共查询到20条相似文献,搜索用时 50 毫秒
1.
M. -W. Ruf A. J. Yencha H. Hotop 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1987,5(1):9-20
Using crossed beams of ground state alkali atoms A (A = Li, Na, K, Rb, Cs) and metastable He(23 S), He(21 S) atoms, we have measured the energy spectra of electrons resulting in the respective Penning ionization processes at: thermal collision energies. The data are interpreted to yield the well depthD e * of the2Σ interaction potentials as follows: He(23 S)+A:D e * (A=Li)=868(20) meV;D e * (Na)=740(25) meV;D e * (K)=591(24) meV;D e * (Rb)=546(18) meV;D e * (Cs)=533(18) meV. He(21 S)+A:D e * (Li)=330(17) meV;D e * (Na)=277(24) meV;D e * (K)=202(23) meV;D e * (Rb)=219(18) meV;D e * (Cs)=277(18) meV. The well depth for He(23 S)+A(2Σ) is always close to 80% of the well depth for Li(2s)+A(X 1Σ). The ionization cross sections for He(21 S)+A are about 3 to 4 times larger than those for He(23 S)+A. 相似文献
2.
Jinru Wang Vladimir Baranov Diethard K. Bohme 《Journal of the American Society for Mass Spectrometry》1996,7(3):261-265
The collision-induced dissociation of the adduct ions C60(C4H8) 2 2+ and C60(C4H8) 3 2+ formed by sequential reactions of C 60 2+ with 1-butene has been investigated by using a selected-ion flow tube (SIFT) apparatus. Experiments at 295 ± 2 K in 0.35 ± 0.02 torr of helium indicated that C 60 2+ adds at least five molecules of 1-butene in a sequential fashion with rates that decrease with the number of molecules added. Collision-induced dissociation experiments in which the downstream sampling nose cone of the SIFT was biased with respect to the flow tube indicated that the adduct ions C60(C4H8) 2 2+ and C60(C4H8) 3 2+ dissociate into C 60 ·+ and (C4H8) 2 ·+ and (C4H8) 3 ·+ , respectively. These observations provide evidence for the occurrence of charge separation in the derivatization of C60 dications and support the “ball-and-chain” mechanism first proposed by Wang et al. in 1992 for the sequential multiple addition of 1,3-butadiene to C 60 2+ and C 70 2+ . 相似文献
3.
S. Suzuki Y. Kojima H. Shiromaru Y. Achiba T. Wakabayashi R. Tellgmann E.E.B. Campbell I.V. Herte 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):410-413
Photoionizationlfragmentation of endohedral fullerenes was investigated by use of laser-de sorption time-offlight (LD-TOF) mass spectroscopy. The velocity distribution of the parent ion (LaC 82 + ) was found to be bimodal, as has previously been shown for laser desorbed C 60 + . The 0 fragment ions have velocity distributions corresponding predominantly to the fast parent ion distribution. The LD-TOF mass spectra taken with a relatively low laser fluence were independent of the delay time of the extraction pulse, showing only a monotonically decreasing pattern of LaC 2n + (as n decreased). However, with higher laser fluence, it was shown that the mass distributions drastically changed from the monotonically decreasing pattern to that of C 2n + and LaC 2n + with magic numbers. Based on these findings, a plausible photoionization/fragmentation mechanism is presented and discussed. 相似文献
4.
Mehdi Moini 《Journal of the American Society for Mass Spectrometry》1992,3(6):631-636
The isomerization of linear C3H 3 + in its reaction with acetylene to cyclic C3H 3 + was studied with a quadrupole ion trap mass spectrometer. The reaction of linear C3H 3 + with 13C2H2 shows that isomerization takes place via a [C5H 5 + ]* activated complex that is unstable relative to disproportionation back into the cyclic and linear forms of C3H 3 + and acetylene. The formation of carbon-13 labeled cyclic and linear C,Hi indicates that isomerization involves skeletal exchange. Collisional stabilization of the [C5H 5 + ]* collision complex was achieved at a helium pressure of approximately 1 mtorr. 相似文献
5.
