共查询到20条相似文献,搜索用时 172 毫秒
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核磁共振成像和核磁共振谱仪是高场超导磁体的主要应用领域.高场超导磁体通常具有较高的磁场和运行电流,在运行过程中超导线会产生较高的电磁应力,其临界特性将发生退化,影响磁体的稳定性.开展高场超导磁体的电磁应力精确分析显得尤为必要.本文发展了一种快速有效的有限元分析方法,第一步,为整个超导磁体系统建立平均有限元模型,采用传统的电磁-结构耦合方法求解电磁应力,获得最大应力位置;第二步,对最大应力所在的超导线圈建立详细有限元模型,采用单积分-结构分析方法精确求解每一组分中电磁应力.基于该模型研究了500 MHz NMR超导磁体的电磁应力.该分析方法也可以用于超导磁体冷却过程中的热应力分析.为高场超导磁体设计和建造提供有益的理论依据. 相似文献
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直到U 元素的离子束都可以从现代重离子加速器上获得,大量的原子和离子光谱容易用束箔方法产生。应用粒子加速器产生的离子束进行实验原子物理学研究,已经成了研究原子结构的重要组成部分之一。随着高分辨谱仪、超导磁体以及激光光源和束箔激发光源的出现和应用,出现了激发态原子的研究。这一研究已经揭示了很多....... 相似文献
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在超导磁约束系统中,超导磁体与射频场、磁场、声场、电场等复合场的兼容耦合是系统稳定运行的关键。探讨了在13.56 MHz频率下的Shoji型天线产生的高频电磁波对超导磁体的影响,高频电磁波会在超导磁体表面产生涡流损耗,进而产生功率损耗并生成热量,导致超导磁体失超。为避免失超现象的发生,在超导磁体室温孔内采用金属屏蔽层进行防护。利用COMSOL软件对整个电磁-射频非线性耦合场进行建模仿真分析,完成了屏蔽层结构的优化选择。基于计算结果,分析讨论了屏蔽层厚度和高度变化对超导磁体上涡流损耗功率的变化影响。通过对超导磁体涡流损耗功率随屏蔽层参数变化进行拟合,最终得到了优化后的屏蔽层参数。 相似文献
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应用NMR技术,其中包括:1H NMR、13C NMR、DEPT、COSY、13C-1H COSY和HMBC,对联萘酚磷酰胺的一对差向异构体的结构进行了研究.对S-R及R-R差向异构体的所有碳氢信号进行了一一归属,并依此考查了差向异构体的构象,分析结果得到了X-ray单晶衍射结果的证实. 相似文献
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Ignazio Licata 《Contemporary Physics》2013,54(4):351-352
It is now possible to obtain informative nuclear magnetic resonance (NMR) spectra from living tissue such as muscle. A discussion is given of the various ways in which NMR can be applied to biological material, and particular emphasis is placed on some recent phosphorus NMR studies of muscle. These studies can provide detailed information about the chemical reactions that are associated with muscular contraction. Mention is made of some of the biochemical and medical applications of NMR that may become feasible in the next few years. 相似文献
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《光谱学快报》2013,46(3):319-342
Abstract The application of nuclear magnetic resonance (NMR) spectroscopy, hyphenated NMR, and diffusion‐ordered spectroscopy (DOSY) to the characterization of mango juice, as an example of a complex food mixture, is described. The compositional changes taking place as a function of ripening were followed, and selected metabolites were quantified by integration of the corresponding NMR peaks. In this way, an overall view of the metabolite changes is obtained, enabling the study of the biochemical mechanisms involved in the ripening process. More than 50 compounds were identified by 1D‐ and 2D‐NMR, but many ambiguous assignments remain due to spectral overlap or insufficient coupling information. The use of Liquid Chromatography (LC‐NMR) and LC‐NMR/Mass Spectrometry (MS) enables a fuller characterization of the soluble pectin fraction to be made; its dependence on ripening stage is discussed. Finally, DOSY adds information on the Mr of many metabolites, including the pectin fractions of ripe and unripe mango juices, and enables further peak assignments to be made. 相似文献
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考察了化学位移各向异性对半整数自旋四极核2D NMR章动的影响.用数值方法对2D NMR章动实验的演化期的Hamiltonian矩阵进行对角化,然后用帐篷法进行粉末平均,获得了自旋为I=3/2、5/2、7/2和9/2的四极核在不同化学位移各向异性下的2D NMR章动谱.实验结果与理论计算符合较好. 相似文献
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Tayler AB Holland DJ Sederman AJ Gladden LF 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,212(1):1-10
Although biomolecular dynamics has been investigated using NMR for at least 40 years, only in the past 20 years have internal motions been characterized at atomic resolution throughout proteins and nucleic acids. This development was made possible by multidimensional heteronuclear NMR approaches that provide near complete sequential signal assignments of uniformly labeled biomolecules. Recent methodological advances have enabled characterization of internal dynamics on timescales ranging from picoseconds to seconds, both in solution and in the solid state. The size, complexity and functional significance of biomolecules investigated by NMR continue to grow, as do the insights that have been obtained about function. In this article I review a number of recent advances that have made such studies possible, and provide a few examples of where NMR either by itself or in combination with other approaches has paved the way to a better understanding of the complex relationship between dynamics and biomolecular function. Finally, I discuss prospects for further advances in this field. 相似文献
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低磁场条件下天然气核磁共振特性的实验研究 总被引:13,自引:3,他引:10
研究天然气在低磁场条件下的核磁共振弛豫特性及含烃因子的变化对天然气的勘探和开发工作具有重要意义,由于受核磁共振仪器耐温、耐压条件的限制,这方面的研究工作非常少,国内还是空白. 本文在一套自行研制的耐高温、耐高压的低磁场(磁场强度0.056T )核磁共振设备上,对我国大庆油田深层天然气的核磁共振特性进行了实验研究,获得了天然气的T1弛豫时间、含烃因子随温度和压力变化的函数关系. 本文的研究内容对我国正在开展的核磁共振测井工作具有重要的参考价值. 相似文献