High-resolution laser spectroscopy of CaNH2: Analysis of the C̃2A1-X̃2A1 system

Laser excitation spectra of the $\text{C}\text{?}{}^2\text{A}{}_1\text{-}\text{X}\text{?}{}^2\text{A}{}_1$ system of CaNH₂ are reported. Due to the spectral density, individual lines could only be resolved and measured using a filtered fluorescence excitation technique, with a monochromator acting as an optical bandpass filter; 140 line positions were measured in this way and assigned to the parallel K_?1 = 1 subband of what is believed to be the vibrational 0-0 band. The molecular constants were determined from a weighted nonlinear least-squares fit of the line positions.

     

2.

Thiocyclopentanone (cyclopentanethione): A vibrational analysis of the Ã1A2 ← X̃1A1 and ã3A2 ← X̃1A1 absorption systems     

《Journal of Molecular Spectroscopy》1987,122(2):371-380

     

3.

High-resolution photoelectron spectrum of the origin band of the X̃+ 2E ← X̃ 1A1 ionising transition of propyne     

U. Jacovella 《Molecular physics》2018,116(23-24):3602-3606

     

4.

The B̃2Σ−g (Πu) ← X̃2A1 system of nitrogen dioxide in neon matrices     

H.D. Bist  J.C.D. Brand  A.R. Hoy  V.T. Jones  R.J. Pirkle 《Journal of Molecular Spectroscopy》1977,66(3):411-420

The $\text{B}\text{?}\text{←}\text{X}\text{?}$ band system of NO₂, ${}^2\text{Σ}{}^{\mathrm{?}}{}_{\mathrm{g}}\text{(π}{}_{\mathrm{u}}\text{) ←}{}^2\text{A}{}_1$, has been measured in absorption in a neon matrix at 6 K, using ¹⁵NO₂ and N¹⁸O₂ in addition to the normal isotope. The spectrum consists essentially of a single, long progression of bands terminating on successive levels of the bending mode in the upper state. Transitions to odd- and even-v₂′ states occur with a uniform intensity distribution indicating that the rotation of the bent ground state of NO₂ about its near-prolate axis is hindered in the matrix. The observations strongly suggest that the top axis of the molecule coincides with a C₂ axis of neon crystals in the polycrystalline matrix. Relative to the vapor absorption the matrix spectrum is red shifted by about 150 cm^?1, the crystal field parameter V₂ and principal constants of the $\text{B}\text{?}$ state of ¹⁴N¹⁶O₂ in neon being

$\text{T}{}_{010}\text{14 571 cm}{}^{\mathrm{?1}}\text{: x}{}_{22}\text{, ?0.3 cm}{}^{\mathrm{?1}}\text{;}$

$\text{w}{}_2\text{460.2 cm}{}^{\mathrm{?1}}\text{: V}{}_2\text{, 80 cm}{}^{\mathrm{?1}}\text{.}$

     

5.

On the P-wave contributions to the cross sections of tt and t̃t̃ near threshold     

《Nuclear Physics B》1996,475(3):507-521

The approach used for the determination of S-wave amplitudes containing the application of the non-relativistic approximation in the case of P-waves leads to unphysical divergencies. We show how to avoid the latter in calculations of contributions to the cross section near threshold in agreement with field theory. This enables us to give quantitatively reliable predictions for the forward-backward asymmetry and for the axial contribution to the total cross section for the top-antitop system. Also the cross section for the production of stop-antistop near threshold is determined.     

6.

Simulation of the Ã2Σ+–X̃2Π absorption and emission spectra of the SiCCl radical     

Alexander O. Mitrushchenkov  Vincent Brites 《Molecular physics》2015,113(13-14):1695-1703

     

7.

Ã-X̃ laser excitation spectroscopy of BrClCS and Br2CS at room temperature and in cold supersonic jets     

《Journal of Molecular Spectroscopy》1987,126(2):307-328

     

8.

