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1.
The cross-section for the~(93)Nb(n,2n)~(92g)Nb reaction has been measured at the neutron energy of 14.6 Me V using neutron activation and accelerator mass spectrometry(AMS)determination of the long-lived product nuclide~(92g)Nb.The neutron energy was generated from the D+T neutron source at the China Institute of Atomic Energy(CIAE).The neutron flux was monitored by measuring the activity of~(92m)Nb produced in the competing reaction channel of~(93)Nb(n,2n)~(92m)Nb.At the neutron energy of 14.6 MeV,the~(93)Nb(n,2n)~(92g)Nb reaction cross-section of(736±220)mb was obtained for the first time.  相似文献   

2.
The 93Nb(p, d)92Nb reaction was studied at a proton energy of 26.3 MeV. Angular distributions were obtained for outgoing deuterons to 37 states in 92Nb up to an excitation energy of 4.2 MeV. The results were compared with DWBA calculations to extract l-values and spectroscopic factors. Fourteen previously unobserved l = 1 transitions were measured.  相似文献   

3.
用能量为80MeV的19F束通过反应76Ge(19F,5n)90Nb布居了90Nb的高自旋态.通过在束γ测量分析90Nb退激γ射线的符合级联关系,发现了19条新的属于90Nb的γ跃迁,建立了90Nb的高自旋态能级纲图.通过经验壳模型计算指定了部分能级的组态,并结合实验DCO比值和与相邻N=49核素的系统比较,确认了新能级的自旋和宇称. The high spin states of~(90)Nb have been populated via reaction~(76)Ge(~(19)F, 5n)~(90)Nb at beam energy of 80 MeV. The de-exciting γ-rays have been measured with in-beam γ-ray spectroscopy method. After γ-γ coincidence analysis, 19 new γ transitions were identified and assigned to~(90)Nb. The new level scheme of~(90)Nb was established. Based on the semi-empirical shell model calculations, the configurations of the levels have been suggested. In addition, the spins and parities of the new levels ...  相似文献   

4.
运用密度泛函方法在(U)B3LYP/Lan L2DZ水平上对Nb_2Ge_n(n=1~4)团簇进行了系统的理论研究,得到Nb_2Ge_n(n=1~4)团簇的最低能结构的几何构型和电子性质.优化结果表明:Nb_2Ge_n(n=1~4)团簇最低能结构的自旋多重度均为单重态.团簇最低能结构的电子态与团簇的大小有关.当n为奇数时,团簇的电子态为~1A~1,n为偶数时电子态为1A.通过对计算平均束缚能和分裂能发现:Nb_2Ge_n(n=1~4)团簇中热力学稳定性最强的是Nb_2Ge_2团簇;最弱的是Nb_2Ge_4团簇.自然电荷分布的结果说明Nb_2Ge_n(n=1~4)团簇中当n=1-2时,电子转移正常,而当n=3-4时出现电荷反转现象.同时还研究了HOMOLUMO能隙、磁性和红外光谱.  相似文献   

5.
Introduction

Among the products of irradiation of natural molýbdenum by deuterons with energies up to 13 MeV, by means γ and X-ray speclrometry were identified these radlonudldes: 99Nb, 92mNb, 95m+gNb 96Nb, 99Mo, 101Mo, 92Tc, 93m+gTc, 94m+g^>Tc, 95m+gTc, 96Tc, 97mTc, 99mTc,101Tc, and 89Zr. With the more intensive lines of γ transitions of 90Nb, 96Nb, 93m+gTc, 94m+gTc, 95m+gTc, 99Tc and 97mTc accurate photon energies have been established and for the lines 1475.7 and 1520.5 keV of 93Tc, 820.2 keV of 95mTc, and 96.4 keV of 97mTc also the absolute intensities of the emitted γ were determined. By means of aluminium foils, by which the set of Mo foils had been interlaid, the atomic recoil in forward and backward direction ivas established for the 17.82 mg/cm2 Mo foils and deuteron energy up to 12.7 MeV and the ion current of 3.4 μA.  相似文献   

