共查询到20条相似文献,搜索用时 15 毫秒
1.
Sergey N. Podyachev Viktor V. Syakaev Svetlana N. Sudakova Roald R. Shagidullin Darya V. Osyanina Ludmila V. Avvakumova Boris I. Buzykin Shamil K. Latypov Ingmar Bauer Wolf D. Habicher Alexander I. Konovalov 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):55-61
A series of new calix[4]phenols, calix[4]resorcinols and calix[4]pyrogallols with acetylhydrazide substitutes has been␣synthesized
with high yields by hydrazinolysis of ester group containing calix[4]arenes. The synthesized calix[4]phenols adopt the cone
conformation while the calix[4]resorcinol and calix[4]pyrogallol derivatives prefer the boat conformation. The amide fragment
of the hydrazide groups predominantly exists in the trans-conformation. The binding ability of synthesized calix[4]arenes toward transition and alkali metals by solvent extraction
has been investigated. 相似文献
2.
E. M. Kasymova A. R. Burilov N. A. Mukmeneva S. V. Bukharov G. N. Nugumanova A. R. Ibragimova A. P. Timosheva L. Ya. Zakharova L. A. Kudryavtseva M. A. Pudovik A. I. Konovalov 《Russian Chemical Bulletin》2009,58(1):138-144
New amphiphilic benzylated calix[4]resorcinols were synthesized by the reaction of tetra-alkylcalix[4]resorcinols with 3,5-di(tert-butyl)-4-hydroxybenzyl acetate. The reaction pathway and the type of the products formed are determined by the structure of the alkyl substituent at the lower rim of tetraalkylcalix[4]resorcinols and the nature of acid used as a catalyst of the process. Self-organization of some synthesized compounds in nonpolar media was studied. 相似文献
3.
N. I. Shatalova E. L. Gavrilova N. A. Sidorov A. R. Burilovb M. A. Pudovik E. A. Krasil’nikova A. I. Konovalov 《Russian Journal of General Chemistry》2009,79(7):1494-1498
By the Mannich reaction in ternary systems calix[4]resorcinol-amino acid (amino acid ester, amino acid ester hydrochloride)-formaldehyde
calix[4]resorcinols were obtained functionalized on the upper molecule rim by amino acid residues. 相似文献
4.
A reaction of calix[4]resorcinols with 3-ethylamino-2,2-dimethylpropanal and aqueous formaldehyde results in new calix[4]resorcinol
derivatives including aldehyde fragments aminomethylated at the higher rim of the molecule. Depending on the structure of
calixarenes and experimental conditions, products of mono and tetra substitution can be obtained. 相似文献
5.
Irina R. Knyazeva Karina M. Mukhamedyanova Victor V. Syakaev Aidar T. Gubaidullin Wolf D. Habicher Alexander R. Burilov 《Tetrahedron letters》2018,59(17):1683-1685
Novel calix[4]resorcinols containing four triazole fragments on the aromatic substituents of the calixarene framework were synthesized via a one-step condensation of resorcinol and its derivatives with 4-(1-benzyl-1H-[1,2,3]triazol-4-ylmethoxy)benzaldehyde. The macrocyclic products are rctt- and/or rccc-isomers, which were isolated and characterized by NMR and single crystal X-ray diffraction studies. The same products were also prepared via the click-reaction of benzyl azide with previously synthesized calix[4]resorcinols containing four alkyne terminal groups on the aromatic substituents. In this case, only rctt-diastereomers of the corresponding calixarenes were isolated, which is governed by conformational features of the starting macrocycles. 相似文献
6.
Smolobochkin A. V. Anikina E. A. Gazizov A. S. Burilov A. R. Pudovik M. A. 《Russian Journal of General Chemistry》2017,87(9):2107-2110
Russian Journal of General Chemistry - Novel calix[4]resorcinols modified by sulfamide fragments were synthesized via acid-catalyzed opening of the pyrrolidine ring in... 相似文献
7.
Gainanova G. A. Bekmukhametova A. M. Saifutdinova M. N. Gavrilova E. L. Zakharova L. Ya. Sinyashin O. G. 《Russian Chemical Bulletin》2015,64(8):1982-1985
Russian Chemical Bulletin - A spectrophotometric method was used to select conditions for the development of aqueous systems based on new calix[4]resorcinols containing amino acid moieties at the... 相似文献
8.
