Equation of state of fluid helium at high temperatures and densities

Hugoniot curves and shock temperatures of gas helium with initial temperature 293 K and three initial pressures 0.6, 1.2, and 5.0 MPa were measured up to 15000 K using a two-stage light-gas gun and transient radiation pyrometer. It was found that the calculated Hugoniot EOS of gas helium at the same initial pressure using Saha equation with Debye-Hückel correction was in good agreement with the experimental data. The curve of the calculated shock wave velocity with the particle velocity of gas helium which is shocked from the initial pressure 5 MPa and temperature 293 K, i.e., theD ≈u relation,D=C ₀+λu (u<10 km/s, λ=1.32) in a low pressure region, is approximately parallel with the fittedD ≈u (λ=1.36) of liquid helium from the experimental data of Nellis et al. Our calculations show that the Hugoniot parameter λ is independent of the initial density p{in0}. TheD≈u curves of gas helium will transfer to another one and approach a limiting value of compression when their temperature elevates to about 18000 K and the ionization degree of the shocked gas helium reaches 10⁻³.     

稠密氦气物态方程研究

用二级氢气炮作为冲击压缩加载工具和多通道瞬态辐射高温计作为主要测量系统,测量了冲击压缩氦气等离子体的光辐亮度历史（初始温度293K,初始压力为1.2MPa）。根据实测记录信号波形的有关特征量,计算得到了氦等离子体的Hugoniot物态方程（含冲击温度）。结果发现：实测Hugoniot物态方程可用Saha方程加Debye-Huckel修正物理模型解释。     

C30混凝土冲击绝热关系和Grüneisen型状态方程的实验研究

采用一级气炮加载技术和锰铜压力计测试技术,对含初始空隙的C30混凝土在一维应变条件下的冲击特性进行了实验测量和分析.基于锰铜压力计测量的压力波形,确定了C30混凝土材料的冲击绝热关系,即冲击波速度D与波后粒子速度u之间满足线性关系.再从C30混凝土的冲击绝热数据出发,获得了计及初始空隙度₀影响的多项式形式Grüneisen型状态方程中的各项系数.实测压力波形还显示：不同位置处的压力波形在迅速上升至峰值后均随时间逐渐衰减,而冲击波峰值又随传播 关键词： Grüneisen型状态方程 冲击绝热关系 混凝土     

反向碰撞法测量Bi的低压Hugoniot数据

在火炮和二级轻气炮上利用反向碰撞技术,通过测量飞片击靶速度以及飞片/窗口的界面粒子速度,获得了金属铋(Bi)在10-45 GPa压力范围内的Hugoniot数据. 该方法克服了电探针法在测量低压Hugoniot数据时由于导通一致性差而不能准确得到冲击波速度的难题,同时又避免了精确测量样品中冲击波走时的问题. 实验获得的冲击波速度(D)-波后粒子速度(u)Hugoniot数据表明,Bi在粒子速度u=0.9 km/s附近D-u曲线发生了明显拐折,产生这一拐折的原因推测与冲击导致的Bi的固-液相变有关. 关键词： Hugoniot数据 反向碰撞 冲击相变 铋     

Kinetics of luminescence induced by sputtering metallic cadmium by a pulsed fast electron beam in helium

Results of an experimental study of the kinetics of luminescence observed when a metallic cadmium foil is bombarded in a helium medium by a 3-ns pulsed beam of 150-keV fast electrons are reported. The foil was irradiated at gas pressures from 76 to 2280 Torr. At a foil temperature of T = 240° C, the de-excitation time of the Beitler levels of the Cd II ion was measured as a function of the buffer gas pressure and the constant of collision quenching of the 5s22D_5/2 level of Cd II by He atoms was determined as k ≈ 3 × 10^-29 cm⁶/s. The experimental data were compared with calculations performed for the gas—vapor mixture in order to find the fraction of excited Cd II ions in the 5s²2D_5/2 state produced directly as a result of sputtering of metallic cadmium by high-energy electrons and by components of the helium plasma. At a helium buffer gas pressure of P ≤ 2.5 atm and a temperature of the cadmium target of T = 240° C, the value of this quantity was found to be α = 0.28 + 0.23P (where P is the helium pressure in atmospheres).     

