On mean flow universality of turbulent wall flows. II. Asymptotic flow analysis

Understanding of the structure of turbulent flows at extreme Reynolds numbers (Re) is relevant because of several reasons: almost all turbulence theories are only valid in the high Re limit, and most turbulent flows of practical relevance are characterized by very high Re. Specific questions about wall-bounded turbulent flows at extreme Re concern the asymptotic laws of the mean velocity and turbulence statistics, their universality, the convergence of statistics towards their asymptotic profiles, and the overall physical flow organization. In extension of recent studies focusing on the mean flow at moderate and relatively high Re, the latter questions are addressed with respect to three canonical wall-bounded flows (channel flow, pipe flow, and the zero-pressure gradient turbulent boundary layer). Main results reported here are the asymptotic logarithmic law for the mean velocity and corresponding scale-separation laws for bulk flow properties, the Reynolds shear stress, the turbulence production and turbulent viscosity. A scaling analysis indicates that the establishment of a self-similar turbulence state is the condition for the development of a strict logarithmic velocity profile. The resulting overall physical flow structure at extreme Re is discussed.     

Geometry and scaling laws of excursion and iso-sets of enstrophy and dissipation in isotropic turbulence

Motivated by interest in the geometry of high intensity events of turbulent flows, we examine the spatial correlation functions of sets where turbulent events are particularly intense. These sets are defined using indicator functions on excursion and iso-value sets. Their geometric scaling properties are analysed by examining possible power-law decay of their radial correlation function. We apply the analysis to enstrophy, dissipation and velocity gradient invariants Q and R and their joint spatial distributions, using data from a direct numerical simulation of isotropic turbulence at Re_λ ≈ 430. While no fractal scaling is found in the inertial range using box-counting in the finite Reynolds number flow considered here, power-law scaling in the inertial range is found in the radial correlation functions. Thus, a geometric characterisation in terms of these sets’ correlation dimension is possible. Strong dependence on the enstrophy and dissipation threshold is found, consistent with multifractal behaviour. Nevertheless, the lack of scaling of the box-counting analysis precludes direct quantitative comparisons with earlier work based on multifractal formalism. Surprising trends, such as a lower correlation dimension for strong dissipation events compared to strong enstrophy events, are observed and interpreted in terms of spatial coherence of vortices in the flow.     

Extensive characterisation of a high Reynolds number decelerating boundary layer using advanced optical metrology

Over the last years, the observation of large-scale structures in turbulent boundary layer flows has stimulated intense experimental and numerical investigations. Nevertheless, partly due to the lack of comprehensive experimental data at sufficiently high Reynolds number, our understanding of turbulence near walls, especially in decelerating situations, is still quite limited. The aim of the present contribution is to combine the equipment and skills of several teams to perform a detailed characterisation of a large-scale turbulent boundary layer under adverse pressure gradient. Extensive particle image velocimetry (PIV) measurements are performed, including a set-up with 16 sCMOS cameras allowing the characterisation of the boundary layer on 3.5 m, stereo PIV and high resolution near wall measurements. In this paper, detailed statistics are presented and discussed, boundary conditions are carefully characterised, making this experiment a challenging test case for numerical simulation.     

Characterisation of backflow events over a wing section

Rare backflow (negative wall-shear stress) events have recently been found and quantified in the near-wall region of canonical wall-bounded turbulent flows. Although their existence and correlation with large-scale events have been established beyond numerical and measurement technique uncertainties, their occurrence at numerically high Reynolds numbers is still rare (less than 1 per thousand and 1 per million at the wall and beyond the viscous sublayer, respectively). To better quantify these rare events, the turbulent boundary layer developing over the suction side of a wing section, experiencing an increasing adverse pressure gradient (APG) without separation along its chord c, is considered in the present work. We find that the backflow level of 0.06% documented in turbulent channels and zero-pressure-gradient (ZPG) turbulent boundary layers is already exceeded on the suction side for x/c > 0.3, at friction Reynolds numbers three times lower, while close to the trailing edge the backflow level reaches 30%. Conditional analysis of extreme events indicates that for increasing Clauser pressure-gradient parameters (reaching β ? 35), the flow reaches a state in which the extreme events are more likely aligned with or against the freestream, and that the otherwise strong spanwise component of the wall-shear stress reduces towards the vicinity of the trailing edge. Backflow events subjected to moderate up to strong APG conditions (0.6 < β < 4.1) exhibit an average width of Δz⁺ ? 20, and an average lifetime of Δt⁺ ? 2. This directly connects with the findings by Lenaers et al., and implies that there is a connection between high-Re ZPG and strong APG conditions.     