6.
The reactions93Nb(p, p)93Nb,93Nb(p, n)93Mo, and93Nb(p, p′) through isobaric analog resonances in94Mo have been used to study the structure of low-lying93Nb states, specifically the degree to which these states can be described as single protons coupled to the core states of92Zr. Excitation curves were obtained from 5.8 to 7.6 MeV incident proton energy, for eight states in93Nb. Results of this work are compared to results from Coulomb excitation studies,93Nb(n, n′γ),93Nb(d,p),92Zr(3He,d),94Mo(d,3He) and other related work.  相似文献   

7.
对A?<10?0核质量区内的核素,研究中子辐射俘获反应中不同反应机制对辐射俘获截面的贡献随靶核质量数和中子入射能量变化的规律.所考虑的反应机制有复合核统计过程和复合核弹性散射道中的辐射俘获及形状弹性散射道中的直接–半直接辐射俘获两种非统计过程.在中子入射能量0.1—20MeV区间,给出了27Al,40Ca,63Cu和93Nb的理论计算结果及与实验数据的比较,并对呈现的变化规律进行了分析讨论  相似文献   

8.
〗采用磁控溅射技术在Si衬底上沉积Si/\[Fe(10 nm)/Nb(4 nm)/Fe(4 nm)/Nb(4 nm)\]2/ \[Fe(4 nm)/Nb(4 nm)\]4多层膜。 用2 MeV的 Xe离子在室温下辐照多层膜。采用俄歇深度剖析、X射线衍射和振动样品磁强计分析辐照引起的多层膜元素分布、 结构及磁性变化。AES深度剖析谱显示当辐照注量达到1.0×1014 ions/cm2时, 多层膜界面两侧元素开始混合; 当辐照注量达到2.0×1016ions/cm2时, 多层膜层状结构消失, Fe层与Nb层几乎完全混合。XRD谱显示, 当辐照注量达到1.0×1014ions/cm2时, Nb的衍射峰和Fe的各衍射峰的峰位相对于标准卡片向小角方向偏移, 这说明辐照引起Nb基和Fe基FeNb固溶体相的形成;当辐照注量大于1.0×1015 ions/cm2时, 辐照引起非晶相的出现。 VSM测试显示,多层膜的磁性随着结构的变化而变化。 在此实验基础上, 对离子辐照引起界面混合现象的机理进行了探讨。The behavior of the metallic multilayers of Si/\[Fe(10 nm)/Nb(4 nm)/Fe(4 nm)/ Nb(4 nm)\]2/\[Fe(4 nm)/Nb(4 nm)\]4 under 2 MeV Xe ion irradiation has been investigated by depth profile analysis of Auger electron spectroscopy,X ray diffraction and vibrating sample magnetometer. The obtained experimental results show that the inter mixing between Fe and Nb layers occurs in the 1.0×1014 ions/cm2 irradiated multilayer sample which results in the formation of Nb based and Fe based FeNb solid solution. For the samples irradiated to fluence larger than 1.0×1014 ions/cm2, amorphisation is observed, and moreover, the layered structure of the multilayer samples is broken up completely for the samples under 1.0×1016 or 2.0×1016 ions/cm2 irradiation. Vibrating sample magnetometer measurement also reveals that the magnetization of the samples changes with the evolution of the structure of multilayers. Possible mechanism of the modification in Fe/Nb multilayers induced by Xe ion irradiation is briefly discussed.  相似文献   

