Pion-Rotational Nucleus Scattering and the Interacting Boson Model

A procedure of combining the medium energy scattering theory in the eikonal approximation with the interacting boson model (IBM) is proposed to study the pion-rotational nucleus scattering. The channel coupling effects in the excitation of nuclear collective state with π^- and π⁺ elastic and inelastic scattering are analyzed. The calculated cross sections for the excitation of 2₁⁺ state of ¹⁵²Sm agmree with the experimental data quite well.     

Pion-Nucleus Scattering and the Interacting Boson Model

A procedure of combining the medium energy scattering theory in the Eikonal approximation with the interacting boson model is proposed to study the pion-nucleus scattering. The channel coupling effects in the excitation of nuclear collective state with ρ^- and ρ⁺ elastic and inelastic scattering are analyzed. The calculated cross sections for the excitation of 2₁⁺ state of ²¹⁸Sn agree with experimental data quite well.     

The new pionic hydrogen experiment at PSI

A new high-precision determination of the strong-interaction shift (_1s) and broadening (Γ_1s) of the ground state in pionic hydrogen (πH) has been started at PSI [1]. This constitutes a direct measurement of the πN scattering lengths a⁺ and a⁻ and is an important test of the methods of chiral perturbation theory.     

Energy Spectra and g Factors of α-A1203:Cr3+ and α-A1203:Mn4+

By diagonalizing the complete d³ energy matrix in a trigonally distorted cubicfield and using the wavefunctions from it, unified calculations of the whole energy spectrum as well as the g factors of the ground state and t₂^{3 2} E excited states for α-A1₂0₃:Cr³⁺ and α-A1₂0₃:Mn⁴⁺ have been carried out respectively. A11 the calculated results are in very good agreement with the experimental data. The comparison between the results of the two crystals has been made, which demonstrates that the covalency of α-A1₂0₃:Mn⁴⁺ is stronger than the one of α-A1₂0₃:Cr³⁺. For the zero-field splittings of the ground state and t₂^{3 2} E , their physical origins are revealed; the comparison and analysis of their values of the two crystals have been made.     

用于α和μ常数变化测量的碘离子光谱研究

分子离子I_2~+的禁戒跃迁光谱有可能用于测量α和μ常数的变化,并且具有增强的灵敏度.通过分析I_2~+在11860—13100 cm~(-1)范围内的转动光谱,拟合了A~2Π_(3/2)-X~2Π_(3/2)系统31个振转带的5759根吸收谱线,得到5个属于X~2Π_(3/2)态和9个属于A~2Π_(3/2)态的振动能级准确的转动光谱常数.在量子噪声极限和1 Hz跃迁线宽的条件下,计算得到X~2Π_(3/2)和X~2Π_(1/2)之间的禁戒跃迁对α和μ常数变化测量的灵敏度为δ_(α/α)≈2.37×10~(-19)a~(-1)和δ_(μ/μ)≈1.18×10~(-18)a~(-1).     

Probing the Stau－Stau－Higgs Couplings in the MSSM at NLC

In the minimal supersymmetric standard model (MSSM) with CP violating phases, this paper discusses the production of the lJghtest neutral Higgs boson in association with tau sleptons at future high-energy e^ e^- linear colliders. In parameter space of the constrained MSSM, the production cross section of e^ e^→h^0T1 T1^- can be very substantial at high energies. This process would provide a production mechanism for probing couplings of neutral Higgs bosoas to tau sleptons as well as some soft supersymmetric breaking parameters at next linear colliders.     

Theoretical study of spin-forbidden cooling transitions of indium hydride using ab initio methods

