多壁碳纳米管对p型Ba0.3FeCo3Sb12化合物热电性能的影响

用两步固相反应法合成了P型Ba填充方钴矿化合物Ba0.3FeCo3Sb12，并采用放电等离子烧结法(SPS)制备了Ba0.3FeCo3Sb12／多壁碳纳米管复合材料．研究了Ba0.3FeCo3Sb12／多壁碳纳米管复合材料的结构及多壁碳纳米管对其热电性能的影响规律：SEM分析表明多壁碳纳米管比较均匀地分布在Ba0.3FeCo3Sb12基体中；随着碳纳米管添加量的增加，Ba0.3FeCo3Sb12／多壁碳纳米管复合材料的电导率下降、塞贝克系数略微下降、晶格热导率大幅度降低，当碳纳米管含量为5％时其晶格热导率最小；当碳纳米管的含量为3％时，本研究得到的Ba0.3FeCo3Sb12／碳纳米管复合材料的最大ZT值达0．78．     

金/多壁碳纳米管复合材料的合成及其三阶非线性光学性质

通过化学吸附法制备了金/多壁碳纳米管复合材料.采用X射线衍射仪、透射电子显微镜和紫外可见光谱仪对复合材料进行表征,制备的金纳米颗粒平均粒径为6nm,且均匀分散在碳纳米管表面.在脉冲宽度为30ps、波长为532nm的激光光源激发下,运用Z扫描技术分别研究金/多壁碳纳米管复合材料和多壁碳纳米管的三阶非线性光学性质.实验结果表明:金/多壁碳纳米管复合材料呈现正的非线性折射效应和饱和吸收性质,其三阶非线性极化率χ(3)为1.89×10-12 esu,比多壁碳纳米管高2.6倍.     

多壁碳纳米管对p型Ba0.3FeCo3Sb12化合物热电性能的影响

用两步固相反应法合成了p型Ba填充方钴矿化合物Ba^0.3FeCo³S b^１2，并采用放电等离子烧结法(SPS)制备了Ba^0.3FeCo³Sb^１2／多壁碳纳米管复合材料. 研究了Ba^0.3FeCo³Sb^１2／多壁碳纳米管复合 材料的结构及多壁碳纳米管对 其热电性能的影响规律：SEM分析表明多壁碳纳米管比较均匀地分布在Ba^0.3 FeCo³S b^１2基体中；随着碳纳米管添加量的增加，Ba^0.3FeCo3Sb^１2/多壁碳 纳米管复合材料的电导率下降、塞贝克系数略微下降、晶格热导率大幅度降低，当碳纳米管 含量为5％时其晶格热导率最小；当碳纳米管的含量为3％时，本研究得到的Ba^{0.3FeCo3Sb１2/碳纳米管复合材料的最大ZT值达078.}     

石蜡-碳纳米管复合材料的热物性研究

为提高石蜡作为相变蓄冷材料的导热性能,制备了碳纳米管添加量分别为0%、1%、2%、3%、4%、5%的石蜡-碳纳米管复合材料,并对其热物性及稳定性进行实验研究。结果表明,随着碳纳米管添加量的增加,复合材料的相变温度基本不变,相变潜热逐渐减小,导热系数逐渐增大。在添加量为5%时,复合材料的融化和凝固相变潜热分别为128.2 J/g和134.4 J/g,比纯石蜡相对减小了15.5%和13.8%;固态和液态导热系数分别为0.487 W/(m·K)和0.516 W/(m·K),比纯石蜡相对提高了39.5%和40.3%,同时具有较好的循环稳定性。     

低浓度高热导率的石墨烯/树脂复合物及其应用

当多个LED密集排列组成大功率照明系统时,散热问题成为影响LED灯发光性能的主要技术瓶颈之一,因此解决散热问题已成为功率型LED应用的先决条件。本文将功能化石墨烯与硅树脂复合制备出了低填充量高导热性能的石墨烯/硅树脂复合材料。石墨烯(Graphene)填充质量分数为0.015时,复合材料的热导率高达2.758 W/(m.K),比纯硅脂基体提高了13倍;添加石墨烯后明显改善了硅树脂的热稳定性。将该复合材料作为热界面材料应用于大功率LED芯片模组基板与灯具冷却外壳之间的散热,能获得很好的增强效果,结果表明石墨烯填充质量分数仅为0.008时,基板与外壳之间的温度差可达到小于5℃,满足大功率LED灯具的散热要求。     

