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1.
Nourallah Hazeri Malek Taher Maghsoodlou Fatemeh Mir Mehrnoosh Kangani Hamideh Saravani Ebrahim Molashahi 《催化学报》2014,(3)
Tetrahydrobenzo[b]pyran and 3,4-dihydropyrano[c]chromene derivatives were synthesized via a one-pot three-component condensation of aromatic aldehydes with malononitrile and dimedone or 4-hydroxycoumarin in excellent yields in the presence of starch solution as a highly efficient homogenous catalyst.The use of a nontoxic and biodegradable catalyst,simple work-up procedure,and short reaction time are advantages of this method. 相似文献
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A Mild and Environmentally Benign Synthesis of Tetrahydrobenzo[b]pyrans and Pyrano[c]chromenes Using Pectin as a Green and Biodegradable Catalyst 下载免费PDF全文
Pectin was applied as a green and biodegradable catalyst for the one‐pot three‐component synthesis of tetrahydrobenzo[b]pyrans and pyrano[c]chromenes, from the condensation between aromatic aldehydes, malononitrile, and dimedone or 4‐hydroxycumarine at ambient temperature. This protocol has many advantages such as mild conditions, high yields, environmental benignity, simple work‐up procedures, short reaction time, as well as the use of a natural, easily accessible, convenient handling, and inexpensive catalyst. Another advantage of this method is that the products do not require further purification such as column chromatography. 相似文献
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A novel poly (ethylene glycol) bridged primary amine functionalized dicationic ionic liquid ([PA‐PEG1000‐DIL][BF4]) was synthesized and characterized by 1H‐NMR, 13C‐NMR, FT‐IR and ESI‐MS. The thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) analysis indicated the high thermal stability of [PA‐PEG1000‐DIL][BF4]. It was used as an efficient and recyclable catalyst for the synthesis of substituted tetrahydrobenzo[b]pyrans through a one‐pot three‐component condensation of aromatic aldehydes, malononitrile and dimedone in 86% ~ 96% yields within 10 ~ 30 min in water. This method offers several advantages such as mild reaction conditions, simple operation and environmental friendliness. Furthermore, the catalyst could be easily recovered and reused for at least five runs without obvious loss of catalytic activity. 相似文献
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Nickel Schiff-base complex immobilized on silica-coated Fe3O4 as a heterogeneous catalyst was designed and characterized by different techniques, such as Fourier transform infrared (FT-IR), X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), inductively coupled plasma (ICP) and vibrating sample magnetometry (VSM) thermogravimetric analysis (TGA), and Brunauer–Emmett–Teller (BET). The synthesized nanocatalyst has been explored as a new and efficient recyclable heterogeneous catalyst for the one-pot three-component synthesis of tetrahydrobenzo[b]pyran derivatives. The reaction proceeds smoothly to supply the respective products in excellent yields and low reaction times. The catalyst can be easily recovered by a magnetic field and reused for eight consecutive reaction cycles without significant loss of activity. 相似文献
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WANG Qiu-yan YU Jing-jun LU Cui-fen CHEN Zu-xing YANG Gui-chun Key Laboratory for the Synthesis Application of Organic Functional Molecules of Ministry of Education School of Chemistry Chemical Engineering Hubei University Wuhan P. R. China 《高等学校化学研究》2009,(3)
A novel and efficient method was developed for the liquid-phase synthesis of N1,4-disubstituted-benzodiazepine-2,5-diones with 2-chloro-5-nitrobenzoic acid as initiating material via 4 step reactions containing esterification,Ulmn reaction,acylation,alkylation and cyclization. The reaction conditions were mild and the overall yields of the products ranged from 45% to 71%. 相似文献
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S. V. Chepyshev Yu. N. Mazurkevich O. S. Lebed’ A. V. Prosyanik 《Chemistry of Heterocyclic Compounds》2007,43(7):844-849
