Influence of IR Radiation on the Electron Mobility in Submicron Layers of GaAs

The influence of optical radiation near the impurity absorption band on the electron mobility in submicron doped gallium arsenide layers formed on semiinsulating substrates is investigated. To determine the lowfield mobility of carriers, a method is used which is based on measurements of the mutual conductance and series resistances of a fieldeffect transistor at low sourcetodrain voltage. It has been established that the electron mobility increases under IR illumination as a consequence of decrease in electron scattering, and this is related to the photoneutralization of deeplying chrome acceptors.     

An ARC Facility for Studying Carbon Plasma and Obtaining Low‐Dimensional Carbon Structures

An experimental DUF2000 facility for spectroscopic investigations of a reducedpressure carbon arc and also for production of lowdimensional carbon structures (fullerenes, nanotubes, etc.) is described.     

Microwave Photonic Signal Down‐Conversion Using a Novel Two‐Frequency Bragg Grating Based Brillouin Fiber Laser

A simple technique using a novel twofrequency Bragg grating based Brillouin fiber laser to downconvert high frequency microwave photonic signals is presented. The mechanism of the Brillouin fiber laser and the principle of this technique for microwave photonic signal downconversion are analyzed. The 12GHz microwave photonic signals are experimentally downconverted to 1.13GHz IF signal with the technique.     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

Spectral‐Luminescence and Generation Properties of 1‐Aza‐2‐Methyl‐6‐Aminopyrene and of Its Protolytic Forms

Spectral manifestations of protolytic forms of 1aza2methyl6aminopyrene in ethanol and aqueous solutions are investigated. The ionization constants of the protolytic forms are determined. The generation properties and photostability of a neutral molecule and a cation in excitation by an excimer XeCl laser are studied.     

Procedure for Automated Measurement and Calculation of the Electrophysical Parameters of Solar Cells

We described the procedures for automated measurement and calculation of the electrophysical parameters of solar cells on the basis of the IBM PC, a solar radiation simulator, V721A digital voltmeters, and a programcontrolled potentiometer which ensure the programmed assignment of the load resistance in the range 0.002–15,000 and measurement of the light voltampere characteristics of the solar cells, a shortcircuit current, and the opencircuit voltage and also calculated the basic parameters of the solar cells, such as the efficiency, the fullfactor of the voltampere characteristics, optimum and maximum power, optimum load resistance, series and shunt resistance, and the matching factor for the ideal and experimental voltampere characteristic of the solar cells. The error in the measurement and calculation of the solar cell parameters does not exceed 0.2%.     

Calculation of Out‐of‐Plane Vibrations of a Porphin Molecule

Using the DFT/B3LYP method with the base set 631G^**, we carried out calculation of the frequencies of the normal vibrations of porphin and of its five isotopic types. Scaling of force constants for outofplane vibrations has been performed in independent natural coordinates. The symmetry coordinates are introduced and a force field for outof plane vibrations of a porphin molecule in independent coordinates of symmetry is obtained. A new correlation of the frequencies of vibrations in the type of the symmetry B _1u for the isotopic type of the d ₂ porphin molecule is suggested on the basis of discrete analysis of the distribution of a potential energy.     

Triplet‐Triplet Electron Excitation Energy Transfer in the Gas Phase for the Carbazol–Diacetyl Donor‐Acceptor Pair

For the carbazol–diacetyl donoracceptor pair, the features of exothermal triplettriplet (TT) transfer of electron excitation energy in the gas phase upon excitation of carbazol by the nitrogen laser radiation which is not absorbed by diacetyl have been investigated. The luminescence spectra of carbazol in the gas phase have been studied. It is shown that carbazol phosphorescence in the gas phase is absent. Therefore, for estimating the TT transfer efficiency and its temperature dependence, in the kinetic approximation the dependences of the intensity of timeresolved delayed fluorescence of carbazol and sensitized phosphorescence of diacetyl on diacetyl pressure have been analyzed. It has been found that in the gas phase the features of the electronic structure of the molecules under investigation are responsible for the low efficiency of transfer (2·10^–4 at 453 K), which increases by an order of magnitude with increasing temperature in the 453–513 K range despite the increasing influence of the back transfer.     