搅拌法制备聚合物微球中油水相对壁厚的影响

为了研究乳液微封装技术中油水相对微球壁厚的影响,推导了在理想状态下微球壁厚、油相质量分数和油水相比这三者之间的函数关系。结果表明:当内相水滴半径和油相质量分数为常数时,微球壁厚是油水相比的单增函数;而当内相水滴半径和油水相比为常数时,微球壁厚是油相质量分数的单增函数。即提高油相质量分数或增大油水相比对增加壁厚而言具有等效性。根据此规律,在搅拌法制备小直径聚苯乙烯微球中,通过调整油水相的各参数,确定了制备小直径厚壁聚苯乙烯微球的关键工艺参数。实验表明:采用搅拌法制备10~25 m壁厚的小直径聚苯乙烯微球时,油相质量分数宜配制为5.3%~7.0%,油水相比宜控制在1.6~2.2之间,而外水相中聚乙烯醇质量分数宜控制在1%~3%之内。     

搅拌法制备聚合物微球中油水相对壁厚的影响

为了研究乳液微封装技术中油水相对微球壁厚的影响,推导了在理想状态下微球壁厚、油相质量分数和油水相比这三者之间的函数关系。结果表明：当内相水滴半径和油相质量分数为常数时,微球壁厚是油水相比的单增函数;而当内相水滴半径和油水相比为常数时,微球壁厚是油相质量分数的单增函数。即提高油相质量分数或增大油水相比对增加壁厚而言具有等效性。根据此规律,在搅拌法制备小直径聚苯乙烯微球中,通过调整油水相的各参数,确定了制备小直径厚壁聚苯乙烯微球的关键工艺参数。实验表明:采用搅拌法制备10~25 m壁厚的小直径聚苯乙烯微球时,油相质量分数宜配制为5.3%~7.0%,油水相比宜控制在1.6~2.2之间,而外水相中聚乙烯醇质量分数宜控制在1%~3%之内。     

聚(2-甲氧基-5-辛氧基)对苯乙炔/单壁碳纳米管复合材料的光致发光特性

采用原位聚合法在无水四氢呋喃(THF)溶液中制备了聚(2-甲氧基-5-辛氧基)对苯乙炔(MOPPV)/单壁碳纳米管(SWNTs)复合材料。通过对该复合材料的红外光谱、X射线衍射、透射电镜、扫描电镜等的研究,证实SWNTs已聚合到MOPPV上且被MOPPV紧密有效地包覆,形成了纳米线网状结构。通过紫外-可见(UV-Vis)吸收光谱和光致发光(PL)谱发现:随着SWNTs掺杂量的增加,该复合材料的吸收强度逐渐增强且最大吸收峰出现红移,其发光强度呈现先升高后降低的趋势,发光峰蓝移。当SWNTs掺杂质量分数为3.85%时,复合材料的发光强度最大,此时最大发光峰位较纯MOPPV蓝移8 nm。研究结果表明:在MOPPV中掺入一定量的SWNTs,能有效地增强复合材料的光致发光强度。     

不同应变率和碳纳米管掺量下混凝土的力学性质与能量演化特征

为研究应变率(加载速率)和多壁碳纳米管掺量对碳纳米管混凝土试样力学性质、能量演化规律及损伤破坏特征的影响,采用RMT-150B岩石力学试验系统,对不同应变率下不同碳纳米管掺量的混凝土试样开展了系列单轴压缩试验。试验结果表明：碳纳米管混凝土试样的延性随着多壁碳纳米管掺量的增加而增大;当应变率恒定时,多壁碳纳米管掺量为0.1%的改性碳纳米管混凝土的单轴抗压强度最大;当多壁碳纳米管掺量恒定时,应变率为5×10^-3 s^-1(0.5 mm/s)时碳纳米管混凝土试样的单轴抗压强度最大;当应变率较大时,在试样峰值应力处,碳纳米管混凝土的能量耗散值占总能量的28.29%;当应变率较小时,试样峰前阶段的能量耗散现象显著,峰值应力处耗散能占比平均高达37.34%;当应变率和多壁碳纳米管掺量均较小时,碳纳米管混凝土在破坏前所吸收的能量大量转化为耗散能,峰后试样能量释放率较小,表现为局部张拉与剪切混合破坏特征;当应变率和多壁碳纳米管掺量均较大时,碳纳米管混凝土在破坏前所吸收的能量主要储存为可释放弹性应变能,在破坏时混凝土试样的能量释放速率较高,碳纳米管混凝土试样破坏...     

