共查询到17条相似文献,搜索用时 234 毫秒
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研究了多种Rh:BaTiO3和Ce:BaTiO3晶体样品的受激背向光折变散射自抽运相位共轭特性和响应时间特性.结果表明,入射光与晶体a面或b面法线的夹角较大时,自抽运相位共轭光有更高的反射率、更快响应时间.利用前向二波耦合特性和相向二波耦合特性对实验现象给予合理的解释.实验结果表明,多数Ce:BaTiO3晶体比Rh:BaTiO3晶体的共轭光反射率高.
关键词:
钛酸钡晶体
二波耦合
自抽运相位共轭
响应时间 相似文献
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用干涉仪的方法测量了Ce:BaTiO3晶体的低频电光系数和压电系数.排除压电效应对光通过晶体引起相位的变化,得到低频下经极化的Ce:BaTiO3单晶的电光系数r42=1945±220pm/V和r13=11.8±1pm/V.从而,为研究Ce:BaTiO3晶体的光折变效应和理论计算提供了精确的线性电光系数
关键词: 相似文献
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在200—300℃范围测量了单斜I镧系五磷酸盐LnP5O14(Ln=La,Ce,Pr、Nd,Sm,Eu,Gd,Tb)晶体的软光学模喇曼谱。不同LnP5O14的Ag-B2g和Ag-Ag软模在铁弹相变点都软化到20cm-1,另一个Bg-B3g软模则软化到38cm-1。软模频率对温度的依赖关系表明,这些晶体是很好的平均场理论系统。Ag-B2g软模与e5的耦合对铁弹相变起主要作用,此软模的强度变化可由双向线性模耦合模型来解释。这个系统Tc从La到Tb的增高是镧系收缩的结果。
关键词: 相似文献
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在不同频率和偏置电场下测量了BaTiO3晶体从三方相到正交相再到四方相相变过程中的介电温谱.基于BaTiO3晶体在电场作用下的偶极子偏转假设和介电特性实验结果,提出BaTiO3各结构相在电场作用下的偶极子偏转路径可以由其相邻相的介电常数随温度的变化特性表现出来.推断出各结构相的偶极子偏转路径,以及偏置电场对偶极子偏转路径的影响.
关键词:
3晶体')" href="#">BaTiO3晶体
介电特性
结构相变
偶极子偏转路径 相似文献
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The far-infrared optical and dielectric properties of ferroelectric perovskite titanate powder BaTiO3 are reported. The terahertz time-domain spectroscopy (THz-TDS) measurement reveals that the low frequency dielectric response of BaTiO3 is closely related to the lowest pair of transverse optical (TO) and longitudinal optical (LO) modes near at 180 cm−1, which is verified by Raman spectroscopy. This result provides a better understanding of the relation of low-frequency dielectric function with the optical phonon mode for ferroelectric materials. Combining terahertz TDS with Raman spectra, the overall low frequency optical phonon response of BaTiO3 is presented in an extended spectral range from 6.7 to 1200 cm−1. 相似文献
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In tetragonal BaTiO3, the over-damped E-polariton frequency of ωχ''(ω, Q), obtained from the near-forward Raman spectra, has been found to follow the usual dispersion relation. From the dispersion relation in a very small q region, ?a has been determined with precision. 相似文献
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Previous polarized infrared reflectivity spectra of BaTiO3 were unable to show the expected differences between the A1 and E phonons. This can be explained by the small penetration of light polarized perpendicularly to the ferroelectric axis in the LO-TO range of the lowest E phonon, where only the crystal surface determines the reflection of light. We show that with an adequate etching of a mono-domain single-crystal it is possible to obtain good quality spectra for both polarizations. 相似文献
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采用水热法制得表面包裹有十二烷基苯磺酸(DBS)和硬脂酸(St)的BaTiO3纳米粒子,平均粒径均为60nm左右.拉曼光谱检测结果表明,样品的确为表面包裹有表面活性剂(DBS或St)的BaTiO3纳米粒子集合体.与未包裹的相比,各光学声子模对应的拉曼振动模式峰均发生了蓝移.还发现不同的包裹体,所导致的蓝移值也不同.从纳米粒子的表面结构及包裹层的压力出发对此现象进行了定性解释和讨论.
关键词:
拉曼光谱
3纳米粒子')" href="#">DBS/ BaTiO3纳米粒子
蓝移 相似文献
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We have used in situ photoemission spectroscopy to investigate Niobium doping in polycristalline BaTiO3. The valence band maximum position progressively shifts from 2.5 eV for undoped to 2.84 eV for Nb-doped films. Ceramics and single crystal have been investigated for comparison with thin films. Nb-doped BaTiO3 ceramics and Nb-doped SrTiO3 single crystal show higher Fermi level position indicating that our doped films are less conducting regarding their bulk parents. This was confirmed by impedance spectroscopy under variable temperature. Large amount of niobium is clearly observable at surface but the amount of dopant is drastically reduced below the near-surface region, as evidenced by depth profile. Therefore, we provide evidence of surface segregation which would explain the contrasted resistivity values reported in literature for such donor-doped films. 相似文献
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采用脉冲激光气相沉积(PLD)方法,在Si(100)晶面上制备了Co:BaTiO3纳米复合薄膜.采用X射线衍射(XRD)结合透射电镜(TEM)方法研究了两种厚度Co:BaTiO3纳米复合薄膜的晶体结构,当薄膜厚度约为30 nm时,薄膜为单一择优取向;当薄膜厚度约为100nm时,薄膜呈多晶结构.原子力显微镜(AFM)分析表明,当膜厚为30nm时,薄膜呈现明显的方形晶粒.采用紫外光电子能谱(UPS)研究了Co的价态和Co:BaTiO3纳米复合薄 相似文献
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采用脉冲激光气相沉积(PLD)方法,在Si(100)晶面上制备了Co:BaTiO3纳米复合薄膜.采用X射线衍射(XRD)结合透射电镜(TEM)方法研究了两种厚度Co:BaTiO3纳米复合薄膜的晶体结构,当薄膜厚度约为30 nm时,薄膜为单一择优取向;当薄膜厚度约为100nm时,薄膜呈多晶结构.原子力显微镜(AFM)分析表明,当膜厚为30nm时,薄膜呈现明显的方形晶粒.采用紫外光电子能谱(UPS)研究了Co的价态和Co:BaTiO3纳米复合薄
关键词:
3')" href="#">BaTiO3
纳米复合薄膜
紫外光电子能谱 相似文献