A mixed-time-scale low-Reynolds-number one-equation turbulence model

In this paper, a new low-Reynolds-number (LRN) one-equation turbulence model for eddy viscosity is proposed. A mixed time scale, representing a combination of three time scales: two time scales made of strain-rate parameter S and vorticity parameter Ω and the turbulent time scale k/?, is introduced into this model. The proposed model is derived from an LRN k?? two-equation model where the mixed time scale has been proved to be very effective for predicting local flows over complex terrains. In the transport equation of the model, the mixed time scale is included in the production and the dissipation terms. The new model is evaluated in channel flows at various Reynolds numbers, boundary layer flows with or without pressure gradient and backward-facing step flows with different expansion ratios and Reynolds numbers. Then the grid convergence of the model is investigated. Finally, the model performance for different values of the weighting constant C_s in the mixed time scale is assessed. The results show that the proposed model reproduces the correct wall-limiting behaviour of turbulent quantities and performs well in the near-wall region of turbulent flows. The model could be expected to be adopted in hybrid Reynolds averaged Navier–Stokes/large eddy simulation methodology for complex wall-bounded flows at high Reynolds numbers.     

Large-eddy simulations of temporally accelerating turbulent channel flow

The unsteady turbulent channel flow subject to the temporal acceleration is considered in this study. Large-eddy simulations were performed to study the response of the turbulent flow to the temporal acceleration. The simulations were started with the fully developed turbulent channel flow at an initial Reynolds number of Re₀ = 3500 (based on the channel half-height and the bulk-mean velocity), and then a constant temporal acceleration was applied. During the acceleration, the Reynolds number of the channel flow increased linearly from the initial Reynolds number to the final Reynolds number of Re₁ = 22,600. The effect of grid resolution, domain size, time step size on the simulation results was assessed in a preliminary study using simulations of the accelerating turbulent flow as well as simulations of the steady turbulent channel flow at various Reynolds numbers. Simulation parameters were carefully chosen from the preliminary study to ascertain the accuracy of the simulation. From the accelerating turbulent flow simulations, the delays in the response of various flow properties to the temporal acceleration were measured. The distinctive features of the delays responsible for turbulence production, energy redistribution, and radial propagation were identified. Detailed turbulence statistics including the wall shear stress response during the acceleration were examined. The results reveal the changes in the near-wall structures during the acceleration. A self-sustaining mechanism of turbulence is proposed to explain the response of the turbulent flow to the temporal acceleration. Although the overall flow characteristics are similar between the channel and pipe flows, some differences were observed between the two flows.     

Verified predictions of shape sensitivities in wall-bounded turbulent flows by an adaptive finite-element method

A Continuous Sensitivity Equation (CSE) method is presented for shape parameters in turbulent wall-bounded flows modeled with the standard k–? turbulence model with wall functions. Differentiation of boundary conditions and their complex dependencies on shape parameters, including the two-velocity scale wall functions, is presented in details along with the appropriate methodology required for the CSE method. To ensure accuracy, grid convergence and to reduce computational time, an adaptive finite-element method driven by asymptotically exact error estimations is used. The adaptive process is controlled by error estimates on both flow and sensitivity solutions. Firstly, the proposed approach is applied on a problem with a closed-form solution, derived using the Method of the Manufactured Solution to perform Code Verification. Results from adaptive grid refinement studies show Verification of flow and sensitivity solvers, error estimators and the adaptive strategy. Secondly, we consider turbulent flows around a square cross-section cylinder in proximity of a solid wall. We examine the quality of the numerical solutions by performing Solution Verification and Validation. Then, Sensitivity Analysis of these turbulent flows is performed to investigate the ability of the method to deal with non-trivial geometrical changes. Sensitivity information is used to estimate uncertainties in the flow solution caused by uncertainties in the shape parameter and to perform fast evaluation of flows on nearby configurations.     