Cluster structure of oriented polyethylene terephthalate films

The surface of polyethylene terephthalate films (the degree of crystallinity is 0.12–0.18) subjected to uniaxial drawing near the glass transition temperature of 353 K has been studied by electron microscopy and IR spectroscopy. Formation of a percolation cluster of densely packed particles, which is deformed as a whole entity, has been revealed in the films. The volume fraction of the cluster (Ω ≈ 0.5) and the degree of chain unfolding (β ≈ 0.7) at 343 K are independent of the drawing ratio in the region 1.1 ≤ λ ≤ 3.0. Near λ = 2.5, plane orientation of chains, for which the radius of particles in the amorphous phase is close to the radius of unperturbed coil, has been found. At 363 K, the cluster framework formation (Ω ≈ 0.6 and β ≈ 1) terminates near λ = 2.5. The drawing ratio λ ≥ 4 corresponds to microfibrils of chains with the parameters Ω ≈ 0.15 and β ≈ 1 and the fractal dimensionality D ≈ 1.     

Mass-spectrometric analysis of diffusion and solubility of helium in cerium-gadolinium ceramics with a submicrocrystalline structure

Diffusion and solubility of helium in Ce_0.8Gd_0.2O_{1.9 − δ} ceramics (δ = 0, 0.015) with a submicrocrystal structure are studied by thermodesorption of helium from preliminarily saturated (in the gas phase) crystals at temperatures of 613 and 673 K in the saturated pressure range 0–21 MPa. It is shown that, in this ceramics (δ = 0), the defect-trap diffusion mechanism operates. The main positions for dissolution are neutral anion vacancies formed as a result of thermal dissociation of impurity-vacancy complexes and saturated up to ∼1 × 10¹⁹ cm⁻³ at P = 6 MPa and T = 673 K. The dissociation energy of the complex and the energy of helium dissolution in the neutral anion vacancy are estimated at ∼2 eV and below −0.3 eV, respectively.     

Double-diaphragm shock tube at the Ioffe Physicotechnical Institute

Results of numerical calculations of the flow in a double-diaphragm shock tube with a tailored contact surface are reported. The calculations were carried out using a model of an ideal shock tube allowing for the real properties of the driver gas at high pressures and equilibrium thermodynamics of the processes behind the shock waves at Mach numbers M _s1 of the shock wave in the working gas varying in the range 5–25. Flow regimes with a tailored contact surface were obtained for Mach numbers M _s1=6.3, 11, and 15 using the double-diaphragm shock tube at the Ioffe Physicotechnical Institute. Under these conditions, the parameters of the working gas were kept constant for more than 1 ms. The calculated data were compared with the experimental results and it was shown that the calculated data may be used to determine the section lengths in a double-diaphragm shock tube and to estimate its operating time. The calculated values of the initial pressure in the sections of the tube were substantially lower than those achieved experimentally. Measurements were made of the static pressure along the axis of a conical nozzle during the expansion of hydrogen (initial temperature T ₀=293 K) and shock-heated nitrogen (T ₀=4000 K). It is found that the expansion of hydrogen is accompanied by deactivation of the rotational degrees of freedom, and that partial freezing of the vibrational degrees of freedom takes place in the nitrogen stream. Zh. Tekh. Fiz. 67, 88–95 (November 1997)     

Mass-spectroscopic study of the diffusion and solubility of helium in submicrocrystalline palladium