Two‐Wave CO2 Laser with Loss Modulation in Both Channels

The nonlinear dynamics of a twowave CO₂ laser with continuous pumping by an electric discharge and loss modulation in both channels is investigated theoretically. In modulation of losses with the same frequencies it is possible, by changing the shift of the phases of modulating signals, to monitor simply enough the amplitude, form, duration, and depth of modulation and also the repetition rate of radiation. Depending on the shift of phases, the maximum response can be concentrated in the lowfrequency region or propagate also to the region of high frequencies. If losses in both channels are modulated with different frequencies, a change in the relationship between these frequencies predominantly leads to a change in the shape, magnitude, and structure of response in the lowfrequency region of the amplitudefrequency characteristic (AFCh). In the highfrequency region of the amplitudefrequency characteristic, beginning from the peaks of the doubling of the vibration period, where inphase modes of radiation are implemented, the response virtually does not change. Similar regularities are observed on change in the shift of phases.     

Analog of the Auger Effect in Radiative Decay of a Trion in a Quantum Well

We have analyzed the energetics of decay of the X ^minus trion (exciton + electron) on the assumption that the exciton and trion are independent excitations of a single twodimensional semiconducting quantum well. For the first time, it has been shown that in filling a well with electrons from a selective donordoped matrix, the binding energy of the trion (of the electron with the exciton) increases linearly with a shift of the Fermi level into the depth of the c band. This agrees with the wellknown experimental data on the lowtemperature radiative decay (photoluminescence) of trions in the heterostructures ZnSe/Zn_0.89Mg_0.11S_0.18Se_0.82 and CdTe/Cd_0.7Mg_0.3Te.     

Calculation of the Tautomeric Properties of 3‐Formyl‐Tetrinic Acid by the ab initio and DFT Methods

We have carried out a nonempirical quantumchemical calculation with full optimization of the geometry of all theoretically possible tautomeric forms of 3formyltetrinic acid (FTRA) according to the Møller–Plesset secondorder perturbation theory with the use of a 6–31G(d) double zeta basis set. The correlation corrections to the total energy of molecules for optimized geometric configurations were calculated in the 631G(d,p) basis. All the possible tautomeric forms of FTRA and the harmonic vibrational frequencies were also calculated within the density functional theory (DFT) with the use of the Perdew–Burke–Ernzerhof (PBE) functional in a threeexponent basis. It is shown that FTRA in vapors (in the perfect gas approximation) exists in the form of a mixture of three enol forms, among which two exoforms predominate. The frequencies and forms of normal vibrations for each cisenol tautomer in the region of vibrations of ketogroups and double bonds differ widely, which permits identification of the tautomers present in the mixture. The possible mechanisms of enolenol transformations of 3acyltetrinic acids are discussed.     

Beatings in the Spin Echo Signal in Media Having a Doublet Structure of the Spectrum

We have obtained an analytical expression for the twopulse echo signal arising in nonresonant excitation of a condensed medium with a nonuniformly broadened spectrum of doublet structure by two pulses of an electromagnetic field of different durations and of the same amplitude. It is shown that in the case where the differences between the carrying frequency of exciting pulses and the central frequencies of the spectral lines differ considerably, beatings are formed in the signal of the twopulse echo. The rate of decay of the amplitude of these beatings is found to depend only on the time of reversible and irreversible relaxation, and their circular frequency is determined by the shift of the spectral lines relative to each other. A technique for separate determination of the inhomogeneous width of the lines and time of the irreversible transverse relaxation is suggested which is based on the analysis of the twopulse echo signal beatings.     

Amplification Coefficient of the Anti‐Stokes Component of Raman Scattering

The theory of intracavity parametric interaction of the components of Raman scattering is developed in the prescribedintensity approximation, which takes into account the reverse reaction of the excited waves to the pumpingwave phase. It is shown that one can substantially improve the conversion efficiency or the amplification coefficient of the antiStokes component by selection of the intracavity geometry, the optimum phase relation between the interacting waves, the pumping level, and the phase mismatch.     

Excitation of Electroluminescence by a Rotating Electric Field

The principle of operation of an electroluminescence capacitor (ELC) in which a powder zinc sulfide electroluminophor is excited by threephase voltage is described. Rotation of the electric field intensity vector in a luminophordielectric layer allows a substantially greater number of energy barriers to be involved in the collision processes in the luminophor grains than in a conventional ELC. This provides the possibility of retarding the ELC degradation: at the same initial brightness the time of its halfdecay increases several times.     

Infrared Spectroscopic Study of N,N‐Dimethylthioformamide Complexes of the Hofmann Type

Four new Hofmanntype complexes, M(DMTF)₂Ni(CN)₄, (where DMTF is dimethylthioformamide, M=Mn, Cd, Co, or Ni) were synthesized and their structure was determined by an elemental analysis and infrared spectroscopy. The IR spectra of DMTF and its nickel tetracyanine complexes with Mn(II), Cd(II), Co(II), and Ni(II) have been investigated within the range 4000–400 cm^–1. The frequency shifts in the metal complexes agree with the assignment of the CS and CN frequencies. The complexes consist of infinite planar polymer layers of |MNi(CN)₄|. Ndimethylthioformamide is coordinated to this layer from above and below; it is a monodentate ligand and is Sbonded through the metal atom in these complexes.     