<Emphasis Type="Italic">β</Emphasis>-distribution for Reynolds stress and turbulent heat flux in relaxation turbulent boundary layer of compression ramp

A challenge in the study of turbulent boundary layers (TBLs) is to understand the non-equilibrium relaxation process after sep-aration and reattachment due to shock-wave/boundary-layer interaction. The classical boundary layer theory cannot deal with the strong adverse pressure gradient, and hence, the computational modeling of this process remains inaccurate. Here, we report the direct numerical simulation results of the relaxation TBL behind a compression ramp, which reveal the presence of intense large-scale eddies, with significantly enhanced Reynolds stress and turbulent heat flux. A crucial finding is that the wall-normal profiles of the excess Reynolds stress and turbulent heat flux obey a β-distribution, which is a product of two power laws with respect to the wall-normal distances from the wall and from the boundary layer edge. In addition, the streamwise decays of the excess Reynolds stress and turbulent heat flux also exhibit power laws with respect to the streamwise distance from the corner of the compression ramp. These results suggest that the relaxation TBL obeys the dilation symmetry, which is a specific form of self-organization in this complex non-equilibrium flow. The β-distribution yields important hints for the development of a turbulence model.     

LES of spatially developing turbulent boundary layer over a concave surface

We revisit the problem of a spatially developing turbulent boundary layer over a concave surface. Unlike previous investigations, we simulate the combined effects of streamline curvature as well as curvature-induced pressure gradients on the turbulence. Our focus is on investigating the response of the turbulent boundary layer to the sudden onset of curvature and the destabilising influence of concave surface in the presence of pressure gradients. This is of interest for evaluating the turbulence closure models. At the beginning of the curve, the momentum thickness Reynolds number is 1520 and the ratio of the boundary layer thickness to the radius of curvature is δ₀/R = 0.055. The radial profiles of the mean velocity and turbulence statistics at different locations along the concave surface are presented. Our recently proposed curvature-corrected Reynolds Averaged Navier-Stokes (RANS) model is assessed in an a posteriori sense and the improvements obtained over the base model are reported. From the large Eddy simulation (LES) results, it was found that the maximum influence of concave curvature is on the wall-normal component of the Reynolds stress. The budgets of wall-normal Reynolds stress also confirmed this observation. At the onset of curvature, the effect of adverse pressure gradient is found to be predominant. This decreases the skin friction levels below that in the flat section.     

Predictions of canonical wall-bounded turbulent flows via a modified k–ω equation

A major challenge in computation of engineering flows is to derive and improve turbulence models built on turbulence physics. Here, we present a physics-based modified k–ω equation for canonical wall-bounded turbulent flows (boundary layer, channel and pipe), predicting both mean velocity profile (MVP) and streamwise mean kinetic energy profile (SMKP) with high accuracy over a wide range of Reynolds number (Re). The result builds on a multi-layer quantification of wall flows, which allows a significant modification of the k–ω equation. Three innovations are introduced: first, an adjustment of the Karman constant to 0.45 is set for the overlap region with a logarithmic MVP; second, a wake parameter models the turbulent transport near the centreline; third, an anomalous dissipation factor represents the effect of a meso-layer in the overlap region. Then, a highly accurate (above 99%) prediction of MVPs is obtained in Princeton pipes, improving the original model prediction by up to 10%. Moreover, the entire SMKP, including the newly observed outer peak, is predicted. With a slight change of the wake parameter, the model also yields accurate predictions for channels and boundary layers.     

Understanding the sub-critical transition to turbulence in wall flows

In contrast with free shear flows presenting velocity profiles with inflection points which cascade to turbulence in a relatively mild way, wall bounded flows are deprived of (inertial) instability modes at low Reynolds numbers and become turbulent in a much wilder way, most often marked by the coexistence of laminar and turbulent domains at intermediate Reynolds numbers, well below the range where (viscous) instabilities can show up. There can even be no unstable mode at all, as for plane Couette flow (pCf) or for Poiseuille pipe flow (Ppf) that are currently the subject of intense research. Though the mechanisms involved in the transition to turbulence in wall flows are now better understood, statistical properties of the transition itself are yet unsatisfactorily assessed. A widely accepted interpretation rests on non-trivial solutions of the Navier-Stokes equations in the form of unstable travelling waves and on transient chaotic states associated to chaotic repellors. Whether these concepts typical of the theory of temporal chaos are really appropriate is yet unclear owing to the fact that, strictly speaking, they apply when confinement in physical space is effective while the physical systems considered are rather extended in at least one space direction, so that spatiotemporal behaviour cannot be ruled out in the transitional regime. The case of pCf will be examined in this perspective through numerical simulations of a model with reduced cross-stream (y) dependence, focusing on the in-plane (x, z) space dependence of a few velocity amplitudes. In the large aspect-ratio limit, the transition to turbulence takes place via spatiotemporal intermittency and we shall attempt to make a connection with the theory of first-order (thermodynamic) phase transitions, as suggested long ago by Pomeau.      

