Interface formation and a structural phase transition for the spherical model of ferromagnetism

A detailed analysis is reported examining the local magnetic susceptibility (r), in relation to the correlation functionG(R) and correlation length , of a spherical model ferromagnet confined to geometry =L ^{d –d} × ^d ( ^d 2,d>2) under a continuous set oftwisted boundary conditions. The twist parameter in this problem may be interpreted as a measure of the geometry-dependent doping level of interfacial impurities (or antiferromagnetic seams) in theextended system at various temperatures. For _j 0, jd-d, no seams are present except at infinity, whereas if _j = 1/2, impurity saturation occurs. For 0 < _j < 1/2 the physical domain _phys =D ^{d –d} × ^d (D>L), defining the region between seams containing the origin, depends on temperature above a certain threshold (T>T ₀). Below that temperature (T>T ₀), seams are frozen at the same position (DL/2,d-d'=1), revealing a smoothly varying largescale structural phase transition.     

Proton spin-lattice relaxation times in ytterbium hydrides

The measurements of the proton (NMR) spinlattice relaxation times have been made in a series of ytterbium hydrides, YbH _x . Results are reported forx=1.80, 1.95, 2.00 and 2.62 and temperatures 4.2T297K. In the orthorhombic phase (1.80x2.00), the spin-lattice relaxation times are dominated by the hyperfine interaction of protons with conduction electrons and the spin diffusion mechanism. In the cubic phase (x=2.62), the relaxation times are five orders of magnitude shorter than in the orthorhombic one. This is interpreted in terms of the proton coupling with the Yb³⁺ ion spin fluctuations.     

The central limit theorem for the spectrum of the random one-dimensional Schrödinger operator

Let H_L = –d²/dt²+q(t,) be an one-dimensional random Schrödinger operator in ²(–L, L) with the classical boundary conditions. The random potential q(t,) has a form q(t, )=F(x_t), where x_t is a Brownian motion on the Euclidean v-dimensional torus, FS^v R¹ is a smooth function with the nondegenerated critical points, min_s ^v F = 0. Let are the eigenvalues of H_L) be a spectral distribution function in the volume [– L,L] and N() = lim_L(1/2L)N_L() be a corresponding limit distribution function.Theorem 1. If L then the normalized difference N _L ^* ()=[N_L() -2L·N()]2L tends (in the sense of Levi-Prokhorov) to the limit Gaussian process N^*(); N^*()0, 0, and N^*() has nondegenerated finitedimensional distributions on the spectrum (i.e., > 0). Theorem 2. The limit process N^*() is a continuous process with the locally independent increments.     

Measurement of the heavy neutrino admixture upper limit from muon capture by3He

The triton energy spectrum of the muon capture reaction µ³Het+_µ where µ³He is the ground state of muonic³He, has been measured by means of a high-pressure ionization chamber in order to investigate a possible heavyv admixture into the µ flavor with high sensitivity. The upper limit of the µ-heavy v_i mixing matrix element squared was obtained to be U_µi²10^–3 for heavy neutrino masses in the range of 25 E_0V75 MeV.     

New interpretation of experiments on the intermediate meson

A new theory of weak interactions is proposed in which the coupling between theV-A currents j(X) and j(X) is achieved not by vector mesons [by a propagator D ^c (X-X)], but by a scalar functionR(X – X), a fermion-antifermion loop which plays the role of a unique film joining two different pointsX andX of completely uncoupled space-times (as a result of which the space becomes a continuum). The existence of the actual currents j results from correlations between the two different spinor layers of Dirac layer formation.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 25–40, February, 1996.     