低浓度氧化石墨烯改性环氧树脂基碳纤维层合板的拉伸性能

将氧化石墨烯(GO)均匀分散到环氧树脂(EP)中,采用真空辅助树脂传递模塑成型的工艺方法制备增强碳纤维(CF)复合材料,研究常温下不同浓度(质量分数为0、0.03%、0.07%和0.10%)GO改性EP/CF层合板的抗拉性能和微观胶联性能,探究低浓度GO对CF增强复合材料力学性能明显改善的阈值。实验结果表明:GO对CF增强环氧复合材料的性能有明显改善作用,与纯环氧基CF层合板相比,随着GO浓度增加,其抗拉性能随之增强;GO官能团可以提高EP基体与CF的结合程度,通过扫描电镜观察到加入GO的层合板中CF与EP的黏结更加紧密,使得啮合效果更强,从而提高了复合材料层合板的拉伸强度;低浓度GO改性下,当GO的质量分数达到0.07%时,层合板的力学性能得到明显改善。     

Guided-Wave Two-Dimensional Acousto-Optic Scanner Using Proton-Exchanged Lithium Niobate Waveguide

Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.     

Hybrid Wavelength and Code Division Multiple Access in Optical Networks

A review of schemes for multiple access in fiber optic networks shows that a hybrid of wavelength and code division multiple access (WCDMA) combines the best features of both. In particular, the hybrid scheme retains the large information carrying capacity of wavelength division multiple access (WDMA) and flexibility of code division multiple access (CDMA). In this paper WDMA, optical CDMA (OCDMA), and WCDMA networks are discussed. In OCDMA networks, concept of incoherent and coherent coding including inverse decoding and matched filter is introduced. The delay performance of both WDMA and WCDMA networks, under the simple suboptimum access protocols based on cyclic search, is computed. It has been shown quantitatively that tuning delay significantly affects the delay performance of both WDMA and WCDMA networks. Futhermore, delay performance of WCDMA networks is always better than the WDMA networks for the same tuning delay, load, and number of users.     

Effect ofγ-radiation on the spectral luminescence characteristics of impure cadmium tungstate crystals

Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation (5.5·10⁴ Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure crystals is analyzed (preliminarily). Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997.     

Femtosecond Transform-Limited Pulse Generation by Compensating for the Linear Chirp of SPM Spectra in Dispersion Shifted Fibers

A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output.     

Sorting of bending magnets for the SSRF booster

The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper.     

Measurement of nonlinear coefficient of optical fiber based on small chirped soliton transmission

We measure the waveform and phase curves of short optical pulses before and after transmission over different lengths of fibers by use of the pulse analyzer with the frequency-resolved optical gating (FROG),and numerically simulate pulse evolution under the experimental conditions.The nonlinear coefficient of the fiber is given by comparing the experimental results with the numerical ones.Difference between the experiment and numerical simulation is analyzed.     

Resonance scattering of canonical elastic shells in absorbing fluid medium

Resonance scattering of elastic spherical shell and cylindrical shell while the surrounding fluid medium has absorption is studied. The normal mode solution derived using exact elastic theory and the separation of variables is still applicable. However, the scattering form function has to be modified for the absorbing medium, otherwise the unreasonable result would be obtained. The backscattering form function in the absorbing medium is redefined, and the form function of elastic spherical and cylindrical shell with vacuum or solid matter filled is calculated in various absorption conditions. The results show that the absorption of surrounding fluid leads to notable attenuation of the coincidence resonances in the mid-frequency, but it has a little influence on the low-frequency resonance scattering induced by the filler inside the shell.     

Single-beam self-referenced phase-sensitive surface plasmon resonance sensor with high detection resolution

A versatile and low-cost single-beam self-referenced phase-sensitive surface plasmon resonance(SPR)sensing system with ultra-high resolution performance is presented.The system exhibits a root-mean-square phase fluctuation of ±0.0028.over a period of 45 min.i.e.a resolution of±5.2×10-9 refractive index units.The enhanced performance has been achieved through the incorporation of three design elements:a true single-beam configuration enabling complete self-referencing so that only the phase change associated with SPR gets detected,a differential measurement scheme to eliminate spurious signals not related to the sensor response,and the elimination of retardation drifts by incorporating temperature stabilization in the liquid crystal phase modulato .Our design should bring the detection sensitivity of non-labeling SPR biosensing closer to that achievable by conventional fluorescence-based techniques.     

Influences of SiO2 protective layers and annealing on the laser-induced damage threshold of Ta2O5 films

Ta2O5 films are prepared on BK7 substrates with conventional electron beam evaporation deposition.The effects of SiO2 protective layers and annealing on the laser-induced damage threshold (LIDT) of the films are investigated.The results show that SiO2 protective layers exert little influence on the electric field intensity(EFI)distribution,microstructure and microdefect density but increase the absorption slightly.Annealing iS effective on decreasing the microdefect density and the absorption of the films.Both SiO2 protective layers and annealing are beneficial to the damage resistance of the films and the latter is more effective to improve the LIDT.Moreover,the maximal LIDT of Ta2O5 films is achieved by the combination of SiO2 protective layers and annealing.