Reaction of 1-alkyl-3-alkylaminopyrrole-2,5-diones with primary arylamine hydrochlorides in methanol or DMSO gives 1-alkyl-3-arylaminopyrrole-2,5-diones
which could also be obtained from the reaction of arylaminofumarates with primary aliphatic amines.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1001–1007, July, 2007. 相似文献
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Knoevenagel‐Michael‐cyclocondensation Tandem Reaction of Malononitrile,Various Aldehydes and Dimedone Catalyzed by Sulfonic Acid Functionalized Pyridinium Chloride as a New Ionic Liquid and Catalyst 下载免费PDF全文
Mohammad Ali Zolfigol Ardeshir Khazaei Ahmad Reza Moosavi‐Zare Javad Afsar Vahid Khakyzadeh Omid Khaledian 《中国化学会会志》2015,62(5):398-403
New ionic liquid sulfonic acid functionalized pyridinium chloride [Pyridine–SO3H]Cl was used for the synthesis of tetrahydrobenzo[b]pyran derivatives by the one‐pot three component condensation reaction of various aldehydes, dimedone and malononitrile at 95 ºC under solvent‐free conditions. 相似文献
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介绍了4类具有络合性质或潜在的络合性质的4-取代苄基-2,6-哌嗪二酮化合物的合法。所合成的化合物中有些表现出明显的体外抑制白血细胞P388生长的活性。 相似文献
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Xue Fei Yang Ling Yi Kong 《中国化学快报》2007,18(4):380-382
A series of 2-aryl-5-alkyl-7-methoxylbenzo[b]furan derivatives have been synthesized by utilizing the coupling of methyl 3-methoxy-4-hydroxy-5-bromocinnamate with cuprous phenylacetylide as the key step.The structures of the new compounds were confirmed by1H NMR,IR and MS.The structure of compound 14 was further confirmed by single crystal X-ray.Compound 17 showed cytotoxic activity against human lung carcinoma A549. 相似文献
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Dr. Shengdong Wang Dr. Régis Guillot Prof. Dr. Jean-François Carpentier Dr. Yann Sarazin Dr. Christophe Bour Prof. Dr. Vincent Gandon Dr. David Lebœuf 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(3):1150-1154
Herein, we report the preparation of bridged tetrahydrobenzo[b]azepines, which was accomplished through an aza-Piancatelli cyclization/Michael addition sequence in a one-pot fashion from readily available precursors. It is noteworthy that a general method to access these scaffolds was hitherto unprecedented. Additionally, the multifaceted aspects of this process have been exemplified through its application to the synthesis of 2-azabicyclo[3.2.1]octanes and bridged tetrahydrobenzo[b]oxepines, along with post-derivatizations. 相似文献
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Rajesh S. Bhosale Chandrakant V. Magar Kuldeep S. Solanke Sandeep B. Mane Sunil S. Choudhary 《合成通讯》2013,43(24):4353-4357
An iodine/DMSO system is introduced as an excellent catalyst in three‐component coupling reactions of tetrahydrobenzo[b]pyran synthesis. The reaction proceeds quickly under very mild reaction conditions. 相似文献
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Z. Stec 《Monatshefte für Chemie / Chemical Monthly》1993,124(3):331-332
Summary 2-Acetoxy- and 2-Hydroxy-2,3-dihydronaphtho[1,8-bc]pyranes were synthesized by decomposition of 1-hydroperoxy-1,2-dihydroacenaphthylene in acetic acid in the presence of perchloric acid.
Synthese von 2-Acetoxy- und 2-Hydroxy-2,3-dihydronaphtho[1,8-bc]pyran
Zusammenfassung 2-Acetoxy- und 2-Hydroxy-2,3-dihydronaphtho[1,8-bc]pyrane konnten durch Zersetzung von 1-Hydroperoxy-1,2-dihydroacenaphthylen in Essigsäure in Anwesenheit von Perchlorsäure synthetisiert werden.相似文献
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Yu. M. Volovenko E. V. Resnyanskaya A. V. Tverdokhlebov 《Chemistry of Heterocyclic Compounds》2002,38(3):324-330
A convenient method has been developed for the synthesis of 3-hetaryl-1,2,4,5-tetrahydropyrrolo[1,2-a]quinazoline-2,5-diones by the interaction of 4-chloro-2-hetaryl-3-oxobutyronitriles with substituted anthranilic acids. 相似文献
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Catalyzed by ytterbium(Ⅲ) triflate hydrate [Yb(OTf)3.xH2O], the Michael addition and cycloeondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran derivatives, respectively were studied. 相似文献