Optical co-ordinates in general relativity 2 — the problem of distance

Summary Let denote the congruence of null geodesics associated with a given optical observer inV ₄. We prove that determines a unique collection of vector fieldsM₍₎ ( =1, 2, 3) and ₍₀₎ overV ₄, satisfying a weak version of Killing's conditions.This allows a natural interpretation of these fields as the infinitesimal generators of spatial rotations and temporal translation relative to the given observer. We prove also that the definition of the fieldsM₍₎ and ₍₀₎ is mathematically equivalent to the choice of a distinguished affine parameter f along the curves of, playing the role of a retarded distance from the observer.The relation between f and other possible definitions of distance is discussed.

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Sommario Sia la congruenza di geodetiche nulle associata ad un osservatore ottico assegnato nello spazio-tempoV ₄. Dimostriamo che determina un'unica collezione di campi vettorialiM₍₎ ( =1, 2, 3) e ₍₀₎ inV ₄ che soddisfano una versione in forma debole delle equazioni di Killing. Ciò suggerisce una naturale interpretazione di questi campi come generatori infinitesimi di rotazioni spaziali e traslazioni temporali relative all'osservatore assegnato. Dimostriamo anche che la definizione dei campiM₍₎, ₍₀₎ è matematicamente equivalente alla scelta di un parametro affine privilegiato f lungo le curve di, che gioca il ruolo di distanza ritardata dall'osservatore. Successivamente si esaminano i legami tra f ed altre possibili definizioni di distanza in grande.

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Work performed in the sphere of activity of: Gruppo Nazionale per la Fisica Matematica del CNR.     

LDA measurements in low Reynolds number turbulent boundary layer

LDA measurements of the mean velocity in a low Reynolds number turbulent boundary layer allow a direct estimate of the friction velocity U from the value of /y at the wall. The trend of the Reynolds number dependence of / is similar to the direct numerical simulations of Spalart (1988).     

Impacts of local dispersion and first-order decay on solute transport in randomly heterogeneous porous media

Stochastic subsurface transport theories either disregard local dispersion or take it to be constant. We offer an alternative Eulerian-Lagrangian formalism to account for both local dispersion and first-order mass removal (due to radioactive decay or biodegradation). It rests on a decomposition of the velocityv into a field-scale componentv , which is defined on the scale of measurement support, and a zero mean sub-field-scale componentv _s , which fluctuates randomly on scales smaller than. Without loss of generality, we work formally with unconditional statistics ofv _s and conditional statistics ofv . We then require that, within this (or other selected) working framework,v _s andv be mutually uncorrelated. This holds whenever the correlation scale ofv is large in comparison to that ofv _s . The formalism leads to an integro-differential equation for the conditional mean total concentration c which includes two dispersion terms, one field-scale and one sub-field-scale. It also leads to explicit expressions for conditional second moments of concentration cc. We solve the former, and evaluate the latter, for mildly fluctuatingv by means of an analytical-numerical method developed earlier by Zhang and Neuman. We present results in two-dimensional flow fields of unconditional (prior) mean uniformv . These show that the relative effect of local dispersion on first and second moments of concentration dies out locally as the corresponding dispersion tensor tends to zero. The effect also diminishes with time and source size. Our results thus do not support claims in the literature that local dispersion must always be accounted for, no matter how small it is. First-order decay reduces dispersion. This effect increases with time. However, these concentration moments c and cc of total concentrationc, which are associated with the scale below, cannot be used to estimate the field-scale concentrationc directly. To do so, a spatial average over the field measurement scale is needed. Nevertheless, our numerical results show that differences between the ensemble moments ofc and those ofc are negligible, especially for nonpoint sources, because the ensemble moments ofc are already smooth enough.     