By the method of helium thermal desorption from submicrocrystalline palladium presaturated in the gaseous phase, the diffusion coefficient D _eff and solubility coefficient C _eff of helium are measured in the range P=0–3 MPa and T=293–508 K. The pressure dependence of C _eff flattens at high pressures. At low saturation pressures, the temperature dependences of the diffusion and solubility coefficients may be divided into (1) high-temperature (400–508 K) and (2) low-temperature (293–400 K) ranges described by the exponentials D _{1, 2}=D ₀exp (−E _{1, 2} ^D /kT) and C _{1, 2}=C ₀exp (−E _{1, 2} ^S /kT). The energies of diffusion activation are E ₂ ^D =0.0036±0.0015 eV and E ₁ ^D =0.33±0.03 eV, and the solution energies are E ₂ ^S =−0.025±0.008 eV and E ₁ ^S =0.086±0.008 eV in the low-and high-temperature ranges, respectively. Mechanisms behind the diffusion and solution of helium are discussed.     

Equation of state of initially liquid carbon monoxide and nitrogen mixture

The modified liquid perturbation variational theory and the improved vdW-1f model were applied to calculating the equation of the state of liquid CO-N₂ mixture with the ratio of 1:1, 4:1 and 1:4, respectively, in the shock pressure range of 9–49 GPa. It was shown that the calculated result for CO-N₂ mixture with the ratio of 1:1 is well consistent with the earlier experimental data. The thermodynamics equilibrium, chemical equilibrium and phase equilibrium were all considered in detail. It was found that Hugoniot of liquid CO-N₂ mixture is moderately softened in the pressure range of 20–30 GPa and 30–49 GPa for different initial proportions, and that the Hugoniot is more softened in the latter pressure range, which means that the structural phase transition occurs near 20 GPa and 30 GPa. Since the shock productions may absorb a plenty of systematic energy, the shock temperature and pressure decline compared with the case of no chemical reaction. Pressures and temperatures increase gradually with the increase in the mole fraction of nitrogen composition. The results for the 1:1 CO-N₂ mixture lie in the middle of two others. Therefore, it was shown that the modified Lorentz-Berthelor rule used in the scheme is effective to study shock-compression properties of liquid CO-N₂ mixture under high temperatures and high pressures. Supported by the National Natural Science Foundation of China (Grant No. 10576020)     

Jeans-Buneman instability in a dusty plasma

A self consistent formulation of the Jeans instability of a dusty plasma with proper inclusion of charge dynamics is described. It is shown that charge fluctuations significantly affect the Jeans as well as the Buneman mode. For plasma particles (electrons and ions) in local thermal equilibrium, the Jeans lengthλ _J is given byλ _J≈λ _g F(R, ε, β/η), whereλ _g is the Debye length of the charged grains,R is the square of the ratio of the Jeans to the plasma frequency of the grains,ε is the square of the ratio of the Debye length of the grains and the plasma particles andβ/η is the ratio of the attachment to the decay frequency of the electronic charges to the grain surface. The functional form ofF is given in the text. Numerical investigation of the Jeans-Buneman mode for a two and three component plasma shows that the Jeans mode dominates atkλ _D≪1 (wherek is the wave number andλ _D is the Debye length of plasma particles), whereas atkλ _D≫1 only the Buneman mode operates. Charge fluctuations reduce the area of overlap of the two modes. Furthermore, in the absence of gravity, there exists a new, charge fluctuation induced unstable mode in a streaming dusty plasma. Astrophysical applications of the results are discussed.     

Decomposition of nitromethane in shock waves: The primary stage and the kinetics of decomposition at pressures of about 40 atm

The kinetics of nitromethane (NM) decomposition and the observed rate constant of the process were measured behind reflected shock wave using absorption spectroscopy at λ = 230 nm, temperatures of 1060 to 1350 K, pressure of ∼40 atm, and initial reactant concentration within 30–100 ppm. It was observed that, at the initial stage, nitromethane decomposes exponentially, without autoacceleration. The results of numerical simulations with the help of three most known kinetic schemes of nitromethane decomposition proved to be in close to agreement with our experimental data over the entire temperature range covered. It was demonstrated that the measured rate constant is identical to the rate constant of the dissociation CH₃NO₂ → CH₃ + NO₂. The temperature dependence of k ₁ was approximated by the Arrhenius formula k ₁ = 2.57 × 10¹⁴ exp(−52.85/RT) s⁻¹ (activation energy in kcal/mol), which suggests that the nitromethane dissociation proceeds in the falloff pressure region.     

