Residence time of metal ions generated from microsecond vacuum arcs

Vacuum gaps of 1 mm with lead or copper cathode are fired by a 13 μs duration sinusoidal arc or a 10 μs duration exponentially-decaying arc, and time-of-flight (TOF) ion measurements are made at variable times after the arc ignition. At the lead cathode, Pb⁺ and Pb⁺⁺ ions are generated and the upper limit on the times for Pb⁺ ion detection are 48 μs and 46 μs from the arc ignition for the sinusoidal and exponential arcs, respectively. At the copper cathode, Cu⁺, Cu⁺⁺, and Cu⁺⁺⁺ ions are generated and detected within 15 μs and 13 μs from the arc ignition for the sinusoidal and exponential arcs, respectively. The residence time of the Pb⁺ ions in the ion acceleration region is approximately 35 μs, regardless of the waveform of the arc current. The residence time of the copper ions, described by the time constant of the time-of-flight ion current delay characteristics, is 3 μs     

Residence time and charge state of silver and zinc ions generatedfrom microsecond vacuum arcs

One mm vacuum gaps with silver or zinc needle-cathode were fired by a 13 μs duration sinusoidal arc or a 9 μs duration exponentially decaying arc. Time-of-flight (TOF) ion measurements were made at variable ion extraction times after the arc ignition to measure the charge state and residence time of the ions. Ag⁺, Ag⁺⁺ and Ag⁺⁺⁺ ions were generated from silver cathode and Zn⁺ and Zn⁺⁺ were generated from zinc cathode. Residual gas atom ions were generated together with the metal ions. Residence times of silver and zinc ions at the acceleration space, which was 15-25 mm apart from the needle cathode, were 5 μs and 17 μs, respectively, regardless the waveform of the arc current. Charge state fractions of silver and zinc ions were determined from the TOF ion currents and were compared with the results by other researchers     

Velocities of copper and silver ions generated from an impulsevacuum arc

Vacuum gaps with copper and silver needle cathodes were fired by a 13 μs duration half-cycle sinusoidal arc, and charge states of the ions were analyzed using the time of flight (TOF) method at different positions in the direction perpendicular to the electrode axis. Velocities of each charge state ion were determined assuming a collisionless flight from the cathode region to the outside of the gap. The velocities of the fastest ions of copper and silver are 2.1 and 1.6×10⁴ m/s, respectively, regardless of the charge state. The velocities of the ions released with the arc extinction are lower, and differ depending on the state of the charge     

Development of an intense pulsed metallic ion beam source

Intense pulse metallic ion beams (Al⁺, Cu⁺, and Pb⁺) were produced by a magnetically insulated ion diode having a metal anode. Metal ion plasmas on the anode could be generated through enhanced electron bombardment by using a radial cathode. The energy, current density, and duration time of the lead ion beam were 30~140 keV, ~7.5 A/cm² (total ion current ⩾0.5 kA), and 800 ns, respectively. The ion current density exceeded the space-charge-limited current by a factor of 50. The lead ions in the first-to-sixth states of ionization were detected by a Thomson-parabola ion-spectrometer together with light loss, such as C⁺ and O ⁺. The ratio of the ion current of heavy metals to the total ion current was measured using a magnetic mass analyzer with a charge collector. The ratio was about 90% for a lead ion beam and 20~50% for Al and Cu ion beams     

Cu掺杂ZnO磁性能的实验与理论研究

采用固相反应法制备了Cu掺杂ZnO样品.在室温下Cu含量3%的样品在室温下表现为铁磁性.样品为n型半导体,载流子的浓度为1015cm-3.利用密度泛函理论(DFT+U)计算了CuZnO体系的Cu2+—O2-—Cu2+,Cu2+—Vo—Cu2+,Cu2+—Vo+—Cu2+,Cu2+—V++o—Cu2+磁交换耦合作用,给出了不同束缚电荷的氧空穴Vo与Cu2+离子之间的超交换机理,提出了CuZnO体系中铁磁性机理为Cu2+—V++o—Cu2+束缚磁极化子模型.     