The rheology of polymeric liquid crystals

The molecular theory of Doi has been used as a framework to characterize the rheological behavior of polymeric liquid crystals at the low deformation rates for which it was derived, and an appropriate extension for high deformation rates is presented. The essential physics behind the Doi formulation has, however, been retained in its entirety. The resulting four-parameter equation enables prediction of the shearing behavior at low and high deformation rates, of the stress in extensional flows, of the isotropic-anisotropic phase transition and of the molecular orientation. Extensional data over nearly three decades of elongation rate (10^–2–10¹) and shearing data over six decades of shear rate (10^–2–10⁴) have been correlated using this analysis. Experimental data are presented for both homogeneous and inhomogeneous shearing stress fields. For the latter, a 20-fold range of capillary tube diameters has been employed and no effects of system geometry or the inhomogeneity of the flow-field are observed. Such an independence of the rheological properties from these effects does not occur for low molecular weight liquid crystals and this is, perhaps, the first time this has been reported for polymeric lyotropic liquid crystals; the physical basis for this major difference is discussed briefly. A Semi-empirical constant in eq. (18), N/m² - c rod concentration, rods/m³ - c ^* critical rod concentration at which the isotropic phase becomes unstable, rods/m³ - C interaction potential in the Doi theory defined in eq. (3) - d rod diameter, m - D semi-empirical constant in eq. (19), s^–1 - D _r lumped rotational diffusivity defined in eq. (4), s^–1 - rotational diffusivity of rods in a concentrated (liquid crystalline) system, s^–1 - D _ro rotational diffusivity of a dilute solution of rods, s^–1 - f distribution function defining rod orientation - F tensorial term in the Doi theory defined in eq. (7) (or eq. (19)), s^–1 - G tensorial term in the Doi theory defined in eq. (8) - K _B Boltzmann constant, 1.38 × 10^–23 J/K-molecule - L rod length, m - S scalar order parameter - S tensor order parameter defined in eq. (5) - t time, s - T absolute temperature, K - u unit vector describing the orientation of an individual rod - rate of change ofu due to macroscopic flow, s^–1 - v fluid velocity vector, m/s - v velocity gradient tensor defined in eq. (9), s^–1 - V mean field (aligning) potential defined in eq. (2) - x coordinate direction, m - Kronecker delta (= 0 if = 1 if = ) - _r ratio of viscosity of suspension to that of the solvent at the same shear stress - _s solvent viscosity, Pa · s - ^* viscosity at the critical concentrationc ^*, Pa · s - v ₁, v₂ numerical factors in eqs. (3) and (4), respectively - deviatoric stress tensor, N/m² - volume fraction of rods - ⁰ constant in eq. (16) - ^* volume fraction of rods at the critical concentrationc ^* - average over the distribution functionf(u, t) (= d ²u f(u, t)) - gradient operator - d ²u integral over the surface of the sphere (|u| = 1)     

Nonlinear viscoelastic properties and change in entanglement structure of linear polymer

Simultaneous measurements of stress relaxation and differential dynamic modulus were made at 268 K over a time scale of 10 to 10⁴⁵ s for nearly monodisperse polybutadiene (M _w =2.2x10⁵, 1,2-structure 70%, M _e =3600) and also one having coarse cross-linking (M _c =29000). Static shear strain ranged from 0.1 to 2.0. In a long-time region (t> _k ), the relaxation modulus G (; t) could be expressed by the product G (0; t) h (y). The observed h() agreed well with the Doi-Edwards theory without use of IA approximation. Both the cured and uncured samples showed initial drop of the differential storage modulus G (), ; t) followed by gradual recovery, but did not attain the value before shearing G (, ; t) for the uncured sample showed smaller values than that for the cured one in the whole measured time scale at the higher strain, confirming the two origins of nonlinear viscoelasticity of well entangled polymer; induced chain anisotropy and induced decrement in entanglement density. G (, ; t) curves for the cured sample agreed well with the BKZ predictions. But the curves for the uncured sample agreed well with the BKZ prediction only at the time scale of t< _k . BKZ prediction showed significant upward deviations at t> _k . Such the differences are discussed in terms of the two origins.Dedicated to Prof. John D. Ferry on the occasion of his 85th birthday.     

On the localness of the spectral energy transfer in turbulence

By utilizing available experimental data for net energy transfer spectra for homogeneous turbulence, contributions P(, ) to the energy transfer at a wavenumber from various other wavenumbers are calculated. This is done by fitting a truncated power-exponential series in and to the experimental data for the net energy transfer T(), and using known properties of P(, ). Although the contributions P(, ) obtained by using this procedure are not unique, the results obtained by using various assumptions do not differ significantly. It seems clear from the results that for a region where the energy entering a wavenumber band dominates that leaving, much of the energy entering the band comes from wavenumbers which are about an order of magnitude smaller. That is, the energy transfer is rather nonlocal. This result is not significantly dependent on Reynolds number (for turbulence Reynolds numbers based on microscale from 3 to 800). For lower wavenumbers, where more energy leaves than enters a wavenumber band, the energy transfer into the band is more local, but much of the energy then leaves at distant wavenumbers.     