Hyperfine Interactions in the Sr0.88Ba0.12HfO3 Compound

The temperature dependence of the hyperfine parameters in a powder sample of the Sr_0.88Ba_0.12HfO₃ compound has been investigated for the first time using perturbed angular correlation spectroscopy. The time spectra were measured as a function of the temperature from 293 to 1273 K. Activated ¹⁸¹Ta nuclei were used as hyperfine probes at the Hf sites. The analysis of the time spectra indicates the presence of two different surroundings for the Ta probes. The most populated site (f ₁≈75% at laboratory temperature) was fitted with the usual static quadrupole hyperfine interactions found in most perovskite-type compounds. The resulting quadrupole frequency is ω _Q ≈24 Mrad/s at this temperature. This frequency continuously decreases to nearly 9 Mrad/s at 1273 K. Its line width temperature dependence displays three regions and the changes observed probably correspond to phase transitions. The other site has a large and temperature independent quadrupole frequency ω _Q ≈120 Mrad/s that reversibly transforms into the first at high temperatures and probably originates from some defect in the structure. This revised version was published online in September 2006 with corrections to the Cover Date.     

Formation of two-dimensional current sheets under high initial pressure conditions

The possibilities of current-sheet formation in two-dimensional magnetic fields with a null line as well as the characteristic features of the plasma dynamics under high initial pressure conditions (helium, P ₀≈300 mtorr) are investigated for the first time. It is shown that current-sheet formation and efficient compression of the plasma into a sheet require that the magnetic field gradient be sufficiently large. A brightly emitting compact region with electron density N _e∼9×10¹⁶ cm⁻³, an order of magnitude higher than the gas atom density, was observed to form at the center of the layer. Zh. éksp. Teor. Fiz. 114, 1202–1214 (October 1998)     

High-Pressure Hydrogen Isotopes Sources Based on Vanadium Hydride

Equilibrium pressures of protium and deuterium desorption over a two-phase area of monohydride-vanadium dihydride were measured. Temperature measurement range was 300–635 K and the pressure range 1–500 MPa. Obtained temperature-dependences of fugacities within the given measurement range are: lgf(MPa) = −2152/T+ 6.6 and lgf(MPa) = −2575/T + 7.4 for protium and deuterium, respectively. The values of enthalpy and entropy for vanadium dihydride phase formation were calculated from obtained relations. Using expressions obtained for fugacities and literature data on hydrogen imperfection the pressures, which can be obtained with vanadium dihydride employed in thermodesorption hydrogen sources, were estimated. Taking into account that due to deterioration in strength properties of the used structural materials, the heating temperature of the load-bearing body is limited to ∼973 K, maximal calculated pressure, which can be obtained with such sources as ≈1820 MPa for protium and ≈2220 MPa for deuterium. This revised version was published online in August 2006 with corrections to the Cover Date.     

Grain-boundary diffusion and solubility of helium in submicrocrystalline palladium

The diffusion and solubility of helium in palladium with a submicrocrystalline structure are investigated by thermal desorption of helium from He-saturated specimens at temperatures T = 293–508 K and saturation pressures P = 0.1–35 MPa. As the saturation pressure rises, the effective diffusion coefficient increases, exhibits a plateau, and then decreases to its initial value. Along with the four plateaus discovered earlier, the solubility versus saturation pressure dependence in the range 25.5–35.0 MPa demonstrates a fifth plateau, where the solubility is as high as (3.0 ± 0.4) × 10¹⁷ cm⁻³. It is shown that the helium diffuses along grain boundaries, at which clusters (traps) consisting of eight to ten vacancies are localized, and dissolves in these clusters. The high value of C _eff in the fifth plateau is explained by pairwise merging of adjacent vacancy clusters. From the D _eff(P) dependences, the vacancy clusters concentration is estimated as C* = 2.32 × 10¹⁶ cm⁻³. Within the experimental error, this value coincides with that obtained from the solubility data. Calculations of the energy of helium-defect interaction in submicrocrystalline Pd that are made using the molecular dynamics method support the experimental results.     