9.
93Nb solid-state NMR spectra of a series of inorganic niobates with Nb in different oxygen coordination environments were measured. For all studied compounds the chemical shielding and quadrupole tensor parameters were determined using conventional and ultrahigh field NMR facilities, ultrahigh speed MAS, DQ STMAS, solid-echo and computer modeling. It has been demonstrated that the 93Nb isotropic chemical shift is sensitive to the coordination number of Nb sites. For the first time the 93Nb NMR chemical shift scale for NbOx polyhedra in solid materials has been proposed: for four-coordinated Nb sites, the isotropic shifts occur from −650 to −950 ppm; five-coordinated Nb sites have the isotropic shifts in the range of –900 to –980 ppm; for six-coordinated Nb sites the isotropic shifts vary from −900 to −1360 ppm; the shifts from −1200 to −1600 ppm are typical for seven-coordinated Nb sites; for eight-coordinated Nb sites the shifts are higher than −1400 ppm. The possible correlation between the value of the isotropic chemical shift and the ionic character of the NbOx–MOy polyhedra association has been suggested. The magnitude of the 93Nb quadrupole coupling constant depends on the local symmetry of Nb sites and may vary from hundreds of kHz to hundreds of MHz.  相似文献   

10.
Energy levels of 93Mo have been investigated by means of the 93Nb(p, nγ)93Mo reaction. The excitation functions of the level de-excitation γ-rays were measured with a Ge(Li) detector under proton bombardment in the energy range 3.0 to 5.0 Me V. A detailed γ-ray decay scheme which includes 69 levels and 123 γ-ray lines was constructed from the threshold energies for 64 γ-rays and the γ-ray excitation functions around five isobaric analogue resonances in the 93Nb(p, nγ) reaction. Spin-parity values for 59 levels and favourable values for 8 levels were assigned from the analysis of relative neutron yields via the isobaric analogue resonances of the parent odd-odd nucleus 94Nb. The results of the present experiment are compared with shell-model calculations.  相似文献   

11.
对149Sm(27Al, 4n)172Re反应产生的172Re在束γ的实验数据进行了重新分析, 新发现了可归属于172Re的3个转动带, 由此建立了由6个转动带构成的172Re高自旋态能级纲图。依据相邻核的带结构知识和推转壳模型分析方法, 对新发现的3个转动带的准粒子组态进行了指定, 讨论了它们的转动特征。We have re analyzed the experimental data of in beam γ spectroscopy for 172Re via the 149Sm(27Al, 4n)172Re reaction. Three rotational bands have been newly found and assigned to 172Re. A new level scheme of 172Re, consisting of 6 bands, is thus presented. Based on the existing knowlegde from the neighboring nuclei and the cranked shell model, the quasiparticle configurtions have been assigned to the 3 newly observed bands and their structure properties have been dicussed.  相似文献   

12.
利用活化方法测量了14MeV中子引起的Pb(n,x)203Hg,W(n,x)182Ta和W(n,x)183Ta的反应截面.中子注量由监督反应93Nb(n,2n)92mNb给出,中子能量利用90Zr(n,2n)89m+gZr和93Nb(n,2n)92mNb反应的截面比来确定.  相似文献   

13.
The γ-decays of the energy levels of 92Nb and 94Tc were measured following the 92Zr(p, n)92Nb and 94Mo(p, n)94Tc reactions. For 92Nb the γ-ray thresholds were measured and a detailed excitation function was obtained near the 93Zr ground-state isobaric analog resonance. Also, γ-γ coincidence measurements with two Ge(Li) detectors were made for both 92Nb and 94Tc. The coincidence measurements determined ten energy levels in 92Nb and two levels in 94Tc. A comparison with particle transfer reactions is used to elucidate the structure of 92Nb levels observed here but not seen in the transfer reactions.  相似文献   

14.
First-principle calculations within the density functional theory framework are used to study the probability of electron capture for the ~7Be nucleus.For this purpose,electron density at the ~7Be nucleus is computed in Al,Au,Pd,Pt,and Pb environments.Our results show that the half-life of ~7Be is changed by implanting ~7Be in host environments.Electron affinity of the media and confinement effects are responsible for the change in the half-life of ~7Be nucleus.Moreover,electric potential at the ~7Be nucleus is calculated.Results show that variations in electric potential are usually consistent with those in electron density at the ~7Be nucleus.  相似文献   

15.
Cross sections for some (n,d*),(n,t) and (n,n'α)reactions have been measured by using the activation method relative to cross sections of 27Al(n,α)24Na or 93Nb(n,2n)92mNb reactions in neutron energies around 14MeV.In this paper some of the published cross section data have also been listed and compared with our results.The neutron energies were determined by the method of cross section ratios for the reactions of 90Zr(n,2n) 89m+gZr and 93Nb(n,2n)92mNb.  相似文献   