Application of the Chapman-Enskog method to the case of a binary two-temperature gas mixture

An interesting property of the flows of a binary mixture of neutral gases for which the molecular mass ratio =m/M1 is that within the limits of the applicability of continuum mechanics the components of the mixture may have different temperatures. The process of establishing the Maxwellian equilibrium state in such a mixture divides into several stages, which are characterized by relaxation times _i which differ in order of magnitude. First the state of the light component reaches equilibrium, then the heavy component, after which equilibrium between the components is established [1]. In the simplest case the relaxation times differ from one another by a factor of ^*.Here the mixture component temperature difference relaxation time _T /, where is the relaxation time for the light component. If 1, 1, so that _T ~1, then for the characteristic hydrodynamic time scale t~1 the relative temperature difference will be of order unity. In the absence of strong external force fields the component velocity difference is negligibly small, since its relaxation time _vt1.In the case of a fully ionized plasma the Chapman-Enskog method is quite easily extended to the case of the two-temperature mixture [3], since the Landau collision integral is used, which decomposes directly with respect to . In the Boltzmann cross collision integral, the quantity appears in the formulas relating the velocities before and after collision, which hinders the decomposition of this integral with respect to , which is necessary for calculating the relaxation terms in the equations for temperatures differing from zero in the Euler approximation [4] (the transport coefficients are calculated considerably more simply, since for their determination it is sufficient to account for only the first (Lorentzian [5]) terms of the decomposition of the cross collision integrals with respect to ). This led to the use in [4] for obtaining the equations of the considered continuum mixture of a specially constructed model kinetic equation (of the Bhatnagar-Krook type) which has an undetermined degree of accuracy.In the following we use the Boltzmann equations to obtain the equations of motion of a two-temperature binary gas mixture in an approximation analogous to that of Navier-Stokes (for convenience we shall term this approximation the Navier-Stokes approximation) to determine the transport coefficients and the relaxation terms of the equations for the temperatures. The equations in the Burnett approximation, and so on, may be obtained similarly, although this derivation is not useful in practice.     

Flow in porous media III: Deformable media

Stokes flow in a deformable medium is considered in terms of an isotropic, linearly elastic solid matrix. The analysis is restricted to steady forms of the momentum equations and small deformation of the solid phase. Darcy's law can be used to determine the motion of the fluid phase; however, the determination of the Darcy's law permeability tensor represents part of the closure problem in which the position of the fluid-solid interface must be determined.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - E Young's modulus for the-phase, N/m² - e i unit base vectors (i = 1, 2, 3) - g gravity vector, m²/s - H height of elastic, porous bed, m - k unit base vector (=e ₃) - characteristic length scale for the-phase, m - L characteristic length scale for volume-averaged quantities, m - n unit normal vector pointing from the-phase toward the-phase (n = -n ) - p pressure in the-phase, N/m² - P p – g·r, N/m² - r ₀ radius of the averaging volume, m - r position vector, m - t time, s - T total stress tensor in the-phase, N/m² - T ⁰ hydrostatic stress tensor for the-phase, N/m² - u displacement vector for the-phase, m - V averaging volume, m₃ - V volume of the-phase contained within the averaging volume, m³ - v velocity vector for the-phase, m/s Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - shear coefficient of viscosity for the-phase, Nt/m² - first Lamé coefficient for the-phase, N/m² - second Lamé coefficient for the-phase, N/m² - bulk coefficient of viscosity for the-phase, Nt/m² - T –T ⁰ , a deviatoric stress tensor for the-phase, N/m²     

Unsteady convective diffusion in a rotating parallel plate channel

The paper presents an exact analysis of the dispersion of a passive contaminant in a viscous fluid flowing in a parallel plate channel driven by a uniform pressure gradient. The channel rotates about an axis perpendicular to its walls with a uniform angular velocity resulting in a secondary flow. Using a generalized dispersion model which is valid for all time, we evaluate the longitudinal dispersion coefficientsK _i (i=1, 2, ...) as functions of time. It is shown thatK ₁=0 andK ₃,K ₄, ... decay rapidly in comparison withK ₂. ButK ₂ decreases with increasing (the dimensionless rotation parameter) for values of upto approximately =2.2. ThereafterK ₂ increases with further increase in and its value gets saturated for large values of (say, 500) and does not change any further with increase in . A physical explanation of this anomalous behaviour ofK ₂ is given.

