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β-Aminocrotonic esters are of great importance as stabilizers for the production of clearly transparent food packaging of PVC. For the purpose of studying the migration into foods a thin-layer Chromatographic and a polarographic method were elaborated. The TLC method consists of the visual comparison of the intensity of the spots after treatment with Fast Blue B salt. The polarographic determination is carried out after nitrosation of the stabilizer. By the TLC method 10?7 g of ester per spot are still detectable; the concentration which is still determinable by cathode-ray polarography is 5×10?7 g of ester and by conventional d.c. polarography 5×10?6g of ester per ml of final solution. After extraction with acetonitrile traces of the stabilizer which are migrated into edible oil are still determinable down to 2 ppm by the methods described.  相似文献   

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