Mössbauer study of the Cu-Zn alloy system

Using the 93.3keV transition in⁶⁷Zn, the Lamb-Mössbauer factor, the electron density and the electric field gradient at the Zn nucleus have been determined for pure Zn metal, the ^–, ^–, ^–, and -phases as well as pure Cu metal.     

A Mössbauer spectroscopic study of cobalt-iron molybdates

Fe _x Co_1–x MoO₄ compounds prepared by coprecipitation were studied by XRD, electrical conductivity and mainly by absorption and emission Mössbauer spectroscopy. FeMoO₄ and CoMoO₄ samples were shown to contain Fe³⁺ and Co³⁺, respectively, in solid solution. Three kinds of Fe _x Co_1–x MoO₄ solids can be described. Forx0.16: one has a -Co(Fe²⁺, Fe³⁺)MoO₄ solid solution. For 0.17x0.25: one has the same solid solution with its surface rich in Fe³⁺. Forx0.26: one has the same solid solution with only bulk Fe³⁺, and ferric molybdate. Studies of reduction by hydrogen and of catalytic reaction of mechanical mixtures of CoMoO₄ and ferric molybdate support these statements.     

Mössbauer spectroscopic study of ferrocene derivatives in the adsorption and liquid-crystalline states

Mössbauer spectra of ferrocene derivatives in the solid, adsorption and liquidcrystalline states were measured at temperatures ranging from 78 to 423 K. The peak intensities of the Mössbauer spectra of ferrocene derivatives adsorbed on silica gel decreased markedly with an increase in temperature. The Mössbauer absorption of [4-(4-methoxyphenoxycarbonyl)-phenoxycarbonyl]alkyl 4-ferrocenylbenzoate at 295 K during the cooling process was observed in what was assumed to be the liquid-crystalline state.     

High-field Mössbauer study of the randomly canted Li-Fe-Ti system

In-field Mössbauer studies have been performed on the Li_0.5(1+t)Fe_2.5–1.5t ,Ti _t ,O₄ system with 1.10 t 1.40. The disordered magnetic properties depend strongly on the chemical disorder and local order induced by thermal treatments. The results are in agreement with low- and high-field magnetization measurements. Locally canted states are observed, with the degree of magnetic disorder depending on the composition and (or) the local chemical disorder.     

Mössbauer spectroscopic study of iron fluoride surface layers

The reaction products formed during exposure of iron foils to hydrogen fluoride in the presence of atmospheric oxygen and water have been examined with conversion electron Mössbauer spectroscopy (CEMS) [1]. After exposure for several hours the product in the corrosion layer was found to consist mainly of the mixed-valence iron fluoride, Fe₂F₅·7H₂O. Although the products formed during the initial steps of the reaction could not be completely characterized, a model for the reaction process is suggested.     

A Mössbauer spectroscopic study of 3d magnetism of R2Fe14B

Guided by the occupancies and iron magnetic moments μ³, ⁵⁷Fe Mössbauer parameters of Y₂Fe₁₄B at 250K, and in turn for other temperatures, of the sublattices of iron were deduced. Plots of μ(T) in reduced coordinates, through the established correlation between hyperfine field Hn and μ, show that the corresponding state of different iron sites is different and all experimental points fall below Brillouin function. The relation between exchange integral deviation parameter Δ and standard deviation of Fe-Fe interatomic distances S is linear, indicating electrostatic nature of exchange interactions between spins in neighboring atoms. It is inclined to the view that fluctuations of exchange integral is responsible for low T_c of R₂Fe₁₄B.     

A Mössbauer spectroscopic study of the magnetocrystalline anisotropy inα-FeOOH

Mössbauer spectra are obtained for a single crystal of -FeOOH, with a magnetic field of up to 10T applied along the c axis. No spin reorientation is observed, indicating a lower limit of 6 × 10⁴ J/m³ for the anisotropy constant K. A theoretical estimate gives K > 1.1 × 10⁶ J/m³.     

Iron-57 Mössbauer spectroscopic study of fluorinated strontium orthoferrite

A nuclear spin maser of a new type, that employs a feedback scheme based on optical nuclear spin detection, has been fabricated. The spin maser is operated at a low static field of 30 mG by using the optical detection method. The frequency stability and precision of the spin maser have been improved by a highly stabilized current source for the static magnetic field. An experimental setup to search for an electric dipole moment (EDM) in ¹²⁹Xe atom is being developed.     

57Fe Mössbauer spectroscopic study of nanostructured zinc ferrite

Nanosize zinc ferrite particles, prepared by nitrate method, were investigated by XRD, TEM, ⁵⁷Fe Mössbauer spectroscopy and VSM. The average particle size in this system varies from 10 to 62 nm as the sintering temperature increases from 300°C to 1,000°C. The lattice parameters in this system are almost constant at a value of ～8.41 Å. The Mössbauer spectra of all the sintered samples show a single doublet. The Mössbauer hyperfine parameters show little change with the change of sintering temperature. The doublets are ascribed to the presence of superparamagnetism in this system, which is also corroborated by the VSM measurements.     

