基于粉末烧结技术制备镱铝共掺大模场光子晶体光纤

采用粉末烧结技术制备出高浓度镱铝共掺石英棒,Yb3+掺杂浓度为12 000ppm(wt).利用此掺镱石英棒作为纤芯,拉制出镱铝共掺大模场光子晶体光纤,光纤模场面积为550μm2,模场直径26μm.实验结果表明:光纤在近红外波段(850～1 033nm)出现一个宽的吸收带,主吸收峰波长位于976nm,在此波长处吸收损耗高于10dB/m;采用波长为971nm的激光泵浦光纤,在1 050～1 125nm波长范围内产生高斯型的荧光峰,峰值波长位于1 088nm处,荧光半宽高45nm.     

Yb/P/Al共掺双包层光纤的制备与激光性能

采用改进化学汽相沉积结合溶液掺杂法制备了Yb/P/Al共掺的石英光纤预制棒,通过光纤芯层的组份和制备工艺的优化,实现了Yb3+的高浓度掺杂和均匀掺杂.预制棒芯层Yb2O3掺杂浓度达到～4wt.％,Yb3+在1 080 nm处荧光寿命为1 780μs.成功拉制出内包层截面形状为八边形的双包层光纤,纤芯直径为7.5 μm,包层吸收系数达到～5 dB/m@976 nm.利用拉制的掺镱双包层光纤开展了全光纤结构的掺镱光纤激光器性能测试实验,实现了5.15W的激光输出,斜率效率达到76％.     

空气包层大模场面积掺镱光子晶体光纤研究

采用改进的化学气相沉积法和气相液相混合掺杂技术制备大芯径掺镱石英光纤预制棒, 以此作为有源纤芯制备了纤芯直径约90 μm的掺镱双包层光子晶体光纤, 纤芯组分为镱铝磷共掺.双包层光子晶体光纤的模场面积约1330 μm², 纤芯数值孔径0.065,包层数值孔径0.5.首次实现了国产掺镱光子晶体光纤的高功率高效率激光输出, 1 m长的光子晶体光纤激光器实现102 W 激光输出,斜率效率76%.     

3 dB带宽达80 nm的双包层掺镱超荧光光纤光源

采用大模面积双包层掺镱光纤作为增益介质搭建了一台双程前向超荧光光纤光源,该光源的输出功率随泵浦源注入电流的增加基本呈线性增加,最大输出功率为341 mW。其独特的优势是现实了掺镱光纤最宽的超荧光输出,在输出功率从201～341 mW之间,超荧光光谱的3 dB带宽超过80 nm。其输出功率虽然不是很高,但是在一般情况下能够满足人们对超荧光的需求。从镱离子的能级结构和镱离子在石英基质中的吸收截面与发射截面出发,分析了能够得到最宽超荧光输出的物理原因。这台双包层掺镱超荧光光纤光源由于充分利用了镱离子在1 025和1 075 nm附近的超荧光辐射,因而能够得到3 dB带宽为80 nm的超荧光输出。     

全固态八边形大模场光子晶体光纤的设计

提出一种新型的全固态八边形大模场低损耗的掺镱石英光子晶体光纤,利用多极法对光纤的结构和特性进行了模拟.这种结构的光子晶体光纤空气孔由掺有少量氧化硼的石英棒代替,简化了制备过程,提高了光纤的热损伤阈值.在波长为1064 μm处,光纤的模场面积可达2000 μm²,还可实现单模传输,而且其弯曲损耗很小,当弯曲半径为5 cm时弯曲损耗小于05 dB/m.这种光纤对光纤激光器和光纤放大器的发展有重要意义. 关键词： 光子晶体光纤 模场面积 弯曲损耗 限制损耗     

基于啁啾光纤布拉格光栅的掺镱保偏锁模光纤激光研究

利用啁啾光纤布拉格光栅作为光谱滤波器和色散控制元件来控制掺镱保偏锁模光纤激光的光谱形状和腔内色散.实验装置采用线性腔设计,利用半导体饱和吸收镜作为锁模器件,实现掺镱保偏光纤激光器的被动锁模激光输出.当泵浦功率为52 mW时,获得了脉冲宽度为4.26ps,重复频率为15.7 MHz,平均功率为9.8mW的稳定锁模脉冲激光输出.输出激光中心波长为1 030nm,3dB谱宽为7.2nm,对应理想傅里叶变换极限脉宽约为150fs.     

大模场面积掺镱双包层光纤研究

采用改进的化学汽相沉积工艺,沉积了光纤阻挡层和疏松层.结合溶液掺杂技术,研究了疏松层沉积温度、镱铝共掺工艺条件对掺镱浓度的影响,研究了大模场面积纤芯的制备工艺,实现了高浓度大模场面积掺镱双包层光纤的研制.测量并分析了光纤的光学性能参数及其激光特性,光纤芯径达到30 μm,纤芯摻镱浓度提高到4 000 ppm以上,芯数值孔径降至0.07,光纤的模场面积从113 μm2 提高到1 256 μm2,光纤的非线性效应阈值功率由12 W提高到大于128 W.     

