Zn2准分子的形成及其发射特性

通过光学抽运Zn(4s¹S₀—4p³P₁)共振线,在充有惰性气体的Zn蒸气中观察到两个连续的发射谱带。实验辨认它们可能归属于Zn₂准分子³∑_u⁺态,这与理论预言一致。研究谱带的时间与温度特性,以及惰性气体对谱带发射的影响。给出分子形成速率的上限和猝灭速率。结果表明,惰性气体分子在Zn₂准分子的形成及衰变中起了主要作用。 关键词：     

Xe^10＋离子EUV发射谱的理论研究

利用组态相互作用方法和扭曲波近似方法系统地计算了Xe^10＋离子的能级、振子强度、辐射跃迁速率以及电子碰撞强度，用得到的原子参数模拟了冕平衡条件下Xe^10＋离子EUV（Extreme Ultra-violet）波段（5-20nm）的发射谱，发射谱的波长位置和相对强度与实验结果符合得较好．研究表明：在较宽的等离子体条件范围内，发射谱的相对强度对温度和密度不敏感.     

XeO~*和XeS~*的紫外发射谱

研究了Xe(6p[1/2]_0 )和Xe(6p[3/2]_2)激发态与含氧分子反应的淬灭动力学.在与N_2O和OCS分子反应中,观察到较强的XeO和XeS紫外发射,其最大强度分别在234nm和227nm,并对发射机构进行了讨论.     

Xe10+离子EUV发射谱的理论研究

利用组态相互作用方法和扭曲波近似方法系统地计算了Xe10 离子的能级、振子强度、辐射跃迁速率以及电子碰撞强度.用得到的原子参数模拟了冕平衡条件下Xe10 离子EUV(Extreme Ultra-violet)波段(5~20nm)的发射谱,发射谱的波长位置和相对强度与实验结果符合得较好.研究表明:在较宽的等离子体条件范围内,发射谱的相对强度对温度和密度不敏感.     

低气压下XeCl准分子的形成研究

本工作利用高频介质阻挡放电对较低气压(70～1330 Pa)Xe/Cl_2混合气体中XeCl准分子的形成过程进行研究。通过探测不同Xe/Cl_2混合气压和不同Xe/Cl_2混合比条件下放电等离子体在285～315nm波长范围的荧光发射谱,得到了XeCl准分子在308nm附近的荧光发射以及荧光强度随气压变化曲线。得出该实验条件下生成XeCl准分子的最佳Xe/Cl_2混合比为4:1。     

等离子体X射线吸收谱及发射谱研究

报道计算高温高密等离子体吸收谱和发射谱（光学薄）的理论方法;该方法基于相对论原子理论,可以计算任何单元素以及多元素等离子体的谱分辨X射线吸收谱和发射谱（光学薄）;应用了量子亏损理论,可以减少计算量。利用该方法计算金等离子体LTE吸收谱,计算结果与实验符合良好。本文还对金等离子体LTE的光学薄发射谱进行了研究, 这将有利于对实验进行进一步的诊断分析。该理论计算方法还可提供等离子体内各电离度能级布居等重要物理参数。因此经“标准实验”检验的该理论计算方法将是提供ICF“精密”物理辐射参数的重要基础。     

等离子体X射线吸收谱及发射谱研究

 报道计算高温高密等离子体吸收谱和发射谱（光学薄）的理论方法;该方法基于相对论原子理论,可以计算任何单元素以及多元素等离子体的谱分辨X射线吸收谱和发射谱（光学薄）;应用了量子亏损理论,可以减少计算量。利用该方法计算金等离子体LTE吸收谱,计算结果与实验符合良好。本文还对金等离子体LTE的光学薄发射谱进行了研究, 这将有利于对实验进行进一步的诊断分析。该理论计算方法还可提供等离子体内各电离度能级布居等重要物理参数。因此经“标准实验”检验的该理论计算方法将是提供ICF“精密”物理辐射参数的重要基础。     