C. Brink L. H. Andersen P. Hvelplund D. H. Yu 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1994,29(1):45-48
A direct measurement of collisionally induced fission of C 60 2+ has been performed. We have measured coincidences between various charged fragments resulting from collisions between C 60 2+ and He atoms. The measurements show that C 60 2+ not only emits C2 units but also breaks up into larger, singly charged parts. In this paper, we report on coincidences between C n + (2≦n≦9) and C m + (42≦m≦48) fragment ions. 相似文献
6.
Yuichiro Tada Masakatsu Ueno Noriaki Tsuchihashi Kiyoshi Shimizu 《Journal of solution chemistry》1993,22(12):1135-1149
The limiting molar conductances Λ0 of potassium deuteroxide KOD in D2O and potassium hydroxide KOH in H2O were determined at 25°C as a function of pressure to disclose the difference in the proton-jump mechanism between an OH? (OD?) and a H3O+ (D3O+) ion. The excess conductance of the OD? ion in D2O λ E O (OD -), as estimated by the equation $$\lambda _E^O (OD^ - ) = \Lambda ^O (KOD/D_2 O) - \Lambda ^O (KCl/D_2 O)$$ increases a little with pressure as well as the excess conductance of the OH? ion in H2O $$\lambda _E^O (OH^ - ) = \Lambda ^O (KOH/H_2 O) - \Lambda ^O (KCl/H_2 O)$$ However, their rates of increase with pressure are much smaller than those of the excess deuteron and proton conductances, λ E O (D +) and λ E O (H +). With respect to the isotope effect on the excess conductance, λ E O (OH -)/λ E O (D +) decreases with presure as in the case of λ E O (H +)/λ E O (D +), but the value of λ E O (OH -)/λ E O (OD -) itself is much larger than that of λ E O (H +)/λ E O (D +) at each pressure. These results are ascribed to the difference in the pre-rotation of water molecules, which is brought about by the difference in the intial orientation of the rotating water molecule adjacent to the OH? (OD?) or the H3O+ (D3O+) ion. 相似文献
7.
Nimer Wehbe Taoufiq Mouhib Aneesh Prabhakaran Patrick Bertrand Arnaud Delcorte 《Journal of the American Society for Mass Spectrometry》2009,20(12):2294-2303
This article investigates the influence of the organic film thickness on the characteristic and molecular ion yields of polystyrene (PS), in combination with two different substrates (Si, Au) or gold condensation (MetA-SIMS), and for atomic (Ga+) and polyatomic (C 60 + ) projectile bombardment. PS oligomer (m/z ~ 2000 Da) layers were prepared with various thicknesses ranging from 1 up to 45 nm on both substrates. Pristine samples on Si were also metallized by evaporating gold with three different thicknesses (0.5, 2, and 6 nm). Secondary ion mass spectrometry was performed using 12 keV atomic Ga+ and C 60 + projectiles. The results show that upon Ga+ bombardment, the yield of the fingerprint fragment C7H 7 + increases as the PS coverage increases and reaches its maximum for a thickness that corresponds to a complete monolayer (~3.5 nm). Beyond the maximum, the yields decrease strongly and become constant for layers thicker than 12 nm. In contrast, upon C 60 + bombardment, the C7H 7 + yields increase up to the monolayer coverage and they remain constant for higher thicknesses. A strong yield enhancement is confirmed upon Ga+ analysis of gold-metallized layers but yields decrease continuously with the gold coverage for C 60 + bombardment. Upon Ga+ bombardment, the maximum PS fingerprint ion yields are obtained using a monolayer spin-coated on gold, whereas for C 60 + , the best results are obtained with at least one monolayer, irrespective of the substrate and without any other treatment. The different behaviors are tentatively explained by arguments involving the different energy deposition mechanisms of both projectiles. 相似文献
8.