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Instationäre konvektive Diffusion in einem rotierenden Parallelplattenkanal

Zusammenfassung In dieser Untersuchung wird eine exakte Analyse der Ausbreitung eines passiven Kontaminierungsstoffes in einer zähen Flüssigkeit gegeben, die, befördert durch einen gleichförmigen Druckgradienten, in einem Parallelplattenkanal strömt. Der Kanal rotiert mit gleichförmiger Winkelgeschwindigkeit um eine zu seinen Wänden senkrechte Achse, wodurch sich eine Sekundärströmung ausbildet. Unter Verwendung eines generalisierten, für alle Zeiten gültigen Dispersionsmodells werden die longitudinalen DispersionskoeffizientenK _i (i=1, 2, ...) als Funktionen der Zeit ermittelt. Es wird gezeigt, daßK ₁=0 gilt und dieK ₃,K ₄, ... gegenüberK ₂ schnell abnehmen.K ₂ nimmt ab, wenn , der dimensionslose Rotationsparameter, bis etwa zum Wert 2,2 ansteigt. Danach wächstK ₂ mit bis auf einem Endwert an, der etwa ab =500 erreicht wird. Dieses anomale Verhalten vonK ₂ findet eine physikalische Erklärung.

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List of symbols C solute concentration - D molecular diffusivity - K _i longitudinal dispersion coefficients - 2L depth of the channel - P ₀ dimensionless pressure gradient along main flow - Pe Péclet number - q velocity vector - Q _x,Q _y mass flux along the main flow and the secondary flow directions - dimensionless average velocity along the main flow direction - (x, y, z) Cartesian co-ordinates Greek symbols dimensionless rotation parameter - the inclination of side walls withx-axis - kinematic viscosity - fluid density - dimensionless time - angular velocity of the channel - dimensionless distance along the main flow direction - dimensionless distance along the vertical direction - dimensionless solute concentration - integral of the dispersion coefficientK ₂() over a time interval     

Theoretical derivation of tangential velocity profiles in a flat vortex chamber-influence of turbulence and wall friction

Summary As part of a study on the hydrodynamics of a cyclone separator, a theoretical investigation of the flow pattern in a flat box cyclone (vortex chamber) has been carried out. Expressions have been derived for the tangential velocity profile as influenced by internal friction (eddy viscosity) and wall friction. The most important parameter controlling the tangential velocity profile is = –u ₀ R/(v+ ), where u ₀ is the radial velocity at the outer radius R of the cyclone, the kinematic liquid viscosity and is the kinematic eddy viscosity. For values of greater than about 10 the tangential velocity profile is nearly hyperbolic, for smaller than 1 the tangential velocity even decreases towards the centre. It is shown how and also the wall friction coefficient may be obtained from experimental velocity profiles with the aid of suitable graphs. Because of the close relation between eddy viscosity and eddy diffusion, measurements of velocity profiles in flat box cyclones will also provide information on the eddy motion of particles in a cyclone, a motion reducing its separation efficiency.List of symbols A cross-sectional area of cyclone inlet - h height of cyclone - p static pressure in cyclone - p static pressure difference in cyclone between two points on different radius - r radius in cyclone - r ₁ radius of cyclone outlet - R radius of cyclone circumference - u radial velocity in cyclone - u ₀ radial velocity at circumference of flat box cyclone - v tangential velocity - v ₀ tangential velocity at circumference of flat box cyclone - w axial velocity - z axial co-ordinate in cyclone - friction coefficient in flat box cyclone (for definition see § 5) - ₁ value of friction coefficient for ₁<< ₂ - ₂ value of friction coefficient for ₂<<1 - = - ₁ value of for ₁<< ₂ - ₂ value of for ₂<<1 - thickness of laminar boundary layer - =/h - turbulent kinematic viscosity - ratio of z to h - k ratio of height of cyclone to radius R of cyclone - parameter describing velocity profile in cyclone =–u ₀ R/(+) - kinematic viscosity of fluid - density of fluid - ratio of r to R - ₁ value of at outlet of cyclone - ₂ value of at inner radius of cyclone inlet - _w shear stress at cyclone wall - angular momentum in cyclone/angular momentum in cyclone inlet - ₁ value of at = ₁ - ₂ value of at = ₂     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Numerical computation of high Rayleigh number natural convection and prediction of hot radiator induced room air motion