天体等离子体中铝发射谱线的研究

结合天体等离子体中铝发射谱和某些能级寿命的测量,对束箔光谱技术可为天体物理学研究提供重要信息和重要性进行了简述     

M带高能光子对发射谱诊断辐射场温度的影响

在稳态近似下通过求解速率方程分别计算了有无M带高能光子存在下,不同温度密度下Cl等离子体的离化度分布以及发射谱,研究了高能光子对等离子体发射谱的影响。研究发现:腔内混有的少量M带高能光子几乎不影响等离子体中重要的离化度分布,但是会激发或者电离各种离子的内壳层电子,从而对发射谱产生重要的影响。因此有M带高能光子存在时,用发射谱诊断等离子体温度时需要同时考虑温度、密度和M带高能光子对发射谱的影响。     

Violet Band Excimer Emission of Zn_2 Excited by Relativistic Electron Beam

ＶｉｏｌｅｔＢａｎｄＥｘｃｉｍｅｒＥｍｉｓｉｏｎｏｆＺｎ２ＥｘｃｉｔｅｄｂｙＲｅｌａｔｉｖｉｓｔｉｃＥｌｅｃｔｒｏｎＢｅａｍＸＩＮＧＤａ１）ＷＡＮＧＱｉ２）ＴＡＮＳｈｉｃｉ１）Ｋｅｎ－ｉｃｈｉＵｅｄａ３）（１）ＩｎｓｔｉｔｕｔｅｏｆＬａｓｅｒＬｉｆ...     

Enhancement of VUV Emission from a Coaxial Xenon Excimer Ultraviolet Lamp Driven by Distorted Bipolar Square Voltages

Enhancement of vacuum UV emission (172 nm VUV) from a coaxial xenon excimer UV lamp (EUV) driven by distorted 50 kHz bipolar square voltages, as compared to that by sinusoidal voltages, is investigated numerically in this paper. A self‐consistent radial one‐dimensional fluid model, taking into consideration non‐local electron energy balance, is employed to simulate the discharge physics and chemistry. The discharge is divided into two three‐period portions; these include: the pre‐discharge, the discharge (most intense at 172 nm VUV emission) and the post‐discharge periods. The results show that the efficiency of VUV emission using the distorted bipolar square voltages is much greater than when using sinusoidal voltages; this is attributed to two major mechanisms. The first is the much larger rate of change of the voltage in bipolar square voltages, in which only the electrons can efficiently absorb the power in a very short period of time. Energetic electrons then generate a higher concentration of metastable (and also excited dimer) xenon that is distributed more uniformly across the gap, for a longer period of time during the discharge process. The second is the comparably smaller amount of “wasted” power deposition by Xe⁺₂ in the post‐discharge period, as driven by distorted bipolar square voltages, because of the nearly vanishing gap voltage caused by the shielding effect resulting from accumulated charges on both dielectric surfaces (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

2D Simulations of Short‐Pulsed Dielectric Barrier Discharge Xenon Excimer Lamp

Self‐consistent two‐dimensional (2D) simulations of short‐pulsed dielectric barrier discharge (DBD) in pure xenon have been performed. It is shown that during short current pulse the traversal inhomogeneity of the plasma parameters can be important only at the end of the current pulse as an edge effect close to the side walls. During the current pulse, the gap voltage drops until the ionization wave reaches the cathode so the current in the cathode sheath is the displacement current. This means that almost all of the absorbed power is deposited into excitation of xenon atoms and not to the ion heating in the cathode sheath as in the traditional glow discharges. This fact is one of the reasons of high efficiency of short‐pulsed DBD. The developed model allows one to estimate the temporal position of the plasma‐sheath boundary. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

蒽醌染料紫外光谱的量子化学CNDO/2研究

茵醌染料在纺织工业中占有重要的位置。将蒽醌环上引入不同的基团则成为不同的染料。应用量子化学CNDO／2方法对蒽醌染料的紫外光谱进行研究,算出了各分子轨道的能量及相应紫外光谱吸收峰的位置。发现引入的助色基其能量差、紫外光谱最大吸收峰及红移呈规律变化,原因均为n-n^*轨道跃迁。     

Influence of the UV radiation wavelength on the curing of oligourethaneacrylate compositions for protective coatings of optical fibers

The curing kinetics of films produced from compositions based on UV-curable oligourethaneacrylates is investigated using, as a source of radiation, an individual spectral line separated by a monochromator from the radiation of a DRT-400 mercury tubular lamp. It has been established that in the region of spectral sensitivity of the composition, the curing time of the film is inversely proportional to the intensity of volumetric absorption of the radiation-source photons by the initiator at the lower surface of the film under study. Individual contributions of some of the lines to the process of composition curing by using the integral spectrum of the radiation source have been evaluated. The spectral-kinetic results obtained were confirmed when using the compositions under study as protective coatings of optical quartz fibers.Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 71, No. 6, pp. 836–840, November–December, 2004.This revised version was published online in April 2005 with a corrected cover date.     