K. P. Balashev M. A. Ivanov T. V. Taraskina E. A. Cherezova 《Russian Journal of General Chemistry》2006,76(5):781-790
A comparative study of dipyrido-and dibenzo-substituted 1,4-diazines {dipyrido[f,h]quinoxaline (dpq), dipyrido[a,c]phenazine (dppz), 6,7-dicyanodipyrido[f,h]quinoxaline (dicnq), dibenzo[f,h]quinoxaline, dibenzo[a,c]phenazine, 6,7-dicyanodibenzo[f,h]-quinoxaline}, o-phenantroline (phen), and also of the complexes [Pt(N∧C)(N∧N)]+[(N∧C)? are deproronated forms of 2-phenylpyridine and 2-(2-thienyl)pyridine; (N∧N) is ethylenediamine, phen, dpq, dppz, dicnq] was carried out by the methods of 1H NMR, electronic absorption, and emission spectroscopy and by cyclic voltammetry. It was found that in frozen solutions of [Pt(N∧C)·(N∧N)]+ complexes the photoexcitation energy decay from two lowest in energy electronic excited states has isolated character and is localized on {Pt(N∧C)} and {Pt(N∧N)} metal-complex fragments: (d-π N∧C * ) and (d-π phen * ) [(N∧N) = phen, dpq, dicnq)] or (d-π N∧C * ) and (π-π diaz * ) [(N∧N) = dppz]. Thermal quenching of the luminescence from the (d-π phen * ) and (π-π diaz * ) states gives rise to luminescence of the complexes in liquid solutions at 293 K only from the (d-π N∧C * ) state. 相似文献
9.
Wei Guo Xiaojing Feng Xingqiang Lu 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(7):1222-1227
We experimentally measured the kinetic energy and angular distributions of fragment ion H+ of H2 as a function of 810 nm femtosecond laser intensity by using velocity map imaging technique. The reasonable origination of dissociation channels (1.0) and (1.1) are proposed. The analysis of the angular distribution indicates the net two-photon pathway via the 3ω crossing dominates over the direct one-photon pathway in channel (1.0). The relative yield of fragment peaks indicates that dissociation and ionization of H 2 + are competitive. The lower laser intensities emphasize the dissociation probability of H 2 + , and the higher laser intensities favor higher ionization stages. 相似文献
10.
T.M. Bernhardt B. Kaiser K. Rademann 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):327-330
Mass-selected antimony cluster ions Sb n + (n = 3-12) and bismuth cluster ions Bi {ntn} + (n = 3-8) are allowed to collide with the surface of highly oriented pyrolytic graphite at energies up to 350 eV. The resulting fragment ions are analysed in a time-of-flight mass spectrometer. Two main fragmentation channels can be identified. At low impact energies both Sb n + and Bi n + cluster ions lose neutral tetramer and dimer units upon collision. Above about 150 eV impact energy Sb 3 + becomes the predominant fragment ion of all investigated antimony clusters. The enhanced stability of these fragment clusters can be explained in the framework of the polyhedral skeletal electron pair theory. In contrast, Bi n + cluster scattering leads to the formation of Bi 3 + , Bi 2 + and Bi+ with nearly equal abundances, if the collision energy exceeds 75 eV. The integral scattering yield is substantially higher in this case as compared to Sb n + clusters. 相似文献
11.
Chahan Yeretzian Robert L. Whetten 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1992,24(2):199-202
The yield of C 60 + ions reflected from the surface of graphite is found to be a bimodal function of the energy of impact. Below 140 eV (6 km/s), the yield decreases with energy and the scattering time-of-flight peak is sharp. Above 170 eV, the yield increases, but the peak is broad and asymmetric, corresponding to delayed electron emission from an impact-heated, neutralized cluster. There is also evidence for fragmentation to C58 and C56. The emission process may be analogous to that reported for scattered C 60 ? . Application of statistical rate theory to either observation (C 60 ± ) gives an estimated 25–30 percent transfer of impact energy into cluster internal modes. The decreasing yield at highest energies (>400 eV) may result from adhesion processes (C60-surface bonding) that could also account for the absence of delayed electron emission in C60-silicon collisions. 相似文献
12.
