共查询到20条相似文献,搜索用时 15 毫秒
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利用数学方法解决化学问题是化学及相关专业学生必备的技能之一。作者Daley,H.O.针对这一需要,为大学学习普通化学的学生编写了这本习题集。通过解题学生可以检验自己对化学原理掌握的深浅程度。 相似文献
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Markus Albrecht 《Journal of inclusion phenomena and macrocyclic chemistry》2000,36(2):127-151
Molecular diversity can easily be generated in metallo-supramolecular systems by simple mixing of oligodentate ligands and appropriate metal ions. In this reaction either a defined coordination compound is formed in a selective self-assembly process or a mixture is obtained. Depending on the system such a mixture can possess a statistical distribution of components or the formation of some species is thermodynamically favored leading to only a few out of several possible compounds (or in the extreme to only one). Simple well-defined mixtures containing only a few components or pure supramolecular aggregates can be generated from sequential or directional ligands, from mixtures of ligands and/or metals, and by introducing templates which support the formation of defined metallo-supramolecular aggregates. In the latter case it is possible first to generate a mixture of components which are in dynamic equilibrium (dynamic combinatorial library). In a second step, a template can be added, which in a dynamic process transforms such a library into one well-defined species. Thus, the initial generation of molecular diversity allows in a subsequent selection step in an evolutionary process the formation of the most favored receptor/substrate adduct (``dynamic combinatorial chemistry'). 相似文献
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Michael Mehring Christian LÖW Ioannis Vrasidas Markus SchÜRmann Klaus Jurkschat 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):311-318
Recent results are reported on the application of the novel O,C,O-coordinating pincer ligand {2,6-[P(O)(OEt)2]2-4-tert-Bu-C6H2} (A) for the synthesis of hypercoordinate organotin(IV) compounds ASnR3 (R = Ph, Cl), heteroleptic stannylenes ASnR (R = Cl, CH2SiMe3) and intramolecularly coordinated 1,2,5-oxaphosphastannolanes. 相似文献
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Tetko IV Gasteiger J Todeschini R Mauri A Livingstone D Ertl P Palyulin VA Radchenko EV Zefirov NS Makarenko AS Tanchuk VY Prokopenko VV 《Journal of computer-aided molecular design》2005,19(6):453-463
Internet technology offers an excellent opportunity for the development of tools by the cooperative effort of various groups
and institutions. We have developed a multi-platform software system, Virtual Computational Chemistry Laboratory, http://www.vcclab.org,
allowing the computational chemist to perform a comprehensive series of molecular indices/properties calculations and data
analysis. The implemented software is based on a three-tier architecture that is one of the standard technologies to provide
client-server services on the Internet. The developed software includes several popular programs, including the indices generation
program, DRAGON, a 3D structure generator, CORINA, a program to predict lipophilicity and aqueous solubility of chemicals,
ALOGPS and others. All these programs are running at the host institutes located in five countries over Europe. In this article
we review the main features and statistics of the developed system that can be used as a prototype for academic and industry
models. 相似文献
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Good research data management (RDM) requires a constant endeavour of the researchers but – first and foremost – user-friendly infrastructure and well accepted standards need to be developed for the researchers. The national research data infrastructure initiative for chemistry in Germany NFDI4Chem sets out to embrace the challenge of creating a general research data management portal and hereby connecting already existing infrastructure as well as to foster the cultural change in chemistry towards digitalization by developing general minimum information standards for all methods used and teaching RDM principles to the community. In order to serve the needs of the chemical community at its best, NFDI4Chem accomplishes regular community surveys. The first survey has been performed in 2019 and the results were condensed into the NFDI4Chem proposal. This article summarizes the design of the study and its results. With regard to the project development, this first national survey serves as zero-point of all upcoming efforts in research data management. 相似文献
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Richard Wiley 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(3):563-564
Abstract In the homopolymerization and copolymerization of vinyl acetate with dibutyl maleate in the presence of the sodium salt of sulfosuccinic acid semiester with nonylphenol ethoxylated with 25 mol ethylene oxide, the initiator, potassium persulfate (KPS), has a higher decomposition rate than in water even after consumption of monomer. The value of the initiator productivity, P, defined as the ratio of the formed polymer over the decomposed KPS, decreases as the batch stage of the semicontinuous process proceeds. The initiator reacts either with free surfactant molecules or with those grafted on poly(vinyl acetate) chains. During the stage of continuous addition of monomers and KPS, a smaller initiator concentration no longer provides proportionality between the added and decomposed amounts of initiator. The increased monomer concentration at the beginning of continuous addition causes the rate of KPS splitting to decrease as most of the surfactant is bound to the surface monomer/polymer particles. 相似文献
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István Kapovits József Rábai Dénes Szabó Miklós Kuti 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):435-436
The reactions of possible spiro-λ4-sulfane precursor diaryl sulfoxides with dehydrating agents have been studied resulting in the formation of cyclic anhydride, spiro-λ4-sulfane, cyclic sulfonium-ylide, lactam-sulfoxide, cyclic sulfonimide and cyclic sulfilimine type of intermediates or products. The structures of the intermediates or products depend on the functional groups attached to the aryl rings at ortho positions and on the reaction conditions applied. 相似文献
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《高等学校化学研究》2007,23(3):272-272
Science in China Sero B: Chemistry, a peer-reviewed academic journal, covers the novel and important research results in the basic and applied fields of chemistry, providing a forum for high-level academic communication. 相似文献
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1 Introduction Science China Press Co.,Ltd.(SCP) is a science and technology(ST) journal publishing company of the Chinese Academy of Sciences(CAS).SCP publishes 16 kinds of academic journals,Science China Series and Chinese Science Bulletin,of which 8 journals are in English and 8 in 相似文献
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To assay the antiviral activities on HSV-1 and CVB3 in vitro of the polysaccharide from Eucheuma striatum, its antiviral mechanism was explored. Vero cells were infected by HSV-1 and CVB3, and they were cultured with serial dilutions of polysaccharide. The cells cytotoxicity of Polysaccharide was evaluated by the MTT method. The inhibitory effects were evaluated by the cytopathic effect (CPE). Its antiviral mechanism was researched by the method of giving samples in different time. The polysaccharide could inhibit the CPE of cells infected by HSV-1 and CVB3. It showed low cytotoxicity on vero cells. Its antiviral activities were better than those of acyclovir and ribavirin which were run in parallel as the positive control samples. The polysaccharide from Eucheuma striatum has potent antiviral activities. Its antiviral mechanism is that it can prevent the virus from absorbing to the cell surface. 相似文献
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PinHuaLI LeiWANG MinWANG JinCanYAN 《中国化学快报》2004,15(11):1295-1298
A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields. 相似文献