Potential of the A 1Σ u + state of He2     

Shaul Mukamel  Uzi Kaldor 《Molecular physics》2013,111(6):1107-1117

The potential of the lowest excited singlet state of He₂ is calculated. The best function includes 209 configurations constructed from 10 σ basis orbitals. Excellent agreement with experimental quantities depending on the shape of the potential near the minimum (equilibrium interatomic separation, vibrational and rotational constants for the lower vibration levels) is obtained. The dissociation energy is 18 600 cm^-1, compared to the experimental 19 910±50 cm^-1. Agreement is not as good for the highest vibrational levels.     

9.

A new study of the ν 2(A 1) infrared band of phosphorus trifluoride     

Hamid Najib  Hicham Msahal 《Molecular physics》2013,111(15):1953-1956

The high-resolution Fourier transform infrared spectrum of phosphorus trifluoride (PF₃) has been reinvestigated in the v_2?=?1 vibrational excited state near 487?cm^?1 (at a resolution of 3?×?10^–3?cm^–1). Thanks to our new accurate rotational ground-state C ₀ value, 0.159970436(69)?cm^–1, and to recent pure rotational measurements, 318 new infrared transitions of the ν ₂ fundamental band have been assigned, extending the rotational quantum number values up to K _max?=?71 and J _max?=?72. A merge, for the first time, of 135 reported microwave data (K _max?=?42 and J _max?=?49) within the v_2?=?1 excited level and 2860 rovibrational transitions yielded improved constants of ν ₂. Parameters of this band have been obtained, up to sextic centrifugal distortion constants, by least-squares fits, σ _IR?=?3.60?×?10^–4?cm^–1 and σ _MW?=?5.53?×?10^–6?cm^–1 (166?kHz). Comparison of these constants with those measured previously by infrared spectroscopy reveals orders of magnitude higher accuracy of these new values.     

10.

Construction of the HL-2A Tokamak     

LIUDequan ZHOUCaipin CAOZeng YANJiancheng LIUYong HL-ATeam 《核工业西南物理研究院年报(英文版)》2002,(1):6-7

HL-2A is the first tokamak with divertor in China. The objectives of HL-2A are to produce more adaptable divertor configurations to study energy exhaust and impurity control, and to study enhanced core plasma confinement by profile control and moderate plasma shaping. HL-2A has well optimized operational flexibility and excellent accessi-bility for the diagnostic systems to facilitate various plasma experiments.     

11.

Ab initio CI study of the vibrational structure of the 1 1Σ− (1 1 A″)←X and 1 1Δ (2 1 A′, 2 1 A″)←X electronic transitions in HCN and DCN     

M. Perić  R.J. Buenker  S.D. Peyerimhoff 《Molecular physics》2013,111(5):843-864

The results of an ab initio CI study of the vibrational/vibronic structure of the 1 ¹Σ^? (1 ¹ A″)←X and 1 ¹Δ (2 ¹ A′, 2 ¹ A″)←X electronic transitions in HCN and DCN are presented. Calculated band positions and intensity distributions within the band progressions are compared with corresponding experimental data. While the theoretical results for the 1A″←X transition reproduce well the structure of the observed A-X spectrum, they place doubt on the Bickel-Innes interpretation of the B-X band system in terms of transitions to the same excited electronic state but accompanied by excitation of a single quantum of the C?H stretching vibrational mode.     

12.

A scanning tunneling microscopy investigation of the 1 × 2 ⇌ 1 × 1 structural transformation of the pt(110) surface     

T. Gritsch  D. Coulman  R. J. Behm  G. Ertl 《Applied Physics A: Materials Science & Processing》1989,49(4):403-406

Lifting of the reconstruction of the clean Pt(110) surface under the influence of adsorbed CO proceeds at 300 K through homogeneous nucleation of small holes (with about 10 × 10 Ų size). At 350 K more correlated displacements of [110] strings take place, a characteristic shared with the reverse process, namely the restoration of the 1× 2 phase after desorption.     

13.