J. D. Coffman M. Gallmann I. V. Hertel 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1989,12(1-4):297-301
A new technique is presented which allows direct observation of initial kinetic energies in multiphoton ionisation-fragmentation processes of molecules and clusters and provides an unambiguous determination of metastable decay channels. Results are presented for the unimolecular loss of a monomer from clusters (C6H6) 8 + to (C6H6) 12 + and for the reaction C6H 6 + →C4H 4 + +C2H2. We also observe a significant amount of probably collision induced fragmentation processes (C6H6) n + →(C6H6) n?x + + (C6H6) x withx much larger than 1. 相似文献
13.
Zhao-yang Liu Rong-bin Huang Lan-sun Zheng 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1996,38(2):171-177
Both positive and negative phosphorus cluster ions were generated from the laser ablation of a red phosphorus sample. The mass distribution of phosphorus cluster ions was found to be very sensitive to the power density of the ablation laser. The P 7 + species exhibits the highest signal intensity in the recorded mass spectra of bare phosphorus cluster cations, as does P 5 - among the anions. Their special structural stability can be attributed to their planar configuration and their aromatic character. As the phosphorus cluster size increases, the odd/even alternation of the signal intensity becomes more pronounced. For the P n + species with n > 24, the relative abundance varies in the order of 8 and P n + with n = 8k + 1 (k = 3–11) are more intense than their neighbors. For comparison, some binary phosphide cluster ions, including CnP m - , SinP m - , BnP m + and AlnP m + , were produced as well. The mass distribution of binary phosphide cluster ions changes with different components. From analysis of the recorded mass spectra of the phosphide cluster ions, the larger clusters may be in a polyhedral configuration and tend to have all valence electrons paired. 相似文献
14.
V. Staemmler 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1990,16(3):219-227
SCF and CEPA calculations are applied to study the structure of small He cluster ions, He n + ,n=2, 3, 4, 5 and some low-lying Rydberg states of He4. The effect of electron correlation upon the equilibrium structures and binding energies is discussed. He 3 + has a linear symmetric equilibrium geometry with a bond length of 2.35a 0 and a binding energyD e =0.165 eV with respect to He 2 + +He (experimentally:D 0=0.17 eV which corresponds toD e ≈0.20 eV). He 4 + is a very floppy molecular ion with several energetically very similar geometrical configurations. Our CEPA calculations yield a T-shaped form with a He 3 + centre (R e = 2.35a 0) and one inductively bound He atom (4.39a 0 from the central He atom of He 3 + ) as equilibrium structure. Its binding energy with respect to He 3 + +He is 0.031 eV. A linear symmetric configuration consisting of a He 2 + centre with a bond length of 2.10a 0 and two inductively bound He atoms (4.20a 0 from the centre of He 2 + ) is only 0.02–0.03 eV higher in energy. We expect that in larger He cluster ions structures with He 2 + and He 3 + centres andn?2 orn?3 inductively bound He atoms have nearly the same energies. In He4 a low-lying metastable Rydberg state (3 Π symmetry for linear He 4 * ,3 B 1 for the T-shaped form) exists which is slightly stronger bound with respect to He 3 * +He than the corresponding ion. 相似文献
15.
Y. Saito H. Ito I. Katakuse 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,19(4):189-190
Manganese cluster ions Mn k + (k?60) have been produced by 7 keV Xe ion bombardment and analyzed by a double-focusing mass spectrometer. Discontinuous variations of intensity are found atk=5, 14, 16, 29, 34, 45 and 54. Most of these magic numbers coincide with or differ by only one from those observed in Ar k + . The similarity in magic numbers between Mn k + and Ar k + indicates that the bonding nature in the charged Mn clusters is similar to that in the charged Ar clusters; The polarization force between a positive ion in the center of a cluster and surrounding neutral atoms is dominant binding force. 相似文献
16.
