细胞骨架微管中水分子Kerr效应对电磁场辐射的影响

微管是细胞骨架的主要组成成分和功能组件,其中充满了属于Kerr介质的液体水。本文运用量子场论路径积分方法,研究微管中水分子与电磁场的相互作用。为了考虑Kerr效应,在系统的哈密顿量中引入电磁场的非谐项。我们给出了含有Kerr非线性项的电磁辐射运动方程,进而讨论了Kerr效应对电偶极子集体辐射的影响。     

Molecular Spectroscopy with Coherent Radiation Sources

Various characteristics of molecules have been clarified by spectroscopic methods in which the interactions of molecules with the radiation field were investigated. A stationary response of a molecule excited by a radiation field appears as a spectral line. Information on molecules may be obtained from position (resonance frequency), intensity, and shape and width of the spectral line. So far the interaction of molecules with the radiation field has been studied primarily in a “frequency domain.” Although molecular spectroscopy is one of the research fields in modern science which has the longest history, a variety of important aspects have been demonstrated very recently in this field as radiation sources have been improved. When the radiation field is “weak,” the photon nature of the radiation field is dominant in the interaction with a molecule, such as in the cases of emission, absorption, and scattering of photons. When the radiation field is “strong,” in the sense that many photons exist in a proper mode of the radiation field, the wave nature of the field plays an important role in the interaction. In this case the radiation may be described in the form of the classical field, say, a sinusoidal function of the time and spatial coordinates, coherently interacting with the molecule, which is described quantum mechanically. Here nonlinear properties would appear in the interactions: saturation in absorption, induced scattering, multiphoton processes, coherent transients, etc.     

Intense interactions of molecules with a short-wavelength electromagnetic radiation field: I. The fundamentals of the nonadiabatic theory

The intense interactions between short-wavelength (SW) electromagnetic radiation with a wavelength λ ≥ 1 Å and intensity up to 10¹⁴ W/cm² and simple and polyatomic molecules are studied with the coherent excitations of high-lying Rydberg and autoionizing states taken into account. The Hamiltonian of a system “molecule + SW radiation” is obtained by using the methods of quantum electrodynamics. Conditions for the applicability of the dipole approximation to describe the interactions of molecules with radiation of the UV, VUV, XUV, and soft X-ray range are found. The fundamentals of the theory of resonance scattering of SW radiation from diatomic, triatomic, and symmetric-and asymmetric-top polyatomic molecules are outlined.     

Optical pumping of trapped neutral molecules by blackbody radiation

Optical pumping by blackbody radiation is a feature shared by all polar molecules and fundamentally limits the time that these molecules can be kept in a single quantum state in a trap. To demonstrate and quantify this, we have monitored the optical pumping of electrostatically trapped OH and OD radicals by room-temperature blackbody radiation. Transfer of these molecules to rotationally excited states by blackbody radiation at 295 K limits the 1/e trapping time for OH and OD in the X(2)Pi(3/2), v" =0, J"=3/2(f) state to 2.8 and 7.1 s, respectively.     

Phase-matched high harmonic generation for the study of rotational coherence molecular dynamics

We report the observation of periodic modulations in the high order harmonic radiation from diatomic molecules in a semi-infinitive gas cell when a preceding femtosecond laser beam, which is off-axis to the high-harmonic generation beam, modifies the phase-matching condition through the field-free alignment of the molecules. The observed modulations of the high harmonic radiation versus the time delay between the pulses result from periodic changes in the nonlinear refractive index associated with rotational Raman coherence. This opens up a new potential technique for studying rotational coherence dynamics in the ground states of molecules.     

Internal vibration energy in polyatomic molecules containing chains of identical biatomic dipoles

The quantum processes of excitation and vibrational energy transport that occur in polyatomic organic molecules under IR radiation are analyzed. The polyatomic organic molecules considered contain substructures with finite numbers of identical biatomic valence bonds, which play the role of antennas that trap and accumulate IR radiation. The result of this analysis can be used for determining the sequences of amino-acid residues in oligopeptides.     

Emission characteristics of plasma based on xenon–rubidium bromide mixture

Luminescence spectra of a longitudinal pulse-periodic discharge in xenon mixture with rubidium bromide vapors (Xe–RbBr) are studied experimentally at low pressures. The conditions leading to the appearance of intense bands of ultraviolet radiation of exciplex XeBr* molecules in the spectral interval between 200 and 400 nm are found. The highest yield of UV radiation of XeBr* molecules is achieved when the temperature of discharge-tube walls is equal to 750°C. A maximum power of UV radiation from the entire plasma volume as high as 4.8 W is obtained.     

Emission characteristics of a barrier discharge in an Ar-H2O mixture

We have experimentally studied the UV radiation of a low-temperature barrier discharge plasma in an Ar-H₂O mixture. The spectral interval 300–400 nm has been examined in detail. Addition of argon with a pressure of 24 kPa to a barrier discharge in water vapor at a pressure of ～0.1 kPa leads to a ninefold increase in the UV radiation power of excited hydroxyl molecules. An increase in the duration of the UV radiation pulse of the mixture in the longitudinal discharge decay has been achieved for the first time, which may be direct evidence of energy transfer from metastable argon atoms to water molecules. An estimate of the upper boundary of the dissociative excitation rate constant of hydroxyl molecules OH*(A ²Σ⁺) upon interaction of metastable argon atoms with water molecules has been obtained.     

