ArF laser CVD of hydrogenated amorphous silicon: The role of buffer gases

ArF laser-induced CVD has been employed to generate hydrogenated amorphous silicon (a-Si:H) from Si₂H₆ gas dilute with He, Ar, or H₂. The formation of amorphous films or powder is found to depend critically on the kind of buffer gas, the stationary total and partial gas pressures, and the substrate temperature. These dependences have been investigated in the 1–5 Torr pressure and 100–400 °C temperature ranges. They are semiquantitatively discussed in terms of ArF laser photolysis of disilane, gas heating by heat flow from the substrate and laser irradiation, diffusion, and gas phase polymerization. Furthermore, photo ionization has been observed but found irrelevant for the a-Si:H layer properties. The photo and dark conductivities ( _ph, _d) of the semiconductor layers are determined by the substrate temperature. The _ph values range between 10^–7 and 10^{–4 –1} cm^–1 and the _d values between 10^–11 and 10^{–8 –1} cm^–1. The maximum ratio _ph/ _d amounts to 4×10⁴. The layers are further characterized by their optical band gap and activation energy. The layer properties are compared to literature values of amorphous films prepared by various photo, HOMO, and plasma CVD methods.     

Baryon decays and gamma-spectroscopy of hypernuclei

The applicability of (K ^–,^–) - and (K ^–,^– N)-reactions on^13,14C and^14,15N nuclei to the study of -transitions in primary and daughter -hypernuclei is discussed. The intensity of -deexcitation of ¹³C state |S ¹²C(15·11 MeV; 1⁺1): 1/2⁺ has been shown to be comparable with the intensity of baryon decay. Isospin selection rules are used to distinguish excitation energy ranges of primary hypernuclei, where the identification of the secondary -lines is probable.Presented at the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985.     

Electrical properties of GaAs layers irradiated by H4 ions

The quantities(D) and(T) are studied in n- and p-GaAs, irradiated at T = 300°K by H⁺ ions (5 MeV). It is shown that the resistance of lightly doped GaAs specimens increases from original values of ₀ to 10⁹ ·cm upon irradiation by H⁺ ions (5 MeV) to integral fluxes up to D^* – 10¹⁵ H⁺/cm². For D > D^* the layer resistance decreases from 10⁹ ·cm to 1 ·cm at 300°K. It was found that all the GaAs specimens intensely irradiated by H⁺ ions had p-type conductivity near 300°K. Isochronic annealing of radiation defects was studied in the temperature interval 20–700°C.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 39–43, January, 1982.     

Temperature dependence of the effective work function for the BaO - W system

The temperature dependence of the work function has been examined for the BaO-W system for degrees of coating less than 1 and about 1 in the range 700–1400 °K; it is found that a monomolecular film gives a negative sign of this coefficient in this temperature range ( /T 10^–4 –10^–3 eV/deg). At 1000–1200 °K, the temperature coefficient is almost zero, while at 1200–1400 °K there is a positive value. If the covering is less than monomolecular, the sign is positive throughout the entire temperature range (/T 10^–4 eV/deg).Deceased.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 9, pp. 65–70, September, 1971.We are indebted to N. I. Éngovatova for direct assistance with the measurements, and to V. Rumyantsev for advice.     

