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对于自由粒子在有限容器中的能态密度,热力学统计教材一般根据半经典量子图像,由驻波条件和德布罗意关系,以动量分立值为基础出发得到;然而根据量子理论,无限深势阱中的粒子存在能量本征态,而非动量本征态.本文以能量本征态为统计对象推导了有限体积中的自由粒子的能态密度,结果与教材一致.但是我们的处理方式显得更为自然.  相似文献   

3.
In contrast to the canonical ensemble where thermodynamic functions are smooth for all finite system sizes, the microcanonical entropy can show nonanalytic points also for finite systems. The relation between finite and infinite system nonanalyticities is illustrated by means of a simple classical spinlike model which is exactly solvable for both finite and infinite system sizes, showing a phase transition in the latter case. The microcanonical entropy is found to have exactly one nonanalytic point in the interior of its domain. For all finite system sizes, this point is located at the same fixed energy value epsilon(c)(finite), jumping discontinuously to a different value epsilon(c)(infinite) in the thermodynamic limit. Remarkably, epsilon(c)(finite) equals the average potential energy of the infinite system at the phase transition point. The result indicates that care is required when trying to infer infinite system properties from finite system nonanalyticities.  相似文献   

4.
The von Neumann entropy cannot represent the thermodynamic entropy of equilibrium pure states in isolated quantum systems. The diagonal entropy, which is the Shannon entropy in the energy eigenbasis at each instant of time, is a natural generalization of the von Neumann entropy and applicable to equilibrium pure states. We show that the diagonal entropy is consistent with the second law of thermodynamics upon arbitrary external unitary operations. In terms of the diagonal entropy, thermodynamic irreversibility follows from the facts that quantum trajectories under unitary evolution are restricted by the Hamiltonian dynamics and that the external operation is performed without reference to the microscopic state of the system.  相似文献   

5.
The quantum Brownian motion model is a typical model in the study of nonequilibrium quantum thermodynamics. Entropy is one of the most fundamental physical concepts in thermodynamics.In this work, by solving the quantum Langevin equation, we study the von Neumann entropy of a particle undergoing quantum Brownian motion. We obtain the analytical expression of the time evolution of the Wigner function in terms of the initial Wigner function. The result is applied to the thermodynamic equilibrium initial state, which reproduces its classical counterpart in the high temperature limit. Based on these results, for those initial states having well-defined classical counterparts, we obtain the explicit expression of the quantum corrections to the entropy in the weak coupling limit. Moreover, we find that for the thermodynamic equilibrium initial state, all terms odd in h are exactly zero. Our results bring important insights to the understanding of entropy in open quantum systems.  相似文献   

6.
梁建武  程资  石金晶  郭迎 《物理学报》2016,65(16):160301-160301
本文基于量子图态的几何结构特征,利用生成矩阵分割法,提出了一种量子秘密共享方案.利用量子图态基本物理性质中的稳定子实现信息转移的模式、秘密信息的可扩展性以及新型的组恢复协议,为安全的秘密共享协议提供了多重保障.更重要的是,方案针对生成矩阵的循环周期问题和因某些元素不存在本原元而不能构造生成矩阵的问题提出了有效的解决方案.在该方案中,利用经典信息与量子信息的对应关系提取经典信息,分发者根据矩阵分割理论获得子秘密集,然后将子秘密通过酉操作编码到量子图态中,并分发给参与者,最后依据该文提出的组恢复协议及图态相关理论得到秘密信息.理论分析表明,该方案具有较好的安全性及信息的可扩展性,适用于量子网络通信中的秘密共享,保护秘密数据并防止泄露.  相似文献   

7.
Motivated by a recent use of Glauber dynamics for Monte Carlo simulations of path integral representation of quantum spin models (Krzakala et al. in Phys. Rev. B 78(13):134428, 2008), we analyse a natural Glauber dynamics for the quantum Ising model with a transverse field on a finite graph G. We establish strict monotonicity properties of the equilibrium distribution and we extend (and improve) the censoring inequality of Peres and Winkler to the quantum setting. Then we consider the case when G is a regular b-ary tree and prove the same fast mixing results established in Martinelli et al. (Commun. Math. Phys. 250(2):301–334, 2004) for the classical Ising model. Our main tool is an inductive relation between conditional marginals (known as the “cavity equation”) together with sharp bounds on the operator norm of the derivative at the stable fixed point. It is here that the main difference between the quantum and the classical case appear, as the cavity equation is formulated here in an infinite dimensional vector space, whereas in the classical case marginals belong to a one-dimensional space.  相似文献   