16.
The spectra of 8Begs fragments emitted in the interaction of 100, 200, 300 and 400 MeV 12C with 59Co, 93Nb and 197Au have been measured and analysed. Our analysis suggests that, before breaking up, 12C may suffer a considerable energy loss which increases with increasing incident energy. The amount of excitation energy provided to the target nucleus in this process increases with decreasing charge of the target nucleus. Received: 3 May 2001 / Accepted: 5 June 2001  相似文献   

17.
The pre-equilibrium exciton model of nuclear reactions is extended to include gamma emission. Possible types of gamma transitions are considered for which densities of final accessible states are derived. The computed gamma spectra in the reaction (n, γ) with En = 14.1 MeV on 93Nb and 139La are compared with experiment.  相似文献   

18.
基于Ru (Z = 44) 丰中子同位素中存在最大三轴形变的理论预言和实验证据,综述了近年来Rh (Z = 45),Pd (Z =46), Ag (Z =47), Cd (Z =48)(质子数Z 位于Ru,Z =44 之上)及Zr (Z =40), Nb (Z =41), Mo (Z =42),Tc (Z =43)(质子数Z 位于Ru,Z =44 之下) 的A~ (100~126) 丰中子同位素中关于三轴形变的形状变迁和形状共存系统性研究的重要进展。252Cf 自发裂变瞬发 射线-- 三重符合、特别是新建立的--- 四重符合数据的系统观测和研究,在Ru, Pd, Cd 和Nb 丰中子同位素中显著扩展或首次观测到了一系列能带,为这个核区原子核形状的研究提供了新的、重要的实验数据。联系此前报道的有关进展,使用PES, TRS, PSM, CCCSM 和SCTAC 理论模型计算拟合新的实验数据,在该核区沿同中素和同位素链,并随自旋和激发能变化各自由度,跟踪原子核形状渐进变化,获得了新的系统性研究成果,显著扩展和深化了人们对原子核形状变迁和形状共存的认知。对于Ru 及其上的Rh (Z = 45), Pd (Z = 46), Ag (Z = 47) 和Cd (Z = 48) 丰中子同位素的研究表明:Rh 丰中子核具有比最大值稍小的三轴形变,γ = 28°,并在103{106Rh 同位素链上鉴别出了手征对称破缺;在三轴形变核112Ru和114Pd(N = 68)中发现了三轴原子核的摆动运动,该摆动运动也可能在114Ru (N = 70)中存在;观察到了从具有最大三轴形变的110,112Ru 中手征破缺到稍小三轴形变的112,114,116Pd 中扰动的手征破缺的过渡;在较软的Ag 核中观察到了丰富的谱学结构,在104,105Ag 中鉴别出了可能的手征对称破缺,在较重的115,117Ag 中提出了趋于三轴形变的软度;具有小形变的Cd核的能级结构被解释为准粒子耦合、准转动和软三轴形变;最近的库伦激发的研究提供了Z = 50, N = 82满壳附近122,124,126Cd 核中出现核集体性的实验和理论证据;上述研究成果展现出从Ru中的最大三轴形变(γ=30°,三轴形变极小增益为0.67 MeV), 经具有大三轴形变的Rh核γ=28°),到Pd核中的稍小、但稳定于中等自旋到高自旋区的三轴形变(γ~41°,三轴形变极小增益为0.32 MeV),再经Ag核中的软度,最后到具有很小形变、但仍出现集体性质、包括软三轴形变的Cd核的过渡。对于Pd核转动带交叉系统性的研究揭示了其第一带交叉(νh11/2)2 中子转动顺排的上行驱动,和第二带交叉(πg9/2)2质子转动顺排的下行驱动效应,成功地解释了114Pd 中的三轴摆动运动,并给出了110-118Pd同位素链中理论早已预言、而比早期理论预言更为完整准确的形状渐进变迁和形状共存的图像。根据该核区的系统研究,发现最大三轴形变出现在112Ru,而在相邻的偶Z(Pd)同位素链,三轴形变极小的中心在114Pd, 两者均为N = 68。上述系统性研究沿相邻的Ru和Pd偶Z同位素链,在N =68同中素中鉴别出最大三轴形变,均比理论预言的108Ru 和110Pd 多4个中子。在Z值位于Ru (Z = 44) 之下的Zr (Z = 40), Nb (Z = 41), Mo (Z = 42) and Tc (Z = 43) 丰中子同位素中,Y和Zr核具有很强的轴对称四极形变,而在较重的Zr同位素中出现了自由度;较重的Nb核(A = 104~106) 基态具有中等程度的软三轴形变和强四极形变,随着自旋和激发能的增加,过渡到接近于轴对称的强四极形变;而较轻的Nb核(A≤103) 基态均接近轴对称形状;在Nb同位素链上基态由球形到强四极形变的形状突变发生在100Nb(N = 59),在100-106Nb同位素链中基态的软三轴形变随中子数增加而增加;在Nb核中还观察到关于软三轴形变的形状共存;Mo核具有大的三轴形变,观察到了振动和手征对称破缺;Tc核具有比最大值稍小的三轴形变,γ=26°,并观察到了手征对称破缺。质子数Z从41到48的A~(100~126)丰中子同位素,特别是Pd和Nb 同位素,呈现出关于三轴形变的过渡特征。This paper reviews the systematic investigations and understanding for the shape transitions and coexistence with regard to triaxial deformations in A s 100 to 126 neutron-rich Rh (Z = 45), Pd (Z = 46), Ag (Z = 47), Cd (Z = 48) and Zr (Z = 40), Nb (Z = 41), Mo (Z = 42), Tc (Z = 43) isotopes with Z beyond and below Ru (Z = 44), respectively, in Ru the maximal triaxial deformation having been predicted and deduced. The recent measurements and studies of prompt triple- and four-fold, γ-γ-γ and γ-γ-γ-γ, coincidence data from the spontaneous fission of 252Cf using Gammasphere have yielded considerable expansion and extension or first observation of the bands in Ru, Pd, Cd, and Nb isotopes,which provided important data for the studies of nuclear shapes in this region. Combined with previous investigations, recent systematic studies of the new data well reproduced by PES, TRS, PSM, CCCSM and SCTAC model calculations have traced shape changes