Smolobochkin A. V. Gazizov A. S. Burilov A. R. Pudovik M. A. 《Russian Chemical Bulletin》2016,65(5):1377-1379
Russian Chemical Bulletin - An acid-catalyzed pyrrolidine ring opening in 2-(2-hydroxynaphthalen-1-yl)pyrrolidine-1-carboxamides in the presence of resorcinols furnished new calix[4]resorcinols or... 相似文献
9.
《Mendeleev Communications》2022,32(1):103-104
Novel first-generation dendrimers on the calix[4]resorcinol core with four branches each containing multiple 1,2,3-triazole units have been synthesized in one-step by acid catalyzed condensation of resorcinols with a new aldehyde dendron, namely, 4-{3,5-bis[(1-benzyl-1H-1,2,3-triazol-4-yl)- methoxy]benzyloxy}benzaldehyde (obtained by alkyne–azide cycloaddition). The reaction proceeds stereoselectively to form rccc-diastereoisomers in high yields. 相似文献
10.
V. V. Yanilkin A. R. Mustafina A. S. Stepanov N. V. Nastapova G. R. Nasybullina A. Yu. Ziganshina S. E. Solovieva A. I. Konovalov 《Russian Journal of Electrochemistry》2011,47(10):1082-1090
The results of authors on designing electroswitchable supramolecular systems based on calix[4]arenes, calix[4]resorcinols,
and transition metal ions and complexes are summarized. We consider systems in which the switching is performed owing to electrochemical
reactions both of groups grafted to the macrocycle and bound substrates. Examples of electrochemically switchable luminescence
are given. 相似文献
11.
Irina R. Knyazeva Victoria I. Sokolova Margit Gruner Wolf D. Habicher Julia K. Voronina Alexander R. Burilov Michael A. Pudovik 《Journal of inclusion phenomena and macrocyclic chemistry》2013,76(1-2):231-235
We have synthesized novel calix[4]resorcinols with four 2-thioxo-1,3,2-dioxaphospholane groups introduced in aromatic substituents in the methylidene bridges of macromolecules by the condensation of new thiophosphorylated benzaldehyde with resorcinol and its derivatives in acidic media with high yields. The formation of only one rctt isomer with corresponding chair conformation is observed, which was determined by 2D NMR-experiments. 相似文献
12.
A. R. Burilov L. I. Vagapova M. A. Pudovik T. N. Pashirova I. S. Ryzhkina L. A. Kudryavtseva A. P. Timosheva W. D. Habicher A. I. Konovalov 《Russian Chemical Bulletin》2006,55(5):920-924
Reactions of calixarenes with methylaminoacetaldehyde dimethyl acetal and formalin gave Mannich bases with the calixarene
platform. It was found by dielcometric titration that calix[4]resorcinols with acetal groups in the aminomethyl fragment form
head-to-head supra-molecular aggregates in chloroform at low concentrations.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 888–891, May, 2006. 相似文献
13.
M. S. Khakimov A. S. Gazizov A. R. Burilov M. A. Pudovik A. I. Konovalov 《Russian Journal of General Chemistry》2009,79(6):1163-1166
Reaction of 2-methylresorcinol and pyrogallol with urea acetals of various structures was studied. Depending on the structure of the acetal used, reaction was established to result in eiter calix[4]resorcinols containing urea fragment or in imidazolidin-2-one derivatives. 相似文献
14.
HAN Ying SUN Juanjuan WANG Genliang YAN Chaoguo 《高等学校化学研究》2014,30(6):919-924
A series of calix[4]pyrrole meso-substituted Schiff bases was synthesized with 5α,10α-di(4- hydroxylphenyl)calix[4]pyrrole or 5α,15β-di(4-hydroxylphenyl)calix[4]pyrrole as starting materials. The synthetic routes included alkylation with methyl a-chlroroaceate, ammonolysis with alkylene diamine, and condensation with salieylladehyde or 2-hydroxynaphthaldehyde. The crystal structures of the new calix[4]pyrroles and their Schiff bases were determined by X-ray diffraction. The coordination properties of the representative ealix[4]pyrrole Sehiff bases to transition metal ions were also investigated by UV-Vis spectra. 相似文献
15.
The reactions of 2-tributylphosphonioacetaldehyde acetal with resorcinol and 2-methylresorcinol in an acidic aqueous-ethanol medium afford calix[4]resorcinols containing four tributylphosphonium groups at the lower rim. The corresponding reactions of the triphenylphosphonium analog give phosphonium salts containing the 2,2-diarylethyl moiety. 相似文献
16.