Synthesis and properties of a new copper(II)-hafnium phosphate Cu0.5Hf2(PO4)3

Phosphates of general formula M_0.5Hf₂(PO₄)₃ with M=Cd²⁺, Ca²⁺, Sr²⁺ and Cu²⁺ were prepared by coprecipitation and characterized by several physical techniques. The compounds containing Cd²⁺, Ca²⁺, Sr²⁺ belong to the Nasicon-type structure, whereas Cu_0.5Hf₂(PO₄)₃ exhibited substantially different DRX patterns. Combined temperature programmed reduction (TPR) and temperature-programmed oxidation (TPO) showed that the copper in Cu_0.5Hf₂(PO₄)₃ was distributed between two energetically different sites in proportions respectively equal to 40 and 60%. Electron Paramagnetic Resonance (EPR) investigations confirmed the TPR/TPO results and revealed that the two sites hosting the Cu²⁺ ions are of orthorhombic symmetry. Moreover, the Cu²⁺ ions might be reduced by hydrogen to Cu⁺. These results were also supported by the UV–visible studies that showed the disappearance, under reducing conditions, of the band corresponding to crystal field transitions of Cu²⁺ ions and the emergence of a new peak attributed to the transitions between (3d)¹⁰ and (3d)⁹(4s)¹ Cu⁺ levels. At the same time, IR spectroscopy confirmed that protons entered the open lattice framework of the material and gave rise to a new protonated phase containing monovalent copper Cu_0.5^IH_0.5Hf₂(PO₄)₃. This redox process was proven to be reversible without any subsequent change in the network of the phosphate.     

Label-free tungsten disulfide quantum dots as a fluorescent sensing platform for highly efficient detection of copper(Ⅱ) ions

A fluorescent probe for the sensitive and selective determination of copper ion(Cu~(2+)) is presented. It is based on the use of tungsten disulfide quantum dots(WS_2 QDs) which is independent of the p H of solution and emits strong blue fluorescence. Copper ions could cause aggregation of the WS_2 QDs and lead to fluorescence quenching of WS_2 QDs. The change of fluorescence intensity is proportional to the concentration of Cu~(2+), and the limit of detection is 0.4 μM. The fluorescent probe is highly selective for Cu~(2+) over some potentially interfering ions. These results indicate that WS_2 QDs,as a fluorescent sensing platform, can meet the selective requirements for biomedical and environmental application.     

Pressure dependence of plasma parameters in medium-vacuum nitrogenarc discharge with the titanium cathode

The plasma properties of a medium-vacuum nitrogen arc discharge from a titanium cathode were studied. The arc chamber use was 400 mm in diameter and 600 mm in length. The cathode diameter and thickness were 64 and 25 mm, respectively. The experimental conditions are given as follows: pressure range=1×10^-3~2×10^-1 torr; N₂ gas flow rate=6 ml/min; arc current=50 A. Electric probe characteristics are measured as a function of pressure and distance from the cathode surface. The analytical results obtained show that the electron energy distribution takes 1-Mx at pressures above 1×10^-2 torr but 2-Mx at pressures under 4×10^-2 torr and that the electron density has a maximum value at a certain pressure. The Ti⁺, Ti⁺⁺, and N ⁺₂ ion spectral intensities are measured as a function of pressure and distance from the cathode surface. On comparison of these results and the electron density, the Ti⁺ spectral intensity turns out to be proportional to that of the electron density. This suggests that the major ion in the plasma volume is of the Ti⁺ species     

Microscopic high speed investigations of vacuum arc cathode spots

The main parameters and dimensions of cathode spots have been under discussion for years. To solve these current questions, a new system was specially designed. The image converting high speed framing camera (HSFC) combines a micrometer lateral resolution with a nanosecond time resolution and a very high optical sensitivity. This camera was used to study the microscopic behavior of vacuum arc cathode spots in a pulsed high current arc discharge on copper. The direct observation of these spots with high resolution revealed that one single cathode spot, as normally observed by optical means, consists of a number of simultaneously existing microscopic subspots, each with a diameter of about 10 μm and a mean distance of 30-50 μm between them. The mean existence time of these subspots on copper was found to be about 3 μs, where the position of a subspot remains unchanged (with an upper limit of about 5 μm) during its existence time. The lower limit of the current density in the cathode spots was estimated to be on the order of 10¹⁰-10¹¹ A/m². An upper limit of the crater surface temperature was estimated by a comparison between the brightnesses of a cathode spot and of a black body radiation lamp to about 3000 K     

