On singularities of electronic state density in liquid metals and disordered metallic alloys

We have performed a qualitative consideration of the problem of structurally dependent singularities of the density of electronic states,N(E), in disordered metallic systems: liquids, glasses and alloys. The appearance of Kohn anomalies atq ₀2K _F (q ₀ being the maximum position of the structure factorS(q);K _F , the Fermi momentum) in thermodynamic properties of liquid and amorphous metals is analyzed. It has been shown that the appearance of these contributions is due to the presence of a diffuse (inelastic) part ofS(q) and that they are no analogs of the Van Hove singularities (VHS) in crystals. The corollary of the hypothesis about the quasicrystalline structure of liquids, i.e. the appearance of blurred VHS's inN(E), is treated. A strict solution of the problem of the Gaussian static disorder effect on the VHS in crystalline alloys is presented. A new energy scale in the relaxation time and, consequently, in kinetic coefficients has been revealed.     

Magnetic and electrical investigations of Fe<Subscript>85-x</Subscript>Co<Subscript>x</Subscript>B<Subscript>15</Subscript> metallic glasses

The magnetic and electrical properties of metallic glasses with the general formula Fe_85-xCo_xB₁₅ were investigated over a large temperature range to study their concentration-dependent physical parameters. All of the samples investigated (x=17,21,30, and 40) were soft ferromagnets with coercive fields H_c1 Oe and high Curie temperatures slightly above 1200 K. The temperature-dependent magnetization behaved irregularly, and exhibited hysteresis during heating and subsequent cooling through the Curie temperature. The variation of the magnetization with temperature demonstrates that one or more phase transformations (crystallization) occurred in the course of the heating. The electrical resistivities exhibited positive temperature coefficients and minima at temperatures below 50 K. We did not observe a nonmonotonic variation of the magnetic and electrical properties with a monotonic change of the Fe_85-xCo_xB₁₅ composition that would correlate with the earlier proposed formation of strong nanoclusters in the vicinity of particular stoichiometrically close Fe:Co ratios. The good soft magnetic characteristics make the Fe_85-xCo_xB₁₅ metal glasses promising candidates for engineering materials in inductive applications. PACS 71.23.Cq; 75.75.+a     

Non-uniqueness of the heat-current operator and the hopping thermoelectric and thermomagnetic phenomena

The Hardy's corrections to the Maradudin's lattice part of the total heat current operator are shown to yield no corrections to the hopping thermoelectric coefficients of amorphous solids and glasses in the lowest (minus-first) order of the electron phonon coupling constant. But even after including the magnetic field (0, 0,), the lowest non-zero (zeroth order) contributions to the Peltier and Seebeck tensors are shown to be diagonal, yielding thus no contribution to the Nernst and Ettingshaussen coefficients. Therefore, the Hardy corrections, which might yield the next (first) order contributions to these coefficients, appear to be crucial for treating the thermomagnetic phenomena in amorphous and glassy materials.     

An unambiguous procedure for discovering relaxation influence on Mössbauer spectra

A mathematical procedure which gives an opportunity to distinguish between relaxation and distribution mechanisms of the Mössbauer line broadening is proposed. It is based on the method of Mössbauer line sharpening developed recently [1] and allows one to answer unambiguously the question whether or not relaxation manifests itself in Mössbauer measurements by examining the wings of the spectrum. The procedure is applied to the spectra of high spin ferric metmyoglobin and (Fe_0.65Ni_0.35)_1–x Mn _x alloys. Analysis of the metmyoglobin spectra manifests the presence of the relaxation influence in the temperature range 10 KT100 K. Analysis of the alloy spectra shows that for the temperatures 4 KT300 K and Mn concentrations 0x0.245 no relaxation is observed and the line broadening is mainly caused by the distributions of magnetic hyperfine fields. A possible explanation of this result is given.     

Effect of pressure on the Curie temperature of annealed Fe-Ni-Cr-Mo-Si-B amorphous alloys

Effect of high pressure on the Curie temperature of annealed Fe₃₀Ni3₆Cr₁₂Mo₂Si₅B₁₅ amorphous alloys has been investigated. It has been shown that the annealed samples e hibit a smaller pressure dependence ofT _c than as-quenched one.Dedicated to Dr. S. Krupika on the occasion of his 65th birthday.We would like to thank Dr. P. Duhaj (Institute of Physics, Slovak Academy of Sciences, Bratislava) for the preparation of amorphous samples and Mrs. H. Kuchárska for technical assistance.     

Theory of molecular motion in liquids and glasses over broad temperature and pressure ranges

An equation for the molecular relaxation time in molten glasses is derived on the basis of hole theory. This equation is a generalization of the familiar equations of Frenkel', Shishkin, Jenckel, et al. The effects of temperature and pressure on the molecular mobility in liquids and glasses are discussed, and there is a discussion of the high-pressure plasticity of inorganic glasses.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 2, pp. 17–23, February, 1971.     

