Coupled thermoviscoplasticity of glassy polymers in the logarithmic strain space based on the free volume theory

The paper outlines a constitutive model for finite thermo-visco-plastic behavior of amorphous glassy polymers and considers details of its numerical implementation. In contrast to existing kinematical approaches to finite plasticity of glassy polymers, the formulation applies a plastic metric theory based on an additive split of Lagrangian Hencky-type strains into elastic and plastic parts. The analogy between the proposed formulation in the logarithmic strain space and the geometrically linear theory of plasticity, makes this constitutive framework very transparent and attractive with regard to its numerical formulation. The characteristic strain hardening of the model is derived from a polymer network model. We consider the particularly simple eight chain model, but also comment on the recently developed microsphere model. The viscoplastic flow rule in the logarithmic strain space uses structures of the free volume flow theory, which provides a highly predictive modeling capacity at the onset of viscoplastic flow. The integration of this micromechanically motivated approach into a three-dimensional computational model is a key concern of this work. We outline details of the numerical implementation of this model, including elements such as geometric pre- and post-transformations to/from the logarithmic strain space, a thermomechanical operator split algorithm consisting of an isothermal mechanical predictor followed by a heat conduction corrector and finally, the consistent linearization of the local update algorithm for the dissipative variables as well as its relationship to the global tangent operator. The performance of the proposed formulation is demonstrated by means of a spectrum of numerical examples, which we compare with our experimental findings.     

Mechanism-based strain gradient crystal plasticity—I. Theory

We have been developing the theory of mechanism-based strain gradient plasticity (MSG) to model size-dependent plastic deformation at micron and submicron length scales. The core idea has been to incorporate the concept of geometrically necessary dislocations into the continuum plastic constitutive laws via the Taylor hardening relation. Here we extend this effort to develop a mechanism-based strain gradient theory of crystal plasticity. In this theory, an effective density of geometrically necessary dislocations for a specific slip plane is introduced via a continuum analog of the Peach-Koehler force in dislocation theory and is incorporated into the plastic constitutive laws via the Taylor relation.     

On a finite strain viscoplastic theory based on a new internal dissipation inequality

This work is focused on the theoretical development and numerical implementation of a viscoplastic law. According to the second law of thermodynamics a dissipation inequality described in the rotated material coordinate system is developed. Based on this dissipation inequality and the principle of maximum dissipation a finite strain viscoplastic model described also in the rotated material coordinate system is formulated. The evolution equations are expressed in terms of the material time derivatives of the rotated elastic logarithmic strain, the accumulated plastic strain and the strain-like tensor conjugate to the rotated back stress. The mathematical structure of this theory is concise and similar to that of the infinitesimal viscoplastic theory. These characteristics make the numerical implementation of this theory easy. The stress integration algorithm and the algorithmic tangent moduli for the infinitesimal theory can be applied to the numerical implementation of the present finite strain theory with a little reformulation. The complicated algorithmic formulations for most of other finite plastic laws can be therefore circumvented. In order to check the effectivity of the present finite strain theory a set of numerical examples under strict deformation conditions are presented. These numerical examples prove the excellent performance of the present viscoplastic material law at describing the finite strain elastoplastic and viscoplastic problems.     

Finite elasto-viscoplastic modeling of polymers including asymmetric effects

Asymmetric effects between compression and tension are a pronounced behavior for glassy polymers such as polycarbonate. For its simulation an elasto-viscoplastic framework is formulated within a geometrically nonlinear theory. Here a new approach within the concept of stress mode dependent weighting functions is used, where each material parameter is additively decomposed into a sum of weighted stress mode-related quantities. The characterization of the stress modes is obtained in the octahedral plane of the deviatoric stress space in terms of the mode angle, such that stress mode dependent scalar weighting functions can be constructed. The constitutive equations are formulated for large strains in terms of logarithmic Hencky strains and its work conjugated Hill stresses. The resulting evolution equations are updated using a semi-implicit Euler scheme, and the algorithmic tangent operator is derived for the finite element equilibrium iteration. The numerical implementation is also used to identify the material parameters thus resulting into a good agreement with experimental data. Furthermore, the model is used to simulate the cold drawing processes for a dumbbell-shaped specimen in tension and a perforated strip in compression and tension.     