Flame front analysis of high-pressure turbulent lean premixed methane–air flames

An experimental study on lean turbulent premixed methane–air flames at high pressure is conducted by using a turbulent Bunsen flame configuration. A single equivalence ratio flame at Φ = 0.6 is explored for pressures ranging from atmospheric pressure to 0.9 MPa. LDA measurements of the cold flow indicate that turbulence intensities and the integral length scale are not sensitive to pressure. Due to the decreased kinematic viscosity with increasing pressure, the turbulent Reynolds numbers increase, and isotropic turbulence scaling relations indicate a large decrease of the smallest turbulence scales. Available experimental results and PREMIX code computations indicate a decrease in laminar flame propagation velocities with increasing pressure, essentially between the atmospheric pressure and 0.5 MPa. The u′/S_L ratio increases therefore accordingly. Instantaneous flame images are obtained by Mie scattering tomography. The images and their analysis show that pressure increase generates small scale flame structures. In an attempt to generalize these results, the variance of the flamelet curvatures, the standard deviation of the flamelet orientation angle, and the flamelet crossing lengths have been plotted against which is proportional to the ratio between the integral and Taylor length scales, and which increases with pressure. These three parameters vary linearly with the ratio between large and small turbulence scales and clearly indicate the strong effect of this parameter on premixed turbulent flame dynamics and structure. An obvious consequence is the increase in flame surface density and hence burning rate with pressure, as confirmed by its direct determination from 2D tomographic images.     

Simulations of turbulent asymptotic suction boundary layers

A series of large-eddy simulations of a turbulent asymptotic suction boundary layer (TASBL) was performed in a periodic domain, on which uniform suction was applied over a flat plate. Three Reynolds numbers (defined as ratio of free-stream and suction velocity) of Re = 333, 400 and 500 and a variety of domain sizes were considered in temporal simulations in order to investigate the turbulence statistics, the importance of the computational domain size, the arising flow structures as well as temporal development length required to achieve the asymptotic state. The effect of these two important parameters was assessed in terms of their influence on integral quantities, mean velocity, Reynolds stresses, higher order statistics, amplitude modulation and spectral maps. While the near-wall region up to the buffer region appears to scale irrespective of Re and domain size, the parameters of the logarithmic law (i.e. von Kármán and additive coefficient) decrease with increasing Re, while the wake strength decreases with increasing spanwise domain size and vanishes entirely once the spanwise domain size exceeds approximately two boundary-layer thicknesses irrespective of Re. The wake strength also reduces with increasing simulation time. The asymptotic state of the TASBL is characterised by surprisingly large friction Reynolds numbers and inherits features of wall turbulence at numerically high Re. Compared to a turbulent boundary layer (TBL) or a channel flow without suction, the components of the Reynolds-stress tensor are overall reduced, but exhibit a logarithmic increase with decreasing suction rates, i.e. increasing Re. At the same time, the anisotropy is increased compared to canonical wall-bounded flows without suction. The reduced amplitudes in turbulence quantities are discussed in light of the amplitude modulation due to the weakened larger outer structures. The inner peak in the spectral maps is shifted to higher wavelength and the strength of the outer peak is much less than for TBLs. An additional spatial simulation was performed, in order to relate the simulation results to wind tunnel experiments, which – in accordance with the results from the temporal simulation – indicate that a truly TASBL is practically impossible to realise in a wind tunnel. Our unique data set agrees qualitatively with existing literature results for both numerical and experimental studies, and at the same time sheds light on the fact why the asymptotic state could not be established in a wind tunnel experiment, viz. because experimental studies resemble our simulation results from too small simulation boxes or insufficient development times.     