The Mössbauer effect and magnetism

The Mössbauer effect enabled the magnetic hyperfine splitting (hfs) in ferromagnetic solids to be observed directly for the first time. It was quickly extended to measurements on antiferromagnets, ferrimagnets and paramagnets, and is now well established as a probe for the study of magnetic materials. Applications have ranged from the old problem of the state of the iron atoms in ferromagnetic alloys to the new magnetic materials, e.g. amorphous magnets, spin glasses, fine particle magnets and multilayers. Some examples where the Mössbauer effect has made an important contribution are described.     

Low-temperature properties of amorphous (Mo1−x Ru x )0.8P0.2 alloys

Amorphous (Mo_1–x Ru _x )_0.8P_0.2 alloys (0.3x0.7) have been investigated with measurements of the specific heatC and thermal conductivity . Also the superconducting properties (critical temperatureT _c and upper critical field) have been determined. Well belowT _c , all alloys show the familiar behavior known for glasses, i.e.CT ⁿ and T _m withn1 andm2 which is attributed to tunneling states (TLS). The largeT _c allows an unambiguous determination of the coefficients ofC and . Compairing our data with literature data, we find no correlation between the TLS density of states and the glass temperature or crystallization temperature, as opposed to insulating glasses where such a correlation appears to exist. The unusual annealing behavior found previously in amorphous Zr–Ni and Zr–Cu, which was attributed to a change in the TLS relaxation-time spectrum, is confirmed in the present work.     

Ultrasound in spin glasses

The change of the sound velocity v(,T) and the damping of sound waves (,T) in spin glasses are calculated in the frame-work of an Ising model with a random distribution of exchange interactions. The calculation is based on linearized equations of motion for the spins and on an improved mean field approximation which includes the Onsager reaction field. Near to the freezing temperatureT _f and at high temperatures v(,T) and (,T) turn out to be approximately proportional to the real and the imaginary parts of the dynamical susceptibility. For the special case of infinite range interactions atT=T _f one has v(, T_f) ( )^1/2 and (, T_f) (/)^1/2 where is the relaxation time of independent spins. However, already slightly aboveT _f the frequency dependence of both quantities becomes rather small for RKKY spin glasses. At high temperatures both, v(,T) and (,T) vary asT ^–1.SFB 125 Aachen-Jülich-Köln     

К ВОПРОСУ O КРИТИЧЕСКО Й ЧАСТОТЕ ПРИ ПРЕРЫВИСТОМ ОСВЕ ЩЕНИИ

c , c n , n AgBr. .     

The temperature vibrations of urea molecules

The structural and dynamic parameters of urea at 112°K and 295°K were determined by the least squares method. The characteristic temperature of the torsional optical vibrations of a molecule about a C-O bond was determined and is in good agreement with the value determined by Raman scattering. The fractional X-coordinate of the nitrogen atom corrected for torsional vibrations was determined and it was found that the magnitude of the projection of the C-N bond in the given temperature range changes only within the limits of observational errors. A new method, called temperature difference synthesis, is described and it is shown that it is suitable for rapid qualitative determination of the thermal anisotropy of the vibrations of atoms in a crystal lattice.

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112°K 295°K. C-O , , . X- , C-N . , , , .

     

More inequalities for critical exponents

A variety of rigorous inequalities for critical exponents is proved. Most notable is the low-temperature Josephson inequalitydv +2 2–. Others are 1 1 +v, 1 1 , 1,d 1 + 1/ (for d),dv, ₃ + (for d), ₄ , and _{2m 2m+2} (form 2). The hypotheses vary; all inequalities are true for the spin-1/2 Ising model with nearest-neighbor ferromagnetic pair interactions.NSF Predoctoral Fellow (1976–1979). Research supported in part by NSF Grant PHY 78-23952.     

The surface layer on a ferromagnetic. The energy of some periodic domain structures

Explicit solutions are found for a number of special cases of the potential problem of periodic charge distribution. The effect of uneven distribution of the charges of a Bloch wall on the magnetostatic energy is studied, the effective width of the Bloch wall is determined, an analytical expression is found for this distribution of poles and finally the effective height of the surface layer is also determined. An expression is derived for the orientation of the vectors of magnetization in the surface layer with respect to the easy directions of magnetization. The stability of the basic domain structure up to an inclination of 6°of the plane under observation to the direction of easy magnetization and the dimensions of the domains in periodic closure structures follow from the calculations.

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. , , , , . . , 6°,, , .