Local fluctuation of the spectrum of a multidimensional Anderson tight binding model

We consider the Anderson tight binding modelH=–+V acting inl ²(Z ^d ) and its restrictionH to finite hypercubes Z ^d . HereV={V _x ;xZ ^d } is a random potential consisting of independent identically distributed random variables. Let {E _j ()} _j be the eigenvalues ofH , and let _j (,E)=||(E _j ()–E),j1, be its rescaled eigenvalues. Then assuming that the exponential decay of the fractional moment of the Green function holds for complex energies nearE and that the density of statesn(E) exists atE, we shall prove that the random sequence { _j (,E)} _j , considered as a point process onR ¹, converges weakly to the stationary Poisson point process with intensity measuren(E)dx as gets large, thus extending the result of Molchanov proved for a one-dimensional continuum random Schrödinger operator. On the other hand, the exponential decay of the fractional moment of the Green function was established recently by Aizenman, Molchanov and Graf as a technical lemma for proving Anderson localization at large disorder or at extreme energy. Thus our result in this paper can be summarized as follows: near the energyE where Anderson localization is expected, there is no correlation between eigenvalues ofH if is large.     

Random walk with persistence

The exact analytic result is obtained for the Fourier transform of the generating functionF(R,s)= _n=0 s ⁿ P(R,n), whereP(R,n) is the probability density for the end-to-end distanceR inn steps of a random walk with persistence. The moments R ²(n), R ⁴(n), and R ⁶(n) are calculated and approximate results forP(R,n) and R ^–1(n) are given.     

Structural Transformations in a Bi2O3 Crystal and in Bi2O3‐Based Solid Solutions in the Temperature Interval 25–750°C

The Raman scattering spectra of isostructural Bi₂O₃ and Bi_1.8Tm_0.2O₃ in the course of heating have been investigated. It is shown that the sequences of structural changes with increase in temperature differ: and ^* , respectively. In the hightemperature region, the structure takes the form of a disordered cube irrespective of the previous history of specimens.     

Cluster size distributions in equilibrium

Equilibrium size distributions for finite system containingM monomers in a volumeV undergoing coagulation (polymerization)/fragmentation, are determined for coagulation rateK _ij and fragmentation rateF _ij , corresponding to the processA _i +A _j A _i+j (hereA _k denotes a cluster containingk monomeric units). It is shown that microscopic detailed balance impliesF _ij /K _ij =a _i a _j /a _i+j , where anda _k are arbitrary. The mean and most probable size distributionc _k = ^–1 a _k e ^–k coincide in the thermodynamic limitM, V, =M/V fixed. If , 2<<3, then the theory predicts a (solgel) phase transition at a well defined value ofq = ^–1, with critical exponents = and = –2. The gel fraction exponent assumes its classical value unity, probably due to the neglect of spatial fluctuations. Finally it is indicated how the theory can in principle be extended to account for isomerism and cyclization.     

Representations of state space transformations by Markov kernels

Every convex subset of a locally convex Hausdorff space (X, ) is equipped with the (-algebra generated by its-relatively open subsets. Within the set () of probability measures on two particular convex subsets are considered: (a) the set ^s () of probability measures with a separable support, and (b) the set ^c () of probability measures with a compact convex support. If is the base of a cone inX, then there exists an affine barycenter map from ^c () onto whose composition with the natural embedding of in ^c () yields the identity map on , and every-continuous affine transformation of can be represented by an affine transformation of ^c () that is induced by a Markov kernel. If (X, ) is a Banach space and is a closed, bounded, generating cone base inX that is contained in a hyperplane, then analogous results are obtained with respect to ^s (). Since the state spaces considered in noncommutative measure theory are cone bases and every change in time of an empirical system can be thought of as an affine transformation of the associated state space (Schrödinger picture), the existence of these representation theorems implies that the time evolution of general empirical systems can be described by dynamical concepts borrowed from classical probability theory.     