M. Braga A. Rosén S. Larsson 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,19(4):435-438
The electronic spectrum of C60 is calculated using quantum mechanical methods. The first allowed transition in C60 is calculated at an energy of 3.5 eV and with an oscillator strength of 0.09. Several transitions are found at higher energies with comparatively strong oscillator strengths, the strongest one being at 5.78 eV (λ=214 nm). The calculated energy level diagram of C60 is also used to predict wavelengths for transitions in C 60 + and C 60 ? . A comparison is made with some recently observed diffuse interstellar bands at 1180 nm and 1320 nm, which have been speculated to originate from C 60 + . 相似文献
17.
L. Brencher B. Nawracala H. Pauly 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1988,10(2-3):211-220
Using crossed molecular beams we have investigated ionizing collisions between potassium atoms in their 42 P 3/2-states, leading to the exit channelsK 2 + +e ?,K ++K ?, andK(42 S 1/2)+K ++e ?, respectively. Measurements of the total ionization cross section as well as of the cross sections for the individual channels are reported as a function of both the relative collision energy (0.2 to 2.4 eV) and the angle between the electric field vector of the exciting laser light and the relative velocity vector. The results are interpreted in terms of the molecular states of theK 2 * quasi molecule which are involved in the ionization process. 相似文献
18.
Xinghua Li Davorka Azinović Slobodan Milošević Goran Pichler 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,28(2):135-140
The7Li2 21 Σ u + →X 1 Σ g + electronic transition has a bound-bound and a bound-free part due to the double minimum nature of the upper 21 Σ u + state. We have studied this transition both experimentally and by performing spectral simulations. When inner well was excited the bound-free part at 4525 Å was observed due to the collisions between Li 2 * and argon. We found that when levels above the barrier are excited the bound-free emission is strongly affected by collisional relaxation of Li 2 * by Li atoms. Conditions for the observation of the bound-free part are discussed. 相似文献
19.
Helge Egsgaard 《Journal of the American Society for Mass Spectrometry》1996,7(6):559-564
The first three reactions of the Calcote mechanism for soot formation, that is, C3H 3 + +C2H2→C5H 5 + , C5H 5 + →C5H 3 + H2, and C5H 3 + +C2H2→C7H 5 + , have been studied based on chemi-ions withdrawn directly from a premixed methane-oxygen flame by supersonic molecular beam sampling. The first reaction is reversible and involves the formation of a specific encounter complex sensitive to pressure and ion kinetic energy. The second reaction appears to require large amounts of internal energy in the C5H 5 + ion to proceed. The third reaction is reversible; however, in contrast to the initiating reaction, the C5H 3 + ion formed from the [C7H 5 + ]* complex exhibits a much lower reactivity. The conclusions are based on ion-molecule reactions as well as collision activation mass spectrometry of isolated chemi-ions. In addition, the product distributions as functions of pressure and ion kinetic energy were studied. 相似文献
20.
T. Kunz S. Neeser H. Langhoff 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,42(2):101-104
The transitions between Ar 2 * (5p) and Ar 2 * (4sΣ u) have been investigated by absorption spectrometry. The fine structure of the Ar 2 * (5p 3 Π g) was attributed to a predominantly Hund’s case a coupling. A spin orbit coupling constant of A = (9.8±0.3) cm-1 results. Absorption by the singlet system allows one to determine the triplet/singlet splitting between the Ar 2 * (4s Σ u) states to be (540 ± 100) cm-1. The transition probabilities of the Ar 2 * (5p) and Ar 2 * (6p) levels were determined by saturation spectrometry yielding values between (0.2–2.5) · 106 s-1. 相似文献