C-15结构(Hf,Zr,Ta)V2和(Hf,Zr,Nb)V2合金超导转变的压力效应研究

本文研究了C-15结构化合物(Zr_0.5Hf_0.5-xTa_x)V₂(x≤0.2)和(Hf_0.5Zr_0.5-xNb_x)V₂(x≤0.2)的超导转变温度T_c及其压力效应?T_c/?P。报道了实验方法与结果。与(Hf_1-xTa_x)V₂和(Zr_1-xTa_x)V₂的情况不同,在(Zr_0.5Hf_0.5-xTa_x)V₂中Ta的引入使常压下的T_c下降,然而(?)T_c/(?)P却大为提高。因此高压下Zr_0.5Hf_0.45Ta_0.05V₂的T_c反而比Hf_0.5Zr_0.5V₂更高。导出了一个基于角动量分波表象能带论方法的描述压力效应的新关系式。它指出导带电子波函数中的高角动量成分变化对T_c的压力效应影响比较重要。这个公式有助于理解上述复杂的实验现象,并能合理地解释某些元素(如Cs,Ba,La等)的T_c随压力剧增的事实。 关键词：     

INTERNAL FRICTION AND ULTRASONIC ATTENUATION RELATED TO CARRIERS IN HIGH Tc SUPERCONDUCTORS

For both BiSrCaCuO and TlBaCaCuO samples, internal frictions (Q^-1) in the kHz range reveal a plateau (Q^-1_p) above T_c and a rapid drop below T_c with the turning points located just at T_c for various samples with different T_c. This anomaly cannot be observed in non-superconducting samples. The ultrasonic attenuation (α) in TlBaCaCuO displays similar results to the internal friction. Moreover, it is discovered that the Q^-1_p is nearly proportional to the carrier density for Y(Pr)BaCuO and Gd(Pr)BaCuO with different Pr contents. These results show that the drop of Q^-1 and a below T_c is closely related to superconducting condensation. The Q^-1_p and α_p can be explained using coupling-model of carriers with local dynamic distortion because high T_c superconductors are strong-correlation systems. Furthermore, by taking account of the smearing of superconducting gap structure resulting from the recombination of quasi-particles and by modifying the BCS relative jump rate as S(E, E', Γ) = Re{1-Δ²/[(E-iΓ)(E'-iΓ)]}, the calculated results of internal friction and ultrasonic attenuation below T_c are in good agreement with the experimental data. The superconducting gap Δ and the damping rate Γ for both BiSrCaCuO and TlBaCaCuO have also been obtained, they are in accordance with those got by tunneling spectrum and NMR methods, etc.     

Intralayer and Interlayer Couplings in the Soliton pairing Model of Superconductivity

Explicit expressions and results for T_c(n) of the layer compounds of Bi and T1 are obtained within the generalized soliton pairing framework, in which T_c, is raised by the cooperation l i of the two couplings, intralayer and interlayer. The calculated values are in good agreement I with the observed T_c's. The maximum possible T_c(∞) is predicted at≈ 200 K.     

On the Free Carrier-Negative U Center Interacting Model for the High-Tc Oxide Superconductor

Using the free carrier-negative U center interacting model, we have investigated the superconducting transitionr,temperature T_c, the specific heat jump at T_c, the coherence length, the penetration depth, the thermodynamic critical field and the isotope effect for the high-T_c oxide superconductor. The theoretical values of these physical quantities are consistent with the experimental values. Further, the residual electronic specific heat in the superconducting state is explained as the result of the inherent instability in this superconductive mechanism.     

Magnetic Excitations and the Curie Temperature of Decamethylchromocenium Tetracyanoethylenide

We describe the molecular ferromagnet decamethylchromocenium tetracyanoethanide [C_rC_p2^*] [TCNE] by a quasi-one-dimensional alternating-spin model with ferromagnetic exchange interaction. The spin-wave theory is used to discuss the magnetic excitation of the molecular ferromagnet. We obtain the magnetizations corresponding to different external magnetic fields without interchain exchange interaction which is consistent with the experimental results. The formula of the Curie temperature T_c is obtained by using the thermodynamic Green's function method. It is found to be related to the spin of donors, to the intrachain exchange interaction and to the spatial anisotropic parameter. The result obtained by this T_c formula is consistent with the experimental result T_c = 3.6 K for [C_rC_p2^*][TCNE].     

The Critical Temperature of Quantum Spin Model Determined with Variational-Cumulant Expansion

The variational-cumulant expansion (VCE)methodis used to calculate the quantum XY model, for which the trial action S₀ does not commute with the action S, with arbitrary magnitude of spin on various one-, twe and three-dimensional lattices. The free energy of the model is expanded to the third order and the analytical formulae of critical temperature T_c are given for each order. To testify this method in a wider range, the Heisenberg model on different lattices is also calculated, which has more comparable results. Weighted fitting method of statistical mathematics is adopted to predict T_c of infinite order.     