Effect of gas pressure on amplitude and duration of electron beam current in a gas-filled diode

The parameters of an electron beam generated in helium in the pressure range p = 10⁻⁴−12 atm are studied. Nanosecond high-voltage pulses are applied to a gap between a tubular cathode and planar anode, which is made of 45-μm-thick AlBe foil. Behind the anode, an electron beam is detected at a helium pressure of 12 atm. The pressure dependence of the beam current amplitude shows three peaks at p ≈ 0.01, ≈ 0.07, and ≈ 3 atm. The beam-induced glow of a luminescent film placed behind the foil and the discharge glow at different helium pressures in the gas-filled diode are photographed.     

Non-steady-state photo-EMF in nanostructured GaN and polypyrrole within porous matrices

We report an experimental investigation of the non-steady-state photoelectromotive force in nanostructured GaN within porous glass and polypyrrole within chrysotile asbestos. The samples are illuminated by an oscillating interference pattern created by two coherent light beams and the alternating current is detected as a response of the material. Dependences of the signal amplitude versus temporal and spatial frequencies, light intensity, and temperature are studied for two wavelengths λ=442 and 532 nm. The conductivity of the GaN composite is measured: σ=(1.1–1.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=442 nm, I ₀=0.045–0.19 W/cm², T=293 K) and σ=(3.5–4.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=532 nm, I ₀=2.3 W/cm², T=249–388 K). The diffusion length of photocarriers in polypyrrole nanowires is also estimated: L _D=0.18 μm.     

Investigation of the Parameters of Muon-Catalyzed Fusion in Double D/T Mixture at High Temperature and Density

Experiments on the study of the muon catalyzed fusion (μCF) process in a double D/T mixture of hydrogen isotopes in the temperature range 300–800 K at densities 0.3–0.5 LHD are performed at the JINR phasotron. The values of the effective μCF parameters (cycling rate λ _c , neutron yield Y _n , muon losses w) are obtained. Tentative dtμ-molecule formation rates on D₂ and DT molecules (λ _dtμ−d and λ _dtμ−t ) are obtained for different mixture temperatures and densities. The results obtained show that λ _dtμ−t increases with temperature, but its value is smaller than theoretical predictions. This revised version was published online in August 2006 with corrections to the Cover Date.     

Profile evolution of edge parameters during L/H and H/L mode transitions on compass-D

On COMPASS-D the profile evolution of electron density, electron temperature, perpendicular electric field, poloidal impurity velocity, and neutral density at the outboard mid-plane has been investigated during ohmic single null diverted (SND) discharges undergoing an L/H, H/L, and another L/H transition. This was achieved using a novel combined diagnostic consisting of thermal helium beam and Doppler spectrometry, sharing the same lines of sight. To generate the transitions first an ELM-free H-mode phase was produced by terminating the gas fuelling. Within this H-mode a stepped gas puff was applied triggering an intermediate L-mode phase followed by a second ELM-free phase. It was found that on COMPASS-D the L/H transition is not preceded by a change in velocity or electric field shear. The maximum electric field shear of ∇ ▽E _ψ ≈2×10³kV/m² develops after the L/H transition around the 95% flux surface. Although the neutral density at the separatrix is of the ordern _D ≈ 10¹⁷m⁻³ no indication of a local influence could be concluded. However, a correlation between the decay of the shear and the gas puff was observed. Presented at the Workshop on Role of Electric Fields in Plasma Confinement and Exhaust, Budapest, 18–19 June 2000. This work was jointly funded by the UK Department of Trade and Industry and EURATOM. The author H. Meyer is funded by a Marie Curie Research Training Grant.