Photoelectron diffraction effects in XPS angular distributions from GaAs(110) and Ge(110) single crystals

Angular distribution measurements of XPS intensities have been made for various spectral lines from GaAs(110) and Ge(110) single-crystal surfaces. Observed angular distribution curves (ADC's) showed steep intensity variations and sharp peaks due to X-ray photoelectron diffraction (XPED) phenomena. The effects of the type of transition process (photoelectron or Auger), electron kinetic energy and crystal structure on the XPED patterns were examined. Considerably different ADC patterns were observed for high-energy photoelectrons and Auger electrons and for low-energy photoelectrons. ADC's for Ga 3d, As 3d and Ge 3d showed almost the same patterns for scans of the type [110] → [100] → [1$\text{1}$0], but they showed substantially different patterns for [110] → [11$\text{1}$] → [00$\text{1}$] scans. These features correspond well with the structural characteristics of GaAs and Ge crystals. A discussion of the applicability of XPS angular distribution measurements to the geometric analysis of crystal surfaces is presented.     

Surface densities of states for normal photoemission from Mo(110) and W(111)

Tight-binding calculations of one-dimensional densities of states on Mo(110) and W(111) are presented. As reported earlier for W(001), hybridization gaps contain localized surface states or resonances, and band-edge singularities are modified near the surface. Prominent structures in directional photoemission spectra are discussed in the light of our results, and further experiments using polarized light are suggested to test our assignments.     

Isothermal desorption of hydrogen molecules from a W(110) surface at temperature ∼5 K

Isothermal desorption of hydrogen molecules from a W(110) surface atT _s ～ 5 K upon rapid shuttering of the molecular beam is observed in a “black chamber” type of ultrahigh-vacuum apparatus. Desorption was detected from three different states, identified as a multilayer condensation state and physisorbed states in the form of a two-dimensional gas and a two-dimensional condensate. The distribution of the physisorbed molecules between these states depends on the intensity of the flux of molecules on the surface; this appears to be responsible for the anomalous decrease of the number of isothermally desorbed molecules as the flux increases.     

Desorption of H2 from W(110) and Fe covered W(110) surfaces

The kinetics of H₂ desorption from H/W(110) and H/Fe₁/W(110) were studied by measuring work function changes Δø vs time at a number of temperatures. Combination with previously determined Δø vs coverage data and differentiation at various fixed coverages gave rate vs T data from which activation energies of desorption could be obtained. E vs coverage results agree well with previously determine ΔH_des results. In the case of H/Fe₁/W(110) this includes a rise from 20 to 30 kcal mol⁻¹ of H₂ at H/Fe = H/W > 0.3. Plots of rate −dθ/dt vs θ (θ being coverage in units of H/W) vary much more steeply than θ² at most coverages for both systems. The θ dependence can be explained almost quantitatively in terms of the variations of ΔH_des and surface entropy S_s with coverage, by assuming that rates of desorption are equal to the equilibrium rates of adsorption. The latter can be formulated thermodynamically, except for a sticking coefficient, s. Values for s(θ, T) can also be obtained and show relatively little temperature dependence.     

Spin-asymmetry in elastic scattering of low-energy electrons from ultrathin Au films on W(110)

We present joint experimental and theoretical results on the elastic scattering of spin-polarized electrons from an epitaxial Au film on a W(110) substrate in the energy range from 8 eV to 27 eV. A time-of-flight technique with a position-sensitive detector is applied to measure secondary emission spectra for spin-up and spin-down primary electrons in a specular geometry. The spin-asymmetry of coherently scattered electrons is obtained by selecting the diffraction spot on the detector. Regions of large asymmetries – with a maximum of about ?60 % – are identified for electron energies of about 14 eV. Relativistic multiple-scattering calculations produce spin-orbit-induced asymmetries which are in agreement with their experimental counterparts. They further reveal that large asymmetries are associated with high intensities. This offers the possibility of an efficient new spin polarimeter with a figure of merit of about 1.5 · 10^?2.     

Impact of space-time extra dimensions on μ+μ− and W + W − angular distributions in e + e − collisions

The effects on μ⁺μ^? and W ⁺ W ^? angular distribution in e ⁺ e ^? collisions, due to the exchange of massive gravitons in space-time with large extra dimensions are considered. It is shown that under beam and detector conditions at TESLA, these effects would be discovered or the constraints on string scale ～4.5 TeV from below would be achieved at 20 fb^?1 of the integrated luminosity and √s = 500 GeV.     