Conductance distributions in random resistor networks. Self-averaging and disorder lengths

The self-averaging properties of the conductanceg are explored in random resistor networks (RRN) with a broad distribution of bond strengthsP(g)g ^–1. The RRN problem is cast in terms of simple combinations of random variables on hierarchical lattices. Distributions of equivalent conductances are estimated numerically on hierarchical lattices as a function of sizeL and the distribution tail strength parameter . For networks above the percolation threshold, convergence to a Gaussian basin is always the case, except in the limit 0. Adisorder length _D is identified, beyond which the system is effectively homogeneous. This length scale diverges as _Dµ^–v ( is the regular percolation correlation length exponent) when the microscopic distribution of conductors is exponentially wide (0). This implies that exactly the same critical behavior can be induced by geometrical disorder and by strong bond disorder with the bond occupation probabilityp. We find that only lattices at the percolation threshold have renormalized probability distributions in aLevy-like basin. At the percolation threshold the disorder length diverges at a critical tail strength µ_c as µ–^–z withz3.2±0.1, a new exponent.Critical path analysis is used in a generalized form to give the macroscopic conductance in the case of lattices abovep _c.     

Scaling of the surface tension of phase-separated polymer solutions

The tension of the interface between the equilibrium phases of a phase-separated polymer solution is obtained in the simplest mean-field approximation from the functional equation for the composition profile of the interface. For temperaturesT near the critical solution temperatureT _c, i.e., for Flory parameter near _c, and for high degrees of polymerizationN, the profile and tension scale with=N ^1/2(– _c), just as do the compositions of the coexisting phases in mean-field approximation. The surface tension in the asymptotic limitN, _c at fixedx, is found to be given bya ²/kT _c (2c'/c)^1/2 N ^-5/4(x), wherea is the lattice spacing of an underlying lattice (or, roughly, the length of a monomer),c andc are the vertical and total coordination numbers of the lattice, and(x) is a scaling function, known for allx, with the asymptotic behavior asx0 and asx. The latter implies that becomes independent ofN asN at fixedT nearT _c; the former implies that becomes proportional toN ^–1/2(1–T/T _c)^3/2 asTT _c at fixedN1, as found previously.     

Surface tension,step free energy,and facets in the equilibrium crystal

Some aspects of the microscopic theory of interfaces in classical lattice systems are developed. The problem of the appearance of facets in the (Wulff) equilibrium crystal shape is discussed, together with its relation to the discontinuities of the derivatives of the surface tension (n) (with respect to the components of the surface normaln) and the role of the step free energy ^step(m) (associated with a step orthogonal tom on a rigid interface). Among the results are, in the case of the Ising model at low enough temperatures, the existence of ^step(m) in the thermodynamic limit, the expression of this quantity by means of a convergent cluster expansion, and the fact that 2^step(m) is equal to the value of the jump of the derivative / (when varies) at the point =0 [withn=(m ₁ sin ,m ₂ sin , cos )]. Finally, using this fact, it is shown that the facet shape is determined by the function ^step(m).     

Ultra-high piezoelectric response in 〈<Emphasis Type="Bold">110</Emphasis>〉- oriented polydomain Pb(Mg<Subscript>1/3</Subscript>Nb<Subscript>2/3</Subscript>)O<Subscript>3</Subscript>- PbTiO<Subscript>3</Subscript> single crystals

The piezoelectric constant and electromechanical coupling coefficients of 110-oriented polydomain0.71Pb(Mg_1/3Nb_2/3)O₃-0.29PbTiO₃ single crystals were determined experimentally by using resonance methods. It was confirmed that the single-crystal system has large electromechanical coupling coefficients k₃₃ (91%), k₃₃ (83%), and k₃₁ (81%), and piezoelectric constant d₃₃ (1400 pC/N), which are comparable to those of 001-oriented crystals, and we also found that the values of k₃₃ and k₃₁ are sensitive to the cuts of the crystals. X-ray-diffraction measurements on 110-oriented crystals have shown that the origin of the high piezoelectric response should be attributed to the orthorhombic distortion. Our results show that the 110-oriented crystals are also promising for a wide range of electromechanical transducer applications, since the 110-oriented crystals can be grown from 110-oriented seed crystals in the modified Bridgman technique. PACS 77.80.Bh; 77.84.Dy; 77.65.Bn     

On the correlation for Kac-like models in the convex case

The aim of this paper is to stu the behavior asm tends to of a family of measures exp[- ^(m)(x)]dx ^(m) on ^m , where ^(m) is a potential on ^m which is a perturbation in a suitable sense of the harmonic potential _j x _j ² .     