Synthesis and Reactivity of Mg(II)–Fe(II)–Fe(III) Hydroxycarbonates

Green rust-like compounds (GRs) were discovered as natural minerals in various hydromorphic soils, where anoxic conditions allow their stability. They may control some redox processes in aquifers and participate to the transformation of various pollutants. Since Mg(II) cations are present in the fields where GRs were discovered, a partial substitution of Mg(II) to Fe(II) leading to intermediate compounds between GRs and usual Mg(II)–Fe(III) hydroxysalts is suspected. Mg(II)–Fe(II)–Fe(II) hydroxycarbonates can be obtained as intermediate oxidation products of (Mg, Fe)(OH)₂ in carbonate-containing aqueous media obeying to [Fe^II _4(1–x)Mg^II _4x Fe^III ₂(OH)₁₂]²⁺ [CO₃ ^2– nH₂O]^–2. TMS spectra at 12 K are similar to those of GRs, i.e., two quadrupole doublets, one due to Fe(II) with a large isomer shift =1.29 mms^–1 (with respect to -iron at room temperature) and quadrupole splitting E _Q=2.76 mms^–1, the other one due to Fe(III) with smaller hyperfine parameters =0.49 mms^–1 and E _Q=0.44 mms^–1. Fe(II) ions oxidise rapidly into Fe(III) with dissolved O₂. The reactivity is similar to that of Fe(II)–Fe(III) hydroxysalts GR, and thus the potential of Mg(II)–Fe(II)–Fe(III) compounds for reducing pollutants.     

How to measure the magnetic moment of the tau lepton

We present a method for obtaining bounds on the magnetic moment of the lepton. In order to do this, we study the radiative decayW as a function of the anomalous magnetic moment of the ,a . One can obtain bounds as good asa < 4.05×10^–2, 2.25×10^–2, 4.5×10^–3, and 2.5×10^–3 at the present Fermilab, future Fermilab, SSC, and LHC, respectively.     

A solution spectrum of the nonlinear Schrödinger equation. II

It was shown in a previous communication that the nonlinear Schrödinger equation exhibits a spectrum of eigenfunctions of the form = _k,A _k (coshkx) ^–k and = _k B _k (coshkx) ^–k–1sinhkx, and the corresponding eigenvalues of the energy are related to a band structure with a characteristic energy gap as a significant feature. In the present paper, it is shown that a further spectrum exists exhibiting the general structure = _k=0 A _k(cosh kx)^–k–1/2and = _k=0 B_k(cosh kx)^–k–3/2sinhkx and yielding also a band structure. An extension of the solution spectrum to a nonlinear Klein-Gordon equation and a nonlinear Dirac equation does not imply essential difficulties, and the corresponding characteristic band structure has to be related to a mass spectrum.     

Vacuum Einstein spaces with axial symmetry

Four classes of solutions are found to the equations R=–2_{; ;} and g _;=0 in three-dimensional space with metric gdxdx and signature (+ ––), equivalent to the Einstein equations R_ij=0 in a vacuum for the metric . The metric ds² assumes axial symmetry and symmetry with respect to the reflection .Translated from Izvestiya Uchebnykh Zavedenii, Fizika, No. 9, pp. 43–45, September, 1976.     

H2-induced changes in electrical conductance of β-Ga2O3 thin-film systems

H₂-induced changes of electrical conductivity in polycrystalline, undoped -Ga₂O₃ thin films in the temperature range of 400–650° C are described. The sheet conductance of these films depends reversibly, according to a power law p ^1/3, on the partial pressure of hydrogen in the ambient atmosphere of the Ga₂O₃ film. A bulk vacancy mechanism is excluded by experiments and it is shown that the interaction is based on a surface effect. Changes in conductance are discussed to result from the formation of an accumulation layer due to chemisorption on the grain surfaces. Typical coverages are determined to be approximately 10^–4 ML for pH₂=0.05 bar and T=600° C. A possible explanation of the p ^1/3 power law is provided.     

Electrical properties of p-type ZnGeP2 irradiated by H+ ions

The properties of p-type ZnGeP₂ [p₀=(5–10)·10¹⁰ cm^–3, ₀=(2–5)·10^–7 (·cm)^–1], irradiated with H⁺ ions [E=5 MeV, T_irr=300 K, D=(1·10¹²–1.7·10¹⁶) cm^–2] are studied. An increase in the resistivity (to gr_max - 5·10¹¹ ·cm) and subsequent reduction in for large currents of H⁺ ions ( - 9·10⁸ ·cm for D - 1.7·10¹⁶ cm^–2), is observed in irradiated crystals. The resistivity of irradiated p-type ZnGeP₂ is found to be very sensitive to hydrostatic pressure [(4–5)·10^–5 bar^–1]. The annealing of radiation defects in the temperature interval (20–600) °C is examined.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 91–93, October, 1991.     