8.
In the one-dimensional Anderson model the eigenstates are localized for arbitrarily small amounts of disorder. In contrast, the Aubry-André model with its quasiperiodic potential shows a transition from extended to localized states. The difference between the two models becomes particularly apparent in phase space where Heisenberg's uncertainty relation imposes a finite resolution. Our analysis points to the relevance of the coupling between momentum eigenstates at weak potential strength for the delocalization of a quantum particle. Received 3 May 2002 / Received in final form 2 October 2002 Published online 29 November 2002  相似文献   

9.
In classical information theory, one of the most important theorems are the coding theorems, which were discussed by calculating the mean entropy and the mean mutual entropy defined by the classical dynamical entropy (Kolmogorov-Sinai). The quantum dynamical entropy was first studied by Emch [13] and Connes-Stormer [11]. After that, several approaches for introducing the quantum dynamical entropy are done [10, 3, 8, 39, 15, 44, 9, 27, 28, 2, 19, 45]. The efficiency of information transmission for the quantum processes is investigated by using the von Neumann entropy [22] and the Ohya mutual entropy [24]. These entropies were extended to S- mixing entropy by Ohya [26, 27] in general quantum systems. The mean entropy and the mean mutual entropy for the quantum dynamical systems were introduced based on the S- mixing entropy. In this paper, we discuss the efficiency of information transmission to calculate the mean mutual entropy with respect to the modulated initial states and the connected channel for the quantum dynamical systems.  相似文献   

10.
It is shown that partial entropy, which is the classical analog of von Neumann entropy in quantum theory, is an effective tool to study the thermodynamic phase transitions in the physical systems. This method captures the intrinsic characters of critical fluctuations and does not need the pre-assumed order parameter. As an example, the finite temperature phase transition in the quantum three-dimensional spin-1/2 Heisenberg model is studied, where the stochastic series expansion quantum Monte Carlo method with operator-loop update is used. It is found that close to the critical temperature, the derivative of partial entropy displays a maximum value and shows finite size scaling behaviors, from which the critical temperature and critical exponents are determined.  相似文献   

11.
Thermodynamic entropy is not an entirely satisfactory measure of information of a quantum state. This entropy for an unknown pure state is zero, although repeated measurements on copies of such a pure state do communicate information. In view of this, we propose a new measure for the informational entropy of a quantum state that includes information in the pure states and the thermodynamic entropy. The origin of information is explained in terms of an interplay between unitary and non-unitary evolution. Such complementarity is also at the basis of the so-called interaction-free measurement.  相似文献   

12.
We develop a prequantum classical statistical model in that the role of hidden variables is played by classical (vector) fields. We call this model Prequantum Classical Statistical Field Theory (PCSFT). The correspondence between classical and quantum quantities is asymptotic, so we call our approach asymptotic dequantization. We construct the complex representation of PCSFT. In particular, the conventional Schrödinger equation is obtained as the complex representation of the system of Hamilton equations on the infinite-dimensional phase space. In this note we pay the main attention to interpretation of so called pure quantum states (wave functions) in PCSFT, especially stationary states. We show, see Theorem 2, that pure states of QM can be considered as labels for Gaussian measures concentrated on one dimensional complex subspaces of phase space that are invariant with respect to the Schrödinger dynamics. “A quantum system in a stationary state ψ” in PCSFT is nothing else than a Gaussian ensemble of classical fields (fluctuations of the vacuum field of a very small magnitude) which is not changed in the process of Schrödinger's evolution. We interpret in this way the problem of stability of hydrogen atom. One of unexpected consequences of PCSFT is the infinite dimension of physical space on the prequantum scale.  相似文献   

13.
陈小余 《中国物理 B》2010,19(4):40308-040308
In quantum information theory, von Neumann entropy plays an important role; it is related to quantum channel capacities. Only for a few states can one obtain their entropies. In a continuous variable system, numeric evaluation of entropy is not easy due to infinite dimensions. We develop the perturbation theory for systematically calculating von Neumann entropy of a non-degenerate system as well as a degenerate system.  相似文献   