掺Yb~(3+)双包层大模场面积微结构光纤光谱特性的研究

掺Yb3+双包层大模场面积微结构光纤(micro-structured fibers,MSF)是作为超大功率光纤激光器的理想介质。本文首先采用非化学气相熔炼法制备出掺Yb3+石英基玻璃材料,然后按照设计要求,通过排布拉制法制备了掺Yb3+双包层大模场面积微结构光纤。分别利用钛宝石飞秒激光器(波长调至为975 nm)和波长为980 nm LD激光器作为激励源,对掺Yb3+双包层大模场面积微结构光纤的荧光光谱进行分析,实验结果表明:该光纤在波长为1 050 nm处产生强的荧光,同时该光纤还能有效的抑制合作发光现象(coopera-tive luminescence)的产生。     

3.8 W光子晶体光纤喇曼激光器

详细研究了光子晶体光纤拉曼激光器,并首次获得瓦量级的二级喇曼光连续输出.所用泵浦源为20W掺镱光纤激光器(IPG,PYL-20M),中心波长为1070.5nm.光子晶体光纤(Crystal-fiber A/S)的纤芯直径为2.1±0.3μm,在1550nm波长处的模场直径为2.8μm,非线性系数γ=11W-1km-1;包层直径为12     

高性能1018 nm光纤及激光器实验研究

对光纤预制棒制备过程中沉积的气体流量、管内压强等参数和光纤掺杂组分进行了研究. 研究发现通过共掺其他元素, 可以使掺镱光纤的荧光谱发生移动. 基于此, 制备了有利于1018 nm激光输出的掺镱双包层光纤. 在增益光纤长度为7 m时, 实现了22.8 W的1018 nm激光输出, 光-光效率接近70%, 并且没有观察到明显的自发辐射和饱和现象. 关键词： 光纤激光器 双包层掺镱光纤 1018 nm     

Fine structure and isotope shift of the 3s4d 3 D-3s3p 3 P, 3s5d 3 D-3s3p 3 P and 3p 2 3 P-3s3p 3 P Transitions of MgI

Summary We report the measurements of the³ D(3s4d)-³ P(3s3p)³ D(3s5d)-³ P(3s3p), and³ P(3p ²)-³ P(3s3p) transition frequency of MgI, the fine-structure separation and isotope shift between²⁴Mg and²⁶Mg. The measurements have been performed in a metastable atomic beam; a good agreement is found for data already existing in the literature. The accuracy of the measurements reported in this paper is mainly limited by the Doppler broadening of theI ₂ transitions used as a reference and by the precision in the knowledge of the related wavelengths.     

LaGaO3:RE3+(RE3+=Eu3+,Ho3+)的光谱

本文用固态反应合成了钙钛矿型的LaGaO3和LaGaO3:RE3+(RE3+=Eu3+,Ho3+)荧光体,并观察了物相随不同的激活离子浓度的变化。测量了化合物在室温下的反射光谱,激发光谱和荧光光谱。研究了Eu3+的D0→7F2和Ho3+的5S2→5I8的荧光强度与激活离子浓度的关系,发现了浓度猝灭,并得到了最大荧光强度的浓度值。     

The gas phase infrared band contours of s-triazine and s-triazine-d3: The fundamentals of C3N3H3 and C3N3D3 and some overtone and combination bands of C3N3H3

The systematic application of band contour techniques to account for most of the observed features of the ir spectra of s-triazine and s-triazine-d₃ have been made as well as a critique as to the limitations of such methods. The experimental and computer methods used to study the gas phase infrared band contours of s-triazine and s-triazine-d₃ are out-lined. Contours of the five E′ fundamentals of s-triazine have been recorded under moderate resolution and analyzed to give the Coriolis constants $\text{ζ}{}_{\mathrm{i}}{}^{\mathrm{z}}$, i = 6–10. The effects of l-resonance are very apparent for ν₈ and ν₉, in the form of holes in the Q branches of these bands. Under the highest resolution available, ν₆ and ν₁₀ also show l-resonance effects. Values of the l-doubling constants $\text{q}{}_{\mathrm{i}}{}^{\mathrm{(+)}}$ were obtained for these four fundamentals. One of the parallel A₂″ fundamentals of C₃H₃N₃ (ν₁₂) has also been studied. It lies close to ν₁₀(E′) and an A × E type of second-order Coriolis resonance may be the cause of the intensity enhancement observed in the inner wings of the ν₁₂ and ν₁₀ bands. Hot bands of the type (ν_i + nν₁₄ ? nν₁₄) have been observed in the contours of ν₈, ν₁₀, and ν₁₂. This is felt to be responsible for the large difference between our observed zeta sum (?1.30) and the theoretical sum (?1.00).The gas phase infrared band contours of the five E′ and 2A₂″ fundamentals of C₃N₃D₃ have also been recorded under moderate resolution. From P-R separations and by computer simulation of the contours, values of the Coriolis constants $\text{ζ}{}_{\mathrm{i}}{}^{\mathrm{z}}$ have been obtained for the E′ modes. The effects of l-resonance have been observed for ν₈(E′) and ν₁₀(E′) and values of the l-doubling constants $\text{q}{}_{\mathrm{i}}{}^{\mathrm{(+)}}$ have been estimated. An extensive series of hot bands of the type (ν₁₂ + nν₁₄ ? nν₁₄) has been observed in the contour of the ν₁₂ (A₂″) fundamental. The mass effect on the Coriolis constants has been discussed.Infrared band contours of the overtone 2ν₇ and seven degenerate E′ combination bands of C₃N₃H₃ have been recorded under moderate resolution. Analysis of these contours using the P-R separation method and computer simulation of the contours has given values of $\text{ζ}{}_{\mathrm{<mtext>eff</mtext>}}{}^{\mathrm{z}}$ for these bands. Fermi resonance between 2ν₇ and ν₆ has been analyzed. The importance of considering both the observed contour as well as the observed frequency when assigning higher tone bands is illustrated.     