Photoconversion of 2-methylphenol, 4-methylphenol, and 2-amino-4-methylphenol in water

We have used fluorescence spectroscopy to study photoconversions of 2-methylphenol (2-MP), 4-methylphenol (4-MP), and 2-amino-4-methylphenol (2-A-4-MP) in water when excited by UV radiation from different sources. We discuss the effect of the acidity of the medium and dissolved oxygen on photoconversions of the indicated methylphenols. The photodegradation efficiency for 2-MP and 4-MP decreases in the absence of oxygen. The photoconversion efficiency for methylphenols in alkaline medium is higher when irradiated by light with λ_rad = 283 nm, while in neutral medium it is higher when irradiated by light with λ_rad = 222 nm. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 5, pp. 566–572, September–October, 2006.     

Optimization of a Dielectric Barrier Discharge for Pulsed UV Emission of XeCl at 308 nm

A pulsed dielectric barrier discharge (DBD) has been investigated in a wide range of experimental conditions with the purpose of optimization for XeCl excimer radiation. For that the following operation parameters had been considered: four different lamps of coaxial geometry with gas gaps in the range of 1.3 ‐ 6.5 mm; gas mixtures of xenon and chlorine containing admixtures of 1%, 2% and 4% Cl₂ at total filling pressures between 5 mbar and 600 mbar; voltage rise times of 20 ‐ 50 ns and voltage amplitudes of up to 12 kV. A maximum radiation pulse energy of 1.8 µ J has been detected at 310 ± 10 nm with an estimated radiation decay by three orders of magnitude within about 5 µ s. It was shown that the minimization of the voltage rise time is essential for enhancing the radiation pulse energy. Furthermore a correlation between the discharge geometry and the optimum pressure for maximum radiation output was observed. The decay characteristics of the excimer emission provides evidence of the harpoon reaction being the main channel of XeCl formation under our operation conditions (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Amplified Spontaneous Emision of K2Yellow Band Excimer and Its Gain Measurement by e-beam-pumpingResearch on Injection-seeded β-BaB2O4Optical Parameteric Oscillator

The design of a high temperature cell appropriate for electron beam side pumping of alkali excimer lasers is described. By using the cell, an amplified spontaneous emission (ASE) and small signal gain coefficient of 4% cm-1 of the K2 yellow band (574 nm) were observed from the e beam excited mixture of K/K2 vapor with argon buffer gas. The dissociative recombination of K+3 is discussed as an efficient formation process of upper states by electron beam pumping.It has demonstrated the feasibility of a β-BaB2O4 optical parametric oscillator(OPO) without frequency control elements that produces very narrow bandwidth, 10 ns pulses via injection seeding. It was achieved by a CW He Ne laser and the experiment threshold for injection seeding is less than 1 mW. With 25 mJ pump energy at 354.7 nm, it has obtained pulse energy of 2 mJ at 632.8 nm and the total effiency is greater than 15%.     

Far infrared stimulated emissions from CO2 laser excited dichloromethane

Six new far-infrared laser frequencies have been obtained in CO₂-laser excited dichloromethane. Competing transitions have enabled assignments to be made to the v₇ band.     

新型可调远红外激光光谱仪及CHF3和SO2的纯转动光谱

文章报道与英国剑桥大学合作建立的新型可调远红外激光光谱仪的技术特点和工作原理。该光谱仪利用二极管的非线性特性 ,将CO2 激光泵浦产生的远红外激光与微波进行混频 ,得到边带远红外激光辐射 ,调节微波频率来实现边带远红外激光的扫描。利用该谱仪观测了CHF3 振动基态J =34～ 33,K =0 ～15和SO2 基态的 194,16～ 183 ,15,382 ,3 6～ 373 ,3 5纯转动光谱 ,并对它们进行了标识。