Direct observation of the second-order Stark effect of theX-B transition in molecular iodine

The second-order Stark shift of the components of the hyperfine structure of the transition¹ _g ⁺ ( = 0,j = 13, 15) ³ _ou ⁺ ( = 43,j = 12, 16) (of molecular iodine have been studied by means of saturated absorption spectroscopy in an external cell with the I₂ vapour located in an electric field. The anisotropic polarizabilities of the upper and lower levels together with the difference between the isotropic polarizabilities of the levels of the transition have been obtained.     

Bianchi and Weyl equations as sufficient equations for Einstein spaces

When the Bianchi equation and the wave equation for the Weyl spinor are written in the form which they take for Einstein spaces, but with the symmetric 4-spinor _ABCD considered arbitrary and with the background space unspecified, ^EA _EBCD=0; (+12) _ABCD –6(AB ^EF ( _CD )EF =0 it is shown that — in general — for this pair of equations to be consistent, the background space has to be an Einstein space, and the symmetric 4-spinor _ABCD has to be the Weyl spinor of this space.     

Expectation Values of Observables in Time-Dependent Quantum Mechanics

Let U(t) be the evolution operator of the Schrödinger equation generated by a Hamiltonian of the form H ₀(t) + W(t), where H ₀(t) commutes for all twith a complete set of time-independent projectors . Consider the observable A=_j P _jjwhere _j j , >0, for jlarge. Assuming that the matrix elements of W(t) behave as for p>0 large enough, we prove estimates on the expectation value for large times of the type where >0 depends on pand . Typical applications concern the energy expectation H₀(t) in case H ₀(t) H ₀or the expectation of the position operator x²(t) on the lattice where W(t) is the discrete Laplacian or a variant of it and H ₀(t) is a time-dependent multiplicative potential.     

On the pointwise behavior of semi-classical measures

In this paper we concern ourselves with the small asymptotics of the inner products of the eigenfunctions of a Schrödinger-type operator with a coherent state. More precisely, let _j and E _j denote the eigenfunctions and eigenvalues of a Schrödinger-type operator H with discrete spectrum. Let _(x,) be a coherent state centered at the point (x, ) in phase space. We estimate as 0 the averages of the squares of the inner products ( _a ^(x,) , _j ) over an energy interval of size around a fixed energy, E. This follows from asymptotic expansions of the form for certain test function and Schwartz amplitudes a of the coherent state. We compute the leading coefficient in the expansion, which depends on whether the classical trajectory through (x, ) is periodic or not. In the periodic case the iterates of the trajectory contribute to the leading coefficient. We also discuss the case of the Laplacian on a compact Riemannian manifold.Research supported in part by NSF grant DMS-9303778     

Determination of the Dipole Moments of the Molecules of 4′-Substituted 3-Hydroxyflavones Using the Electrooptic Absorption Method

The dipole moments in the equilibrium ground ( _g) and excited Franck–Condon states ( _e ^FC) of the molecules of 4-(methoxy)-3-hydroxyflavone (FOM), 4-(dimethylamino)-3-hydroxyflavone (FME), and 4-N-(15-azacrown-5(-3-hydroxyflavone (FCR) in 1,4-dioxane were measured. Characteristic of these probes is excited-state intramolecular proton transfer. For comparison, the dipole moments of the molecules of 4-(dimethylamino)-3-methoxyflavone (FME3ME) were measured, for which the excited-state intramolecular proton transfer is lacking. It is established that in the case of FME, FCR, and FME3ME the dipole moments _g and _e ^FC are parallel to the absorption transition dipole moment m _a responsible for absorption. Among the compounds studied, FOM has the least values of _g and _e ^FC, only 9.4·10^–30 and 26.3·10^–30 C·m, respectively. The dipole moments _g, _e ^FC and m _a are not parallel to one another, and the angles between them lie in the range 4–55°. This effect is due to FOM not having a strong electron-donating group, such as an amino group.