Infrared spectra of matrix isolated BH3NH3, BD3ND3, and BH3ND3

The infrared spectra of ammonia-borane, BH₃NH₃, and two of its deuterated isotropic species, BD₃ND₃ and BH₃ND₃, isolated in argon matrix at liquid hydrogen temperature have been measured. Well resolved bands for these three isotopic species have been observed for all the fundamentals. A complete frequency assignment based on C₃v molecular symmetry has been made. A set of force constants have been calculated from the data for the two isotopes BH₃NH₃ and BD₃ND₃ using a valence force field. The agreement between experiment and frequencies calculated from these force constants for the mixed isotopic species, BH₃ND₃, substantiates the present assignment.     

Dielectric investigations of solid solutions SrTiO3-KTaO3 and SrTiO3-KNbO3

The temperature dependences of the dielectric constant and dielectric hysteresis loops in ceramic samples of (1 ? x)SrTiO_3?x KNbO₃ and (1 ? x)SrTiO_3?x KTaO₃ (0 ≤ x ≤ 0.3) solid solutions prepared using different heat treatments have been investigated. Phase diagrams of the studied solid solutions have been constructed in the T-x coordinates. It has been shown that, after quenching of samples (spontaneous cooling at room temperature after long-term heating at the sintering temperature of the ceramic samples), the temperature of the induced phase transition increases because of the weakening of random electric fields associated with nonisovalent impurities due to their “frozen” nonequilibrium redistribution. For small concentrations x, strong dielectric relaxation is observed in the temperature range of 150–250 K. A model of relaxing centers, which is based on the local charge compensation of heterovalent impurities, has been proposed.     

Modulated magnetic structures of ErPb3, HoPb3, ErTl3 and HoTl3

Neutron diffraction experiments have been carried out on the magnetically ordered phases of ErPb₃, HoPb₃, ErTl₃ and HoTl₃. The magnetic moments were found to be sinusoidally modulated with a propagation vector of (0, 0.2, 0.5) for the Pb-compounds and (0.38, 0.38, 0.16) for the Tl-compounds.Work supported by the Bundesministerium für Forschung und Technologie     

Ba3La(BO3)3基质中Tb3+的光致发光

以高温固相法合成了Ba3La(BO3)3∶Tb3 发光材料。在254nm紫外光激发下,研究了Ba3La(BO3)3∶Tb3 的激发光谱、发射光谱、发光强度与Tb3 浓度的关系。确定了Ba3La(BO3)3基质中Tb3 的自身浓度猝灭机理;探讨了助熔剂LiCO、敏化剂Ce3 、Bi3 的加入对荧光粉的发光强度的影响。     

Terahertz Vibrational Modes in CH3NH3PbI3 and CsPbI3 Perovskite Films

JETP Letters - Films of CH3NH3PbI3 organometallic perovskite, which is currently considered as a promising basic material for new-generation solar cells, as well as films containing CsPbI3...     

CH_3NH_3 Formed by Electron Injection at Heterojunction Inducing Peculiar Properties of CH_3NH_3PbI_3 Material

The effect of formed CH_3NH_3 at the heterojunction on properties of CH_3NH_3PbI_3 material is investigated based on experiment and theoretical calculation. Our calculation results show that the giant dielectric constant, anomalous hysteresis and long-lasting polarization for CH_3NH_3PbI_3 originate from the formed CH_3NH_3 at the heterojunction. It is found that the induced weak EPS by the reorientation of CH_3NH_3 sub-group along the built-in electric field enables us to effectively increase the ordering of entire lead-halide framework. In addition, the heterojunction has an advantage of channel separation between carrier transport and electron diffusion. These properties of the heterojunction are the main origin of the high efficiency of CH_3NH_3PbI_3 solar cells.