Crystal structure and Mössbauer spectroscopic study of FeSnF6·6H2O

Large single crystals of FeSnF₆·6H₂O were grown when aqueous hydrofluoric solutions of SnF₂ and FeF₂ were allowed to evaporate in air. Tin-119 Mössbauer spectroscopy at ambient temperature shows a single line at slightly negative isomer shift relative to CaSnO₃ at room temperature (=–0.380(6) mm/s, =0). This is characteristic of tetravalent tin octahedrally coordinated by fluorine. The X-ray crystal structure shows that tin(IV) is coordinated by 6 fluorine atoms, and Fe(II) by 6 water molecules. Both sites show a slight distortion from octahedral symmetry: the six distances are equal (Sn-Fe=1.941(3) Å and Fe-O=2.112(3) Å), whereas there are two values of angles (Fe-Sn-F=90.4(1)° and 89.6(1)°; O-Fe-O=91.1(1)° and 88.9(1)°). The material is an ionic compound [SnF₆]^2–[Fe(H₂O)₆]²⁺.     

Gamma-x ray coincidence Mössbauer spectroscopic study of the aftereffects in sulfate hydrates

The anomalous charge states formed after the electron capture decay, of⁵⁷Co in FeSO₄·H₂O and FeSO₄·7H₂O are investigated using the conventional Mössbauer emission spectroscopy and a gamma-X ray coincidence method. This method is based on the idea that a Mössbauer spectrum observed with the coincidence technique only when K-X rays are emitted is reflected by isolated events with a reduced influence of the Auger-electron self-irradiation. The formation of the anomalous electronic and structural configuration is attributed to the self-radiolysis of the H₂O and SO ₄ ^2? ligands in the nearest and the second nearest coordination shells around the decaying atom.     

Mössbauer effect study of Ni1−xCuxMnyFe2−yO4 system

The Mössbauer effect technique has been employed for the study of magnetic properties of spinel series Ni_1?xCu_xMn_yFe_2?yO₄ with 0.0≤x≤1.0, and y=0.6. The substitution of Mn³⁺ and Cu²⁺ ions results in a slight decrease of the hyperfine field at B‐ as well as A‐sites. The area ratio of Fe³⁺ ions at the A‐ and B‐site at 77 K indicates that Cu²⁺, Ni²⁺ and Mn³⁺ ions occupy the octahedral sites in an evidence for complete inverse spinel in this system. The temperature dependence of the hyperfine parameters has been studied for composition with x=0.5 where Nèel point T_N and Debye temperature θ_D are found to be 650 and 679 K, respectively. The temperature dependence of the sublattice magnetization σ(T) obeys a one‐third‐power law in the range 0.5N<0.99.     

A Mössbauer spectroscopic study of the effect of molybdenum during preparation of Nd-Fe-B magnets

Elements in atomic ratios Nd₂(Fe_0.9Mo_0.1)₁₄B were melted in an induction furnace and annealed in order to examine the effect of molybdenum during the preparation of Nd-Fe-B magnets. A phase analysis has been made from ⁵⁷ Fe Mössbauer spectroscopic measurements in the temperature range of 100 to 700 K. It is found that two iron containing phases are formed, one Mo rich Fe alloy and the other Nd-Fe(Mo)-B isostructural to Nd₂Fe₁₄B. The Nd_1.1Fe₄B₄ phase usually found in Nd-Fe-B magnets is not observed in these samples. The Curie temperature, T_c, is found to be 605(5) K from the Mössbauer as well as vibrational sample magnetometer measurements on the same sample. At low temperatures, the average hyperfine field at Fe nuclei is found to show a decrease with respect to the value for Nd₂Fe₁₄B.     

Mössbauer study of magnetic order in RBa2Fe3O8

Complete replacement of copper by iron in RBa₂Cu₃O₇ leads to RBa₂Fe₃O₈ (R=Y, rare earth). Mössbauer spectroscopy measurements of⁵⁷Fe and¹⁵¹Eu in RBa₂Fe₃O₈ (R=Y, Eu, Ho, Er) at temperatures 4.2–800 K have been performed. Some of the spectra reveal two inequivalent iron sites, probably corresponding to iron in the Fe(2) site (fivefold oxygen coordination) and in the Fe(1) site (octahedral oxygen coordination). In all compounds the iron moments order antiferromagnetically at the same Néel temperatureT _N720 K. The¹⁵¹Eu Mössbauer spectra of EuBa₂Fe₃O₈ show that the Eu ion is trivalent and exposed to a small exchange field from the iron sublattices.     