14.
p-Mechanics is a consistent physical theory which describes both quantum and classical mechanics simultaneously (V. V. Kisil, p-Mechanics as a physical theory. An Introduction, E-print:arXiv:quant-ph/0212101, 2002; International Journal of Theoretical Physics 41(1), 63–77, 2002). We continue the development of p-mechanics by introducing the concept of states. The set of coherent states we introduce allows us to evaluate classical observables at any point of phase space and simultaneously to evaluate quantum probability amplitudes. The example of the forced harmonic oscillator is used to demonstrate these concepts.  相似文献   

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This paper examines the nature of classical correspondence in the case of coherent states at the level of quantum trajectories. We first show that for a harmonic oscillator, the coherent state complex quantum trajectories and the complex classical trajectories are identical to each other. This congruence in the complex plane, not restricted to high quantum numbers alone, illustrates that the harmonic oscillator in a coherent state executes classical motion. The quantum trajectories we consider are those conceived in a modified de Broglie-Bohm scheme. Though quantum trajectory representations are widely discussed in recent years, identical classical and quantum trajectories for coherent states are obtained only in the present approach. We may note that this result for standard harmonic oscillator coherent states is not totally unexpected because of their holomorphic nature. The study is extended to coherent states of a particle in an infinite potential well and that in a symmetric Poschl-Teller potential by solving for the trajectories numerically. For the Gazeau-Klauder coherent state of the infinite potential well, almost identical classical and quantum trajectories are obtained whereas for the Poschl-Teller potential, though classical trajectories are not regained, a periodic motion results as t→∞. Similar features were found for the SUSY quantum mechanics-based coherent states of the Poschl-Teller potential too, but this time the pattern of complex trajectories is quite different from that of the previous case. Thus we find that the method is a potential tool in analyzing the properties of generalized coherent states.  相似文献   

17.
Tomograms are obtained as probability distributions and are used to reconstruct a quantum state from experimentally measured values. We study the evolution of tomograms for different quantum systems, both finite and infinite dimensional. In realistic experimental conditions, quantum states are exposed to the ambient environment and hence subject to effects like decoherence and dissipation, which are dealt with here, consistently, using the formalism of open quantum systems. This is extremely relevant from the perspective of experimental implementation and issues related to state reconstruction in quantum computation and communication. These considerations are also expected to affect the quasiprobability distribution obtained from experimentally generated tomograms and nonclassicality observed from them.  相似文献   

18.
We consider a quantum spin system consisting of a finite subsystem connected to infinite reservoirs at different temperatures. In this setup we define nonequilibrium steady states and prove that the rate of entropy production in such states is nonnegative. Received: 7 June 2000 / Accepted: 5 November 2000  相似文献   

19.
We present, on a simple model of aone-dimensional crystal lattice, the consequences of theassumption that the phases in the action-anglerepresentation are random. We prove that this assumptionamounts to the introduction of a stochastic measurewhich can be interpreted as a Gaussian noise. Thepresence of noise gives rise to a new spectralrepresentation of states of the lattice. It is shownthat this new spectral representation of states can alsobe extended on an infinite lattice through a rigorouslydefined transition to the thermodynamic limit. Thetraditional spectral representation, as a superposition of independent modes, of such states as atomicdisplacements leads to meaningless expressions in thethermodynamic limit. One of the main results is thatunder the random phase assumption the interactions lead to the appearance of equilibrium states.We obtain an explicit spectral representation of suchstates. This specific model illustrates howprobabilistic behavior of an infinite system can bederived from classical laws of dynamics.  相似文献   

20.
We present a comparison of quantum and “semiclassical” trajectories of coherent states that correspond to classical breather solutions of finite discrete nonlinear Schrödinger (DNLS) lattices. The main goal is to explain earlier numerical observations of recurrent return to the vicinity of initial coherent states corresponding to stable breathers that are also spatially localized. This effect can be considered as a quantum manifestation of classical spatial localization. We show that these phenomena are encoded in a simple expression for the distance between the quantum and semiclassical states that involves the basic frequencies of the classical and quantum systems, as well as the breather amplitude and quantum spectral decomposition of the system. A corollary is that recurrence phenomena are robust under perturbation of the initial conditions for stable breathers.  相似文献   

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