The angular distributions of elastic scattering of 12,13C+Zr

To obtain the neutron spectroscopic amplitudes for \begin{document}${}^{90-96}$\end{document}Zr overlaps, experimental data of elastic scattering with small experimental errors and precise optical potentials were analyzed. In this study, the elastic scattering angular distributions of \begin{document}${}^{12,13}$\end{document}C + \begin{document}${}^{A} {\rm{Zr}}$\end{document} (A = 90, 91, 92, 94, 96) were measured using the high-precision Q3D magnetic spectrometer in the Tandem accelerator. The S?o Paulo potential was used for the optical potential. The optical model and coupled channel calculations were compared with the experimental data. The theoretical results were found to be very close to the experimental data. In addition, the possible effects of the couplings to the inelastic channels of the \begin{document}${}^A {\rm{Zr}}$\end{document} targets and \begin{document}${}^{12, 13}$\end{document}C projectiles on the elastic scattering were studied. It was observed that the couplings to the inelastic channels of the \begin{document}${}^{12,13}$\end{document}C projectiles could improve the agreement with the experimental data, while the inelastic couplings to the target states are of minor importance. The effect of the one-neutron stripping in the \begin{document}${}^{13}$\end{document}C+\begin{document}${}^A {\rm{Zr}}$\end{document} elastic scattering was also studied. The one-neutron stripping channel in \begin{document}${}^{13}$\end{document}C + \begin{document}${}^A {\rm{Zr}}$\end{document} was found to be not relevant and did not affect the elastic scattering angular distributions. Our results also show that in the reactions with the considered zirconium isotopes, the presence of the extra neutron in \begin{document}${}^{13}$\end{document}C does not influence the reaction mechanism, which is governed by the collective excitation of the \begin{document}${}^{12}$\end{document}C core.     

Influence of the halo upon angular distributions for elastic scattering and breakup

The angular distributions for elastic scattering and breakup of halo nuclei are analysed using a near-side/far-side decomposition within the framework of the dynamical eikonal approximation. This analysis is performed for ¹¹Be impinging on Pb at 69 MeV/nucleon. These distributions exhibit very similar features. In particular they are both near-side dominated, as expected from Coulomb-dominated reactions. The general shape of these distributions is sensitive mostly to the projectile-target interactions, but is also affected by the extension of the halo. This suggests the elastic scattering not to be affected by a loss of flux towards the breakup channel.     

Dichroism in angular resolved VUV-photoemission from the (0001) surfaces of thin Gd and Nd films epitaxially grown on W(110)

We present investigations of the electronic and magnetic structure of the Rare Earth valence states. In particular, we have examined ultra thin films of the rare earth metals gadolinium and neodymium epitaxially grown on tungsten (110). Various experiments on dichroism in angular resolved photoemission have been performed using circularly as well as linearly polarised light in the VUV-range with photon energies below 40 eV. A special emphasis was placed on the investigation of the surface state, which was observed for both Gd and Nd. A very small magnetic splitting of about 25 meV was observed for the surface state of ferromagnetic Gd. A magnetic ordering of a Nd-monolayer on a remanently magnetised Fe-film is observed. Large dichroism effects are found for the surface state as well as the valence bands of paramagnetic Nd. In the latter case, these are used to determine the dispersion of the valence bands. Different numerical approaches are presented, one based on atomic photoionisation theory, another is based on a one-step model of solid state photoemission. Atomic photoionisation theory is used together with three-step calculations to explain the non-magnetic circular dichroism observed in the Gd 4f emission. The capability of dichroism experiments for resolving details of the electronic structure and for sensitive tests of photoemission calculations is demonstrated. Received 21 September 1998     

Ion angular distributions in electron stimulated desorption: Oxygen and CO on W(111)

The ion angular distributions resulting from electron stimulated desorption (ESD) of oxygen and carbon monoxide chemisorbed on a tungsten (111) crystal have been determined. The O⁺ ions released during ESD of adsorbed oxygen exhibit three-fold symmetric angular distributions in orientational registry with the W(111) substrate. The CO⁺ and O⁺ ions released during ESD of a monolayer of CO are desorbed normal to the (111) surface. Models for both oxygen and CO adsorption are discussed. The data for CO are consistent with adsorption of CO in “standing up” carbonyl structures in the virgin and α-CO binding states.     

The adsorption of nitric oxide on W(110) at 300 K: An electron spectroscopic study

Nitric oxide adsorbs dissociatively onto W(110) at 300 K. The simplest interpretation requires adsorption into three states. In the first of these N and O penetrate the surface. In the second state N and O form an overlay er on the W(110) surface. The third state also involves surface penetration but this is deeper than for state 1. The adsorbate stoichiometry was 1:1 throughout adsorption at 300 K. The occupancy of each state was similar after a 300 L exposure when the total amount adsorbed exceeded 17 (±2) × 10¹⁸ atoms m^?2.     