The magnetic circular dichroism spectrum of the 1 B 2u ←1 A 1g transition of benzene in the vapour phase     

I.N. Douglas  R. Grinter  A.J. Thomson 《Molecular physics》2013,111(5):1257-1266

The magnetic circular dichroism (MCD) spectrum of the ¹ B _2u ←¹ A _1g transition of benzene has been measured in the vapour phase. Many of the bands due to transitions between single vibronic levels display A terms. It has been shown that the angular momentum arises by vibronic mixing both of the ¹ E _1u state with the ¹ B _1u state and of the ¹ E _2g states with the ¹ A _1g ground state by e _2g vibrations. The magnitudes and signs of the experimental and calculated ratios, A/D, for the A ₀ ⁰ vibronic origin are in excellent agreement. Two strong MCD progressions of opposite sign with B-term dispersion have been observed in regions of low absorption. These are identified with vibronic origins due to the v ₈ and v ₉ e _2g modes. By contrast the MCD spectrum of hexadeuterobenzene vapour has a much lower magneto-rotational strength and displays none of the striking features of the benzene MCD spectrum.     

14.

The high-resolution spectrum of the ν1 + ν2 band of NO2: A spin-induced perturbation in the ground state     

《Journal of Molecular Spectroscopy》1987,125(1):99-114

The spectrum of the ν₁ + ν₂ band of NO₂ has been studied with a resolution of 0.025 cm⁻¹. Spin-rotation constants and rotational constants are reported. An interesting perturbation has been found in the ground state of the molecule which occurs when the K_a = 0 and K_a = 2 levels become accidentally nearly degenerate around N = 42. An explanation of this interaction is presented.     

15.

A theoretical study on the mechanisms of the N2(X1 ) + O+(4Su) reaction involving the 14A″ and X2Π states of the N2O+ ion and the predissociation of the X2Π state     

Hai-Bo Chang  Qingyong Meng  Hua Dong 《Molecular physics》2013,111(16):2137-2145

     

16.

Control of LHCD on the HL-2A Tokamak     

WANG Mingwei LI Bo FENG Kun RAO Jun KANG Zihua LI Xiujuan LILi WANG Minghong FAN Mingjie 《核工业西南物理研究院年报(英文版)》2004,(1):77-79

in order to study non-indutive plasma current production, the lower hybrid current drive（LHCD） experiment on the HL-2A tokamak is carried out. Simultaneously a microcomputer has been used to control the whole LHCD system. During the experiment this year, we can monitor and protect the LHCD system by use of the microcomputer control system, which will imediately switch off the microwave power to be launched into the tokamak if the plasma is disrupted. All this ensure that the microwave is injected into the equipment correctly.     

17.

Status and Plan of the HL-2A Project     

YANJianeheng ZHOUCaipin LIUYong LIUDequan HL-ATeam 《核工业西南物理研究院年报(英文版)》2001,(1):1-7

HL-2A is a new divertor tokamak under construction at Southwestern Institute of Physics (SWIP), Chengdu, China, based on the experience from HL-1 and HL-1M. HL is the short term of a Chinese word that means “ Toroidal Current Device“ . The main objectives of HL-2A are to produce more adaptable divertor configurations to study energy exhaust and impurity control(the first divertor tokamak plasma in China), and to study enhanced plasma confinement by profile control and moderate plasma shaping.     

18.

Nonlinear Shift of the Raman A1 Mode in Ga-Incorporated CuInSe2 Thin Films          下载免费PDF全文

徐传明孙云  李凤岩张力 薛玉明何青  刘洪图 《中国物理快报》2006,23(4):1002-1004

Composition dependence of quaternary CuIn1-x GaxSe2 films on Ga content has been systematically investigated by Raman scattering. The dominant A1 mode shifts from 174cm^-1 for CuInSe2 to 185cm^-1 for CuGaSe2 in an approximately polynomial curve other than a linear curve, indicating existence of asymmetric distribution of Ga and In on a microscopic scale in films. With Ga content x 〉 0.3, the significantly broadening and intensity decrease of A1 modes suggest the degradation of crystalline quality of chalcopyrite phase. Additionally, the quenching of additional Raman band at 183cm^-1 for the Ga-rich films reveals that CuAu-ordered phase can coexist in nominal chalcopyrite CuInSe2 films but not in CuGaSe2, due to Ga inhibition effect.     

19.