The feasibility of spin-forbidden cooling of the In H molecule is investigated based on ab initio quantum chemistry calculations. The potential energy curves for the X~1Σ_(0~+)~+, a~3Π_~(0~-), a~3Π_(0~+), a~3Π_1, a~3Π_2, A~1Π_1, 1~3Σ_(0~-)~+, and 1~3Σ_1~+states of In H are obtained based on multi-reference configuration interaction plus the Davidson corrections method. The calculated spectroscopic constants are in good agreement with the available experimental data. In addition, the influences of the active space and spin–orbit coupling effects on the potential energy curves and spectroscopic constants are also studied. For Re of a~3Π_(0~-), a~3Π_(0~+), a~3Π_1, and a~3Π_2 states, the error from large active space is small. The potential energy curve of the A~1Π_1state is not smooth for small active space. The spin–orbit coupling effects have great influences on the potential well depth and equilibrium internuclear distance of the A~1Π state. The Franck–Condon factors and radiative lifetimes are obtained on the basis of the transition dipole moments of the a~3Π_(0~+) → X~1Σ_(0~+)~+, a~3Π_1 → X~1Σ_(0~+)~+, and A~1Π_1 → X~1Σ_(0~+)~+ transitions. Our calculation indicates that the a~3Π_1( ν'= 0) → X~1Σ_(0~+)~+(ν = 0) transition provides a highly diagonally distributed Franck–Condon factor and a short radiative lifetime for the a3Π1 state, which can ensure rapid and efficient laser cooling of In H.The proposed laser drives a~3Π_1 → X~1Σ_(0~+)~+ transitions by using three wavelengths.     

NH4H2PO4和ND4D2PO4晶体微结构的拉曼光谱研究

本文利用偏振拉曼光谱和第一性原理, 对磷酸二氢铵(NH₄H₂PO₄, ADP)和不同氘含量磷酸二氢铵DADP晶体的晶格振动模式进行了研究. 实验测得了不同几何配置、200–4000 cm^-1范围的偏振拉曼光谱, 分析在不同氘含量条件下921 cm^-1和3000 cm^-1附近拉曼峰的变化. 在ADP晶体中, 基于基本结构单元NH₄⁺ 和H₂PO₄^-基团的振动模, 用第一性原理进行了数值模拟, 进一步明确拉曼峰与晶体中原子振动的对应关系; 通过洛伦兹拟合不同氘含量DADP晶体的拉曼光谱中2000–2600 cm^-1处各峰的变化讨论了DADP 晶体的氘化过程, 结果表明氘化顺序是先NH₄⁺ 基团后H₂PO₄^-基团, 研究结果为今后此类材料的生长和性能优化奠定了基础.     

磷酸二氢根离子对香豆肼化合物的高选择性荧光增强

设计合成了荧光探针N,N-二.乙基氨基香豆素-3-肼基-2,4-二硝基苯肼(DC).光谱滴定实验显示,H2PO4-与DC能够以1∶1的化学计量比形成配合物.进一步的实验发现,和相同含量的DC溶液相比,该配合物溶液的相对光致荧光强度显著增强,同时伴有紫外吸收光谱红移,溶液颜色由橙黄色迅速变为紫色.其它阴离子,如F-、NO...     

Analysis of the scattering of 46 MeV protons from Be and C

An analysis is made of the measurements of the elastic and inelastic scattering of 46 MeV protons by ³Be and ¹²C. The optical and collective models are used. There is considerable ambiguity in the optical parameters, and it was not found possible to obtain good fits to cross sections and polarizations simultaneously. Large quadrupole deformations were found for both ¹²C (β₂ ≈ 0.6) and ⁹Be(β₂ ≈ 1). The inelastic scattering from ¹²C agrees best with deformation of both real and imaginary parts of the optical potential, while ⁹Be shows a preference for real coupling. The 14.1 MeV level in ¹²C is interpreted as the 4⁺ rotational state, while the angular distribution for the 7.6 MeV 0⁺ level is well described by double quadrupole excitation via the lowest 2⁺. Interpretations are suggested for other inelastic transitions, including the excitation of spin and isospin oscillations.     