Measurements of the behaviour of neutral atom density in a diffusevacuum arc by laser-induced fluorescence (LIF)

The method of laser-induced fluorescence was used to study the behavior of the absolute neutral vapor density of a diffuse vacuum arc on FeCu contacts. The local and temporal resolutions were 1 mm³ and 10 μs, respectively. The arc current had a sinusoidal shape of 5.8-ms duration with peak values of 90 and 510 A. It was found that the maximum densities of the iron and copper atoms are 1.2×10 ¹⁷ m^-3 and 7.5×10¹⁷ m^-3, respectively. During the arc the density was correlated with the current. At current zero the measured densities decreased to 10 ¹⁶ m^-3. After current zero, an exponential density decay with a time constant of about 100 μs was observed, indicating the recovery of dielectric strength after current zero. Measurements of the neutron iron vapor density at different spatial positions in the electrode gap reveal a nonisotropic distribution. From the measurements of the population distribution of the iron ground-state multiplet a ⁵D, the excitation temperature was derived. This temperature was low compared with the cathode spot temperature 2500-4000 K and decreased from 1600 K at the current maximum to 1000 K at current zero. The results indicate that the generation of neutrals is caused by flying evaporating metal droplets rather than by molten surface areas     

Investigation of arc roots of constricted high current vacuum arcs

The anodic and cathodic arc roots of constricted high current vacuum arcs were investigated with a fast framing charge-coupled device camera of 1 μs exposure time. The experiments were performed with cup-shaped contacts, with sinusoidal currents of amplitudes between 20 and 100 kA, and a sine halfwave duration of 10-12 ms. The arcs were drawn by contact separation and accelerated by the Lorentz force between the arc current and the transverse magnetic field generated by the contrate contact. The anode and cathode arc roots behave reproducibility and arc scaleable within the range of currents investigated. Both types of arc roots are elliptical, with a major to minor axis ratio of 1.4. The major axis points are in the direction of arc propagation. Anodic and cathodic arc root cross-sectional areas as a function of current can both be described by a potential law with a common exponent of 0.76. For currents of 20-100 kA, mean current densities of 81-121 and 41-60 kA/cm ² were found in anode and cathode arc roots, respectively. Estimations of their temperature and vapor densities were performed. For the investigated current range T_A≈3300-3600 K, n_A ≈1.6*10¹⁹-2.2*10¹⁹cm^-3 and T _C≈3200-3400 K, n_C≈0.8*10¹⁹-1.2*10 ¹⁹ cm^-3 were found for anode and cathode, respectively     

Reanalysis of the Z_c(4020), Z_c(4025), Z(4050) and Z(4250) as Tetraquark States with QCD Sum Rules

In this article, we calculate the contributions of the vacuum condensates up to dimension-10 in the operator product expansion, and study the C γμ- Cγνtype scalar, axial-vector and tensor tetraquark states in details with the QCD sum rules. In calculations, we use the formula μ = (M 2X/ Y /Z-(2Mc)2)~(1/2) to determine the energy scales of the QCD spectral densities. The predictions MJ =2=(4.02+0.09-0.09) GeV, MJ =1=(4.02+0.07-0.08) GeV favor assigning the Zc(4020) and Zc(4025) as the JP C= 1+-or 2++diquark-antidiquark type tetraquark states, while the prediction M++J =0=(3.85+0.15-0.09) GeV disfavors assigning the Z(4050) and Z(4250) as the JP C= 0diquark-antidiquark type tetraquark states. Furthermore, we discuss the strong decays of the 0++, 1+-, 2++diquark-antidiquark type tetraquark states in details.     