Adjoint wall functions: A new concept for use in aerodynamic shape optimization

The continuous adjoint method for the computation of sensitivity derivatives in aerodynamic optimization problems of steady incompressible flows, modeled through the k–ε turbulence model with wall functions, is presented. The proposed formulation leads to the adjoint equations along with their boundary conditions by introducing the adjoint to the friction velocity. Based on the latter, an adjoint law of the wall that bridges the gap between the solid wall and the first grid node off the wall is proposed and used during the solution of the system of adjoint (to both the mean flow and turbulence) equations. Any high Reynolds turbulence model, other than the k–ε one used in this paper, could also profit from the proposed adjoint wall function technique. In the examined duct flow problems, where the total pressure loss due to viscous effects is used as objective function, emphasis is laid on the accuracy of the computed sensitivity derivatives, rather than the optimization itself. The latter might rely on any descent method, once the objective function gradient has accurately been computed.     

Intermittency,Moments, and Friction Coefficient during the Subcritical Transition of Channel Flow

The intermittent distribution of localized turbulent structures is a key feature of the subcritical transitions in channel flows, which are studied in this paper with a wind channel and theoretical modeling. Entrance disturbances are introduced by small beads, and localized turbulent patches can be triggered at low Reynolds numbers (Re). High turbulence intensity represents strong ability of perturbation spread, and a maximum turbulence intensity is found for every test case as Re ≥ 950, where the turbulence fraction increases abruptly with Re. Skewness can reflect the velocity defects of localized turbulent patches and is revealed to become negative when Re is as low as about 660. It is shown that the third-order moments of the midplane streamwise velocities have minima, while the corresponding forth-order moments have maxima during the transition. These kinematic extremes and different variation scenarios of the friction coefficient during the transition are explained with an intermittent structure model, where the robust localized turbulent structure is simplified as a turbulence unit, a structure whose statistical properties are only weak functions of the Reynolds number.     

Characteristic boundary conditions for simulations of compressible reacting flows with multi-dimensional,viscous and reaction effects

A generalized formulation of the characteristic boundary conditions for compressible reacting flows is proposed. The new and improved approach resolves a number of lingering issues of spurious solution behaviour encountered in turbulent reacting flow simulations in the past. This is accomplished (a) by accounting for all the relevant terms in the determination of the characteristic wave amplitudes and (b) by accommodating a relaxation treatment for the transverse gradient terms with the relaxation coefficient properly determined by the low Mach number asymptotic expansion. The new boundary conditions are applied to a comprehensive set of test problems including: vortex-convection; turbulent inflow; ignition front propagation; non-reacting and reacting Poiseuille flows; and counterflow cases. It is demonstrated that the improved boundary conditions perform consistently superior to existing approaches, and result in robust and accurate solutions with minimal acoustic wave interactions at the boundary in hostile turbulent combustion simulation conditions.     

A multi-scale simulation method for high Reynolds number wall-bounded turbulent flows

We present an assessment and enhancement of the hybrid two-level large-eddy simulation method (A.G. Gungor and S. Menon, A new two-scale model for large eddy simulation of wall-bounded flows, Prog. Aerosp. Sci. 46 (2010), pp. 28–45), a multi-scale formulation for simulation of high Reynolds number wall-bounded turbulent flows. The assessment of the method is performed by examining role of static and dynamic blending functions used to perform hybridisation of two-level simulation (K. Kemenov and S. Menon, Explicit small-scale velocity simulation for high-Re turbulent flows, J. Comput. Phys. 220 (2006), pp. 290–311; K. Kemenov and S. Menon, Explicit small-scale velocity simulation for high-Re turbulent flows. Part 2: Non-homogeneous flows, J. Comput. Phys. 222 (2007), pp. 673–701) and large-eddy simulation methods. The sensitivity of first- and second-order turbulence statistics to the type of blending functions is investigated by simulating a fully developed turbulent flow in a channel at a friction Reynolds number Re_τ = 395 and comparing the results with those obtained using a direct numerical simulation. The first-order statistics do not show any significant differences for different blending functions, but the second-order statistics show some minor differences. The dynamic evaluation of the hybrid region and the blending function is necessary for non-equilibrium and complex flows where use of a static blending function can lead to inaccurate results. We propose two criteria for the dynamic evaluation; first evaluates extent of the hybrid region based on the subgrid turbulent kinetic energy and the second estimates the blending function based on a characteristic length scale. The computational efficiency of the method is enhanced by incorporating a hybrid programming paradigm where a standard domain decomposition by the message-passing-interface library is combined with the open multi-processing based parallelisation. A further enhancement of the method is achieved by incorporating a closure model for the unclosed hybrid terms in the governing equations, which appear due to hybridisation of two-level- and large-eddy-simulation methods. The model is based on an order of magnitude approximation and a preliminary assessment of the model shows improvement of turbulence statistics when used to simulate turbulent flow in a periodic channel. The assessment and improvements to the multi-scale method make it more suitable for simulation of practical wall-bounded turbulent flows at higher Reynolds number than a conventional large-eddy simulation. This is demonstrated by simulating two representative cases; turbulent flow at high Reynolds number in a periodic channel and flow over a bump placed on the lower surface of a channel, where a relatively coarser computational grid is found to be sufficient for reasonably accurate results.     