Mössbauer effect and discovery of new hexagonal ferrites prepared at 980^\circ C

In the present article, undoped and Codoped Mtype Srhexaferrites have been prepared at low temperatures down to 980 C for the first time by the usual ceramic procedure and sintering technique. On these materials, a CoK Xray diffraction analysis and the room temperature ⁵⁷Fe Mössbauer spectroscopy (MES) were carefully performed. The results obtained are described and interpreted. The mechanism of Co substitution partially in place of iron and the site of its occupancy were proposed and established.     

Calculation of Quantum‐Chemical Characteristics of the Ground and Excited Electronic States of Porphin and Its Tetrapyrrole Isomers

Using the CNDO/S method, we have performed quantumchemical calculations of the ground and excited electronic states of porphin molecules (symmetry D _2h ) and a number of porphin isomers: porphycene (C_2h ), hemiporphycene, corphycene (C_2v ), isoporphycene, and three nonsynthesized structural isomers of the porphin skeleton by its bridge groups —(CH) _meso —. The results of the calculations are compared with the corresponding data for the freebase porphin molecule (H₂P). Near the boundary between the occupied and vacant orbitals the isomers form rows of singleelectron levels with similar energy characteristics. For the MOs of these isomers, the H₂P MOs closest in distribution on the comparable atomic centers are given. The weak (Q) and strong (B) transitions in the visible and near UV regions point to the porphyrin type of spectra of all the isomers. The calculation data on the excited electronic states of N, g, and ntype H₂P near and above the B states are given; the presence of such states in other isomers is shown. The calculation does not point to a difference in the position of the first singlet transitions in the first five isomers. The calculation data on the lower singlettriplet transitions are also reported.     

Anti‐Stokes Luminescence of Cadmium Telluride Nanocrystals

For the first time, the antiStokes luminescence in colloidal solutions of CdTe nanocrystals on excitation below the absorption edge has been discovered. The maximum spectral shift to the shortwave region relative to the excitation energy E _con ^max = 319 meV is obtained for meansized nanocrystals (2.5 nm). The conversion efficiency of the absorbed radiant energy is 1.3·10^–2%. The rise in the antiStokes photoluminescence intensity with increasing temperature and the linear dependence on the exciting radiation intensity have been established. It is shown that the effect observed cannot be caused by twophoton excitation or by Auger recombination. It is assumed that the basic mechanism of the luminescence observed is the radiative recombination through the energy levels of the states attributable to the disturbance of the crystal structure in the nanocrystals.     

Absorption Spectra of Pentamers of Tetrapyrrole Compounds in Aqueous Solutions

Pentamers of two types have been obtained in aqueous solutions containing mixtures of two tetrapyrrole compounds, in whose molecules there are positively or negatively charged peripheral groups. The pentamers of one type include one molecule of mesotetra(4Nmethylpyridyl) porphin (TMPP) and four molecules of the complex of mesomono(nsulfophenyl)etioporphyrin II with palladium (PdSPhEP), and the pentamers of the other type include one molecule of sulfonated phthalocyanine (PCS) and four molecules of TMPP. The absorption bands of the pentamers are broadened and shifted toward longer wavelengths in comparison with the bands obtained as a result of the addition of the spectra of the monomers. It seems that the changes in the absorption spectra are first of all due to the change in the interaction of the molecules of the pigments with the molecules of the surrounding in formation of associates and due to the influence of the resonance dipoledipole interaction between the molecules in the associates. The influence of the intermolecular photoinduced charge transfer is also possible (it is most probable for the associates with PCS). We have revealed an effective quenching of the fluorescence of PCS and TMPP solutions upon heteroassociation.     

Updated Analysis of Gallium Chelate and Vanadium Chelate Solutions with 4‐(2‐Pyridylazo)Resorcinol and Xylenol Orange

The characteristic factors of the gallium and vanadium chelates with the ligands 4(2pyridylazo)resorcinol (PAR) and xylenol orange (XO) have been determined with the aid of the principle of correction, which makes it possible to eliminate the influence of the surplus ligand in the solution of its chelate with methane (which makes calculation easier) and thereby provides a more acceptable method in comparison with others. The real molar coefficients of extinction of the chelates Ga and V with PAR and XO have been determined and a detailed calculation of the stoichiometric ratios of chelates has been made. The results have shown that the chelates formed have the following structure: Ga(PAR), Ga(XO), V(PAR)₂, and V(XO).