119Sn-mössbauer,IR, and DSC study of tin oxyfluoride glasses

The¹¹⁹Sn-Mössbauer spectra ofxSnO·(70–x)SnF₂·30P₂O₅ glasses (0 x70) measured at 78 K comprised a doublet due to Sn²⁺ (=3.30–3.36 mm s^–1, = 1.70–1.72 mm s^–1) and a weak singlet due to Sn⁴⁺ located at –0.23 mm s^–1 with respect to BaSnO₃. The and of Sn²⁺ were comparable to those of Sn₂P₂O₇. Small Debye temperatures (146 and 155 K) were obtained from the low-temperature measurements. These results indicate that Sn²⁺ and Sn₄₊ occupied interstitial sites, being loosely and ionically bonded to distorted PO_4–x F _x tetrahedra.     

Two-frequency method for increasing the signal-to-noise ratio for nuclear quadrupole resonance14N low-frequency transitions

A method is proposed for increasing the signal-to-noise ratio during detection of NQR¹⁴N low-frequency transitions, consisting in a preliminary saturation of the _o(_–) transition before accumulation of the multiplet signals of the spin echo or induction signals, observed during the action of a series of 90 pulses on the _–(_o) transition. The gain in signal-to-noise ratio achieved by the two-frequency action is calculated theoretically, and the maximum value is found to be 3/(3 –) for _– and 3(1 + )/4 for _o. It is shown that the envelope of the induction signal for an increase in the time between the 90 pulses decreases according to one exponent for _o, while for _– and ₊ it decreases according to two exponents, and the approach to equilibrium of the system of¹⁴N nuclei is oscillatory in nature.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 61–64, November, 1987.     

Thermoelectric properties of Ag2Se

To obtain information on the temperature and concentration dependence of thermoelectric quality factor Z and to clarify the nature of scattering in Ag₂Se a study was made of electrical conductivity , thermo-emf , and thermal conductivity in silver selenide over the temperature range T=80–450°K at concentration levels of 2–43·10²⁴ m^–3. It is shown that in Ag₂Se the Lorentz number L, determined experimentally from the electronic fraction of the thermal conductivity, is less than the Sommerfeld number L_o. Calculation of L/L_o(n) performed with a theory considering inelastic scattering of carriers, shows that the inelasticity is produced by electron interaction. Comparison of experimental data on the temperature dependence of lattice thermal conductivity with theory permits the conclusion that in Ag₂Se in range 80–300°K the basic role in phonon scattering is played by three-phonon Umklapp processes. It is shown that with increase in T and decrease in n the thermoelectric quality factor of silver selenide increases. The highest value of Z was achieved in a specimen with electron concentration n=2·10²⁴ m^–3 at T=320°K. The rapid decrease in Z upon phase transition is related to discontinuous decrease in and at this point.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 27–31, October, 1981.     

Short-term electrical relaxation in alkaline halide crystals

The temperature dependence of total conductivity in KCl and NaCl monocrystals with calcium impurity in the audio frequency range is studied, It is established that in the temperature range 50–350°C only one of the observed relaxation processes is described by the dipole relaxation mechanism with characteristic time = ₀exp (E/T); the values ₀ = 10^–14sec, E = 0.65eV, and ₀ = 10^–14sec, E = 0.7eV are obtained for KCl and NaCl respectively. Relaxations with values of ₀ and E differing from those above which were observed in the given temperature and frequency range are produced by resistance of the near electrode region.Translated from Izvestiya VUZ. Fizika, No. 6, pp. 101–106, June, 1973.     