Bahram Mokhtari Kobra Pourabdollah 《Journal of inclusion phenomena and macrocyclic chemistry》2013,77(1-4):23-31
Calix[4]pyrrole is one such class which holds a great promise in the fields of sensors and their unique behavior as sensors owes to its structural flexibility. Anion binding ability of calix[4]pyrrole has been modified in a variety of ways. Introduction of electron releasing and electron withdrawing groups at the meso position or at β-pyrrolic positions leads to calix[4]pyrrole with deep cavities and fixed walls which shows increased selectivity and modified binding effects. Strapping of calix[4]pyrrole is another way to modify its structural behavior which is responsible for its binding behavior. Choice of strap could play a profound role not only in increasing the intrinsic anion binding affinity of calix[4] pyrrole, but also in modulating the receptor anion stoichiometry, thereby modifying potentially the inherent anion binding selectivity. Calix[n]pyrroles with extended cavities have also been synthesized. Such as calix[3]bipyrrole binds bromide substantially with high affinity than calix[4]pyrrole. Calix[4]pyrrole has also been used to produce anion sensors that can report the presence of anion by means of a color change. The medium effect on the complexation of calix[4]pyrrole and anion has been investigated in various solvents. Calix[4]pyrrole has also been used to increase the ionic conductivity of solid polymer electrolyte by anion complexation of the metal salt. Calix[4]pyrrole has been used to obtain optical sensors using surface plasmon resonance technique. Composite films of cellulose acetate containing calix[4]pyrrole has also been reported which has potential usage in packaging, storage and preservation. In nut shell, calix[4]pyrrole can be modified in a variety of ways to form versatile sensors which can be used in variety of ways in various areas. 相似文献
17.
V. V. Khrizanforova I. R. Knyazeva I. R. Nizamiev T. V. Gryaznova V. I. Sokolova S. A. Krasnov M. K. Kadirov A. R. Burilov Yu. G. Budnikova O. G. Sinyashin 《Russian Journal of General Chemistry》2013,83(4):663-669
Nickel complexes of 1:1 composition with calix[4]resorcinols (L) modified with thiophosphyl fragments were synthesized. In the process of electrochemical reduction these complexes are capable of providing spherical homogeneous Ni(0)L particles with a narrow size distribution, stable both on the electrode and in the solution. The redox properties of the metal complexes were studied. The dimensions of the complexes obtained were estimated using the atomic force microscope (AFM) equipped with an electrochemical attachment. 相似文献
18.
A novel protection/deprotection method leading to the regioselective ipso-substitution of calix[4]arenes is described. The introduction of nosyl (p-nitrobenzenesulfonyl) groups into the lower rim of partly alkylated tert-butylcalix[4]arenes leads subsequently to the exclusive ipso-nitration of the alkylated phenol rings, while the protecting groups can be easily removed in the next step. This method gives dialkoxy- or trialkoxy-substituted calix[4]arenes with nitro groups on the alkylated rings and tert-butyl groups on the remaining ones. The above substitution pattern is complementary to the isomers so far known in the chemistry of calix[4]arenes and could be used in the design of novel type of calixarene-based receptors. 相似文献
19.
Wong MS Xia PF Zhang XL Lo PK Cheng YK Yeung KT Guo X Shuang S 《The Journal of organic chemistry》2005,70(7):2816-2819
[reaction: see text] A facile and efficient protocol for the synthesis of oligophenylene OPP(n)-substituted calix[4]arenes (with n up to 4) via iodo-substituted oligoarylcalix[4]arenes has been developed. The cooperation effect of the proximate fluoroionophores in hexylsulfanyl end-capped OPP(n)-substituted calix[4]arene assemblies leads to metal ion binding enhancement. 相似文献
20.
Gaeta C Vysotsky MO Bogdan A Böhmer V 《Journal of the American Chemical Society》2005,127(38):13136-13137
Tetraurea calix[4]arenes with four loops form exclusively heterodimers with open-chain urea calix[4]arenes when they are dissolved in aprotic solvents. These assemblies can be considered as pseudorotaxanes. If open-chain tetraureas ending with maleic imide functions are used, their Diels-Alder reaction with 1,4,5,8-tetrapentoxyanthracene leads to tetra[2]rotaxanes which cannot be split into the single calixarene parts by hydrogen bond breaking solvents. 相似文献