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1.
Optical absorption spectra of single crystals of the ferromagnetic semiconductor VBO3 are studied at high pressures up to 70 GPa achieved in a diamond-anvil cell. An electronic transition accompanied by sharp changes in the optical parameters and a decrease in the optical gap from E 0 = 3.02 eV to 2.25 eV is found at the pressure P C ~ 30 GPa. The gap does not disappear in the high-pressure phase and its value becomes typical of semiconductors. This is indicative of a semiconductor-semiconductor transition. The transition to the metallic state may occur at the critical pressure P met ≈ 290 GPa. 相似文献
2.
D. P. Kozlenko T. A. Chan S. E. Kichanov Z. Jirák L. S. Dubrovinsky B. N. Savenko 《JETP Letters》2011,92(9):590-594
The crystal structure and Raman spectra of Pr0.7Ca0.3MnO3 manganite at high pressures of up to 30 GPa and the magnetic structure at pressures of up to 1 GPa have been studied. A structural
phase transition from the orthorhombic phase of the Pnma symmetry to the high-pressure orthorhombic phase of the Imma symmetry has been observed at P ∼ 15 GPa and room temperature. Anomalies of the pressure dependences of the bending and stretching vibrational modes have
been observed in the region of the phase transition. A magnetic phase transition from the initial ferromagnetic ground state
(T
C = 120 K) to the A-type antiferromagnetic state (T
N = 140 K) takes place at a relatively low pressure of P = 1 GPa in the low-temperature region. The structural mechanisms of the change of the character of the magnetic ordering
have been discussed. 相似文献
3.
The optical absorption spectra from bismuth ferrite (BiFeO3) have been studied at high pressures up to 60 GPa in diamond anvil cells. An electronic transition at which the energy of the optical absorption edge decreases sharply from ~1.5 eV to zero has been observed at room temperature in a pressure range of 45–55 GPa. This indirectly indicates a insulator-metal transition. The observed electronic transition correlates with the recently revealed structural and magnetic transitions induced by high pressures in this crystal. The behavior of the optical absorption edge with decreasing the pressure is completely reversible in correlation with the reversibility of the magnetic transition. The “smearing” of the structural transition in pressure is caused by thermal fluctuations between the high-spin state and low-spin state of the Fe3+ ions near the transition. 相似文献
4.
V. P. Glazkov S. E. Kichanov D. P. Kozlenko B. N. Savenko V. A. Somenkov 《JETP Letters》2002,76(4):215-217
The transformation of magnetic structure under hydrostatic and quasi-hydrostatic pressures up to 4 GPa was studied for iron borate FeBO3 by the neutron diffraction method. Under quasi-hydrostatic conditions, the orientation of iron magnetic moments changes at pressures P≥1.4 GPa. Under hydrostatic conditions, no changes in the magnetic structure of iron borate were observed up to 2.1 GPa. This behavior is caused by the influence of the inhomogeneity (in magnitude and direction) of elastic stresses on the configuration of magnetic sublattices. 相似文献
5.
I. A. Troyan M. I. Eremets A. G. Gavrilyuk I. S. Lyubutin V. A. Sarkisyan 《JETP Letters》2003,78(1):13-16
The optical absorption spectra of iron borate FeBO3 were measured in diamond anvil cells at high pressures up to P=82 GPa. The electronic transition with an abrupt jump in the absorption edge from ~3 to 0.8 eV was observed at P≈46 GPa. The resistance and its temperature dependence were directly measured for FeBO3 at high pressures up to 140 GPa. It was established that the electronic transition at P≈46 GPa was accompanied by the insulator-semiconductor transition. In the high-pressure phase, the thermoactivation gap decreases smoothly at 46<P<140 GPa approximately from 0.55 to 0.2 eV following the linear law. The extrapolated value of the pressure at which the sample becomes fully metallic is equal to about 210 GPa. 相似文献
6.
