共查询到20条相似文献,搜索用时 15 毫秒
1.
Haj-Hussein AT 《Talanta》1995,42(12):2053-2057
A flow-injection method for the ultraviolet spectrophotometric determination of silver, based on its reaction with nickelocyanide ion, Ni(CN)2−4, in ammoniacal buffer medium (pH 10) and subsequent measurement of the decrease in the absorption of the Ni(CN)2−4 complex at 275 nm is described. The calibration graph is linear in the range 10–400 μm silver. At a sampling rate of about 60 samples h−1 with 35 μl sample injections, precision was about 1% relative standard deviation. The proposed method was successfully applied to the determination of silver in some common silver minerals. 相似文献
2.
Hosny Ibrahim 《Analytica chimica acta》2005,545(2):158-165
The utility of carbon paste electrode modified with silver ethylmercurythiosalicylate (silver thimerosal) in both static mode and flow injection analysis (FIA) is demonstrated. The electrode was fully characterized in terms of composition, response time, thermal stability, usable pH and ionic strength ranges. It has been shown that diisononyl phthalate (DINP) acts as more suitable solvent mediator for preparation of the electrode, which exhibits linear response range to Ag(I) extending from 5.0 × 10−7 to 1.0 × 10−3 M with detection limit of 2.5 × 10−7 M and Nernstian slope of 59.3 ± 1.0 mV/decade. The proposed chemically modified carbon paste electrode shows a very good selectivity for Ag(I) over a wide variety of metal ions and successfully used for the determination of the silver content of silver sulphadiazine (burning cream) and developed radiological films. The electrode was also used as an indicator electrode in the potentiometric titration of thiopental and thimerosal with AgNO3. 相似文献
3.
A catalytic differential kinetic method with Kalman filter for the simultaneous determination of multi-component is described. The oxidization of Rhodamine B (RB) by potassium periodate in a slightly acid solution is a slow reaction. But iron(III), silver(I) or manganese(II) has a differential catalytic effect on the oxidation reaction of RB in the presence of 1,10-phenanthroline as the activator. So iron, silver and manganese can be simultaneously determined by measuring the decreasing absorbance of the dye (RB) at 555 nm. A flow injection analysis stopped-flow spectrophotometric system with a microcomputer performs the determinations. This method has been applied to determining iron, silver and manganese of alloy samples with satisfactory results. 相似文献
4.
A rapid and inexpensive gas-diffusion (GD) flow injection method for the on-line determination of Hg(II) in aqueous samples is described. The analytical procedure involves the injection of a Hg(II) sample into a 1.5 M H2SO4 carrier stream which is merged with a reagent stream containing 0.6% SnCl2 and 1.5 M H2SO4. Under these conditions Hg(II) is reduced to metallic mercury which partially evaporates through a Teflon membrane into an acceptor stream containing 1.75×10−4 M KMnO4 in 0.3 M H2SO4. The decrease in the absorbance of the acceptor stream at 528 nm corresponding to the absorption maximum of the permanganate anion can be related to the original concentration of Hg(II) in the sample. The method is characterized by a detection limit of 4 μg l−1 and a sampling frequency of 8 h−1. The flow system was successfully applied to the analysis of river samples spiked with Hg(II). 相似文献
5.
Fernando Lázaro María Dolores Luque de Castro Miguel Valcárcel 《Fresenius' Journal of Analytical Chemistry》1985,321(5):467-470
Summary In this paper the authors report on several methods for the direct determination of EDTA and indirect determination of iron(III), based on the inhibition effect of EDTA on the catalytic action of copper (II) on the oxidation of 2,2-dipyridyl ketone hydrazone by hydrogen peroxide and on the decrease of this inhibition effect in the presence of Fe(III), respectively. These methods allow the determination of EDTA in the ranges of 0.4–2.0 g · ml–1 and 0.2–1.0 g · ml–1 for the normal and reversed FIA modes, respectively, and of 40–240 ng · ml–1 for Fe(III) by reversed FIA.
Katalytisch-fluorimetrische Bestimmung von EDTA und Eisen(III) durch FließinjektionsanalyseInhibitionsmethoden
Zusammenfassung Verfahren zur direkten Bestimmung von EDTA sowie zur indirekten Bestimmung von Eisen(III) werden beschrieben. Sie beruhen auf der Inhibitorwirkung von EDTA auf den katalytischen Effekt von Kupfer(II) bei der Oxidation von 2,2-Dipyridylketonhydrazon mit Wasserstoffperoxid bzw. auf der Schwächung dieser Inhibitorwirkung in Gegenwart von Eisen(III). Es ist mit diesen Methoden möglich, EDTA im Bereich von 0,4–2,0 g/ml (normale FIA) bzw. 0,2–1,0 g/ml (umgekehrte FIA) und Eisen im Bereich von 40–240 ng/ml (umgekehrte FIA) zu bestimmen.相似文献
6.
7.
8.
9.
10.
Cerium(III) (1–100 μg l?1) is determined by injection into a carrier stream of hydrochloric, perchloric or sulphuric acid, and monitoring its native fluorescence. Cerium(IV) can be determined similarly by incorporating a zinc reductor minicolumn into the system. Splitting the injection sample so that only part passes through the reductor, and the remainder by-passes it, allows total cerium and cerium(III) to be detected from the two sequential fluorescence peaks obtained. 相似文献
11.