分子在失调腔中的辐射行为及双腔Maser的振荡现象

本文用量子力学的方法处理了分子在失调腔中的辐射行为。解释了Higa在双腔Maser实验中发现的现象:当第一个腔的频率失调达到某一临界值时,在第二个腔中发生按分子中心频率的突发振荡。求出产生这种突发振荡现象的临界失调公式。也考虑了合作效应的影响。并定性地解释了Страховский等的分子在第二腔中的辐射功率与第一腔频率失调程度的相关性的实验。     

Laser sounding of molecular iodine in the atmosphere

The lidar equation for the fluorescence of ¹²⁷I₂ molecules is numerically solved. All the radiation wavelengths of a copper vapor laser are considered with the aim of choosing the one that is the most appropriate for detection of the minimum possible concentration of iodine molecules when this laser is used as a radiation source of a fluorescence lidar.     

Intense Infrared Laser-Induced Radiation–Collision Involvement of Molecules That Do Not Absorb Laser Radiation in Resonance with a Laser Field in a Two-Component Molecular Medium

JETP Letters - Effective radiation–collision involvement of molecules that do not absorb laser radiation in resonance with a laser field in a two-component molecular medium that includes...     

Light-induced conversion of nuclear spin modifications of molecules

We report a new effect in which one nuclear spin modification of molecules is converted into another in a resonance laser radiation field. The effect is based on selective (with respect to modifications) optical excitation and the difference of the conversion rates of spin modifications for excited and unexcited molecules. The effect is expected to be very substantial and should occur for all molecules capable of absorbing the radiation of existing lasers. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 8, 498–503 (25 October 1999)     

Investigation of the stability of Mn<Subscript>12</Subscript> single molecule magnets

The stability of single crystals and monolayers of Mn₁₂ single molecule magnets under the influence of X-ray radiation and other possibly disruptive influences has been investigated by means of synchrotron radiation. Clear evidence for radiation induced sample degradation was found for both single crystals and monolayers. The comparison with spectra obtained after damaging the molecules by Ar⁺ sputtering, metal evaporation or water moistening indicates a possibility to distinguish between radiation damage and other external influences. The results clarify some of the previous conflicting reports on the integrity of Mn₁₂ molecules deposited on surfaces and are linked to the investigations aiming at studies of the electronic and magnetic properties of individual Mn₁₂ clusters.     

Quantum theory of the raman effect

The system of coupled Stokes and Antistokes radiation interacting with two level molecules is analyzed for different degrees of molecular cooperation. The generation of Stokes radiation from three level molecules is also studied. In both examples the electromagnetic field and the molecular levels are quantized and an exact solution to the Schrödinger equation is presented. The results give an insight into the role molecular coherence effects play in both spontaneous and stimulated Raman scattering.     

Computer study of the spectral characteristics of the disperse water methane system

The interaction of water clusters that adsorbed methane molecules with infrared radiation is studied by molecular dynamics. The presence of methane molecules in the disperse water system leads to an increase in absorption and emission of infrared radiation and a strong depletion of the Raman spectrum. In this case, the reflection coefficient of a monochromatic plane electromagnetic wave increases and its frequency spectrum significantly changes. The comparison of experimental data for similar characteristics of water, methane, or their mixtures is presented.     

Light-induced evaporation and condensation growth of aerosol particles

We analyze the possibility of resonant optical radiation inducing evaporation and condensation growth of aerosol particles suspended in a vapor-gas mixture. The molecules of the vapor absorb radiation selectively as to velocity. We examine the Knudsen regime, in which the particle radius is much smaller than the mean free path of the molecules. Zh. éksp. Teor. Fiz. 113, 1036–1047 (March 1998)     

Collective spontaneous emission of dye molecules and lasing

The threshold pump power density for lasing in dye solutions is found to depend on the photon energy of pumping radiation. An increase in the pumping photon energy can significantly lower the threshold pump power of dye lasers. For an ethanol solution of rhodamine 6G with a concentration of 4×10¹⁸ cm^?3, the threshold power density for pumping radiation with a wavelength of 532 nm is 20-fold higher than for pumping radiation with a wavelength of 347 nm. This phenomenon is associated with the competition of collective spontaneous emission, which can lead to the efficient deactivation of excited molecules in femtosecond times, and the dephasing of excited molecules due to the intramolecular nonradiative processes of absorbed-energy conversion. An increase in the dephasing rate with the increasing energy of exciting photons lowers the efficiency of collective spontaneous emission and increases the concentration of dephased excited molecules responsible for lasing.     

Selecting molecules embedded in nanodroplets (clusters) of superfluid helium

A method of selecting molecules embedded in nanodroplets (clusters) of superfluid helium is proposed, which is based on the selective vibrational excitation of embedded molecules by intense IR laser radiation. This action leads to a significant decrease in size of the excited clusters, after which these clusters are separated with respect to size via scattering of the cluster beam on a crossing atomic beam. The method is described in detail and the possibility of selecting SF₆ molecules in liquid helium nanodroplets using the excitation by CO₂ laser radiation and the angular separation via scattering on a xenon atomic beam is demonstrated. The results show that, by using this technique, it is possible to separate molecules with respect to isotope (element) composition. Advantages and drawbacks of the method are analyzed.     

Role of weak transitions in multiphoton excitation of molecules by IR laser radiation

Simultaneous excitation of a considerable part of molecules from many rotational levels of the ground state to higher vibrational states by IR laser radiation can be explained by considering weak transitions in a rotational band structure as it is shown at the example of SF₆ molecule. Very accurate compensation of anharmonicity in relatively wide spectral interval at comparatively low intensity of laser radiation can be explained on this basis. The considered scheme can be applied to the molecules of various symmetry with arbitrary anharmonicity.