Analysis of the High-Resolution Infrared Spectrum of the PHD2 Molecule: ν1 and 2ν1 Bands     

Onopenko  G. A. 《Russian Physics Journal》2002,45(4):341-345

The results of investigation into the infrared spectra of the PHD₂ molecule including the ₁ fundamental band centered at 2324.005 cm^–1 (with a resolution of 4.2·10^–3 cm^–1) and the first 2₁ valence overtone centered at 4563.634 cm^–1 (with a resolution of 8.8·10^–3 cm^–1) are given in the present paper. Based on an analysis of the results obtained, 1340 and 1020 lines are referred to the ₁ and 2₁ bands, respectively. This data are used to calculate 316 and 248 vibrational-rotational energies of the (100000) and (200000) excited vibrational states, respectively. Since both bands can be considered as isolated, we take advantage of the Watson Hamiltonian (the reduction A in the I ^r representation) to describe their rotational structure. The calculated spectroscopic parameters of the examined states of the PHD₂ molecule correlate well with each other and with the corresponding parameters of the ground vibrational state.     

20.

The Introduction to the ECRH System of the HL-2A Tokamak     

RAO Jun KANG Zhihua ZHOU Jun WANG Mingwei LU Zhihong LI Xiujuan 《核工业西南物理研究院年报(英文版)》2004,(1):58-61

The 1 MW/68 GHz/1 s ECRH system of HL-2A device is being designed or fabricated. The O mode wave beams are injected into plasma from low field side of the HL-2A tokomak. Because the EC wave can heat plasma locally, it is a very versatile scheme which has been employed to heating, current drive, profile control, confinement improvement. Up to now, the basic physical and engineering parameters of the whole system have been fixed and the subsystems are being designed or fabricated.     

		Main parameters
	$\text{X}\text{?}{}^2\text{A}{}_1$	$\text{C}\text{?}{}^2\text{A}{}_1$
$\text{T}{}_{\mathrm{k?1}}\text{= 1}$	3-	17375.129(5)
B	0.30079(6)	0.30562(6)
C	0.29319(6)	0.29789(8)
$\text{?}{}_{\mathrm{aa}}$	3-	?0.66(4)
$\text{?}{}_{\mathrm{bb}}$	3-	?0.0356(8)
$\text{?}{}_{\mathrm{cc}}$	3-	?0.0453(8)

The B̃2Σ−g (Πu) ← X̃2A1 system of nitrogen dioxide in neon matrices

The $\text{B}\text{?}\text{←}\text{X}\text{?}$ band system of NO₂, ${}^2\text{Σ}{}^{\mathrm{?}}{}_{\mathrm{g}}\text{(π}{}_{\mathrm{u}}\text{) ←}{}^2\text{A}{}_1$, has been measured in absorption in a neon matrix at 6 K, using ¹⁵NO₂ and N¹⁸O₂ in addition to the normal isotope. The spectrum consists essentially of a single, long progression of bands terminating on successive levels of the bending mode in the upper state. Transitions to odd- and even-v₂′ states occur with a uniform intensity distribution indicating that the rotation of the bent ground state of NO₂ about its near-prolate axis is hindered in the matrix. The observations strongly suggest that the top axis of the molecule coincides with a C₂ axis of neon crystals in the polycrystalline matrix. Relative to the vapor absorption the matrix spectrum is red shifted by about 150 cm^?1, the crystal field parameter V₂ and principal constants of the $\text{B}\text{?}$ state of ¹⁴N¹⁶O₂ in neon being

$\text{T}{}_{010}\text{14 571 cm}{}^{\mathrm{?1}}\text{: x}{}_{22}\text{, ?0.3 cm}{}^{\mathrm{?1}}\text{;}$

$\text{w}{}_2\text{460.2 cm}{}^{\mathrm{?1}}\text{: V}{}_2\text{, 80 cm}{}^{\mathrm{?1}}\text{.}$

     

On the P-wave contributions to the cross sections of tt and t̃t̃ near threshold

The approach used for the determination of S-wave amplitudes containing the application of the non-relativistic approximation in the case of P-waves leads to unphysical divergencies. We show how to avoid the latter in calculations of contributions to the cross section near threshold in agreement with field theory. This enables us to give quantitatively reliable predictions for the forward-backward asymmetry and for the axial contribution to the total cross section for the top-antitop system. Also the cross section for the production of stop-antistop near threshold is determined.     

