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采用固态反应法制备了(La2/3Ca1/3)(Mn(3-x)/3Gax/3)O3(x=0.00,0.10,0.15,0.20,0.30)体系的系列样品。通过系统地测量其零场和1.6特斯拉(T)磁场下样品的电阻率-温度关系以及一定温度下磁电阻率与磁场的关系,发现随Ga^3+替代量的增加其磁电阻率峰和电阻率峰均向低温方向移动,磁电阻率峰值增大,并伴生磁电阻率峰展宽效应。作者认为,上述结果是由于Ga^3 相似文献
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《中国物理》2003,12(9):792-795
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实验上探讨了Y3+离子掺杂对La2/3-xYxCa1/3MnO3(0<x<0.2)单相样品的结构及其输运性质的影响.结果表明,随着Y的掺杂,晶胞参数收缩,从顺磁性半导体到铁磁性金属的转变温度Tc明显降低,而巨磁阻效应却大大提高.为了探讨其物理起因,我们对Tc温度以上的导电机理通过定量分析电阻随温度的变化而得以研究,结果表明,载流子的迁移遵从跳跃方式而不是热激活形式,在此基础上对Y掺杂作用进行了讨论. 相似文献
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L12/3Ca1/3MnOz薄膜中的巨磁阻效应 总被引:1,自引:0,他引:1
采用直流磁控溅射法在ZrO2衬底上首次成功地制备了La2/3Ca1/3MnOz薄膜,X-射线衍射结果表明该膜具有良好的择优取向,并首次观察到十分明显的巨磁阻效应,在6个特斯拉磁场下,室温时的磁阻比为6%,而78度K时竟高达2500%,中还对磁阻比的磁场关系作了简单的讨论 相似文献
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KNO3/Al2O3和K2CO3/Al2O3的强碱性研究 总被引:4,自引:0,他引:4
采用CO2-TPD及Hammett批示剂法测定了KNO3/Al2O3及K2CO3/Al2O3样品的碱量和碱强度。当KNO3,K2CO3的负载量低于其单层分散阈值时,能在AlO3均匀分布并产生强度为18.4的强碱位;高于其单层分散阈值后则能生成强度为27.0的超强碱位。 相似文献
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We utilize the random network model based on phase separation scenario to simulate the conductive behaviour and anisotropic characteristics of resistivity for La2/3Ca1/3MnO3 (LCMO) thin films. The simulated results agree well with our experimental data, showing a metal-to-insulator transition from a high-T paramagnetic (PM) insulating phase to a low-T ferromagnetic (FM) metallic phase in both the untilted film deposited on a (001) SrTiO3 (STO) substrate and the tilted film grown on a vicinal cut STO substrate. It is found that the resistivity of the tilted sample is higher than that of the untilted one, displaying prominent anisotropic characteristics. The studies reveal that the tilting not only decreases the conduction of the FM domains, but also increases the activation energy of the PM regions, inducing the enhancement of resistivity. All those results suggest that the intrinsic inhomogeneity in the phase separation system plays a significant role in the electrical conductivity and the resistive anisotropy is related to the structure of the crystal lattice. 相似文献
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A series of (La_{1-x}Tb_x)_{2/3}Sr_{1/3}MnO_3 polycrystalline samples has been studied by means of x-ray diffraction, magnetostriction, and thermal expansion measurements. It has been found that this series undergoes a phase transition from a rhombohedral to an orthorhombic form at the doping level x≈0.20 at room temperature accompanied by an anisotropic magnetostriction up to -50×10^{-6} under a magnetic field of 1T. The linear and volume magnetostrictions vary with chemical composition, even change sign. At T=80K, the magnetostrictions for the samples of x=0.20 and 0.40 exhibit different behaviours. The sample of x=0.20 has positive volume and linear magnetostrictions and a negative anisotropic magnetostriction, while the sample of x=0.40 has an opposite behaviour. The magnitude of volume magnetostriction for both the samples is essential (~10^{-4}) at T=80K under a magnetic field of 4T. We conclude that these anomalous effects are due to the charge delocalization and the structural phase transition between orthorhombic and rhombohedral forms induced by the applied magnetic field. 相似文献
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用多组态HFR方法系统地计算了高剥离粪钠CrⅩⅣ-FmXC离子(Z=24-100)单电子组态的能级,相应谱线的跃迁波长,跃迁概率和振子强度,在已有实验的基础上,用自编的Fortran程序对HF计算的3p^2P1/2,3/2能级结果进行了最小二乘拟合计算,从而预测计算了CrⅩⅣ-FmXC离子3s^2S1/2-3p^2P1/2,3/2跃迁的谱线波长。计算结果与已有的实验值均符舍得很好,尤其是与最近测量的实验值相当一致:而与其他理论预测值也基本吻合。 相似文献
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Er^3+/Yb^3+掺杂全光纤环形激光器 总被引:1,自引:1,他引:0
本文报道利用Er~(3+)/Yb~(3+)掺杂单模光纤首次研制成功的环形谐振腔结构的可调谐(调谐范围宽于70nm)全光纤激光器的设计原理及其实验结果. 相似文献
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本文用米氏方法导出了三种组分构成的均匀球形复合微粒子光学散射截面的计算公式,并计算了复合微粒子Al2O3/MgO/C在特定红外光波波长下的光学散射截面。给出了复合微粒子中不同组分的介质层厚度与散射截面的关系曲线,最后对结果作了简单讨论。 相似文献
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XUZhao-Xin ZHANGJun YINGHe-Ping 《理论物理通讯》2003,40(5):623-630
The ground-state and thermodynamic properties of quantum mixed-spin chains of 1/2-1/2-1-1 and 3/2-3/2-1-1 are investigated by a quantum Monte Carlo simulation with the loop-cluster algorithm. For 1/2-1/2-1-1 chain, we find it hastwo phases separated by an energy-gap vanishing point in the ground-state. For 3/2-3/2-1-1 chain,the numerical results show two energy-gap vanishing points isolated by different phases in its ground-state. Our calculations indicate that all these ground state phases can be understood by means of valence-bond-solid picture, and the thermodynamic behavior at finite temperatures is continuous as a function of parameter α=J2/J1. 相似文献
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