Dirac's cosmology with varying cosmological constant

The phenomenological approach to investigating the decay of the vacuum energy density is generalized in the spirit of Dirac's large number hypothesis. Different arguments are outlined to justify an universal dependence of the type =H ² ( is a pure number andH is the Hubble parameter). Such time-varying A does change the predictions of the earlier Dirac's cosmology. The deceleration parameter (q ₀=(2–)/(1+)) and the age parameter (H ₀t₀=(1+)/3) are now compatible with the observations. The model also allows a power-law inflationary phase and a rate of matter creation smaller than the one present in the steady state universe.     

The low energy scattering for slowly decreasing potentials

For the radial Schrödinger equation with a potentialq(x) decreasing at infinity asq ₀ q ^–, (0, 2), the low energy asymptotics of spectral and scattering data is found. In particular, it is shown that forq ₀>0 the spectral function vanishes exponentially as the energyk ² tends to zero. On the contrary, there is always a zero-energy resonance forq ₀<0. These results determine the local asymptotics of solutions of the time-dependent Schrödinger equation for large timest. Specifically, for positive potentials its solutions decay as exp(–₀ t ^(2–)/(2+), ₀>0,t. In the case (1, 2) it is shown that for ±q ₀>0 the phase shift tends to ± ask0 and its asymptotics is evaluated.     

Magnetic and electric hyperfine interactions in the system EuSm

Magnetic and electric hyperfine interactions in the system EuSm were investigated with the isomeric 11/2^– state in¹⁴⁵Eu by applying the time-differential perturbed angular distribution (TDPAD) method. The temperature dependence of paramagnetism was studied between 90 K and 1000 K by measuring the magnetic hyperfine interaction frequency _L=g_NN¹ (T)B_ext. The paramagnetic correction factor strictly follows the Curie-Weiss relation =1+C/(T-), withC=–50(2) K and =–29(5) K. This is compatible with a hyperfine field ofB _int(0)=–25(1) T, a valence of two for Eu in Sm, and antiferromagnetic order at low temperatures.The temperature dependence of the electric quandrupole coupling constant v_Q, investigated between 100 K and 400 K, can be reproduced by a linear temperature variation v_Q(T)=v_Q(0) (1-AT), with v_Q(0)=16.2(4) MHz andA=7.2(8)·10^–4 K^–1.The paramagnetic relaxation time _rel of the nuclear alignment is proportional to the temperature of the sample, with _rel T^–1=3.7(2) ·10^–9s K^–1.This leads to the Korringa relation _J T=const=5.1(5)·10^–11s K for the relaxation time of the 4f electronic spinJ. Assuming that the relaxation ofJ is mainly caused by exchange interaction between conduction electrons and localized 4f electrons at the Eu site, an exchange integral of |J _eff|=0.10(2) eV can be deduced.     

Nonlinear piezoresistance in p-type silicon

An investigation was made of the longitudinal and transverse piezoresistance and electrical conductivity of p-type silicon under conditions of uniaxial compression, x [111], in the temperature range 77–300°K and hole concentration range 2.10¹⁵–5.10¹⁸ cm^–3. The transverse component of the electrical conductivity tensor, [11¯2], was found to depend nonmonotonically on the degree of compression. Compression decreases ₄₄ and increases the combination ₁₁ + 2₁₂. The nonlinearity oi the longitudinal piezoresistance increases with increasing hole concentration and T = 77°K. The results are explained by the rearrangement of the valence band under the deformation and the formation near the top of this band of a section of the spectrum described in the approximation of low energies of Pikus-Bir theory.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 3–7, October, 1980.     

Analysis of the order parameter for uniform nearest particle system

The uniform nearest particle system (UNPS) is studied, which is a continuoustime Markov process with state space . The rigorous upper bound ^(mf) = ( – 1)/ for the order parameter ₂, is given by the correlation identity and the FKG inequality. Then an improvement of this bound ^(mf) is shown in a similar fashion; C( – 1)/|log( – 1) for >1. Recently, Mountford proved that the critical value _c=1. Combining his result and our improved bound implies that if the critical exponent exists, it is strictly greater than the mean-field value 1 in the weak sense.