O_2分子B~3Σ_u~-态势能曲线的从头计算

B~3Σ_u~-态是O_2的最强的三重跃迁(B~3Σ_u~-←XΣ_g~-)Schumann-Runge(SR)带的上态,SR吸收带在保护地球、阻止紫外辐射等方面起着关键作用.SR连续带的光解离是平流层O原子及O_3的主要来源,掌握详细准确的O_2分子的电子态势能曲线,有助于对这些光谱现象的深入理解.本文通过MOLPRO软件,采用包含Davison修正的内收缩的多参考组态相互作用(ic MRCI+Q)方法,对O2的B~3Σ_u~-态的势能曲线进行了计算,采用的多参考组态函数来自完全活性空间自洽场计算.首先,采用共价组态构成多参考组态,对和B~3Σ_u~-态对称性相同的四个态进行了态平均计算,发现B3Σ_u~-态不存在双势阱结构,文献(Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy 2014 124 216)中双势阱的产生是根的振荡(root flipping)造成的,即B~3Σ_u~-态的势能曲线在核间距约为0.2 nm处跳变到能量相近的23?态的势能曲线上.本文中的态平均计算避免了这种根的振荡.接着,采用完全活性空间组态相互作用的方法计算B~3Σ_u~-态的势能曲线,通过改变活性空间的轨道组成,发现带有2π_u轨道电子布居的里德伯组态对B~3Σ_u~-态的束缚态的特征的出现是必不可少的.最后,通过将2π_u轨道加入到活性空间中,实现将相关的里德伯组态加入到多参考组态,对B~3Σ_u~-态的势能曲线进行了icMRCI+Q计算,得到相较于以往的理论计算与实验值更加相近的势能曲线以及光谱常数.本文探讨里德伯组态贡献的过程为如何确定多参考组态相互作用计算中的参考组态、提高理论计算的准确度提供了可以借鉴的途径.     

Fermion Coherent State Studies of One-Dimensional Hubbard Model

We present a comparative study of the ground state of the one-dimensional Hubbard model. We first use a new fermion coherent state method in the framework of Fermi liquid theory by introducing a hole operator and considering the interactions of two pairs electrons and holes. We construct the ground state of the Hubbard model as ｜〉=[f＋∑^tφk1σ1hk2σ2ck3σ3hk4σ4 ∏exp（ρck1σ1 hk2σ2）]｜〉0,where φ and ρ are the coupling constants. Our results are then compared to those of varlational methods, density functional theory based on the exact solvable Bethe ansatz solutions, variational Monto-Carlo method （VMC） as well as to the exact result of the infinite system. We find satisfactory agreement between the fermion coherent state scheme and the VMC data, and provide a new picture to deal with the strongly correlated system.     

Four-Particle Entangled State Representation and Its Squeezing Transformation

The four-particle EPR entangled state | p,χ₂,χ₃,χ₄〉is constructed. The corresponding quantum mechanical operator with respect to the classical transformation p→e^λ₁p, χ₂→ e^λ₂χ₂, χ₃→e^λ₃χ₃, and χ₄→e^λ₄χ₄ in the state |p,χ₂ ,χ₃ ,χ₄〉is investigated, and the four-mode realization of the SU(1,1) Lie algebra as well as the corresponding squeezing operators are presented.     

铥原子收敛于4f13(2F7/2o)6s(7/2,1/2)4o和4f13(2F7/2o)6s(7/2,1/2)3o偶宇称里德伯系列能级的电子关联效应

本文在多通道量子亏损理论框架下,利用相对论多通道理论,计算了铥原子收敛于4f¹³（²F_7/2^o）6s（7/2,1/2）₄^o和4f¹³（²F_7/2^o）6s（7/2,1/2）₃^o的三个偶宇称里德伯系列.通过将计算结果与美国国家标准与技术研究院数据进行比较,展示了两种类型的电子关联效应：1）里德伯系列之间的相互作用,导致里德伯系列的能级出现整体偏移;2）一个孤立的干扰态镶嵌在一个里德伯系列中,破坏了该里德伯系列能级的规则性.     

Adsorption and angle-resolved electron-stimulated desorption of CCl4 on Ru(0001)

The adsorption and electron-stimulated desorption of CCl₄ on Ru(0001) have been studied at 100 K using a variety of surface analytical techniques, including thermal desorption spectroscopy, Auger electron spectroscopy, low-energy ion scattering, and mass and angle-resolved electron-stimulated desorption (ESDIAD). CC1₄ is found to dissociate partially for fractional monolayer coverages, and to adsorb molecularly above a coverage of 13%. Upon electron bombardment, Cl⁺ ions are found to desorb with their angular distribution directed along the surface normal; this implies that CC1₄ orients with one C-C1 bond normal to the surface. The total yield of Cl⁺ increases linearly with increasing molecular CC1₄ coverage up to one monolayer, which implies that Cl⁺ stems mainly from molecular CCl₄ and that interadsorbate quenching is not significantly affecting the desorption yield. Beyond a coverage of 1 ML, the Cl⁺ yield continues to increase, and starts leveling off after 2 ML. We estimate the yield from a thick layer of CCl⁴ to be of the order of 3 × 10⁻⁸ ions/electron. The angular distribution of the desorbing Cl⁺ ions widens with increasing CCl₄ exposure. Besides Cl⁺, higher mass fragments of CCl₄, such as CCl⁺, CCl₂⁺ and CCl₃⁺ are also found to desorb from multilayers upon electron bombardment.     