Lifshitz时空s波超导模型的关联长度和穿透深度

在D=d+2维各向异性的Lifshitz黑洞时空背景中, 在探子极限下, 用解析方法研究了临界温度附近引力系统的微扰, 计算出超导的关联长度ξα(1/T_c)(1-(T/T_c)^-1/2, 这与平均场论的结果一致. 进一步, 考虑在该系统中加一个均匀外磁场, 计算出穿透深度λα(T_c-T)^-1/2, 该结果与Ginzburg-Landau理论相符.     

Determination of the magnetic transition temperature of dilute ferromagnetic alloys - the Pd(Gd) case

The determination of T_c in dilute alloys is examined. As an example, magnetization vs field data in a Pd_0.95Gd_0.05 alloy are presented. For this alloy, it was not possible to determine a value of T_c using Arrott-Belov-Kouvel (ABK) plots; the conditions for the applicability of ABK plots were not satisfied. Results of very-low-field ac and dc magnetization vs T, which depend mainly on the demagnetization factor, yield a more precise measure of T_c. We conclude that the latter procedures are more useful than ABK plots for determination of T_c in dilute alloys.     

PREPARATION,SUPERCONDUCTIVITY AND STRUCTURE OF THE LaBaCaCu3O7-x SUPERCONDUCTORS WITH Tc HIGHER THAN 80 K

In this paper, the preparation process of the tetragonal LaBaCaCu₃O_7-x (LBCCO) superconductor with T_c=84 K is repored. The superconductivity and structure of the LBCCO superconducting phase are investigated by means of X-ray diffraction (XRD), transmission electron microscope(TEM) and superconductivity measurements, The results indicate that the superconducting phase with T_c=82K in the LBCCO system has a tetragonal structure with a=0.3966nm, c=l.1838nm and space group P4/mmm. About 50% of the Ca and La atoms are located in 1d sites (i.e. Y site in the YBCO structure). It is confirmed that there is in fact no orthorhombic to tetragonal transition in this material. The relationship between the oxygen content and T_c is also presented.     

插层FeSe高温超导体的高压研究进展

通过对FeSe进行化学插层可以将其超导转变温度（T_c）从约8 K提高到40 K以上,实现高温超导电性.最近,我们对两种插层FeSe高温超导材料（Li_0.84Fe_0.16）OHFe_0.98Se和Li_0.36（NH₃）_yFe₂Se₂开展了高压调控研究,发现压力会首先抑制高温超导相（称为SC-I相）,然后在临界压力P_c以上诱导出第二个高温超导相（称为SC-Ⅱ相）,呈现出双拱形T-P超导相图.这两个体系的P_c分别约为5和2 GPa,两个体系SC-Ⅱ相的最高T_c分别可以达到约52和55 K,比相应SC-I相的初始T_c提高了10 K.对（Li_0.84Fe_0.16）OHFe_0.98Se的正常态电输运性质分析表明,SC-I和SC-Ⅱ相的正常态分别具有费米液体和非费米液体行为,意味着这两个超导相可能存在显著差异.此外,还发现这两个体系的SC-Ⅱ相的T_c与霍尔系数倒数1/R_H（∝载流子浓度n_e）具有很好的线性依赖关系.对（Li_0.84Fe_0.16）OHFe_0.98Se的高压X射线衍射测量排除了其在10 GPa以内发生结构相变的可能,因此P_c以上SC-Ⅱ相的出现和载流子浓度的增加很可能起源于压力导致的费米面重构.     

Generalized Nonlocal Ginzburg-Landau Equations

In a previous paper we established a set of nonlocal Ginzburg-Landan equations near T_c. In this paper this set of equations is generalized to the cases well below T_c. the generalization is characterized by two new kernel functions which can be reduced to a similar form aa that obtained previously. The form factor resulted from first principle calculation is in good agreement with neutron scattering data.     

THE ANALYTICAL RESULT OF THE EFFECT OF THE VIRTUAL QUARK LOOPS TO SU(2) AVERAGE PLAQUETTE ENERGY

By using hopping parameter expansion and cumulant expansion, as an example, we calculate analytically the effect of fermion determinant to average plaquette energy < E_p > up to k⁶ order. The corrections of the fermion determinant to < E_p > are controllable small in our approximation.     

THE LINEAR ELIASHBERG EQUATION

Fn the present paper, the linear Eliashberg equation is converted into a new integral equation and from it, the following T_C formula is derived analytically in the weak coupling limit:T_c=28/πωlog·(πlog/π_c)μ^*/λ^*-μ^* exp{-1+λ/λ-μ^*}, where In γ=C=0.5772 is the Eater constant.     

Real-Time Thermal Field Theory Analyses of 2D Gross-Neveu Model

The discrete symmetry breaking and possible restoration at finite temperature T are analyzed in 20 Gross-Neveu model by the real-time thermal field theory in the fermion bubble approximation. The dynamical fermion mass m is proven to, be scale-independent and this fact indicates the equivalence between the fermion bubble diagram approximation and the meanfield approximation used in the auxiliary scalar field approach. Reproducing of the nonzero critical temperature T_c = 0.567m(O), m(0) is the dynamical fermion mass at T = 0, shows the equivalence between the real-time and the imaginary-time thermal. field theories in this problem. However, in the real-time formalism, more results including absence of scalar bound state, the equation of criticality curve of chemical potential-temperature and the ln(T_c/T) behavior of m² at T ≤ T_c can be easily obtained. The last one indicates the second-order phase transition feature of the symmetry restoration.     