Size effects and idealized dislocation microstructure at small scales: Predictions of a Phenomenological model of Mesoscopic Field Dislocation Mechanics: Part I

A Phenomenological Mesoscopic Field Dislocation Mechanics (PMFDM) model is developed, extending continuum plasticity theory for studying initial-boundary value problems of small-scale plasticity. PMFDM results from an elementary space-time averaging of the equations of Field Dislocation Mechanics (FDM), followed by a closure assumption from any strain-gradient plasticity model that attempts to account for effects of geometrically necessary dislocations (GNDs) only in work hardening. The specific lower-order gradient plasticity model chosen to substantiate this work requires one additional material parameter compared to its conventional continuum plasticity counterpart. The further addition of dislocation mechanics requires no additional material parameters. The model (a) retains the constitutive dependence of the free-energy only on elastic strain as in conventional continuum plasticity with no explicit dependence on dislocation density, (b) does not require higher-order stresses, and (c) does not require a constitutive specification of a ‘back-stress’ in the expression for average dislocation velocity/plastic strain rate. However, long-range stress effects of average dislocation distributions are predicted by the model in a mechanistically rigorous sense. Plausible boundary conditions (with obvious implication for corresponding interface conditions) are discussed in some detail from a physical point of view. Energetic and dissipative aspects of the model are also discussed. The developed framework is a continuous-time model of averaged dislocation plasticity, without having to rely on the notion of incremental work functions, their convexity properties, or their minimization. The tangent modulus relating stress rate and total strain rate in the model is the positive-definite tensor of linear elasticity, and this is not an impediment to the development of idealized microstructure in the theory and computations, even when such a convexity property is preserved in a computational scheme. A model of finite deformation, mesoscopic single crystal plasticity is also presented, motivated by the above considerations.Lower-order gradient plasticity appears as a constitutive limit of PMFDM, and the development suggests a plausible boundary condition on the plastic strain rate for this limit that is appropriate for the modeling of constrained plastic flow in three-dimensional situations.     

A conventional theory of mechanism-based strain gradient plasticity

There exist two frameworks of strain gradient plasticity theories to model size effects observed at the micron and sub-micron scales in experiments. The first framework involves the higher-order stress and therefore requires extra boundary conditions, such as the theory of mechanism-based strain gradient (MSG) plasticity [J Mech Phys Solids 47 (1999) 1239; J Mech Phys Solids 48 (2000) 99; J Mater Res 15 (2000) 1786] established from the Taylor dislocation model. The other framework does not involve the higher-order stress, and the strain gradient effect come into play via the incremental plastic moduli. A conventional theory of mechanism-based strain gradient plasticity is established in this paper. It is also based on the Taylor dislocation model, but it does not involve the higher-order stress and therefore falls into the second strain gradient plasticity framework that preserves the structure of conventional plasticity theories. The plastic strain gradient appears only in the constitutive model, and the equilibrium equations and boundary conditions are the same as the conventional continuum theories. It is shown that the difference between this theory and the higher-order MSG plasticity theory based on the same dislocation model is only significant within a thin boundary layer of the solid.     

Application of corotational rates of the logarithmic strain in constitutive modeling of hardening materials at finite deformations

In this paper a finite deformation constitutive model for rigid plastic hardening materials based on the logarithmic strain tensor is introduced. The flow rule of this constitutive model relates the corotational rate of the logarithmic strain tensor to the difference of the deviatoric Cauchy stress and the back stress tensors. The evolution equation for the kinematic hardening of this model relates the corotational rate of the back stress tensor to the corotational rate of the logarithmic strain tensor. Using Jaumann, Green–Naghdi, Eulerian and logarithmic corotational rates in the proposed constitutive model, stress–strain responses and subsequent yield surfaces are determined for rigid plastic kinematic and isotropic hardening materials in the simple shear problem at finite deformations.     

A nonlocal strain gradient plasticity theory for finite deformations

Strain gradient plasticity for finite deformations is addressed within the framework of nonlocal continuum thermodynamics, featured by the concepts of (nonlocality) energy residual and globally simple material. The plastic strain gradient is assumed to be physically meaningful in the domain of particle isoclinic configurations (with the director vector triad constant both in space and time), whereas the objective notion of corotational gradient makes it possible to compute the plastic strain gradient in any domain of particle intermediate configurations. A phenomenological elastic–plastic constitutive model is presented, with mixed kinematic/isotropic hardening laws in the form of PDEs and related higher order boundary conditions (including those associated with the moving elastic/plastic boundary). Two fourth-order projection tensor operators, functions of the elastic and plastic strain states, are shown to relate the skew-symmetric parts of the Mandel stress and back stress to the related symmetric parts. Consistent with the thermodynamic restrictions therein derived, the flow laws for rate-independent associative plasticity are formulated in a six-dimensional tensor space in terms of symmetric parts of Mandel stresses and related work-conjugate generalized plastic strain rates. A simple shear problem application is presented for illustrative purposes.     

