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Manuel A.V. Ribeiro da Silva Ana I.M.C. Lobo Ferreira Joana I.T.A. Cabral Ana Filipa L.O.M. Santos Ana Rita G. Moreno Tiago L.P. Galvão Inês M. Rocha Paula M.V. Fernandes Sílvia Q. Salgueiro Vanessa A.F. de Moura Isabel M.S.C. Oliveira Paula C. Cotelo Mariana R.A. Ribeiro 《The Journal of chemical thermodynamics》2009,41(9):984-991
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Manuel A.V. Ribeiro da Silva Luísa M.P.F. Amaral 《The Journal of chemical thermodynamics》2009,41(3):349-354
The standard (p° = 0.1 MPa) molar enthalpies of combustion, , for crystalline 2-furanacrylic acid, 3-furanacrylic acid, and 3-(2-furyl)-2-propenal and for the liquid 2-furanacrylonitrile were determined, at the temperature 298.15 K, using a static bomb combustion calorimeter. For these compounds, the standard molar enthalpies of phase transition, , at T = 298.15 K, were determined by Calvet microcalorimetry. For the two crystalline furanacrylic acids the vapour pressures as function of temperature were measured by the Knudsen effusion technique and the standard molar enthalpies of sublimation, , at T = 298.15 K were derived by the Clausius–Clapeyron equation. The results are as follows:
Empty Cell | |||
Calvet | Knudsen | ||
2-Furanacrylic acid (cr) | 3149.8 ± 0.5 | 103.0 ± 0.7 | 103.3 ± 0.5 |
3-Furanacrylic acid (cr) | 3151.5 ± 0.7 | 104.9 ± 1.1 | 106.8 ± 0.5 |
3-(2-Furyl)-2-propenal (cr) | 3425.7 ± 1.2 | 82.3 ± 0.4 | |
2-Furanacrylonitrile (l) | 3562.5 ± 1.3 | 65.2 ± 0.6 |
Compound | |||
---|---|---|---|
Calvet | Knudsen | ||
2,5-Dimethyl-3-furancarboxylic acid (cr) | 600.4 ± 1.5 | 99.0 ± 1.7 | 100.9 ± 0.5 |
3-Acetyl-2,5-dimethylfuran (l) | 352.1 ± 1.8 | 57.5 ± 1.5 | |
4,5-Dimethyl-2-furaldehyde (l) | 294.5 ± 1.7 | 57.7 ± 0.6 |
Empty Cell | /(kJ · mol?1) | /(kJ · mol?1) | /(kJ · mol?1) |
---|---|---|---|
2-Chloronitrobenzene | 2939.5 ± 0.7 | 18.7 ± 1.0 | 80.9 ± 1.5 |
3-Chloronitrobenzene | 2915.8 ± 0.8 | 42.4 ± 1.2 | 82.5 ± 1.5 |
4-Chloronitrobenzene | 2921.7 ± 1.4 | 36.5 ± 1.6 | 76.2 ± 2.1 |
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