along the isotonic and isotopic chains, respectively,and with changing excitations/spins as well, significantly expanding our knowledge of shape transitions/coexistence in nuclei.For the neutron-rich Ru and beyond, Rh, Pd, Ag and Cd isotopes, triaxial deformations γ= 28°,slightly smaller than the maximal value, were deduced in Rh (Z = 45) isotopes, with chiral symmetry breaking proposed in 103-106Rh; onset of wobbling motions were identified in 112Ru and 114Pd (N =68),and probably also in 114Ru (N =70); evolution from chiral symmetry breaking in 110,112Ru with maximal triaxial deformations to disturbed chirality in 112,114,116Pd with less pronounced triaxial deformations was proposed; rich nuclear structure was proposed in soft Ag isotopes with possible chiral doubling structure suggested in 104,105Ag, and softness towards triaxial deformation proposed in heavier 115,117Ag;quasi-particle couplings, quasi-rotations and soft triaxiality were suggested in Cd (Z =48) isotopes with small deformations; onset of collectivity was recently suggested in 122,124,126Cd in the vicinity of Z =50 and N = 82 closed shells by studies of Coulomb excitations; shape evolutions from maximal triaxial deformations in Ru (γ=30°, with triaxial minimum energy gain of 0.67 MeV), through Rh with large triaxial deformations ( γ=28°), to less pronounced triaxiality in Pd (with triaxial minimum energy gain of 0.32 MeV), then soft triaxiality in Ag, and finally to slightly deformed Cd isotopes but with emergence of collectivity and soft triaxiality were proposed. The systematic studies of the band crossings in Pd revealed up-rising drivings of the first band crossings caused by (νh11/2)2 and down-sloping drivings of the second band crossings by (πg9/2)2, explained the onset of wobbling motions in 114Pd,and showed a long-sought picture of shape evolution and coexistence in the Pd isotopic chain which is more complete but complex than earlier predictions. Based on the systematic studies in the mass region,maximal triaxial deformation is found to be reached in 112Ru and less-pronounced triaxiality centered at 114Pd, both for N =68, four neutrons more than predicted in earlier theoretical calculations.In the neutron-rich Zr (Z =40), Nb (Z =41), Mo (Z =42) and Tc (Z =43) isotopes with Z just below Ru, large quadrupole deformations of axially symmetric shapes were deduced in Y and Zr isotopes, with emergence of the degree of freedom having been suggested for heavier Zr isotopes; medium triaxial deformations were deduced for the ground states of heavier (A > 104) Nb isotopes, and, with increasing excitations and spins, evolution from medium triaxial deformations with strong quadrupole deformations at ground states to nearly axially-symmetric shapes were deduced; light Nb isotopes (A6103) have near axially-symmetric shapes with strong quadrupole deformations; combining with the identification of onset of strong quadrupole deformation at 100Nb in the Nb isotopic chain, an increase of soft triaxiality with increasing neutron number was proposed in 100-106Nb. Shape coexistence with regard to soft triaxiality is also proposed in Nb isotopes; large triaxial deformations, vibrations and chiral doublets were proposed in Mo isotopes; chiral doubling and large triaxial deformations (γ ~26°) slightly smaller than the maximal triaxiality were suggested in Tc isotopes.The neutron-rich nuclei with Z ranging from 41 through 48 and A ~100 to 126, especially the Pd and Nb isotopes are thus found to be transitional nuclei with regard to triaxiality.  相似文献   