Size-dependent sharp indentation—I: a closed-form expression of the indentation loading curve

In this paper, a closed-form expression of the size-dependent sharp indentation loading curve has been proposed based on dimensional analysis and the finite deformation Taylor-based nonlocal theory (TNT) of plasticity (Int. J. Plasticity 20 (2004) 831). The key issue is to link the results of FEM based on TNT plasticity with those obtained using conventional FEM by taking as the effective strain gradient, η, that presented in the work of Nix and Gao (J. Mech. Phys. Solids 46 (1998) 411), thus avoiding large-scale finite element computations using strain gradient plasticity theories. Two experiments carried out on 316 stainless-steel and pure titanium have been used to verify the effectiveness of the present analytical model; the results demonstrate that the present analytical expression of the size-dependent indentation loading curve corresponds very well to the experimental indentation loading curve. The empirical constant, α, in the Taylor model estimated from the experimental data has the correct order of magnitude. Also, the results presented in this part can be further applied to establish an analytical framework to extract the plastic properties of metallic materials with sharp indentation on a small scale where the size effect caused by geometrically necessary dislocations is significant. This will be discussed in detail in the second part of the paper.     

Roles of plastic spin in shear banding

In this paper, the effects of plastic spin on shear banding and simple shear are examined systematically. Three types of plastic constitutive model with plastic spin are considered: (i) a non-coaxial model in which the direction of the plastic strain rate depends on that of the stress rate; (ii) a strain-softening model based on the J₂ flow theory; and (iii) the pressure-sensitive porous plasticity model. All the constitutive models are formulated in viscoplastic forms and in conjunction with non-local concepts that have been recently focused and discussed. First, behavior in simple shear is examined by numerical analysee with the aforementioned constitutive models. Moreover, some experimental evidences for stress response to simple shear are shown; that is, several large torsion tests of metal tubes and bars are carried out. Next, finite element simulations of shear banding in plane strain tension are performed. A critical effect of plastic spin on shear banding is observed for the noncoaxial model, while an almost negligible effect is observed for the porous model. The identical effects of plastic spin are observed, whether nonlocality exists or not. Finally, we discuss the relationship between the behavior in simple shear and the shear band formation. It is emphasized that this is a critical issue in predicting shear banding in macroscopic grounds.     

Rate equations for viscoplastic materials subjected to finite strains

The constitutive equations for plasticity proposed by Voyiadjis [1984] and Voyiadjis & Kiousis [1987] are modified here in order to introduce rate sensitivity in the plastic region. Some of the basic concepts of the theory of viscoplasticity outlined by Naghdi & Murch [1963], Perzyna & Wojno [1966], and Eisenberg & Yen [1981] are used in this work in order to obtain the proposed viscoplastic constitutive model for finite strain deformation analysis.Uniaxial loading-reverse loading tests are conducted so as to check the validity of the proposed constitutive model as well as to determine its material parameters. The model is effectively used in simulating numerically the obtained experimental results at finite strains.     

X-ray microdiffraction and strain gradient crystal plasticity studies of geometrically necessary dislocations near a Ni bicrystal grain boundary

We compare experimental measurements of inhomogeneous plastic deformation in a Ni bicrystal with crystal plasticity simulations. Polychromatic X-ray microdiffraction, orientation imaging microscopy and scanning electron microscopy, were used to characterize the geometrically necessary dislocation distribution of the bicrystal after uniaxial tensile deformation. Changes in the local crystallographic orientations within the sample reflect its plastic response during the tensile test. Elastic strain in both grains increases near the grain boundary. Finite element simulations were used to understand the influence of initial grain orientation and structural inhomogeneities on the geometrically necessary dislocations arrangement and distribution and to understand the underlying materials physics.     

A critical state sand model with elastic–plastic coupling

Soil elastic moduli are highly pressure-dependent. Experimental findings have indicated that the elastic shear modulus of sands depends on p^χ, where p is mean principal effective stress and χ is a non-dimensional parameter. χ practically remains unchanged for shear strains less than 10⁻⁵ where the mechanical behavior is purely elastic. However, experiments have revealed that the emergence of plasticity for shear strains larger than 10⁻⁵ provokes a gradual increase in χ. Technically, this observation is an elastic–plastic coupling effect in which plasticity causes to change the elastic characteristics. Here, this issue is considered in hyper-elasticity framework in conjunction with a critical state compatible bounding surface plasticity platform for granular soils. To this aim, constitutive equations linking χ to a proper kinematic hardening parameter are presented. Then, using the proposed approach, a hyper-elastic theory is modified to consider the mentioned elastic–plastic coupling effect in the whole domain of the elastoplastic behavior. Adopting the improved hyper-elasticity necessitates the modification of a number of basic plasticity platform elements. In this regard, dilatancy and plastic hardening modulus of the bounding surface platform are modified. Successful performance of the modified constitutive model is presented against experimental data of loading/unloading triaxial tests.     

