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A. V. Kopytin E. N. Pyatova A. F. Zhukov Yu. A. Politov K. E. German A. Yu. Tsivadze 《Journal of Analytical Chemistry》2008,63(9):888-890
A polymeric membrane for an ion-selective electrode is proposed on the basis of supramolecular systems including a polymeric compound (polyvinyl chloride, PVC) and an ionophore (ionic liquid tetradecylphosphonium dicyanoaurate) in which ionic liquid is simultaneously used as a PVC plasticizer. The selectivity, linear response range, and potential stability of ion-selective electrodes with the optimum membrane composition are measured. The detection limit for Au(I) with the developed electrode is 4.5 × 10?7 M. 相似文献