E. G. Ponyatovskii G. E. Abrosimova A. S. Aronin V. I. Kulakov I. V. Kuleshov V. V. Sinitsyn 《Physics of the Solid State》2002,44(5):852-856
The effect of high pressure on the structure of Cu2O is investigated. Polycrystalline samples are treated during different periods of time at different temperatures and pressures in the vicinity of the kinetic curve of the decomposition Cu2O → Cu+CuO. The structure of the samples subjected to thermobaric treatment is characterized by x-ray diffraction, electron diffraction structural analysis, and electron microscopy at atmospheric pressure. It is found that, upon treatment of Cu2O at temperatures and pressures close to the decomposition region, the microstructure undergoes a transformation into the nanocrystalline state. 相似文献
7.
P. A. Usachev R. V. Pisarev A. M. Balbashov A. V. Kimel A. Kirilyuk Th. Rasing 《Physics of the Solid State》2005,47(12):2292-2298
Optical properties of the orthorhombic thulium orthoferrite TmFeO3 were studied in the spectral range from 0.64 to 5.4 eV. In the weak absorption region, below 2.2 eV, the energies of localized optical transitions in the Tm3+ and Fe3+ ions were determined. The dispersion relations of the real and imaginary parts of the principal refractive indices along three crystallographic axes were found. In the region of strong absorption, above 2.2 eV, the energies of six charge-transfer transitions were determined. The experimental data fit well to the concept of charge-transfer transitions in the FeO 6 9? octahedral complexes providing a dominant contribution to the optical properties of the orthoferrites. Optical birefringence and its temperature dependence were measured for the three principal directions of light propagation, and the anisotropic magnetic contribution to birefringence in the region of spin-orientational transitions was isolated. 相似文献
8.
Change in the crystal structure of the BiFeO3 multiferroic at high pressures up to 70 GPa in a diamond anvil cell has been studied by the method of synchrotron x-ray diffraction at room temperature. The experiment has been carried out under hydrostatic conditions with helium as a pressure-transferring medium. An anomaly has been observed in the behavior of the structural parameters at pressures P c ≈ 40?50 GPa. This anomaly correlates with the effect of the magnetic collapse of iron moments revealed in this pressure range. It has been found that the bulk compression modulus is equal to B 0 = (75.5 ± 15.5) GPa in the interval 0 < P < P c and is almost quadrupled to a value of B = (292 ± 9) GPa in the interval P > P c. When the pressure decreases, the behavior of the structural parameters is completely reversible in correlation with the reversibility of the magnetic transition. The “diffuseness” of the structural transition in pressure is explained by thermal fluctuations between the high-and low-spin states of Fe3+ ions in the transition region. 相似文献
9.
R. M. Shymkiv S. A. Sveleba I. V. Karpa I. N. Katerynchuk I. M. Kunyo E. I. Phitsych 《Journal of Applied Spectroscopy》2012,78(6):823-828
Optical absorption spectra in thin [N(CH3)4]2CuCl4 crystals in the thickness range 10 μm ≤ d < 100 μm have been studied. Strengthening of the crystal field has been found with
a decrease in the [N(CH3)4]2CuCl4 crystal size. The reasons for absorption band shifts in the visible region depending on the [N(CH3)4]2CuCl4 crystal thickness and the manifestation of a size effect in crystals with an incommensurate superstructure are discussed. 相似文献
10.
R. Z. Levitin E. A. Popova R. M. Chtsherbov A. N. Vasiliev M. N. Popova E. P. Chukalina S. A. Klimin P. H. M. van Loosdrecht D. Fausti L. N. Bezmaternykh 《JETP Letters》2004,79(9):423-426
Cascade of phase transitions in GdFe3(BO3)4 at 156, 37, and 9 K has been detected by specific heat measurements and further studied by Raman scattering and Nd3+ spectroscopic probe method. A weakly first-order structural phase transition at 156 K is followed by a second-order antiferromagnetic ordering phase transition at 37 K and a first-order spin-reorientational phase transition at 9 K. 相似文献
11.
