraction of events containing a second electron. The semileptonic charm branching ratios obtained are 0.11 ± 0.03 and 0.16 ± 0.06 respectively. A single event with three electrons and hadrons is found, consistent with the estimated background. The 90% confidence upper limit for σ(e+e? → 3e + hadrons) is 0.1 nb.  相似文献   

10.
We calculate the production of narrow resonances with even charge conjugation 3PJ=1,2 in e+e? annihilation in the quarkonium and vectordominance models. We give unitarity bounds for Γ(3PJ → e+e?) in terms of Γ(3PJ → γγ) and Γ(3PJ → e+e?). The electromagnetic production dominates through the neutral current at low energies independent of details of the model. For masses above 10 GeV the situation is reversed.  相似文献   

11.
A weak emission spectrum of I2 near 2770 Å is reanalyzed and found to to minate on the A(1u3Π) state. The assigned bands span v″ levels 5–19 and v′ levels 0–8. The new assignment is corroborated by isotope shifts, band profile simulations, and Franck-Condon calculations. The excited state is an ion-pair state, probably the 1g state which tends toward I?(1S) + I+(3P1). In combination with other results for the A state, the analysis yields the following spectroscopic constants: Te = 10 907 cm?1, De = 1640 cm?1, ωe = 95 cm?1, R″e = 3.06 A?; Te = 47 559.1 cm?1, ωe = 106.60 cm?1, R′e = 3.53 A?.  相似文献   

12.
New quarks and new flavor-changing neutral currents give multiple lepton plus hadron final states in e+e-, vμN, vμN. We observe that (i) e+e- is a favored place to search for their effects through inclusive ratios σ(e+e-+x:σ (μ+μ- +x): σ(e±μ±+x) and same sign leptons e±e±+x, μ±μ±+x,e±μ±+x. Above a new flavor threshold four charged lrpton final states may become important. (ii) Trilepton final states in vμN, vμN are not sensitive to the presence of flavor-changing neutral currents. Much more sensitive are the processes vμN are +e-+βand (for charm changing neutral currents) vμN→e+β.  相似文献   

13.
14.
We present a quite general expression of the longitudinal A| and the transverse A asymmetries for the single and pair production electroweak (pseudo) scalars (Higgs, π, σ, Sμ …) from polarized e+e- colliding beams via annihilation mechanism. We suggest that the measurements of A| and A can reveal the nature of such spinless bosons and, then, the nature of the electroweak breaking, if these spinless bosons are produced at LEP and SLC energies.  相似文献   

15.
The v = 1 ← 0 vibration-rotation bands of the NS radical in the X2Π12 and X2Π32 electronic states were observed by using a tunable diode laser. From the least-squares analysis the band origins were determined to be 1204.2755(12) and 1204.0892(19) cm?1, respectively, for X2Π12 and X2Π32. The rotational and centrifugal distortion constants and the internuclear distance in the X2Π electronic state were obtained as follows: Be = 0.775549(10) cm?1, De = 0.00000129(33) cm?1, and re = 1.49403(4) A?, with three standard deviations indicated in parentheses.  相似文献   

16.
We have searched for the supersymmetric partner of the photon, the photino, by investigating two-photon and single photon final states in e+e? collisions. No significant signals were observed, which excludes the existence of the photino in the mass range 0.08–18 GeV/c2 at the 95% confidence level, subject to the assumptions d=(100 GeV)2 and me?=40 GeV/c2, where d is the supersymmetry breaking scale parameter and me? is the scalar electron mass.  相似文献   

17.
In the Born-Oppenheimer approximation the dipole moment of the vibrational levels of a 1Σ electronic state of a heteronuclear diatomic molecule can be expressed as a power series in [(Beωe)(v + 12)], where v is the vibrational quantum number, and to order (Beωe)2 this expression is
μv=[μe+(Beωe)2μc]+μ1[(Beωe)(v+12)]+μ2(Beωe)(v+12)]2
Similarly the nuclear quadrupole coupling constant eQq of each nucleus in the molecule can be expressed as
eQq=[eQqe+(Beωe)2eQqc]+eQq1[(Beωe)(v+12)]+eQq2(Beωe)(v+12)]2
In this paper the effect of the breakdown of the Born-Oppenheimer approximation on the expressions for μv and eQq for an isolated 1Σ ground electronic state of a heteronuclear diatomic molecule is determined. The effect is to change only μc and eQqc and, therefore, to alter the relationship between the μv or eQq values of two isotopes of a molecule. The intensities of the lines in the rotation and rotation-vibration spectrum are also slightly modified by this effect.For the HCl molecule we find that
μv=[1.0908+(Beωe)(164)]+8.6[(Beωe)(v+12)]?9.5[(Beωe)(v+12)]2D
where the second term (+164 D) would have the value ?4 D in the Born-Oppenheimer approximation. Similarly for the 35Cl nucleus of the HCl molecule we have
eQq=[?66.806+(Beωe)(2460)]?472.23[(Beωe)(v+12)]+750[(Beωe)(v+12)]2MHz
where the second term (+2460 MHz) would be ?110 MHz in the Born-Oppenheimer approximation.  相似文献   

18.
The 0-0, 1-1, 2-2, and 3-3 bands of the A2Π-X2Σ+ transition of the tritiated beryllium monohydride molecule have been observed at 5000 Å in emission using a beryllium hollow-cathode discharge in a He + T2 mixture. The rotational analysis of these bands yields the following principal molecular constants.
A2Π:Be = 4.192 cm?1; re = 1.333 A?
X2Σ:Be = 4.142 cm?1; re = 1.341 A?
ωe′ ? ωe″ = 16.36 cm?1; ωe′Xe′ ? ωe″Xe″ = 0.84 cm?1
From the pure electronic energy difference (EΠ - EΣ)BeT = 20 037.91 ± 1.5 cm?1 and the corresponding previously known values for BeH and BeD, the following electronic isotope shifts are derived
ΔEei(BeH?BeT) = ?4.7 ≠ 1.5cm1, ΔEei(BeH?BeT) = ?1.8 ≠ 1.5cm1
and related to the theoretical approach given by Bunker to the problem of the breakdown of the Born-Oppenheimer approximation.  相似文献   

19.
We distinguish electron and positron tracks from νe and νe charged-current interactions in a large bubble chamber f ed with a neon-hydrogen mixture. No evidence is seen for an excess of νe interactions from primary νe sources secondary νμνeorνeνe oscillations. Upper limits on oscillation parameters, majoron sion and lepton-number violating π and K decays are presented.  相似文献   

20.
The fundamental bands of the CF radical in the X2Π12 and X2Π32 electronic states were observed by using an infrared tunable diode laser as a source. Zeeman modulation could be used in detecting lines not only in the 2Π32 state, but also in 2Π12, because the CF radical deviates considerably from Hund's case (a). From the least-squares analysis of the observed spectra, the following molecular constants were obtained: Be = 1.416 704 (37) cm?1, αe = 0.018 419 (50) cm?1, re = 1.271 977 (17) A?, De = 6.68 (15) × 10?6cm?1, p0 = 0.008 580 (21) cm?1, p1 = 0.008 52 (11) cm?1, and ν0 = 1286.1281 (5) cm?1, with three standard errors in parentheses.  相似文献   

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