Summary Ethylenediamine is proposed as activator for the oxidation of sulphanilic acid with persulphate, catalysed by traces of silver(I). The kinetic equations of the uncatalysed and the catalytic reactions were studied, as well as the influence of the acidity, the temperature and the activator concentration. On that basis a catalytic method is developed for determination of 1–35 ng of Ag+ per ml with 2.3% relative error. The influence of 17 ions which usually accompany silver was also studied.
Zusammenfassung Äthylendiamin wurde als Aktivator für die durch Silber katalysierte Oxydation von Sulfanilsäure mit Persulfat vorgeschlagen. Die kinetischen Reaktionsgleichungen der unkatalysierten und der katalysierten Reaktion wurden geprüft, der Einfluß der Acidität, der Temperatur und der Aktivatorkonzentration untersucht. Auf dieser Grundlage wurde eine katalytische Bestimmungsmethode für 1 bis 35 ng Ag/ml ausgearbeitet, deren relative Fehlerbreite 2,3% beträgt. Der Einfluß von 17 üblichen Begleitionen des Silbers wurde ebenfalls untersucht.相似文献
12.
13.
14.
15.
A direct, simple and rapid flow-injection method is described for determining buprenorphine hydrochloride (10?8–10?4 M) based on its chemiluminescent oxidation with potassium permanganate in polyphosphoric acid. The limit of detection is 1 × 10?8 M (0.5 pmol per injection) and the log-log calibration is linear up to 1 × 10?4 M; the r.s.d. is 0.7% for a 10 μg ml?1 solution (n = 10). The method is directly applicable to aqueous solutions of tablets containing the drug (0.2 mg/tablet). 相似文献
16.
The epoxy-impregnated graphite tube electrode bulk modified with 2-mercaptobenzoxazole, employed in a wall-jet configuration, was found to be useful for the continuous flow and flow injection stripping voltammetric determinations of AgI, HgII and BiIII. For continuous flow, detection limits for AgI, HgII and BiIII were 1.8 × 10−10 M, 1.9 × 10−9 M and 9.5 × 10−9 M, respectively (10 min accumulation, S/N = 3). Precisions for 5.00 × 10−9 M AgI, 1.00 × 10−8 M HgII and 1.00 × 10−7 M BiIII were 10.5%, 5.77 % and 7.90% (relative standard deviations, n = 6), respectively. In the case of flow injection stripping, with a 500 μL injection loop, detection limits of 0.59 ng, 2.0 ng and 120 ng were obtained for AgI, HgII and BiIII, respectively (S/N = 3). Selected metal ions, inorganic and organic substances were investigated for interferences. The electrode was tested with a certified sample and then applied to the determinations of the metal ions in a urine and a sea-water sample. 相似文献
17.
18.
A sensitive catalytic kinetic spectrofluorimetric method for determining ng ml(-1) of selenium by flow injection analysis has been developed. The method, based on the catalytic effect of Se (IV) on the reduction of resorufin by sulphide, in the presence of cetylpyridinium chloride, is monitored spectrofluorimetrically (lambda(ex)=480 nm; lambda(em)=583 nm). The linearity range of the calibration graph is dependent on the concentration of sulphide. The variables affecting the rate of the reaction were investigated. The method is simple, rapid, precise, sensitive, and widely applicable. The limit of detection is 1 ng ml(-1) Se (IV), and the calibration range is 5-1000 ng ml(-1). Sampling rate is 60 samples h(-1), and the relative standard deviation of 12 determinations of 100 ng ml(-1) Se was 0.76%. The determination of Se (IV) in the presence of Se (VI) and total selenium is described. The method was applied to the determination of Se in selenium tablets, and several synthetic samples. 相似文献
19.
A method for sensitive and selective determination of silver based on the catalytic effect of silver(I) ion on the oxidation of Janus Green by peroxodisulfate is described. o-Phenanthroline is used as an activator. The rate of the decrease in absorbance of Janus Green (at 615 nm) is proportional to the concentration of silver in the range of 0.3-4.0 ng mL(-1) and 4.0-500.0 ng mL(-1). The theoretical limit of detection was 0.25 ng mL(-1). The method is free from most interferences. The method was applied to the determination of silver in plants (the uptake of silver by plants), in photographic solutions, lake water and several synthetic samples. 相似文献
20.
We presented a new strategy for ultrasensitive detection of DNA sequences based on the novel detection probe which was labeled with Ag+ using metallothionein (MT) as a bridge. The assay relied on a sandwich-type DNA hybridization in which the DNA targets were first hybridized to the captured oligonucleotide probes immobilized on Fe3O4@Au composite magnetic nanoparticles (MNPs), and then the Ag+-modified detection probes were used to monitor the presence of the specific DNA targets. After being anchored on the hybrids, Ag+ was released down through acidic treatment and sensitively determined by a coupling flow injection–chemiluminescent reaction system (Ag+–Mn2+–K2S2O8–H3PO4–luminol) (FI–CL). The experiment results showed that the CL intensities increased linearly with the concentrations of DNA targets in the range from 10 to 500 pmol L−1 with a detection limit of 3.3 pmol L−1. The high sensitivity in this work may be ascribed to the high molar ratio of Ag+–MT, the sensitive determination of Ag+ by the coupling FI–CL reaction system and the perfect magnetic separation based on Fe3O4@Au composite MNPs. Moreover, the proposed strategy exhibited excellent selectivity against the mismatched DNA sequences and could be applied to real samples analysis. 相似文献