D. P. Kozlenko N. T. Dang Z. Jirák S. E. Kichanov E. V. Lukin B. N. Savenko L. S. Dubrovinsky C. Lathe C. Martin 《The European Physical Journal B - Condensed Matter and Complex Systems》2010,77(3):407-411
The crystal and magnetic structures of Pr0.15Sr0.85MnO3
manganite have been studied by means of powder X-ray and neutron diffraction
in the temperature range 10–400 K at high external pressures up to 55 and 4 GPa, respectively. A structural phase transition
from cubic to tetragonal
phase upon compression was observed, with large positive pressure
coefficient of transition temperature dT
ct
/dP = 28(2) K/GPa. The C-type
antiferromagnetic (AFM) ground state is formed below T
N
≈ 260 K
at ambient pressure. While at ambient pressure the structural and magnetic
transition temperatures are close, T
ct
~ T
N
, upon compression
they become decoupled with T
N
≪ T
ct
due to much weaker
T
N
pressure dependence with coefficient dT
N
/dP = 3.8(1) K/GPa. 相似文献
12.
M. V. Gorev V. S. Bondarev S. I. Raevskaya I. N. Flerov M. A. Malitskaya I. P. Raevskii 《Bulletin of the Russian Academy of Sciences: Physics》2016,80(9):1046-1050
Temperature dependences of specific heat Cp(T) and coefficient of thermal expansion ;(T) for Na0.95Li0.05NbO3 sodium-lithium niobate ceramic samples are investigated in the temperature range of 100–800 K. The Cp(T) and α(T) anomalies at T3 = 310 ± 3 K, T2 = 630 ± 8 K, and T1 = 710 ± 10 K are observed, which correspond to the sequence of phase transitions N ? Q ? S(R) ? T2(S). The effect of heat treatment of the samples on the sequence of structural distortions was established. It is demonstrated that annealing of the samples at 603 K leads to splitting of the anomaly corresponding to the phase transition Q → R/S in two anomalies. After sample heating to 800 K, the only anomaly is observed in both the Cp(T) and ;(T) dependence. Possible mechanisms of the observed phenomena are discussed. 相似文献
13.
A. V. Malakhovskii S. L. Gnatchenko I. S. Kachur V. G. Piryatinskaya A. L. Sukhachev V. L. Temerov 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(5):721-723
Optical absorption spectra of the trigonal crystal of TbFe3(BO3)4 in the vicinity of the 7F6 → 5D4 transition in a Tb3+ ion were studied as a function of temperature (2–70 K) and magnetic field strength (0–60 kOe) at 2 K. The splitting of the
excited states of Tb3+ due to both the magnetic ordering of iron and an external magnetic field was determined. Abrupt splitting of the absorption
lines of Tb3+ at temperature TN of the magnetic ordering of the subsystem of iron was revealed, suggesting that the nature of such splitting is not entirely
magnetic. 相似文献
14.
Electrical transport and structural characterizations of isoelectronically substituted Ba(Fe0.9Ru0.1)2As2 have been performed as a function of pressure up to ~ 30 GPa and temperature down to ~ 10 K using designer diamond anvil cell. Similar to undoped members of the AFe2As2 (A = Ca, Sr, Ba) family, Ba(Fe0.9Ru0.1)2As2 shows anomalous a-lattice parameter expansion with increasing pressure and a concurrent ThCr2Si2 type isostructural (I4/mmm) phase transition from tetragonal (T) phase to a collapsed tetragonal (cT) phase occurring between 12 and 17 GPa where the a is maximum. Above 17 GPa, the material remains in the cT phase up to 30 GPa at 200 K. The resistance measurements show evidence of pressure-induced zero resistance that may be indicative of high-temperature superconductivity for pressures above 3.9 GPa. The onset of the resistive transition temperature decreases gradually with increasing pressure before completely disappearing for pressures above ~ 10.6 GPa near the T-cT transition. We have determined the crystal structure of the high-T c phase of Ru-doped BaFe2As2 to remain as tetragonal (I4/mmm) by analyzing the X-ray diffraction pattern obtained at 10 K and 9.7 ± 0.7 GPa, as opposed to inferring the structural transition from electrical resistance measurement, as in a previous report [S.K. Kim, M.S. Torikachvili, E. Colombier, A. Thaler, S.L. Bud’ko, P.C. Canfield, Phys. Rev. B 84, 134525 (2011)]. 相似文献
15.
We have used x-ray photoelectron spectroscopy to investigate the charge state of oxygen found in the basal structural plane
of YBa2Cu3O6+γ.. We have observed a change in this state after thermal treatment, with a transition to the adjacent structural phase region.
