Inner-shell ionization by positron and electron impact

Measurements of relative cross sections of K- and L-shell ionization of silver and gold targets by positron and electron impact at projectile energies of 30–70 keV are reported. The experiments were performed at the slow positron source TEPOS at the linac of the Strahlenzentrum. This source and the experimental equipment will be described briefly and the experimental results will be presented in detail. In addition, plane wave Born (PWBA) calculations were performed. They include an electron exchange term and the deceleration or acceleration of the incident projectile in the nuclear field of the target atom. The present experimental results agree well with these calculations; for L-shell ionization, they are at variance with a previous experiment where a different energy dependence was observed.     

Inner-shell excitation-ionization in potassium by electron impact

A new autoionization peak in potassium at 20 eV is attributed to excitation of the 3p⁵4s²-levels at 18.72 and 18.98 eV. Metastable ions contribute to the total ionization cross section for energies above 24.4 eV.     

Comparison of inner-shell ionization by relativistic electron and positron impact

Ratios of K/L shell X-ray yields by 10–20 MeV electrin and positron impact on Au have been measured with an accuracy of better than ±1.6%. The results show that the K-shell X-ray production cross section by electron impact is about 2% larger than by positron impact.     

Inner-shell ionization of atoms by electron,positron and photon impacts

Plane wave Born approximation with Coulomb, relativistic and exchange corrections is employed to obtain L1-, L2- and L3-subshell ionization cross sections of several atoms due to electron and positron impacts for projectile energy varying from the threshold of ionization to 60 times the threshold energy. Photoionization cross sections for all the three L-subshells of the atoms are also calculated using the hydrogenic approximation for the atomic wave functions. For L3-subshell the present cross sections due to electron impact are in good agreement with a number of experimental data for different atoms over the entire energy range investigated. For L1- and L2-subshells the present calculations yield qualitative agreement with the experimental data. The agreement between the present results and the limited experimental data for positron impact is also satisfactory. The hydrogenic approximation for the L-subshell photoionization is found to be good at small photon energies but it underestimates the cross sections at large photon energies.     

Inner-shell excitation of formaldehyde,acetaldehyde and acetone studied by electron impact

Excitation and ionisation of the carbon and oxygen 1s electrons of formaldehyde, acetaldehyde and acetone have been examined by small-angle inelastic scattering of 2.5-keV electrons, with energy resolutions in the range 0.20–0.50 eV FWHM. Features in the electron energy loss spectra below the inner-shell ionisation thresholds have been assigned to transitions to unoccupied valence (π*) and Rydberg orbitals. Broad maxima in the inner-shell continua of all three molecules have been interpreted as resonances associated with transitions to σ*(CO) orbitals. The assignments of the acetaldehyde and acetone spectra have been supported by comparison with those for CH₄ and H₂ CO. The adiabatic first ionisation potential of H₂ NO and H₂ CF have been estimated from the inner-shell spectra of formaldehyde using the equivalent-core analogy.     

Inner-shell electron capture by impact of positron on the multi-electron atomic targets

The first-order Coulomb-Born approximation has been applied to the study of positronium formation through K-shell electron capture in the collision of positron with multi-electron atomic targets. The single-zeta Roothaan-Hartree-Fock wave functions are used to describe the electron initial bound states. The differential and total cross sections are computed for the impact of positron on helium, carbon, neon, sodium and argon atoms, with the formation of positronium in its ground state. For helium atoms, the calculated total cross sections are compared with the available experimental data and other theoretical calculations. The comparison shows a good agreement between the present calculations and the measurements.     

Triple ionization of lithium by electron impact

Ejection of the three electrons from lithium in a single electron collision has been observed for the first time. Triply charged lithium was observed in an ion time-of-flight spectrum following electron impact on a sample of ultracold, trapped lithium. The higher signal/background afforded by the trap environment made the observation of Li3+ possible. We measured the ratios of triple-to-double and double-to-single ionization at an impact energy of 1000 eV. The 3+/2+ ratio is approximately 0.001, a value 2 orders of magnitude lower than semiempirical predictions. We present a simple method that uses photoionization data combined with sum-rule analysis to predict the asymptotic charge-state ratios. The sum-rule predictions compare reasonably with experiment and shake calculations, but disagree sharply with the semiempirical estimates.     

Double ionization of helium by relativistic highly charged ion impact

We consider an interesting realization of the fundamental four-body problem: double ionization of helium in superintense electromagnetic fields generated by highly charged ions in relativistic collisions. We show how the simultaneous interaction of such fields with all three target constituents (which is not described by first-order theory) strongly influences the collision dynamics even at very high collision energies and how a “genuine” photoemission-like pattern may emerge in collisions at extreme relativistic energies. A very good agreement with available experimental data is obtained.     