Pulsed dye laser diagnostics of vacuum arc cathode spots

The ignition and arc phases of vacuum arcs were investigated using differential dye laser absorption photography with simultaneous high spatial (micrometer) and temporal (nanosecond) resolution. The discharge duration was 800 ns, the current 50-150 A, the electrode material copper, and the cathode-anode distance less than 50 μm. A 0.4 ns laser pulse (tunable, γ=480-530 nm) was used to obtain momentary absorption photographs of the cathode region. During ignition, an optically thick anode plasma expanded toward the cathode, decaying within 25 ns after bridging the electrode gap. In the arc phase, a fragmentary structure of the cathode spots was observed in situ for the first time. The microspots have a characteristic size of 5-10 μm. They appear and disappear on a nanosecond time scale. The plasma density of the microspots was estimated to be greater than (3-6)×10²⁶ m^-3     

Measurement of cathode spot parameters with pulsed laserdiagnostics

The cathode spot formation in air within the first 170 ns was investigated by laser absorption photography and ps-pulse interferometry. The discharge was initiated between electrodes made from Ag or Pd with cathode-anode distance below 300 μm, the arc duration was some milliseconds, and the arc current 5-10 A. Picosecond holographic interferometry and momentary absorption photography yielded spatial-temporal density distributions in the ignition phase of the cathode spot. An absolute electron density value on the order of 4×10²⁶ m^-3 has been found. In contrast to vacuum, the cathode spot plasmas broaden little with increasing distance from the cathode, thus narrow plasma channels are observed in the vicinity of the cathode surface having diameters <20 μm     

Pulse intense metal-ion diode with a vacuum arc plasma anode

An intense pulsed ion beam of metal was extracted from a magnetically insulated ion diode operated in a mode of plasma prefill generated from a vacuum arc discharge, anode plasma source. With this ion diode, an intense metal-ion beam of a high melting-point metal (Ta) was obtained. A variety of operational modes appeared, depending on the amount of plasma in the diode gap at the initiation of the high-voltage pulse. The energy, current, and duration time of the ion beam were 20~100 keV, ~1 kA, and 1 μs, respectively. Measurements of ions were performed with an ion energy analyzer or a biased ion collector located at the end of a long drift tube and a Thomson parabola ion spectrometer. The Ta ions in the first to fifth states of ionization were detected accompanied by C⁺, O⁺, F⁺, and H⁺ . A Ta ion beam current of about half the total ion flux was obtained in this experiment     

Measurement of the tungsten ion concentration after forcedextinction of a vacuum arc

The concentrations of singly ionized and neutral tungsten atoms were measured by laser-induced fluorescence after the forced extinction of vacuum arcs between tungsten-copper butt contacts, 28-mm in diam. and 10-mm apart. The 50-Hz current was forced to zero at its maximum of 200 A in 1.3 μs by application of a reverse voltage. Near current zero, the ion concentration of 4×10¹⁷ m^-3 is of the same order of magnitude as the atomic tungsten concentration, which is 6×10¹⁷ m^-3. While the concentration of the neutrals remains virtually constant during 20 μs after current zero, the ion concentration decays by three orders of magnitude in the same time. The decay-time constant varies from 1.9 μs close to the postarc cathode to 3.6 μs near the postarc anode. It is concluded that the dielectric recovery of vacuum gaps after diffuse arcs is mainly controlled by residual charge carriers     

Electron paramagnetic resonance study of copper impurity charge-states in PbWO4 scintillator

The study of two types of Cu²⁺ centres observed in nominally pure PbWO₄ crystals grown by Bridgman and Czochralski methods was carried out by electron paramagnetic resonance (EPR). One of centres, called Cu²⁺(I), arises after oxygen compensation, while the second one, called Cu²⁺(II) requires, in addition, infrared illumination at low temperatures, being thermally stable only up to 22–23 K. The EPR spectra of both Cu²⁺ centres are described by rhombic symmetry g-tensors with the Z-principal axis lying close to, or in the (ab) plane of the crystal. It is proposed that in both centres the Cu²⁺ ions substitute for Pb²⁺ ions. The additional reduction of the local crystal-field symmetry is connected with a CuWO₄ wolframite-type lattice distortion for the Cu(I) and a Jahn–Teller distortion of the regular PbWO₄ lattice for the Cu(II). It was also found that either IR irradiation or thermal heating activate the transfer of an electron between two closely spaced Cu²⁺ centres.     