Potential of the A 1Σ u + state of He2

The potential of the lowest excited singlet state of He₂ is calculated. The best function includes 209 configurations constructed from 10 σ basis orbitals. Excellent agreement with experimental quantities depending on the shape of the potential near the minimum (equilibrium interatomic separation, vibrational and rotational constants for the lower vibration levels) is obtained. The dissociation energy is 18 600 cm^-1, compared to the experimental 19 910±50 cm^-1. Agreement is not as good for the highest vibrational levels.     

A new study of the ν 2(A 1) infrared band of phosphorus trifluoride

The high-resolution Fourier transform infrared spectrum of phosphorus trifluoride (PF₃) has been reinvestigated in the v_2?=?1 vibrational excited state near 487?cm^?1 (at a resolution of 3?×?10^–3?cm^–1). Thanks to our new accurate rotational ground-state C ₀ value, 0.159970436(69)?cm^–1, and to recent pure rotational measurements, 318 new infrared transitions of the ν ₂ fundamental band have been assigned, extending the rotational quantum number values up to K _max?=?71 and J _max?=?72. A merge, for the first time, of 135 reported microwave data (K _max?=?42 and J _max?=?49) within the v_2?=?1 excited level and 2860 rovibrational transitions yielded improved constants of ν ₂. Parameters of this band have been obtained, up to sextic centrifugal distortion constants, by least-squares fits, σ _IR?=?3.60?×?10^–4?cm^–1 and σ _MW?=?5.53?×?10^–6?cm^–1 (166?kHz). Comparison of these constants with those measured previously by infrared spectroscopy reveals orders of magnitude higher accuracy of these new values.     

Construction of the HL-2A Tokamak

HL-2A is the first tokamak with divertor in China. The objectives of HL-2A are to produce more adaptable divertor configurations to study energy exhaust and impurity control, and to study enhanced core plasma confinement by profile control and moderate plasma shaping. HL-2A has well optimized operational flexibility and excellent accessi-bility for the diagnostic systems to facilitate various plasma experiments.     

Ab initio CI study of the vibrational structure of the 1 1Σ− (1 1 A″)←X and 1 1Δ (2 1 A′, 2 1 A″)←X electronic transitions in HCN and DCN

The results of an ab initio CI study of the vibrational/vibronic structure of the 1 ¹Σ^? (1 ¹ A″)←X and 1 ¹Δ (2 ¹ A′, 2 ¹ A″)←X electronic transitions in HCN and DCN are presented. Calculated band positions and intensity distributions within the band progressions are compared with corresponding experimental data. While the theoretical results for the 1A″←X transition reproduce well the structure of the observed A-X spectrum, they place doubt on the Bickel-Innes interpretation of the B-X band system in terms of transitions to the same excited electronic state but accompanied by excitation of a single quantum of the C?H stretching vibrational mode.     

A scanning tunneling microscopy investigation of the 1 × 2 ⇌ 1 × 1 structural transformation of the pt(110) surface

Lifting of the reconstruction of the clean Pt(110) surface under the influence of adsorbed CO proceeds at 300 K through homogeneous nucleation of small holes (with about 10 × 10 Ų size). At 350 K more correlated displacements of [110] strings take place, a characteristic shared with the reverse process, namely the restoration of the 1× 2 phase after desorption.     

The magnetic circular dichroism spectrum of the 1 B 2u ←1 A 1g transition of benzene in the vapour phase

The magnetic circular dichroism (MCD) spectrum of the ¹ B _2u ←¹ A _1g transition of benzene has been measured in the vapour phase. Many of the bands due to transitions between single vibronic levels display A terms. It has been shown that the angular momentum arises by vibronic mixing both of the ¹ E _1u state with the ¹ B _1u state and of the ¹ E _2g states with the ¹ A _1g ground state by e _2g vibrations. The magnitudes and signs of the experimental and calculated ratios, A/D, for the A ₀ ⁰ vibronic origin are in excellent agreement. Two strong MCD progressions of opposite sign with B-term dispersion have been observed in regions of low absorption. These are identified with vibronic origins due to the v ₈ and v ₉ e _2g modes. By contrast the MCD spectrum of hexadeuterobenzene vapour has a much lower magneto-rotational strength and displays none of the striking features of the benzene MCD spectrum.     