The two-dimensional stationary turbulent buoyant flow and heat transfer in a cavity at high Rayleigh numbers was computed numerically. The k– turbulence model was used. The time-averaged equations for momentum, energy and continuity, which are coupled to the turbulence equations, were solved using a finite difference formulation. In order to validate the computer code, a comparison exercise was carried out. The test results are in good agreement with the internationally accepted benchmark solution. Grid-refinement shows the necessity of a very fine grid at high Rayleigh numbers with especially small grid-distances in the near-wall region. The computed boundary layer velocity profiles are in excellent agreement with available experimental data. The local heat transfer in the turbulent part of the boundary layers is predicted 20% too high. Computations were carried out for the natural convective flow in a room induced by a hot radiator and a cold window. Various radiator configurations and types of thermal boundary conditions were applied including thermal radiation interaction between surfaces.Nomenclature a thermal diffusivity (m²/s) - C constant in _t expression - D cavity dimensions (m) - g acceleration of gravity (m/s²) - G _k production/destruction of k by buoyancy (kg/ms³) - h enthalpy (J/kg) - IX index of grid point - k turbulent kinetic energy (m²/s²) - m dimensionless stratification parameter - Nu overall Nusselt number - Nu _y local Nusselt number - NX total number of grid points - p pressure (N/m²) - P _k production of k by shear stress (kg/ms³) - Q heat flux through wall (W/m) - Ra overall Rayleigh number - Ra _y local Rayleigh number - Re _t turbulent Reynolds number - S source term in -equation (kg/ms⁴) - S source term for - T _c, T _h temperatures of cold and hot walls (K) - T _s (y) stratification temperature on vertical mid-line (K) - T ₀ mean cavity temperature (K) - u, v horizontal and vertical velocity components (m/s) - u ₀ Brunt-Vaisälä velocity scale (m/s) - x, y horizontal and vertical coordinates (m) - non-linearity parameter for grid - coefficient of thermal expansion (l/K) - jet angle (°) - diffusivity for - S dissipation rate for turbulent kinetic energy (m²/s³) - variable to be solved - thermal conductivity (W/mK) - , _t kinematic and eddy viscosities (m²/s) - stream function (kg/ms) - density (kg/m³) - _k, , _t constants in k– model     

The chaotic response of a fluttering panel: The influence of maneuvering

The influence of maneuvering on the chaotic response of a fluttering buckled plate on an aircraft has been studied. The governing equations, derived using Lagrangian mechanics, include geometric non-linearities associated with the occurrence of tensile stresses, as well as coupling between the angular velocity of the maneuver and the elastic degrees of freedom. Numerical simulation for periodic and chaotic responses are conducted in order to analyze the influence of the pull-up maneuver on the dynamic behavior of the panel. Long-time histories phase-plane plots, and power spectra of the responses are presented. As the maneuver (load factor) increases, the system exhibits complicated dynamic behavior including a direct and inverse cascade of subharmonic bifurcations, intermittency, and chaos. Beside these classical routes of transition from a periodic state to chaos, our calculations suggest amplitude modulation as a possible new mode of transition to chaos. Consequently this research contributes to the understanding of the mechanisms through which the transition between periodic and strange attractors occurs in, dissipative mechanical systems. In the case of a prescribed time dependent maneuver, a remarkable transition between the different types of limit cycles is presented.Nomenclature a plate length - a _r u _r /h - D plate bending stiffness - E modulus of elasticity - g acceleration due to gravity - h plate thickness - j₁,j₂,j₃ base vectors of the body frame of reference - K spring constant - M Mach number - n 1 + ₀/g - N ₁ applied in-plane force - p–p aerodynamic pressure - P pa ⁴/Dh - q ₀/2 - Q _r generalized Lagrangian forces - R rotation matrix - R ₄ N, a ²/D - t time - kinetic energy - u plate deflection - u displacement of the structure - u _r modal amplitude - v₀ velocity - x coordinates in the inertial frame of reference - z coordinates in the body frame of reference - Ka/(Ka+Eh) - - elastic energy - 2qa ³/D - a/_mh - Poisson's ratio - material coordinates - air density - _m plate density - - _r prescribed functions - _r sin(r z/a) - angular velocity - a/v₀ - skew-symmetric matrix form of the angular velocity     

Investigations of mean and turbulent flow characteristics of a two dimensional plane diffuser