Kinetic theory of desorption: Energy and angular distributions

The transformation of interacting fermions into free bosons known e.g. from the solution of the Luttinger model is reconsidered in a condensed version which combines all fermionic degrees of freedom in a single boson field. This simplifies calculations as compared to the usual separate treatment of the charge degrees of freedom. The representation of the fermions is exact. The Thirring-Schwinger model is described and solved with special emphasis on boundary effects. Implications for massive fermions are briefly mentioned.     

Energy and angular distributions of photoelectrons in multiphoton ionization

The energy and angular distributions of photoelectrons in the photoionization of an atom or ion by powerful laser radiation are calculated. The results obtained are valid for all values of the Keldysh parameter γ. Linear and circular polarizations of the light are considered. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 8, 493–497 (25 October 1999)     

Surface crystallography of W(110) and W(110) p (2×1)-O: The position of W atoms

The position of W atoms in the surface layers of clean W (110) and W (110) p (2 × 1)-O is studied using Constant-Momentum-Transfer Averaging of LEED intensities. It is shown that the clean surface is not relaxed to an uncertainty of < 0.06 Å. Analysis of superstructure beam intensity averages from W(110) p (2 × 1)-O indicates that oxygen does not reconstruct W(110) at these coverages and below 1000 ° K. An upper limit of 0.05 Å can be put on the out-of-plane displacement of W atoms by the oxygen. Substrate beam averages from W (110) p (2 × 1)-O verify the non-reconstruction. The use of CMTA for adsorbed-layer crystallography in general is briefly discussed.     

The inelastic scattering of He from Cu(001) at 20 K

The inelastic scattering of He atoms from a (001) surface of copper at 20 K has been studied. The energy analyzer consists of a LiF crystal situated close to the normal of the copper sample crystal. Incident energies of 23 and 64 meV have been used and evidence has been obtained of energy gain and energy loss events. The energy analyzer can be used in two modes: (1) to fix the analyzer crystal to receive atoms of a certain energy range while scanning the sample crystal or (2) to scan the analyzer crystal for a particular setting of the sample crystal. No evidence of phonons from a surface wave branch was found and most of the inelastic events occur very close to the forward direction.     

Production and decay angular distributions of the Y1 (1385) in the line-reversed reactions: π+p → K+Y1 (1385) and K−p → π−Y1 (1385) at 11.5 GeV/c

We have measured in a single experimental setup, the differential cross sections and decay angular distributions of the Y¹ (1385) produced in the two line-reversed reactions: $\text{π}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^{\mathrm{+}}\text{Y}{}^{\mathrm{1+}}\text{(1385) (279}\text{events/ω}\text{b}\text{)}\text{and K}{}^{\mathrm{?}}\text{p}\text{→ π}{}^{\mathrm{?}}\text{Y}{}^{\mathrm{1+}}\text{(1385)}$ (190 events/ωb) at 11.5 GeV/c. The data have been derived from a triggered bubble-chamber experiment using the SLAC Hybrid Facility. We find the differential cross sections and Y¹ polarizations for the two reactions to be in agreement with exchange-degeneracy predictions, if kinematic differences are taken into account. The Stodolsky-Sakurai and additive quark model predictions are in agreement with the main features of the decay angular distributions of the Y¹ (1385), except for small violations at low momentum transfer, which can be associated with a finite helicity non-flip contribution in the forward direction.     

Scattering of Li+ from LEED characterized W(110) and Si (111) surfaces at energies between 2 and 20 eV

Energy and angular distributions of Li⁺ ions scattered from W(110) and Si(111) surfaces have been measured for a wide range of scattering angles and for beam energies between 2 and 20 eV. The collision process can be explained in terms of binary collisions with single surface atoms, if the influence of the attractive part of the interaction potential is taken into account. A square well approximation for the potential makes it possible to predict the form of the energy spectrum as well as the behaviour of the angular distribution of the scattered particles for both systems. The influence of adsorbed atoms and molecules on the scattering behaviour has been investigated. Exposure of the W surface to H₂, O₂ and CO shows that surface coverages exceeding 10% of a monolayer very drastically influence the scattering. The results from the clean surfaces indicate that sufficiently precise measurements of the energy spectra of the scattered particles can yield very detailed information about the form of the interaction potential. The form of the energy spectra also contains information as to the extent of vibrational excitation of the surface atoms.