     

Pulsed laser crystallization of hydrogen-free a-Si thin films for high-mobility poly-Si TFT fabrication

The possibility to fabricate high-mobility polysilicon TFTs by nanosecond pulsed laser crystallization of unhydrogenated amorphous Si thin films has been investigated. Two types of lasers have been used: a large area ( 1 cm²) single ArF excimer laser pulse and a small diameter ( 100 m) frequency-doubled Nd:YAG laser beam, working in the scanning regime. Processed films have been characterized in detail by different optical and microscopic techniques. Device performances indicate that the best results are achieved with the excimer laser leading to high mobility values (up to 140 cm²/Vs) which are much larger than in polysilicon TFTs fabricated onto the same quartz substrates by low-temperature thermal (630° C) crystallization of amorphous Si films (_fe55 cm²/Vs).     

Ward's identity in critical dynamics

We consider the relaxation of an order-parameter fluctuation of wave numberk in a system undergoing a second-order phase transition. In general, close to the critical point, wherek ^{–1 –1} (the correlation length) the relaxation rate has a linear dependence on/k of the form (k, ) = (k, 0)x(1–a/k). In analogy with the use of Ward's identity in elementary particle physics, we show that the numerical coefficienta is readily calculated by means of a mass insertion. We demonstrate, furthermore, that this initial linear drop is the main feature of the full/k dependence of the scaling functionR ^–x (k,), wherex is the dynamic critical exponent andR=(k²+ ²)^1/2 is the distance variable.     

The distribution of ions and their valencies in manganese ferrites I. MnFe2O4+γ ferrites

A model for the distribution of cations in the spinel lattice of manganese ferrites MnFe₂O₄₊ was elaborated on the basis of the experimental studies of the basic magnetic quantities, electrical conductivity and magnetic relaxation of the given ferrites, taking into consideration their crystallographic properties. The conclusions following from this model are in good agreement with the experimental results obtained by us and by other authors both for stoichiometric manganese ferrite and for a ferrite where 0.

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I. MnFe₂O₄₊

, MnFe₂O₄₊ . , , , , , 0.

     

Contribution to the thermodynamics of the isomorphous γ ⇆ α-transition in metallic cerium

Using the method of the theory of thermodynamic stability and the form of the lines of the phase equilibrium of the isomorphous -transition in metallic cerium, the authors investigate the behavior of the basic thermodynamic characteristics of this transition in the two-phase region and in a neighborhood of the critical point. Attention is focused primarily on the little-studied adiabatic quantities (T/C_V, (–P/V)_S, (T/V)_S). It is shown that along the phase tie-lines these quantities do not depend on V and S; in the limit of the critical point all adiabatic quantities have nonzero minima, and all isodynamic quantities (T/Cp, (–P/V)_T, (T/V)_P) approach zero according to the same law. The obtained thermodynamic results are compared with existing experimental data and models which can be interpreted thermodynamically. It is concluded that critical phenomena in cerium correspond to critical behavior of the first type.Dnepropetrovsk State University Dedicated to the 300th Anniversary of the Unification of the Ukraine with Russia.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 66–70, May, 1991.     

Energy loss of warm and hot carriers in surface inversion layers of polar semiconductors

A theory for the hot carrier transport in surface inversion layers is presented, including scattering by polar optical phonons. Formulas for the current-voltage characteristics, the energy relaxation time, and the warm electron coefficient are given using Howard's wave function for the calculation of the matrix elements.The work was supported by the Ludwig Boltzmann Gesellschaft zur Förderung der wissenschaftlichen Forschung and by the Fonds zur Förderung der wissenschaftlichen Forschung in Österreich     

Energy criterion in the interpretation of dielectric relaxation

The universal fractional-power-law frequency dependence of relaxation seen in most solid dielectrics has the unique property that the ratio of macroscopic energy lost per radian to energy stored is independent of frequency. In a recent publication we have shown that this energy criterion is satisfied if the energy loss in every microscopic dipolar reversal is independent of the rate of reversals. The present paper derives for the first time a quantitative relationship between the macroscopic energy loss per radian and the microscopic loss , thus providing a justification of the energy criterion approach. The relationship between this new frequency-domain interpretation of relaxation processes and the currently accepted theories of universal behaviour is discussed.     

A contribution to the theory of the triple crystal diffractometer

The first part of the paper gives a general equation for triple-crystal arrangement with perfect crystals on the assumption that the third crystal is rotated. It is shown that in the case of perfect crystals the shape of the reflection curve is practically independent of the vertical divergence. The case of mosaic crystals is also solved and the possibility of rotation by other than the third crystal is considered. A method is proposed for investigating the imperfection of a crystal which is different from methods used up to now. The paper is supplemented by some experimental results.

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