We have shown that changes in the charge state of oxygen can be used as an indicator of structural changes occurring in YBa2Cu3O6+δ.. We have found that the rate of structural relaxation yttrium barium cuprate depends on the amount of structural water
it contains.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 195–198, March–April, 2007. 相似文献
16.
(NH4)3NbOF6 single crystals were grown, polarization-optical studies were performed, and birefringence was measured over the temperature range 90–500 K. A sequence of first-order structural phase transitions was found at temperatures T 1↓ = 259.7 K and T 2↓ = 257.7 K with temperature hysteresis δT 1 = 0.9 K and δT 2 = 1.9 K. The transitions are accompanied by twinning and the following change in the crystal symmetry: cubic ? tetragonal ? monoclinic. Optical second harmonic generation is found to occur at room temperature, which indicates that the cubic phase is not centrosymmetric. It is assumed that the phase transitions are ferroelastic and ferroelectric in nature. 相似文献
17.
The dielectric and magnetic measurements of the KMnF3 crystals obtained by the Czochralski and Bridgman methods have been performed. Three structural transitions have been observed
in the crystals. The mutual arrangement of the temperature of magnetic ordering and the temperature of the lower structural
transition determines the number and type of magnetic transitions in these crystals. 相似文献
18.
A. M. Balagurov I. A. Bobrikov V. Yu. Pomjakushin E. V. Pomjakushina D. V. Sheptyakov I. O. Troyanchuk 《JETP Letters》2011,93(5):263-268
The magnetic and crystal structures of the Pr0.5Sr0.5CoO3 metallic ferromagnet have been studied by the neutron diffraction technique. It is demonstrated that below 150 K, the compound
is mesoscopically separated into two crystalline phases with different spatial symmetries and with different directions of
the magnetic anisotropy. The phase separation exists down to 1.5 K, and at temperatures below 90 K, the low-symmetry phase
occupies about 80% of the sample volume. The main structural difference between the phases is the configuration of oxygen
atoms around praseodymium and, to a certain extent, around cobalt. The ferromagnetic structure with the magnetic moment lying
in the basal plane of the structure (μCo ≈ 1.7 μ
B
at 1.5 K) arises at 234 K, whereas the component directed along the long axis of the unit cell appears at 130 K. The formation
of the new structural phase and change in the orientation of the magnetic moment give rise to the anomalies of the physical
and magnetic characteristics of this compound observed earlier at temperatures about 120 K. 相似文献
19.
S. V. Gorbunov A. F. Zatsepin V. A. Pustovarov S. O. Cholakh V. Yu. Yakovlev 《Physics of the Solid State》2005,47(4):733-737
A time-resolved cathodo-and photoluminescence study of nanostructural modifications of Al2O3 (powders and ceramics) excited by heavy-current electron beams, as well as by pulsed synchrotron radiation, is reported. It was found that Al2O3 nanopowders probed before and after Fe+ ion irradiation have the same phase composition (the γ-phase/δ-phase ratio is equal to 1), an average grain size equal to ~17 nm, and practically the same set of broad cathodoluminescence (CL) bands peaking at 2.4, 3.2, and 3.8 eV. It was established that Al2O3 nanopowders exhibit fast photoluminescence (PL) (a band at 3.2 eV), whose decay kinetics is described by two exponential stages (τ1 = 0.5 ns, τ2 = 5.5 ns). Three bands, at 5.24, 6.13, and 7.44 eV, were isolated in the excitation spectrum of the fast PL. Two alternate models of PL centers were considered, according to which the 3.2-eV luminescence either originates from radiative relaxation of the P? centers (anion-cation vacancy pairs) or is due to the formation of surface analogs of the F+ center (F S + -type centers). In addition to the fast luminescence, nano-Al2O3 was found to produce slow luminescence in the form of a broad band peaking at 3.5 eV. The excitation spectrum of the 3.5-eV luminescence obtained at T = 13 K exhibits two doublet bands with maxima at 7.8 and 8.3 eV. An analysis of the luminescent properties of nanostructural and single-crystal Al2O3 suggests that the slow luminescence of nanopowders at 3.5 eV is due to radiative annihilation of excitons localized near structural defects. 相似文献
20.