全剥离离子94mRu44+的衰变研究

在兰州重离子加速器冷却储存环（HIRFL-CSR）上,用等时性质量谱仪首次研究了百微秒量级全剥离离子94mRu44+的衰变。94mRu44+由初级束流112Sn轰击Be靶产生,经过放射性束流线RIBLL2的筛选后注入到等时性设置的实验环CSRe中,并利用安装在实验环中的飞行时间探测器测量离子在CSRe中的循环周期。94mRu44+退激引起的质量改变会带来其循环周期的变化,由此直接观测到了94mRu44+退激到基态的过程。确定了本次实验中衰变事例探测的灵敏区间,并讨论了衰变发生时刻的测量精度。同时,测量了短寿命核素94mRu44+的质量,其半衰期约为100 μs,这是目前储存环质量谱仪测量的最短寿命核素的质量。The decay of the fully stripped ion 94mRu44+ in the order of one hundred microseconds has been studied for the first time by using the Isochronous Mass Spectrometry (IMS) at the HIRFL-CSR facility in Lanzhou. 94mRu44+ was produced via projectile fragmentation of a 112Sn primary beam bombarding on a 9Be production target. After the in-flight separation with RIBLL2, the ions were injected into the experimental ring (CSRe) and then stored there. The revolution times of the stored ions were measured by a Time-of-Flight (TOF) detector. Due to the mass change of a 94mRu44+ ion caused by its de-excitation to the ground state, hence the revolution time change, the decay process of 94mRu44+ could be directly observed in the CSRe. The sensitive window for detection of the decay events and the measurement precision of the decay time have been determined in this work. At the same time, we measured the mass of short-lived 94mRu44+ with the half-life about one hundred microseconds, which is the shortest among nuclides that have been studied by using storage-ring mass-spectrometry.     

碳点嫁接海藻酸钙复合结构的制备及其对Cu2+的检测

基于铜离子与碳点的荧光猝灭作用,建立了用碳点作为荧光探针来检测铜离子的新方法。该方法将碳点还原后再嫁接于海藻酸钙,从而得到一种新型的含还原碳点的海藻酸钙薄膜荧光探针。用荧光分光光度计和紫外-可见分光光度计对探针的荧光特性以及探针与金属离子的相互作用进行了研究。研究结果表明：改性后的荧光探针具有很高的荧光强度,因此可以根据探针荧光强度的变化实现对铜离子的检测,并通过乙二胺四乙酸二钠（EDTA）的作用实现对铜离子的重复检测。铜离子浓度在5×10^-6~100×10^-6 mol·L^-1范围内与该荧光探针的荧光猝灭强度呈良好的线性关系。该方法不仅可以对铜离子检测,更实现了对碳点的固载,该技术有望实现荧光探针的回收再利用。     

Excitation, ionization, and reaction mechanism of a reactivecathodic arc deposition of TiN

This paper discusses the excitation, ionization and reaction mechanism of reactive cathodic arc deposition of TiN. Such arc plasmas art operated in the arc discharge type PVD apparatus. The 50 A arc is operated in N₂ atmosphere of 0.13 to 26.6 Pa. The arc voltage, the electron energy distribution and the spectral intensities are measured as a function of pressure. The deposited films are analyzed by XPS. It follows from the result that (1) the N₂ molecules impact with the high energy electron to be excited or ionized; (2) Ti ⁺⁺ ions which are initially emitted from the cathode spot recombine with electrons and turn Ti⁺ ions and Ti atoms and the recombination ratio increases with increasing pressure; (3) the TiN compound is produced on the substrate surface in the ensuing process, the excited N₂ are adsorbed on the substrate surface, the N ₂ are dissociated to N atoms through collisions with Ti⁺ ions of 40-60 eV, the N atoms react with the Ti atoms to form TiN