19.
The satellite-transition MAS (STMAS) experiment offers an alternative approach to established methods such as dynamic angle spinning (DAS), double rotation (DOR), and multiple-quantum MAS (MQMAS) for obtaining high-resolution NMR spectra of half-integer quadrupolar nuclei. Unlike the multiple-quantum experiment, STMAS involves two-dimensional correlation of purely single-quantum coherences; satellite transitions in t(1) (or F(1)) and the central transition in t(2) (or F(2)). To date, STMAS has primarily been demonstrated for nuclei with spin quantum numbers I = 3/2 and, to a lesser extent, I > 5/2. However, many chemically relevant nuclei possess I > 3/2, such as (17)O and (27)Al (both I = 5/2), (59)Co (I = 7/2), and (93)Nb (I = 9/2). Here, we discuss the application of STMAS to nuclei with spin quantum numbers from I = 3/2 to 9/2. First, we consider the practical implementation of the STMAS experiment using (87)Rb (I = 3/2) NMR as an example. We then extend the discussion to include nuclei with higher spin quantum numbers, demonstrating (27)Al, (45)Sc (I = 7/2), (59)Co, and (93)Nb STMAS experiments on both crystalline and amorphous samples. We also consider the possibility of experiments involving satellite transitions other than m(I) = +/- 1/2 <--> +/- 3/2 and, using (93)Nb NMR, demonstrate the correlation of all single-quantum satellite transitions up to and including m(I) = +/- 7/2 <--> +/- 9/2. The absolute chemical shift scaling factors in these experiments are discussed, as are the implications for isotropic resolution.  相似文献   

20.
High-spin states in nucleus (~139)Pm have been studied using the reaction ~(116)Cd(~(27)Al, 4n)~(139)Pm. Two dipole cascades have been found. Spin and parity assignments were based on the Directional Correlation of Oriented Nuclei (DCO) ratios and systematic behavior in neighboring odd-proton nuclei. The level structures of ~(139)pm are compared with those of the N = 78 isotone ~(141)Eu in which two dipole bands have been confirmed as magnetic rotational bands. The close similarity between them suggests that the dipole bands in ~(139)Pm may be magnetic rotational bands.  相似文献   

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