A Mössbauer effect study of MgFe2O4

A slowly cooled sample of the ferrimagnetic spinel MgFe₂O₄ has been studied with ⁵⁷Fe Mössbauer spectroscopy over a wide temperature range both with and without high magnetic fields. The observed temperature dependence of the A and B site hyperfine parameters is discussed. Conclusions about the spin structure, the magnetic exchange interactions and the supertransferred hyperfine fields are presented.     

Mössbauer study of the (Ru1-xFex)Sr2GdCu2O8-δ system and two of its possible impurities: SrRuO3 and Gd2CuO4

Mössbauer spectra of a series of samples of the weak ferromagnetic $ {\left( {Ru_{{1 - x}} Fe_{x} } \right)}Sr_{2} GdCu_{2} O_{{8 - \delta }} M?ssbauer spectra of a series of samples of the weak ferromagnetic system reveal the existence of three dissimilar sites where the Fe atoms can go into the structure. The M?ssbauer parameters of the three observed quadrupole doublets, together with the relative population on each site, allow the following site assignment for the iron atoms: Fe³⁺ in four-fold planar coordination at Ru sites; Fe³⁺ in five-fold pyramidal coordination also at Ru sites and Fe²⁺ or Fe³⁺ in five-fold coordination at Cu sites. This assignment implies the formation of oxygen-vacancies at the charge reservoir (the RuO₂ planes) that affect the structure and the superconducting and magnetic properties of the undoped system. Moreover, a close correlation between the oxygen content, calculated through the M?ssbauer data, and the measured cell volume is established. We also report the M?ssbauer spectra of two compounds (SrRu_0.95Fe_0.05O₃ and Gd₂Cu_0.95Fe_0.05O₄) that could be formed as impurities during the synthesis of our samples.     

Experimental study of the amorphous phases of group-IV semiconductors by the119mSn Mössbauer probe

The amorphous phases of silicon, germanium, and -tin have been studied by Mössbauer emission spectroscopy on ion-implanted, radioactive^119mSn. Amorphous samples have been produced by ion implantations of various elements and by vacuumevaporation techniques. The same well-defined type of complex spectrum is observed for all investigated amorphous samples. These spectra are characterized by an increase in average isomer shift of (0.15±0.03) mm/s, a line broadening of 20±2%, and the same Debye temperature as compared with spectra of substitutional Sn in the respective crystalline host lattices. The spectra are proposed to originate from Sn atoms incorporated substitutionally in the amorphous host with distorted local surroundings. The recrystallization of the amorphous phase upon thermal and laser annealing has been monitored. After appropriate annealing, spectra characteristic of crystalline materials are observed for most samples. An exception are high-dose, inert-gas implanted samples where different complex defects seem to be formed in the annealing process.     

Identification of the species formed in the Fe/MgO system: A Raman and Mössbauer study

A set of samples of Fe/MgO, in the concentration range between 1.5 and 9 wt% of Fe, was prepared by the impregnation method and then calcined at 1073 K. All of them were characterized by XRD and Raman and Mössbauer spectroscopies. The data obtained show that the solids are made up of MgFeO₄ nanoclusters and Fe³⁺ ions dispersed in the MgO matrix. The size of the clusters and the amounts of each phase were calculated using the XRD and Mössbauer data.     

A Mössbauer spectroscopic study of simulated weathering of Didwana ordinary chondrites

A sample of an ordinary chondrite fall, Didwana-Rajod, Rajasthan, India which was shown to be largely unweathered, was exposed to weathering in laboratory conditions. Wet and dry cycle of different strengths (0.01 and 0.1 M) of sodium sulfate solution was applied for different periods of time (maximum of 140 days). An attempt was made to simulate meteorite weathering more or less analogous to environmental exposure in desert-like conditions. It is found that lower concentration of the attacking ions is more effective in weathering the meteorite. Kamacite is affected in early cycles of weathering more than any other mineral. The olivine to pyroxene ratio is much less affected.     

Mössbauer spectroscopic study of FeAl1−x Co x

We report the results of a Mössbauer study of the alloy sytem FeAl_1?x Co _x forx ≥ 0.3 at temperatures down to 83 K. Magnetic splitting is observed forx ≥ 0.35 at all temperatures. However, forx=0.3, no splitting is observed at room temperature, and superparamagnetic behavior occurs at LN₂ temperature. The magnetically split spectra are fitted each with a distribution of hyperfine fields and the average hyperfine field \(\bar B_{hf} \) as a function of temperature is obtained. The variation of \(\bar B_{hf} \) withT is explained using the model of magnetic clusters with collective magnetic excitations from which the saturation hyperfine field and the magnetic anisotropy energy for these clusters are obtained. Also, the results are discussed using the model of random atomic distributions, and the agreement between the calculated and the experimentally obtained distributions of hyperfine fields is found improve asx increases.