Aspect ratio effects in turbulent duct flows studied through direct numerical simulation

Three-dimensional effects in turbulent duct flows, i.e., sidewall boundary layers and secondary motions, are studied by means of direct numerical simulation (DNS). The spectral element code Nek5000 is used to compute turbulent duct flows with aspect ratios 1–7 (at Re_{b, c} = 2800, Re_{τ, c} ? 180) and aspect ratio 1 (at Re_{b, c} = 5600, Re_{τ, c} ? 330), in streamwise-periodic boxes of length 25h. The total number of grid points ranges from 28 to 145 million, and the pressure gradient is adjusted iteratively in order to keep the same bulk Reynolds number in the centreplane with changing aspect ratio. Turbulence is initiated via a trip forcing active during the initial stages of the simulation, and the statistical convergence of the data is discussed both in terms of transient approach and averaging period. Spanwise variations in wall shear, mean-flow profiles, and turbulence statistics are analysed as a function of aspect ratio, and also compared with the spanwise-periodic channel (as idealisation of an infinite aspect ratio duct). The computations show good agreement with experimental measurements carried out in parallel at the Illinois Institute of Technology (IIT) in Chicago, and highlight the relevance of sidewall boundary layers and secondary vortices in the physics of the duct flow. The rich array of secondary vortices extending throughout the upper and lower walls of the duct, and their dependence on Reynolds number and aspect ratio, had not been reported in the literature before.     

Self-similar turbulent boundary layer with imposed pressure gradient. Velocity-defect law

Self-similar flows in a turbulent boundary layer when the free-stream velocity is specified as a power function of the longitudinal coordinate are investigated. The self-similar formulation not only simplifies solving the problem by reducing the equations of motion to ordinary differential equations but also provides a mean for formulating the closure conditions for these equations. It is shown that for the class of flows under consideration that depend on three governing parameters, the dimensionless mixing length in the outer region is a function of the normalized distance from the wall and the exponent m of the power law. In calculations, this function is assumed to be independent of pressure gradient, which gives the results very close to experimental data. As a result of an exact asymptotic solution of the problem, we establish the characteristic scale of the velocity defect in the outer region (the velocity-defect law) valid in the entire range of variation of the Clauser similarity parameter.     

Three-dimensional direct numerical simulation of turbulent channel flow catalytic combustion of hydrogen over platinum

The turbulent catalytic combustion of a fuel-lean hydrogen/air mixture (equivalence ratio ? = 0.24) was investigated by means of three-dimensional direct numerical simulation (DNS) in a platinum-coated plane channel with a prescribed wall temperature of 960 K and an incoming Reynolds number, based on the channel height, of 5700. Heat transfer from the hot catalytic walls laminarized the flow, as manifested by the progressive suppression of the high vorticity components of the flow aligned parallel to the channel walls at increasing streamwise distances. The impact of turbulence suppression on the mass transfer towards or away from the catalytic wall was subsequently assessed. Far upstream where high turbulence fluctuations persisted, the instantaneous local transverse gradient of the limiting hydrogen reactant (a quantity proportional to the catalytic reaction rate) as well as the instantaneous hydrogen concentration at the wall exhibited strong fluctuations by up to 300%, a result of finite-rate chemistry induced by the high inrush events towards the catalytic walls. Fourier analysis of the reaction rate fluctuations yielded peak frequencies of less than 1 kHz, values comparable to the thermal response frequencies of typical materials in commercial catalytic geometries. This has direct implications on the thermal stress of the reactor walls as well as on the decoupling between flow and solid thermal modeling currently used in practical catalytic reactors. Far downstream, the dampening of turbulence resulted in weaker hydrogen concentration fluctuations with nearly symmetric distributions. Finally, computed transverse turbulent species fluxes indicated inherent weaknesses of near-wall turbulence models in describing turbulent transport of species with disparate molecular diffusivities.