Morphology,rheology property,and crystallization behavior of PLLA/OMMT nanocomposites prepared by an innovative eccentric rotor extruder

An innovative eccentric rotor extruder, which can generate continuous elongation flow, was used to fabricate the poly(L‐lactide) (PLLA)/organo‐modified montmorillonite (OMMT) nanocomposites in different OMMT concentrations. The morphology of the nanocomposites was characterized by thermal gravimetric analyzer, X‐ray diffractometer, and transmission electron microscope. The results showed that the OMMT nanoparticles were uniformly dispersed in the PLLA matrix and mainly existed in intercalation mode. The intercalation and exfoliation process of OMMT in the eccentric rotor extruder may be a double‐side exfoliation, which is more effective than the layer‐by‐layer peeling mechanism based on the shear flow. The influence of OMMT on the rheological behavior of PLLA was investigated by dynamic rheological measurements, showing greater improvement of rheological properties for the nanocomposites. The thermo‐mechanical properties analysis indicated that significant enhancement of E′ can be seen for all the nanocomposites. Presence of intercalated OMMT platelets did not lead to a significant shift of the E″ and tan δ curves compared with that of pure PLLA. The crystallization and melting behavior was studied by differential scanning calorimetry, which indicated that the incorporation of OMMT nanoparticles slightly increased the crystallinity of PLLA matrix. The polarizing microscope was further carried out and showed that the dispersed OMMT nanoparticles acted as a heterogeneous nucleating agent to promote the crystallization of PLLA.     

Poly(lactic acid)/poly(butylene succinate)/calcium sulfate whiskers biodegradable blends prepared by vane extruder: Analysis of mechanical properties,morphology, and crystallization behavior

Ternary blends of PLA/PBS/CSW with different weight fractions were prepared using a vane extruder. The mechanical properties, morphology, crystallization behavior and thermal stability of the blends were investigated. For the PLA/CSW blend, the tensile strength decreased, the flexural strength and modulus increased compared with pure PLA. For PBS, the addition of CSW had little influence on the mechanical properties. For the ternary blends PLA/PBS/CSW, the tensile strength, flexural strength and modulus decreased compared with pure PLA, while the elongation at break and the impact strength increased significantly. The brittle-ductile transition of the blends took place when the PBS weight fraction reaching 30 wt%. As a soft component in the blends, PBS was beneficial to improve the tensile ductility and the toughness of PLA. SEM measurements reveal that PLA/PBS/CSW blends were immiscible. When the weight fraction of PBS was 50 wt%, significant phase separation was observed, and CSW had preferential location in the PBS phase of the blend. DSC measurement and POM observation reveal that CSW had a heterogeneous nucleation effect on PLA and PBS matrix. The addition of PBS improved the crystallization of PLA and the thermal resistance of the PLA/PBS/CSW blends significantly.