This paper reports the investigation of mean and turbulent flow characteristics of a two-dimensional plane diffuser. Both experimental and theoretical details are considered. The experimental investigation consists of the measurement of mean velocity profiles, wall static pressure and turbulence stresses. Theoretical study involves the prediction of downstream velocity profiles and the distribution of turbulence kinetic energy using a well tested finite difference procedure. Two models, viz., Prandtl's mixing length hypothesis and k- model of turbulence, have been used and compared. The nondimensional static pressure distribution, the longitudinal pressure gradient, the pressure recovery coefficient, percentage recovery of static pressure, the variation of U _max/U _bar along the length of the diffuser and the blockage factor have been valuated from the predicted results and compared with the experimental data. Further, the predicted and the measured value of kinetic energy of turbulence have also been compared. It is seen that for the prediction of mean flow characteristics and to evaluate the performance of the diffuser, a simple turbulence model like Prandtl's mixing length hypothesis is quite adequate.List of symbols C ₁ , C ₂ ,C turbulence model constants - F _x body force - k kinetic energy of turbulence - l _m mixing length - L length of the diffuser - u, v, w rms value of the fluctuating velocity - u, v, w turbulent component of the velocity - mean velocity in the x direction - _A average velocity at inlet - U _bar average velocity in any cross section - U _max maximum velocity in any cross section - V mean velocity in the y direction - W local width of the diffuser at any cross section - x, y coordinates - dissipation rate of turbulence - _m eddy diffusivity - Von Karman constant - mixing length constant - _l laminar viscosity - _eff effective viscosity - v kinematic viscosity - density - _k effective Schmidt number for k - effective Schmidt number for - stream function - non dimensional stream function     

Dehnungsverhalten von Polyäthylen-Schmelzen

Zusammenfassung In einem Dehnungsrheometer werden Spannungs-Dehnungs-Diagramme von Polyäthylen-Schmelzen bei 150 °C und bei konstanter Dehnungsgeschwindigkeit gemessen ( zwischen 0,001 und 1 sec^–1). Weiterhin wird der reversible (elastische) Dehnungsanteil bestimmt. Messungen mit einem Dehnungstester für Kunststoff-Schmelzen ergänzen die Ausführungen.Die Ergebnisse zeigen deutlich, daß bei Dehnung mit zunehmender Verformungsgeschwindigkeit die Dehnungsviskosität nicht abnimmt, im Gegensatz zu dem bekannten strukturviskosen Verhalten bei Scherung.Bei Dehnungen bis zu=1 kann das Verhalten unabhängig von beschrieben werden, wenn als viskoelastische Materialfunktion die Dehnungs-Spannviskosität betrachtet wird. In diesem Bereich von gilt dabei die BeziehungT(t)=3 _s (t) mit _s (t) als zeitabhängige Scherviskosität im linear-viskoelastischen Bereich.Bei größeren Dehnungen und nicht zu kleinen Dehnungsgeschwindigkeiten zeigt verzweigtes Polyäthylen eine zusätzliche starke Spannungszunahme. In dem Bereich dieser zusätzlichen Verfestigung ist das Verhalten im wesentlichen eine Funktion der Dehnung und fast unabhängig von . Die zusätzliche Verfestigung scheint eine Folge der Verzweigungsstruktur des verzweigten Polyäthylens zu sein, da bei Linear-PE ein derartiger Verlauf des Spannungs-Dehnungs-Diagramms nicht beobachtet wird.Die Betrachtung des reversiblen Dehnungsanteils _R zeigt bei der ausführlich untersuchten Schmelze I (verzweigtes PE) drei verschiedene Bereiche: Unterhalb einer Grenzdehnungsgeschwindigkeit ist _R =0, unterhalb einer Versuchszeitt ^** ist _R =. Im dazwischenliegenden Bereich treten elastische und viskose Dehnungsanteile auf,= _R + _V , wobei für niedrige gilt, daß _R lg . Die Grenze wird der Frequenz der thermisch aktivierten Platzwechsel zugeordnet,t ^** erscheint als Zeit, innerhalb der die Verhakungen wie fixierte Vernetzungen wirken.In dem Anhang wird der Einfluß der Grenzflächenspannung zwischen PE-Schmelze und Silikonöl auf die Ergebnisse der Dehnungsversuche diskutiert.