Inner-shell ionization created by fluorine ions in nearly symmetric collisions

We have measured projectile and target X-ray cross sections for F + Si, S, Ar and Kr collisions at projectile energies from 1 to 25 MeV. The experiments were performed under single collision conditions using a differentially pumped gas target. X-rays were measured by a Si(Li) detector and a proportional counter. The experimental cross sections are compared to predictions of theoretical models for direct and quasi-molecular ionization. Effects of multiple ionization that influence theK-shell fluorescence yields were examined using experimental information from line energy shifts and intensity ratios.     

甲烷分子电子碰撞电离和解离的实验研究

本文利用反应显微成像技术(reaction microscope)研究了54 eV电子入射甲烷分子导致的电离解离过程,详细分析了电离解离产生的CH⁺₂,CH⁺,C⁺离子碎片的动能分布情况.实验结果表明,该入射能量下产生CH⁺₂,CH⁺,C⁺离子碎片主要贡献来自2a₁内价轨道电子的直接电离过程产生的离子态(2a< 关键词： 反应显微成像谱仪 电离解离 能量沉积 动能分布     

Glauber amplitude for ionization of helium by electron impact

The high-energy Glauber approximation is used to derive the formula for scattering amplitude for ionization of helium atom by electron impact. The scattering amplitude is expressed as a one dimensional integral involving MeijerG-functions. This may further be expressed in a closed form as simple sums of Meijer functions by writing down the series expansion for Bessel and Meijer functions. Further, the asymptotic behaviour of these amplitudes is examined for both large and small momentum transfers.     

Single and double ionization of lead by electron impact

Theoretical calculations of electron impact single and double ionization cross-sections for ground state lead atoms have been performed in the binary encounter approximation (BEA) in the energy region ranging from respective near thresholds to 3000 eV. The accurate expression for (cross-section for energy transfer including exchange and interference as given by Vriens and Hartree-Fock velocity distributions for the target electrons have been used throughout the calculations. It is concluded that beyond 10.64 eV impact energy single ionization cross-sections are well explained by considering ionization of 6p and 6s shells only. The direct double ionization cross-sections obtained theoretically cannot explain the recent experimental observations. Inclusion of contributions of the Auger effect due to vacancy in 5d and 5p shells brings the results of double ionization cross-sections in reasonably good agreement with the experimental data. The identification of the shells whose ionization leads to the Auger effect contributing to double ionization is a remarkable aspect of the present investigation.Received: 15 January 2004, Published online: 30 March 2004PACS: 34.80.Dp Atomic excitation and ionization by electron impact     

Single and double ionization of gallium by electron impact

Electron impact single and double ionization cross sections of gallium have been calculated in the binary encounter approximation using accurate expression for σ_Δ;E including exchange and interference as given by Vriens and Hartree-Fock velocity distributions for the target electrons throughout the calculations. It is concluded that the ionization of 3d shell contributes partly to single ionization and partly to double ionization. The results so obtained show reasonably good agreement with the experimental data.     

Double and triple ionization of silver clusters by electron impact

The production of silver cluster cations Ag(n)(2+) (for several selected sizes in the range n = 39-119) and Ag(n)(3+) (for n = 58, 61, 67) by electron impact ionization of neutral precursors has been studied. The scaling of appearance energies with cluster radius follows the metallic droplet model but, curiously, with a slope which is estimated to be quite different from the literature values for single ionization, Ag(n)(+), as well as for the appearance of smaller Ag(n)(2+) ions. It is also found that as the electron energy increases, the yield of high-charge cations grows faster than that of singly-charged Ag(n)(+). This behavior is consistent with the power-law dependence of post-threshold ionization. The mechanisms involved in multiple ionization phenomena in clusters of noble metals are not yet fully understood and call for further experimental and theoretical examination.     

Cross section for single ionization of magnesium by electron impact

The direct single ionization cross sections for electron scattering with magnesium are calculated by applying a complex equivalent-local polarization potential in momentum space from the ionization threshold (7.64 eV) to 500 eV. The present results are in excellent agreement with the recent experimental measurements in both shape and magnitude. The present results are also compared with other theoretical calculations.     

非共面几何条件下102eV电子碰撞He单电离反应的三体耦合效应

在前人工作的基础上,通过引入有效索末菲参数考虑三体耦合效应,计算了非共面几何（垂直平面与垂直动量转移平面）条件下,102eV的电子碰撞He单电离反应的全微分截面,将其计算结果与3C、DWB2、我们前期的理论结果及实验数据进行了比较。     

Mn and Cu K-shell ionization cross sections by slow electron impact

Near the threshold energy, electron induced Mn and Cu K-shell ionization cross sections have been measured. Except for energies very close to threshold, the results are in good agreement with the semi-empirical formula of Green and Cosslett.     

Triple differential cross section in ionization of hydrogen by electron impact

A novel model is proposed to study the ionization of atomic hydrogen by fast election impact in coplanar asymmetric geometry making use of the post form of the transition matrix element for the energy shell and the two-potential formula. Based on the approximation of projectile plane waves and three-body problems, the transition matrix element is decomposed into two parts: the structure and scattering factor and the correlation factor. The contributions of these factors to triple differential cross sections are investigated using the method of asymptotic and convergent series.