A variational multiscale constitutive model for nanocrystalline materials

This paper presents a variational multi-scale constitutive model in the finite deformation regime capable of capturing the mechanical behavior of nanocrystalline (nc) fcc metals. The nc-material is modeled as a two-phase material consisting of a grain interior phase and a grain boundary effected zone (GBAZ). A rate-independent isotropic porous plasticity model is employed to describe the GBAZ, whereas a crystal-plasticity model which accounts for the transition from partial dislocation to full dislocation mediated plasticity is employed for the grain interior. The constitutive models of both phases are formulated in a small strain framework and extended to finite deformation by use of logarithmic and exponential mappings. Assuming the rule of mixtures, the overall behavior of a given grain is obtained via volume averaging. The scale transition from a single grain to a polycrystal is achieved by Taylor-type homogenization where a log-normal grain size distribution is assumed. It is shown that the proposed model is able to capture the inverse Hall-Petch effect, i.e., loss of strength with grain size refinement. Finally, the predictive capability of the model is validated against experimental results on nanocrystalline copper and nickel.     

On modeling the micro-indentation response of an amorphous polymer

Interest in instrumented indentation experiments as a means to estimate mechanical properties has grown rapidly in recent years. Although numerous nano/micro-indentation experimental studies on polymeric materials have been reported in the literature, a corresponding methodology for extracting material property information from the experimental data does not exist. This situation for polymeric materials exists primarily because baseline numerical analyses of sharp indentation using appropriate large deformation constitutive models for the nonlinear viscoelastic–plastic response of these materials appear not to have been previously reported in the literature. An existing, widely used theory for amorphous polymers (e.g. [Boyce, M., Parks, D., Argon, A.S., 1988. Large inelastic deformation of glassy polymers. Part 1: Rate dependent constitutive model. Mechanics of Materials 7, 15–33; Arruda, E.M., Boyce, M.C., 1993. Evolution of plastic anisotropy in amorphous polymers during finite straining. International Journal of Plasticity 9, 697–720]) has been recently found to lack sufficient richness to enable one to quantitatively reproduce the major features of the indentation load-versus-depth curves for some common amorphous polymers [Gearing, B.P., 2002. Constitutive equations and failure criteria for amorphous polymeric solids. Ph.D. thesis, Massachusetts Institute of Technology].This study develops a new continuum model for the viscoelastic–plastic deformation of amorphous polymeric solids. We have applied the constitutive model to capture salient features of the mechanical response of the amorphous polymeric solid poly(methyl methacrylate) (PMMA) at ambient temperature and stress states under which this material does not exhibit crazing. We have conducted compression-tension strain-controlled experiments, as well as stress-controlled compression-creep experiments, and these experiments are used to calibrate the material parameters in the constitutive model for PMMA.We have implemented our constitutive model in a finite-element computer program, and using this finite-element program we have simulated micro-indentation experiments on PMMA. We show that our constitutive model and finite element simulations reproduce the experimentally-measured indentation load-versus-depth response with reasonable accuracy.     

On the overall moduli of non-linear elastic composite materials

From the work of R. Hill on constitutive macro-variables it is known that for an inhomogeneous elastic solid under finite strain an overall elastic constitutive law may be defined. In particular, the volume average of the strain energy of the solid is a function only of the volume-averaged deformation gradient. In view of the importance of this result it is re-derived in this paper as a prelude to a discussion of composite materials. A composite material consisting of a dilute suspension of initially spherical inclusions embedded in a matrix of different material is considered. For second-order isotropic elasticity theory an expression for the overall bulk modulus of the composite material is obtained in terms of the moduli of the constituents. When the inclusions are vacuous a known result for the bulk modulus of porous materials is recovered. In certain situations the strengthening/ weakening effects of the inclusions are less pronounced in the second-order theory than in the linear theory.     

Rate-dependent quasi-flow corner theory for elastic/visco-plastic materials

A rate-dependent quasi-flow plastic constitutive model with punch-speed sensitivity is proposed for the large-deformation sheet metal forming process, which is based on the quasi-flow corner theory and U–L formulation for the virtual work-rate equation. Three kinds of constitutive theories with strain rate dependence, classical flow theory, deformation theory with rate form obeying non-orthogonality rule, and the present quasi-flow corner theory, are introduced into the U–L finite element formulation to simulate the deformation localization processes of plane strain tension in order to investigate effects of strain rate sensitivity on the localizing deformation characters. Furthermore, three kinds of typical forming processes sheet metals, one being an uniaxial stretching and another being a square cup drawing with circular blank, and third being a deep drawing of an oil pan, actual industrial forming part, are also numerically simulated by the present model and compared with experimental results. Good agreement between numerical simulation and experimental ones exhibits the validity of the quasi-flow corner theory.