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Summary Stress-strain relations for different PE melts are measured at 150 °C in an extensional rheometer under the condition of a constant extensional strain rate ( between 0,001 and 1 sec^–1). Further, the recoverable (elastic) portion _R of the total strain ( in Hencky's measure) is determined and additional measurements with a tensile tester for polymer melts are described.The results show clearly that in extension there is no decrease of the tensile viscosity with increasing deformation rate, in contrast to the well-known pseudoplastic behaviour in shear. Within total strains<1 the tensile behaviour can be described independently from by means of a viscoelastic material function called stressing viscosity . In this range of the relation _T (t)=3 _s (t) holds, where _s (t) is the stressing viscosity in shear in the linear viscoelastic range. For larger tensile strains and not too small branched PB shows a remarkable increase in stress. This work-hardening behaviour is mainly a function of and almost independent from . This additional hardening seems to be due to the branches in branched PE, because linear PE does not show this effect.The discussion of the recoverable tensile strain _R gives three regions of tensile rate: Below a critical there is _R =0. At times shorter thant ^** the equation _R = is valid. Within these limits both elastic and viscous portions of the total strain= _R + _V exist. may correlate with the frequency of the thermally activated position changes of the molecular segments.t ^** is assumed to be the time for the entanglements to act as fixed cross-links.In the appendix the influence of the interface tension between PE melt and silicone oil on the results of the tensile experiments is discussed.

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Vorgetragen auf der Deutschen Rheologen-Tagung, Berlin, 11.-13. Mai 1970.

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An der Weiterentwicklung des Dehnungsrheometers, an der Durchführung und Auswertung der Messungen waren die HerrenB. Kienle, F. Landmesser, M, Reuther undF. Scherr beteiligt. Herr Dr.F.Ramsteiner und HerrH. Schroeck haben sich um die Herstellung der Stränge aus Linear-PE bemüht. Herr Dr.W. Ball besorgte die GPC-Messungen und Herr Dr.P. Simak die Ultrarot-Untersuchung. Den vorgenannten Herren sei für ihre Hilfe beim Zustandekommen dieser Arbeit gedankt. Herrn Dr.H. Baur danke ich für wertvolle Diskussionen.     

Heteroclinic orbits in singular systems: A unifying approach

We consider singularly perturbed systems , such that=f(, _o, 0). _o ^m , has a heteroclinic orbitu(t). We construct a bifurcation functionG(, ) such that the singular system has a heteroclinic orbit if and only ifG(, )=0 has a solution=(). We also apply this result to recover some theorems that have been proved using different approaches.     

Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems

In this paper we continue the geometrical studies of computer generated two-phase systems that were presented in Part IV. In order to reduce the computational time associated with the previous three-dimensional studies, the calculations presented in this work are restricted to two dimensions. This allows us to explore more thoroughly the influence of the size of the averaging volume and to learn something about the use of anon-representative region in the determination of averaged quantities.

Nomenclature

Roman Letters A interfacial area of the– interface associated with the local closure problem, m² - a _i i=1, 2, gaussian probability distribution used to locate the position of particles - l unit tensor - characteristic length for the-phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1,2,3 lattice vectors, m - m convolution product weighting function - m _V special convolution product weighting function associated with a unit cell - n _i i=1, 2 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume,V, m³ - x position of the centroid of an averaging area, m - x ₀ reference position of the centroid of an averaging area, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters V /V, volume average porosity - _{a i} standard deviation ofa _i - _r standard deviation ofr - intrinsic phase average of      

Parameter determination for thermodynamical models of the pseudoelastic behaviour of shape memory alloy by resistivity measurements and infrared thermography