The high-resolution spectrum of the ν1 + ν2 band of NO2: A spin-induced perturbation in the ground state

The spectrum of the ν₁ + ν₂ band of NO₂ has been studied with a resolution of 0.025 cm⁻¹. Spin-rotation constants and rotational constants are reported. An interesting perturbation has been found in the ground state of the molecule which occurs when the K_a = 0 and K_a = 2 levels become accidentally nearly degenerate around N = 42. An explanation of this interaction is presented.     

Control of LHCD on the HL-2A Tokamak

in order to study non-indutive plasma current production, the lower hybrid current drive（LHCD） experiment on the HL-2A tokamak is carried out. Simultaneously a microcomputer has been used to control the whole LHCD system. During the experiment this year, we can monitor and protect the LHCD system by use of the microcomputer control system, which will imediately switch off the microwave power to be launched into the tokamak if the plasma is disrupted. All this ensure that the microwave is injected into the equipment correctly.     

Status and Plan of the HL-2A Project

HL-2A is a new divertor tokamak under construction at Southwestern Institute of Physics (SWIP), Chengdu, China, based on the experience from HL-1 and HL-1M. HL is the short term of a Chinese word that means “ Toroidal Current Device“ . The main objectives of HL-2A are to produce more adaptable divertor configurations to study energy exhaust and impurity control(the first divertor tokamak plasma in China), and to study enhanced plasma confinement by profile control and moderate plasma shaping.     

Nonlinear Shift of the Raman A1 Mode in Ga-Incorporated CuInSe2 Thin Films

Composition dependence of quaternary CuIn1-x GaxSe2 films on Ga content has been systematically investigated by Raman scattering. The dominant A1 mode shifts from 174cm^-1 for CuInSe2 to 185cm^-1 for CuGaSe2 in an approximately polynomial curve other than a linear curve, indicating existence of asymmetric distribution of Ga and In on a microscopic scale in films. With Ga content x 〉 0.3, the significantly broadening and intensity decrease of A1 modes suggest the degradation of crystalline quality of chalcopyrite phase. Additionally, the quenching of additional Raman band at 183cm^-1 for the Ga-rich films reveals that CuAu-ordered phase can coexist in nominal chalcopyrite CuInSe2 films but not in CuGaSe2, due to Ga inhibition effect.     

Analysis of the High-Resolution Infrared Spectrum of the PHD2 Molecule: ν1 and 2ν1 Bands

The results of investigation into the infrared spectra of the PHD₂ molecule including the ₁ fundamental band centered at 2324.005 cm^–1 (with a resolution of 4.2·10^–3 cm^–1) and the first 2₁ valence overtone centered at 4563.634 cm^–1 (with a resolution of 8.8·10^–3 cm^–1) are given in the present paper. Based on an analysis of the results obtained, 1340 and 1020 lines are referred to the ₁ and 2₁ bands, respectively. This data are used to calculate 316 and 248 vibrational-rotational energies of the (100000) and (200000) excited vibrational states, respectively. Since both bands can be considered as isolated, we take advantage of the Watson Hamiltonian (the reduction A in the I ^r representation) to describe their rotational structure. The calculated spectroscopic parameters of the examined states of the PHD₂ molecule correlate well with each other and with the corresponding parameters of the ground vibrational state.     

The Introduction to the ECRH System of the HL-2A Tokamak

The 1 MW/68 GHz/1 s ECRH system of HL-2A device is being designed or fabricated. The O mode wave beams are injected into plasma from low field side of the HL-2A tokomak. Because the EC wave can heat plasma locally, it is a very versatile scheme which has been employed to heating, current drive, profile control, confinement improvement. Up to now, the basic physical and engineering parameters of the whole system have been fixed and the subsystems are being designed or fabricated.