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The vibrational spectra of the following compounds were measured: X+AlMe4; X+GaMe4 and X+InMe4 (with X = Na, K, Me4P+, Me4As+ or Me4Sb+). For the purpose of comparison the spectra of compounds of group IV and V elements were taken from the literature or measured a second time. With a new procedure for determination of force-constants a set of comparable force-constants for the tetramethyl compounds of the elements Al, Si, P/Ga, Ge, As/In, Sn, Sb was obtained.  相似文献   

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