Two thermodynamical models of pseudoelastic behaviour of shape memory alloys have been formulated. The first corresponds to the ideal reversible case. The second takes into account the hysteresis loop characteristic of this shape memory alloys.Two totally independent techniques are used during a loading-unloading tensile test to determine the whole set of model parameters, namely resistivity and infrared thermography measurements. In the ideal case, there is no difficulty in identifying parameters.Infrared thermography measurements are well adapted for observing the phase transformation thermal effects.Notations 1 austenite 2 martensite - ₍₎ Macroscopic infinitesimal strain tensor of phase - ₍₂₎ ^f Traceless strain tensor associated with the formation of martensite phase - Macroscopic infiniesimal strain tensor - Macroscopic infinitesimal strain tensor deviator - _f Trace - Equivalent strain - ^pe Macroscopic pseudoelastic strain tensor - x Distortion due to parent (austenite =1)product (martensite =2) phase transformation (traceless symmetric second order tensor) - M Total mass of a system - M() Total mass of phase - V Total volume of a system - V() Total volume of phase - z=M(2)/M Weight fraction of martensite - 1-z=M(1)/M Weight fraction of austenite - u ₀ ^* () Specific internal energy of phase (=1,2) - s ₀ ^* () Specific internal entropy of phase - Specific configurational energy - Specific configurational entropy - ₀ ^f (T) Driving force for temperature-induced martensitic transformation at stress free state ( ₀ ^f T) = T ^*–Ts ^*) - Kirchhoff stress tensor - Kirchhoff stress tensor deviator - Equivalent stress - Cauchy stress tensor - Mass density - K Bulk moduli (K ₀=K) - L Elastic moduli tensor (order 4) - E Young modulus - Energetic shear (₀ = ) - Poisson coefficient - M _s ^o (M _F ^o ) Martensite start (finish) temperature at stress free state - A _s ^o (A _F ^o ) Austenite start (finish) temperature at stress free state - C _v Specific heat at constant volume - k Conductivity - Pseudoelastic strain obtained in tensile test after complete phase transformation (AM) (unidimensional test) - ₀ Thermal expansion tensor - r Resistivity - 1MPa 10⁶ N/m ² - ⁽⁾ Specific free energy of phase - _n Specific free energy at non equilibrium (R model) - _n ^eq Specific free energy at equilibrium (R model) - _n ^v Volumic part of ^eq - Specific free energy at non equilibrium (R _L model) - _conf Specific coherency energy (R _L model) - _c Specific free energy at constrained equilibria (R _L model) - _it (T) Coherency term (R _L model)     

Rayleigh problem in slip flow with transverse magnetic field

An analytical continuum solution of the Rayleigh problem in slip flow with applied magnetic field is obtained using a modified initial condition and slip boundary conditions. The results are uniformly valid for all times and show that the velocity slip and the local skin friction coefficient remain almost unaffected by the imposition of the magnetic field for small times. They increase however with the magnetic field for large times. The present results reduce to the corresponding results of the hydrodynamic case when there is no magnetic field.Nomenclature A constant - b characteristic length - B magnetic field vector - B ₀ magntidue of the applied magnetic field normale to the plate - B _x magnitude of the induced magnetic field parallel to the plate - C slip coefficient, (2–f)/f - C _f skin friction coefficient, - C _D average drag coefficient - erfc(_x) complementary error function, - E electric field vector - f Maxwell's reflection coefficient - H _a Hartmann number, (B ₀ ² b ²/)^1/2 - nondimensional magnetic parameter - J current vector - Kn=L/b Knudsen number - L mean free path - M Mach number - p constant parameter - P _m magnetic Prandtl number, Re _m/Re= ₀ - q velocity vector - Re Reynolds number, Ub/ - Re _m magnetic Reynolds number, ₀ Ub - t time - nondimensional time, tU/b - u velocity of the fluid parallel to the plate - nondimensional velocity, u/U - U velocity of the plate - Laplace transform of - x, y coordinates along and normal to the plate respectively - y nondimensional distance, y/b - Z nondimensional parameter, 1/Re ^1/2 Kn - ratio of specific heats - boundary layer thickness - velocity slip - viscosity - ₀ magnetic permeability - kinematic viscosity - nondimensional time parameter, ( /Re)^1/2/Kn - density - electrical conductivity     

Correlations between porous medium flow data and turbulent tube flow results for aqueous hydroxypropylguar solutions (Part 2)

Turbulent tube flow and the flow through a porous medium of aqueous hydroxypropylguar (HPG) solutions in concentrations from 100 wppm to 5000 wppm is investigated. Taking the rheological flow curves into account reveals that the effectiveness in turbulent tube flow and the efficiency for the flow through a porous medium both start at the same onset wall shear stress of 1.3 Pa. The similarity of the curves = ( _w ) and = ( _w ), respectively, leads to a simple linear relation / =k, where the constantk or proportionality depends uponc. This offers the possibility to deduce (for turbulent tube flow) from (for flow through a porous medium). In conjunction with rheological data, will reveal whether, and if yes to what extent, drag reduction will take place (even at high concentrations).The relation of our treatment to the model-based Deborah number concept is shown and a scale-up formula for the onset in turbulent tube flow is deduced as well.