FeSi/Si成份调制膜的二维磁性和死层效应

成功地制成了FeSi/Si非晶态成分调制膜,固定Si层厚度,系统改变FeSi层厚度d_m发现,随d_m下降,饱和磁化强度M_s单调减小,这主要是死层效应的贡献,OK下死层厚度约为5.8?,随d_m减小,调制膜逐渐由三维磁性转变为二维磁性,表现为出现低磁滞和无磁滞效应,线性的M_s(T)-T关系和Curie温度T_c的单调下降,T_c满足如下关系:△T_{c关键词：}     

Magnetic impurities in amorphous superconductors:TKondo>Tc

Measurements of upper critical field as a function of temperature and Fe-concentration are reported for the amorphous superconductors ((Mo_.6Ru_.4)_.80G_.20)_1−cFe_c, where G is a glass-former. The linear shapes of the H_c2 vs. T curves near T_c agree well with predictions made by Matsura, Ichinose, and Nagaoka, for T_Kondo > T_c.     

A Trial of Variational-Cumulant Expansion on Simple Ising Model With Second Order Phase Transition

The standard variational-cumulant expansion (VC) combined with a scheme for the enumeration of connected diagrams is employed to study the simple Ising model with the second-order phase transition. This model is evaluated to the 5th order approximations. A comparison with the 2-dimensional exact results shows that thermodynamic quantities converge rather slowly to the exact values in the intermediate region. A strict analytical calculation of the critical temperature with the 5th order approxinlation both for J_i and cumulant expansion suggests that VC chn achieve rather high standard accuracy if the variational parameters J_i could be determined up to higher degrees of corrections rather than the first one. Anomalies are found for U, C and M at extremely low temperature. A detailed study of M implies that thermodynamic formulae should be carefully chosen in VC approach so as to avoid these anomalies.     

高质量FeSe单晶薄膜的制备及相关性能表征

在铁基超导体中,FeSe具有最简单的晶体结构和化学组成,而且其超导转变温度具有较大的调控空间,因此适合作为超导机理研究和应用的载体.高质量样品的研制是物性研究和器件应用的前提,本文系统地研究了利用激光脉冲沉积技术制备FeSe薄膜的工艺条件,在多种衬底上成功地制备出高质量的β-FeSe薄膜,并首次实现了超导临界转变温度从小于2 K到14 K的连续调控,这为FeSe超导机理研究提供了样品支持.为探究FeSe薄膜超导电性变化的起因,从β-FeSe超导电性与晶格常数c正相关出发,基于简单的费米面填充假设,第一性原理计算可以很好地解释晶格常数c的变化规律,但该假设并不能完全符合角分辨光电子能谱实验给出的电子结构演变过程.因此β-FeSe薄膜的超导电性、晶格结构和电子结构三者之间的关系还有待澄清,该问题的解决将为FeSe超导机理研究提供重要的线索,而上述系列高质量的β-FeSe薄膜样品恰好能为该问题的研究提供理想的载体.本文根据实验和已有的相关研究结果,详细介绍了FeSe薄膜的脉冲激光沉积制备及其优化,以期为后续的薄膜研究应用提供参考.     

Top-Quark Condensate at Finite Temperature and Electroweak Symmetry Restoration

The gap equation at finite temperature in the top-quark condensate scheme of electroweak symmetry breaking is proven to have the identical form in both the imaginary and real time formalisms of thermal field theory. By means of the gap equation, combined with the basic relation to define the vacuum expectation value v of the effective Higgs field, we analyze the dependence on temperature T and chemical potential p of the dynamical top-quark mass as the order parameter characteristic of symmetry breaking, and obtain the p-T criticality curve for symmetry restoration. We find out that the critical temperature T_c = 2υ for μ = 0 and the critical chemical potential μ_c = 2 π υ / √3 for T = 0. When μ = 0, the top-quark mass near T_c has the leading (T_c² - T²)^1/2 behavior with an extra factor dependent on temperature T and the momentum cutoff Λ. However, it is generally argued that the symmetry restoration at T ≥ T_c is still a second-order phase transition.     

白光LED用稀土荧光粉的制备和性质

在还原气氛保护下利用高温固相法合成了化学组分为(M₁,M₂)₁₀(PO₄)₆X₂(M₁=Ca,Sr,Ba;M₂=Eu,Mn;X=F,Cl,Br)的可被紫光激发的蓝光、绿光和红光荧光粉,制备了紫光LED芯片+蓝光荧光粉+YAG荧光粉的二基色白光LED;紫光LED芯片+蓝光荧光粉+红光荧光粉的二基色白光LED,以及紫光LED芯片+蓝光荧光粉+绿光荧光粉+红光荧光粉的三基色白光LED。测试了所有制备的白光LED在不同的直流电驱动下的色度坐标、相关色温和显色指数。