The Role of a1(1260) in π-p→a1-(1260)p and π-p→π-ρ0p Reactions Near Threshold

We report on a theoretical study of the π^-p→a₁^-(1260) p and π^-p→π^-ρ⁰p reactions near threshold within an effective Lagrangian approach. The production process is described by t-channel ρ⁰ meson exchange. For the π^-p→π^-ρ⁰p reaction, the final π^-ρ⁰ results from the decay of the a₁(1260) resonance, which is assumed as a dynamically generated state from the K^*K and ρπ coupled channel interactions. We calculate the total cross section of the π^-p→a₁^-(1260)p reaction. It is shown that, with the coupling constant of the a₁(1260) to ρπ channel obtained from the chiral unitary theory and a cut off parameter Λρ~1.5 GeV in the form factors, the experimental measurement can be reproduced. Furthermore, the total and differential cross sections of π^-p→a₁^-(1260)p→π^-ρ⁰p reaction are evaluated, and it is expected that our model calculations can be tested by future experiments. These reactions are important for the study of the a₁(1260) resonance and would provide further constraints on the properties of the a₁(1260) state.     

Production Rate of Ds+Ds- at φ(4030)

By using a generalized relativistic quark pair creation model (QPCM), the hadronic decay processes of φ(4030), assigned as the 3S state of cc, are investigated. The relative rates of φ(4030) → DD, DD^*+DD^*, D^*D^*,and in particular D_s⁺D_s^- are calculated and compared with data. The nodes of the radially excited wavefunctions of charmonium states are found to be significant for these decay processes. Considering the SU(3) suppression factor of ~3 for the s quark pair creation relative to the u and d quarks, we obtain σ(e⁺e^- → φ4(4030) → D_s⁺D_s^-) ~ 0.9 nb.     

三苯膦-铂(Ⅱ)络合物的质子核磁共振研究(Ⅰ)

过渡金属离子的d-电子特性,使得它们的络合物可以在很多有机合成反应中起催化作用,含三苯磷配体的反式铂氢络合物就是一种稳定的、广泛应用的催化剂^[1.2.3.4.]。为此,本工作合成了反式-[PtHXL₂],L=PPh₃,X=Cl^-、Br^-、I^-、NO₃^-、NO₂^-、NCS^-六种铂络合物,并测定了其¹H-NMR谱。实验获得该络合物系列中,与铂(Ⅱ)相连的质子在高场具有较大的化学位移,即δ_H=-12~-24ppm和很大的铂-氢偶合常数即J_pt-H=900-1400Hz,以及磷氢偶合常数即J_p-H≈15Hz。此外,还研究了配体对铂-氢的¹H化学位移及铂-氢偶合常数;铂-氢键长对铂-氢的¹H化学位移的影响,并找出了一定的规律性。从而得到了络合物的顺反异构,键合异构及电子密度分布的有关信息。关于铂络合物的核磁共振研究,虽有过报道^[5.6],但配体为三苯膦的反式-[PtH(PPh³)₂]系列络合物NMR研究,尚未见报道。     

15-王冠-5硝酸镨的晶体结构

15-王冠-5硝酸镨晶体的分子式为Pr(NO₃)₃C₁₀H₂₀O₅,属单斜晶系,空间群为C_2h⁵-P2₁/α,晶胞参数α=13.622埃,b=14.599埃,c=9.336埃,β=95°20′,晶胞内分子数z=4,用Pw-1100四圆衍射仪收集衍射强度数据,独立衍射点数2853个,用重原子法解晶体结构,结构参数的修正采用准对角矩阵最 关键词：